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Thesis (M.M.S.E.)--University of Delaware, 2009. / Principal faculty advisor: John W. Gillespie, Dept. of Materials Science. Includes bibliographical references.

In the initial stage, the sample preparation was done by using the techniques of Anodic etching and anodic forming processes where a repeated trial and error method of sample preparation headed towards making out a suitable sample set for characterization. After this step, the set of 2 different industrial samples were introduced and anodic oxide forming process was carried out in different electrolytes.    In the sample preparations, 4 different electrolytes were used 15% wt. Ammonium Adiphate, 1.5% wt. Ammonium Phosphate, 7% wt. Boric acid and 15% Penta Borate at different stages for performing the anodic oxide forming process. Minimum forming voltages of 20V to a maximum of 100V was employed in the sample preparation and to overcome the waiting time in forming the etched samples a higher current of 0.5A was used.   After the samples preparation, Electrochemical Impedance spectroscopy was used as a tool for characterising the various groups of samples and for observing the micro structures of various samples, they were fractured and the observed on the cross section by SEM.   After the analysis of the etched samples was made, an attempt to compare the results of the data of these samples to that of the 2 set of industrial samples was made and found that the resultant data wasn’t stable enough to characterize since huge scattering were occurring and whereby the simulation of the CPE circuit for the chosen circuit in the analysis was not possible.   Under the analysis, a randomly chosen industrial sample was also used and the resultant data was utilised in understanding the response of the system to different electrolytes. / Sammanfattning   Avhandlingsarbetet har genomförts på KEMET AB i samarbete med yttekniklaboratoriet vid JTH i syfte att karakterisera den etsade anodiska aluminiumfolien som grundprov med anodisering och etsning för ytbehandling.   I inledningsskedet gjordes provberedningen med användning av teknikerna för anodisk etsning och anodbildande processer där en upprepad provnings- och felmetod för provberedning ledde ut mot att utarbeta en lämplig provuppsättning med avseende på karakterisering. Efter detta steg infördes uppsättningen av 2 olika industriella prover och anodoxidbildande process utfördes i olika elektrolyter.   I provpreparaten användes 4 olika elektrolyter 15 % vikt Ammoniumadiphat, 1,5 vikt% Ammoniumfosfat, 7 vikt% Borsyra och 15 % Penta-borat vid olika steg för utförande av anodoxidbildningsförfarandet. Minimala formningsspänningar på 20V till ett maximum av 100V användes i provframställningen och för att övervinna väntetiden vid bildning av de etsade proven användes en högre ström av 0,5A.   Efter provberedningen användes elektrokemisk impedansspektroskopi som ett verktyg för att karakterisera de olika grupperna av prover och för att observera mikrostrukturerna i olika prover, de bröts och de observerades i tvärsnittet av SEM.   Efter att analysen av de etsade proverna gjordes ett försök att jämföra resultaten av data från dessa prover till den för de två uppsättningarna av industriella prover. Det är konstaterat att de resulterande data inte var stabila nog att karakterisera eftersom stor spridning inträffade och varigenom simuleringen av CPE-kretsen för den valda kretsen i analysen inte var möjlig.   Under analysen användes också ett slumpmässigt valt industriellt prov och de resulterande data användes för att förstå systemets respons till olika elektrolyter.

The master´s thesis deals with verification of thermal insulating property of thermoreflection foil insulations. The teoretical part of thesis focuses on the energy demand of buildings, the problems of heat transfer material, terms required for study of thermoreflection thermal insulation and experimental methods for determination of thermal insulating properties of insulators. In the next part the chapter is accompanied by an overview of the most common insulation materials which used in construction. The last part of teoretical part is devoted to the description of thermoreflect formation and analysis of the spread of thermal insulating layers of thermoreflection thermal insulation. The first part of thesis is devoted to the use of thermoreflection therm insulation in buildings. The second part of thesis is devoted to the design, assembly and calibration of the measuring device that uses a method of protected warm chamber. It is declared as a binding method of detection of the heat transfer performance of thermoreflection thermal insulation. The developed measuring device allows detection of endpoints in some direction of propagation of heat. Measurment of heat transfer coefficient devoted the third part of practical part. This part contains a description of the samples used for the measurement of the heat transfer coefficient. In the fourth chapter of the practical part are presented the results of the heat transfer coefficient measurments on selected samples of thermoreflection foil insulation. It is shown the characteristic of heat transfer coefficient of individual samples, the dependence of the heat transfer coefficient on the position of the sample in the measuring device and the recommendation of an appropriate use of sample in the works for the climatic conditions of the Czech republic. The work concludes the chapter of comparing and evaluating of all samples with practical recommendations.