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Thesis (Ph. D.)--Open University.

The study of magmatic processes and their location in the crustal profile is fundamental for the understanding of the volcanic systems and their associated hazards. Changes and continuities in magma storage zones, fractional crystallization and crustal contamination are studied over a time span of 300 ka in Puyehue Volcano in the Southern Volcanic Zone, Chile. Using thermobarometric models outlined in Putirka (2008), bulk assimilationand fractional crystallization modelling this study show that: a) fractional crystallization of plagioclase and clinopyroxene in Puyehue Volcano occurs in the upper 20 km of the crust with plagioclase preceding clinopyroxene in the crystallization sequence, b) fractional crystallization of basaltic andesites is dominated by plagioclase with a break in th e geochemical trend at around 55 wt% SiO2caused by an increased share of pyroxene fractionation and the onset of significant magnetite fractionation, c) both old and young Puyehue volcanics are contaminated by a gabbroic lithology of the lower crust as suggested previously by Jicha et al. (2007) and d) the Anticura Group lavas and a single Puyehue Volcano sample reflect magma-metasediment interaction with likely in the middle to upper crust. / El estudio de los procesos magmáticos y su ubicación en el perfil de la corteza terrestre es fundamental para la comprensión de los sistemas volcánicos y sus riesgos asociados. Cambios y continuidades en las zonas de almacenamiento de magma, cristalización fraccionada y contaminación cortical correspondientes a un lapso de 300 ka se estudiaronen Volcán Puyehue en la Zona Volcánica Sur, Chile. Utilizando modelos termobarométricos descritos en Putirka (2008) más un modelamiento de la asimilación y cristalización fraccionada este estudio muestra que: a) la cristalización fraccionada de plagioclasa y clinopiroxeno en el Volcán Puyehue se produce en los 20 Km superiores de la corteza y que la plagioclasa precede al clinopiroxeno en la secuencia de cristalización, b) la cristalización fraccionada de andesitas basálticas está dominada por plagioclasa con un quiebre en la tendencias geoquímicas en torno al 55 wt%SiO2causado por un aumento relativo delfraccionamiento piroxeno y ael comienzo de un fraccionamiento significativo de magnetita, c) las rocas volcánicas del Volcán Puyehue, tanto lasantiguas como las recientes, están contaminadas por una litología de gabro de la corteza inferior como se ha sugeridoanteriormente por Jicha et al. (2007) y d) las lavas del Grupo Anticura además de una sola muestra Volcán Puyehue evidencian interacción entre magma y metasedimentos que probablemente ocurrió en la corteza media o superior / Studiet av magmatiska processer och deras placering i jordskorpans profil är väsenlig för förståelsen av den vulkaniska system och dithörande risker. I denna studie granskas förändringar och kontinuiteter i lagringszoner för magma, fraktionerad kristallisation och jordskorpsföroreningar över en tidsperiod på 3 00 ka i Puyehue vulkan i den Södra Vulkaniska Zonen, Chile. Till denna ändamål användes termobarometriska modeller beskrivna i Putirka (2008) och andra modeller för assimilering och fraktionerad kristallisation som visar att: a) fraktionerad kristallisation av plagioklas och klinopyroxen i Puyehue vulkanen sker i de övre 20 km av jordskorpan och att plagioklas föregår clinopyroxene i kristallisations följden, b) fraktionerad kristallisering av andesitiska basalterförhärskas av plagioklas samt att den geokemiska utvecklingen förändras omkring 55 wt% SiO2på grund av en ökad fraktioneringsandel av pyroxen plus uppkomsten av betydande magnetit fraktionering, c) både gamla och unga Puyehue vulkaniter är förorenade av ett gabbroisk litologi från den undre kontinentalskorpanså som detföreslagits tidigare av Jicha et al. (2007) och d) Anticura Group lavornasamt ett enda Puyehue-prov reflekterar magma-metasediment interaktion som sannolikt sker i mitten eller övre delenav kontinentalskorpan.

Intermediate igneous rocks exposed in the Badger Pass area and 3.5 km away in the McDowell Springs area of Beaverhead County, Montana, previously mapped as Cretaceous intrusive (Ki), and Cretaceous undifferentiated volcanics (Kvu) respectively, exhibit little geochemical variation. Trace element, and lead isotope analyses provide strong evidence allowing for a single source. REE patterns, obtained through ID-ICP-MS, are essentially identical. Mineral/melt Eu analyses reveal that Eu behaved predominantly as a divalent cation, refuting an earlier study asserting that trivalent Eu dominated. Data suggest rocks were formed under low oxygen activity conditions, not oxidizing conditions as previously reported. Geochemical data combined with field mapping allow us to establish the temporal relationship between late Cretaceous thrusting, intrusion, and volcanism in this locale. Folding, faulting and thrusting were significantly, if not entirely, completed prior to the commencement of volcanism. Volcanism included contemporaneous thrust plate intrusion, foreland extrusion, and hypabyssal foreland intrusion.

