No / This is the second in a series of three papers from a project that has attempted to answer the question ‘does the application of agrochemicals accelerate the corrosion of archaeological metals in the top 50cm of the soil?’. We have approached it through a combination of field-based experiments, by establishing laboratory microcosms and by using geochemical modelling techniques to understand the processes involved. This paper reports on two different experimental approaches in the laboratory - a microcosm designed to mimic one of the burial sites (the ‘Lab Bin’ experiments), and a simpler one to understand the reaction between metal samples and concentrated aqueous solutions of the fertilizers and laboratory reagents used (the ‘Lab Beaker’ experiments). The bins were monitored for in situ corrosion and aqueous effluent collected for13 weeks, after which they were excavated and the metal coupons examined. The Lab Beakers were monitored for in situ corrosion for seven weeks, and then the coupons examined. We focus here on a sub-set of the data relating to the behaviour of the thinnest samples of copper in each case. As with the field data previously reported, the results are sometimes contradictory, but on balance this project has demonstrated that applied agricultural chemicals are likely to accelerate the rate of corrosion of metal objects within 50cm of the surface. In particular, it is likely that any fertilizers containing KCI will be particularly aggressive.

No / This is the third in a series of papers from a pilot project that has attempted to answer the question ‘does the application of agrochemicals accelerate the corrosion of archaeological metals in the top 50cm of the soil?’. We have approached it by a combination of field-based experiments, by establishing laboratory microcosms and by using geochemical modeling techniques to understand the processes involved. This paper reports on the geochemical modelling simulations that trace the potential corrosion pathways followed in two sets of laboratory microcosm experiments (‘Lab Beakers’ and ‘Lab Bins’) and one field experiment (at Palace Leas). This approach uses soil solution as the fluid mediating corrosion in the soil vadose zone. Soil solution was displaced following controlled exposure to fertilizers. Modelling using The Geochemists Workbench was carried out to mimic the experimental conditions, and predictions were compared with image analysis results, limited XRD analysis and published corrosion observations. We focus here on a sub-set of the data relating to the behaviour of the thinnest samples of copper in each case. As with the field and laboratory data previously reported, the results are sometimes contradictory, but on balance this project has demonstrated that applied agricultural chemicals are likely to accelerate the rate of corrosion of metal objects within 50cm of the surface. In particular, it is likely that any fertilizers containing KCI (‘potash’) will be particularly aggressive. Geochemical modeling generates plausible corrosion predictions based on post-depositional interaction between archaeological copper and soil solution, and appears to be useful in helping to simplify and understand corrosion pathways in naturally complex systems.

No / Part of a project that has attempted to answer the question ‘does the application of agrochemicals accelerate the corrosion of metals in the top 50cm of the soil? ’ is reported. We have approached the question by a combination of field-based experiments (on two sites), establishing laboratory microcosms (one involving simple aqueous systems and the other a series of simulated burial experiments) and by using geochemical modelling techniques to understand the processes involved. Two different experimental approaches in the field are documented — one using in situ monitoring of corrosion potentials and the other assessing the degree of induced corrosion using image analysis on recovered samples. The first was carried out on arable land close to the University of Bradford to which we applied different fertilizer regimes. The second was established on land owned by the University of Newcastle at Palace Leas, Morpeth, Northumberland, which has a documented field management regime extending back over one hundred years. We focus here on a sub-set of the data relating to the behaviour of the thinnest samples of copper in each case. There does seem to be some evidence of an effect resulting from the applied fertilizer, but the data are sometimes contradictory. We suggest a number of improvements for future field experiments that monitor in situ corrosion in the vadose zone.

The water and heat exchange in thesoil-snow-vegetation-atmosphere system was studied in order toimprove the quantitative knowledge of land surface processes.In this study, numerical simulation models and availabledatasets representing arable land, sub-alpine snowpack, andboreal forest were evaluated at both diurnal and seasonaltimescales. Surface heat fluxes, snow depth, soil temperatures andmeteorological conditions were measured at an agriculturalfield in central Sweden during three winters and two summersfrom 1997 to 2000 within the WINTEX project. A one-dimensionalsimulation model (COUP) was used to simulate the water and heatbalance of the field. Comparison of simulated and measured heatfluxes in winter showed that parameter values governing theupper boundary condition were more important for explainingmeasured fluxes than the formulation of the internal mass andheat balance of the snow cover. The assumption of steady stateheat exchange between the surface and the reference height wasinadequate during stable atmospheric conditions. Independentestimates of the soil heat and water balance together with thecomparison of simulated and measured surface heat fluxes showedthat the eddy-correlation estimates of latent heat fluxes fromthe arable field were on average 40 % too low. The ability of a multi-layered snowpack model (SNTHERM) tosimulate the layered nature of a sub-alpine snowpack wasevaluated based on a dataset from Switzerland. The modelsimulated the seasonal development of snow depth and densitywith high accuracy. However, the models ability to reproducethe strong observed snowpack layering was limited by theneglection of the effect of snow microstructure on snowsettling, and a poor representation of water redistributionwithin the snowpack. The representation of boreal forest in the land surfacescheme used within a weather forecast (ECMWF) model was testedwith a three-year dataset from the NOPEX forest site in centralSweden. The new formulation with separate energy balances forvegetation and the soil/snow beneath the tree cover improvedthe simulation of seasonal and diurnal variations in latent andsensible heat flux. Further improvements of simulated latentheat fluxes were obtained when seasonal variation in vegetationproperties was introduced. Application of the COUP model withthe same dataset showed that simulation of evaporation fromintercepted snow contributed to a better agreement with themeasured sensible heat flux above forests, but also indicatedthat the measurements might have underestimated latent heatflux. The winter sensible heat flux above the forest wasfurther improved if an upper limit of the aerodynamicresistance of 500 s m-1 was applied for stable conditions. A comparison of the water and heat balance of arable landand forest confirmed the general knowledge of the differencesbetween these two surface types. The forest contributed withconsiderably more sensible heat flux to the atmosphere than thearable land in spring and summer due to the lower albedo andrelatively less latent heat flux. Latent heat flux from theforest was higher in winter due to the evaporation ofintercepted snow and rain. The net radiation absorbed by theforest was 60 % higher than that absorbed by the arable land,due to the lower surface albedo in winter. Key words:soil; snow; land surface heat exchange;forest; arable land; eddy-correlation. / QC 20100614