The study aimed to identify deterioration problems, repair and conservation needs of andesites on the walls of the Ankara Castle. Decay forms of walls were documented by visual examination. Samples taken from the surface of the weathered andesites were examined for their basic physical, mechanical compositional and minerological properties. The bulk density and total porosity were determined as basic physical properties. The mechanical properties were expressed as ultrasonic velocity and modulus of elasticity (Emod). Compositional and mineralogical properties were determined by optical microscopy and XRD analyses. Soluble salt content of the andesite samples was determined by spot tests of anions and electrical conductivity measurements. Findings were evaluated in terms of the long-term weathering behaviour of andesites under the effect of the prevailing climate, air pollution problems of Ankara, dampness problems of the structure, previous repairs with incompatible cement mortars. The surfaces of Ankara Castle andesite blocks were heavily weathered. The results were compared with the physical and mechanical properties of fresh andesites from G&ouml / lbaSi-Ankara quarry. The surface of the andesite blocks at the Ankara Castle, had low bulk density and high porosity, low ultrasonic velocity and low Emod values. Thin section and XRD analyses supported those results by revealing the presence of physical and chemical weathering on feldspars and other main minerals of andesite, as well as the presence of amorphous minerals at the surface.

Thesis (Ph. D.)--Pennsylvania State University. / Includes bibliographical references (p. 118-124).

New geochemical data consisting of major and 15 trace element analyses are presented for 41 rocks from three andesitic and associated basaltic rock occurrences in the North Eastern Cape Province. These include the Pronksberg, Belmore and Roodehoek localities. Field evidence suggests that the three andesites were emplaced during the early stages of Karoo volcanicity. Geochemical variations within the Pronksberg and Roodehoek andesite are small, manifesting the undifferentiated nature of the magmas. Variations within the Belmore andesite are interpreted as representing fractionation of orthopyroxene, accompanied by only minor plagioclase fractionation. Differences in trace element concentrations and inter-element ratios between the andesites and associated basalts of the Pronksberg and Belmore volcanic suites precludes the possibility of the two rock types being genetically related. Geochemical differences constrain the possibility of the three andesites being cogenetic. Magmatic processes resulting in their formation are, however, thought to be similar. The differences in chemistry between the Pronksberg Basalt (High K Type) and Pronksberg Basalt (Drumbo Type) are interpreted as representing the combined influence of weathering, the presence of amygdales and the within-flow variations of alkali elements on the Pronksberg Basalt (High K Type). Similarities in petrography and chemistry justifies a correlation of the Pronksberg Basalt (Drumbo Type) with the Drumbo Basalt Member in the Barkly East area. Data for the Drumbo Basalt (This study) in the Barkly East area confirms and complements previously presented data. Normative chemistry and strontium isotope data indicate a process involving crustal assimilation or melting of crustal rocks as being the most likely explanation for the genesis of the Karoo andesites / KMBT_363 / Adobe Acrobat 9.53 Paper Capture Plug-in

Ngauruhoe is an active basaltic andesite to andesite composite cone volcano at the southern end of the Tongariro volcanic complex, and most recently erupted in 1954-55 and 1974-75. These eruptions constructed the inner crater of Ngauruhoe, largely composed of 1954-55 deposits, which are the basis of this study. The inner crater stratigraphy, exposed on the southern wall, is divided into seven lithostratigraphic units (A to G), while the northern stratigraphy is obscured by the inward collapse of the crater rim. The units are, from oldest to youngest: Unit A, (17.5 m thick), a densely agglutinated spatter deposit with sharp clast outlines; Unit B, (11.2 m) a thick scoria lapilli deposit with local agglutination and scattered spatter bombs up to 1 m in length; Unit C, (6.4 m thick) a clastogenic lava deposit with lateral variations in agglutination; and Unit D, (10 m thick) a scoria lapilli with varying local agglutination. The overlying Unit E (15 cm thick) is a fine ash fallout bed that represents the final vulcanian phase of the 1954-55 eruption. Unit F is a series of six lapilli and ash beds that represent the early vulcanian episode of the 1974-75 eruption. The uppermost Unit G (averaging 10 m thick) is a densely agglutinated spatter deposit that represents the later strombolian phase of the 1974-75 eruption. Units A-D juvenile clasts are porphyritic, with phenocrysts of plagioclase, orthopyroxene, clinopyroxene, minor olivine, within a microlitic glassy groundmass. Quartzose and greywacke xenoliths are common in most units, and are derived from the underlying basement. The 1954-55 and 1974-75 eruptions are a product of a short-lived, continental arc medium-K calc-alkaline magma. The magma originated from the mantle, then filtered through the crust, undergoing assimilation and fractionation, and evolving to basaltic andesite and andesite compositions. The magma body stagnated in shallow reservoirs where it underwent further crustal assimilation and fractionation of plagioclase and olivine, and homogenisation through magma mixing. Prior to the 1954-55 eruption a more primitive magma body was incorporated into the melt. The melt homogenised and fed both the 1954-55 and 1974-75 eruptions, with a residence time of at least 20 years. The 1954-55 eruption produced alternating basaltic andesite and andesite strombolian activity and more intense fire fountaining, erupting scoria and spatter that built up the bulk of the inner crater. A period of relative quiescence allowed the formation of a cooled, solid cap rock that resulted in the accumulation of pressure due to volatile exsolution and bubble coalescence. The fracturing of the cap rock then resulted in a vulcanian eruption, depositing a thin layer of fine ash and ballistic blocks. The 1974-75 eruption commenced with the rupturing of the near-solid cap rock from the 1954-55 eruption in an explosive vulcanian blast, the result of decompressional volatile exsolution and bubble coalescence, and possible magma-water interaction. The eruption later changed to strombolian style, producing a clastogenic lava that partially flowed back into the crater.

Development of homes, roads, and commercial buildings in northern Utah has grown significantly during the last several decades. Construction has expanded from the valley floor to higher elevations of benches, foothills, and other elevated regions of the Wasatch Mountain Front. Construction in the higher elevation areas are a concern due to potential for landslides, both new and reactivated. Landslides have been identified in this region and are dated as Pleistocene to historical in age. A possible landslide of about 0.5 km2 on the south slope of Traverse Mountain has been mapped by the Utah Geological Survey in 2005. Its surface exhibits hummocky topography and is comprised of Oligocene-age volcanic ash, block and ash flow tuffs, and andesite lava. Landslides along the Wasatch Mountain Front are complex features usually characterized by dense vegetation and poor outcrop and require a combination geological and geophysical methods to study their thickness, slope, lateral extent, and style of emplacement. Our study incorporates trenching, boreholes, and LiDAR aerial imagery. Unique to the study of landslides is our use of seismic reflection with a vibroseis source over the mapped landslide deposit. The seismic parameters of source, station spacing, and processing method provide a coherent, albeit low-resolution, image of the upper 500 m of the subsurface beneath the landslide. A major reflector boundary in our seismic profiles has an apparent dip of 4° to the south, approximately parallel with the surface topography. Its elevation and seismic character are indicative of a contact between the Oligocene-age volcanic rocks on top of a portion of the Pennsylvanian-age Bingham Mine Formation, a mixed carbonate and siliciclastic sequence. The reflector defines an asymmetric graben-like structure bounded by a north-northwest-trending normal fault system. Analysis of trenches, boreholes and local geology reveals a faulted, chaotic body of block and ash flow tuffs, surrounded by andesite lavas. Using LiDAR and surface geological reconnaissance, a possible toe or margin of a landslide has been interpreted in the north-west portion of the study area. The combination weakened block and ash flow tuffs and abundant clay production from this unit contribute to the likelihood of a coalescence of landslides in this mapped landslide area. The integration of LiDAR, trenching, boreholes and reflection seismology provides the range and resolution of data needed to assess the complex geology of landslides.

The Wildcat Creek Tuff is a thin (~3-12 m), rhyolite to andesitic ash-flow tuff with a minimal extent of 1500 km2 in Malheur county, eastern Oregon. The previously undated tuff yielded a single crystal, anorthoclase 40Ar/39Ar age of 15.49±0.02 Ma and thus is closely related to mafic and silicic volcanism of the Columbia River Province. The tuff texturally stands out by its high proportion of co-mingled mafic inclusions appearing as dark, scoriaceous, and phenocryst-poor fragments, and their proportion dictate bulk tuff compositions ranging from rhyolite (74% SiO2) to andesite (59% SiO2). Glass analyses confirm rhyolite end member at 74-75 wt.% SiO2 and two mafic members, one at 59-60 wt.% SiO2 and the other at 56-57 wt.% SiO2. Rare plagioclase and even rarer pyroxene phenocrysts with compositions clustering at An60-74 and An35-45, and Mg17-19 and Mg80-84, respectively, similarly suggest two andesitic magmas with the 60% member being the dominant mafic composition. It has distinctly lower TiO2 and CaO, slightly lower FeO, and comparable Al2O3, MgO, and alkalis. Eruption of crystal-poor dacitic to basaltic-andesitic cognate components is also observed in other Miocene ash-flow tuffs from eastern Oregon, like the Rattlesnake, Dinner Creek, and the Devine Canyon Tuffs, as well as other less voluminous tuffs. However, the high proportion of mafic components in the Wildcat Creek tuff seems currently unrivaled. The co-eruption of intermediate magmas with rhyolite implies that mafic magmas were tapped from a common reservoir, and these magmas increased in proportion during the course of the eruption(s). This continued up to the point where nearly all deposited tuff material consisted of andesite. This is consistent with progressively deeper magma withdrawal, in turn implying that mafic magmas resided below the rhyolites as a discrete magma batch. Dacitic components of voluminous rhyolitic tuffs have been recently interpreted as remelted samples of a crystal mush after crystal-poor rhyolites where extracted. Dacitic Wildcat Creek Tuff samples do not bear any evidence of this. To the contrary, small negative Eu anomalies, normal Ba and Sr concentrations, and nearly aphyric nature are consistent with a large portion of mixing between Wildcat Creek Tuff rhyolites and regional mid Miocene, Fe-rich, and crystal poor basaltic andesite magmas that occur ubiquitously as lava flows.