Diss. Uppsala : Sveriges lantbruksuniv., 2003.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniversitet, 2004. / Härtill 4 uppsatser.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv., 2007. / Härtill 4 uppsatser.

Spontaneous restoration of wetlands on arable field was observed in the part of South Bohemia. The main aim of the study was to describe colonization of the newly formed wetlands by plants in relation to character of the site and its surroundings (age and size of the wetland, distance to the field margin and to a nearest permanent wetland). Data were collected during six seasons (2011, 2012, 2013, 2014, 2015, 2016) and analyzed using regression analyses, scatterplots and ordination analyses (DCA, CCA). There were found no significant effects of the distance to the permanent wetland and the distance to the edge of the field on species composition of the newly created wetlands. The effect of successional age of wetlands on their species composition was significant. Species with a higher colonization ability were relatively more frequent in those wetlands located in a longer distance form the edge of the field. Participation anemochorious and hydrochorious species increased during a succesional time on studied wetlands, the proportion zoochorious and hemerochorious species decreased. These conclusions, however, be taken with caution, because it captured with a relatively small margin successional age. In general, it was shown that spontaneous restoration of wetlands on arable land is possible and runs to (semi)natural wetland vegetation.

Society depends on bumblebees for the ecosystem service in the pollination of crops. Bumblebee declines have been documented, mostly due to intensification of agriculture and loss of species-rich semi-natural grasslands, an important bumblebee habitat. To conserve bumblebee diversity and the ecosystem service of pollination, it is important to do analyses on multiple spatial scales to see how the intensification of agriculture affects bumblebees at a landscape level. In this study, I related abundance of bumblebees in 476 sites in southern Sweden (total abundance and abundance of declining/non-declining, long-tongued/short-tongued, and species preferring open terrain vs. forest boundaries) to amount of land use types (semi-natural grassland, arable land, forest, water and “other land use”) at 34 spatial scales (radii 100 to 40,000 m). Arable land had a negative effect on total bumblebee abundance at scales from 464 to 10,000 m and forest had a negative effect at scales from 2929 to 5412 m. Semi-natural grassland showed no clear effects – however, the partial regression coefficients were consistently negative. Arable land had a negative effect on non-declining species, long- and short-tongued species and on species preferring forest boundaries at larger scales, e.g. regions dominated by agriculture. Forest had a positive effect at smaller scales on species preferring forest boundaries and a negative effect at larger scales on species preferring open terrain and on declining species. The results suggest that arable land is a non-habitat for bumblebees and that semi-natural grassland does not affect bumblebee abundance at a landscape level.

STUDENT NUMBER: 0516082G Master of Science in Resource Conservation Biology Faculty of Science / The aim was to determine the availability of marula (Sclerocarya birrea) (A.Rich.) Hochst. Subsp.cafra (Sond.) Kokwaro trees for the harvesting of nut oils, through determining abundance, population structure and regeneration capacity, within the context of the socioeconomic and biophysical dimensions of villages in Zvishavane, Zimbabwe. Both arable and non arable lands in the study area were sampled within four randomly selected villages to measure species abundance, regeneration and population dynamics of the trees. The socioeconomic factors influencing marula commercialisation were determined through participatory rural appraisal (PRA) and household questionnaire survey techniques. Vegetation characteristics were assessed through the point centre quarter (PCQ) method by placement of transects across sampled villages. All households (100%) collected marula fruit for their household use, mainly for brewing marula beer, making jam and selling kernels for snacks or oil pressing. In 2005, the mass of marula harvest per household averaged 160 ± 18 (SD) kg, with a range of 50-800 kg within the study area. A linear regression analysis indicates no increase in mass of marula harvest with larger sizes of household (r2 = 0.0089, d.f = 50, p = 0.4048). In addition, household interviews revealed that there was no association between level of household wealth status and the household’s use of traditional medicine from marula trees (χ2 = 0.2233, d.f = 2, p = 0.8944). The vegetation survey indicated a elatively high density of marula within the study area of 8.03 ± 3.19 stems ha-1. There was a significant difference in marula densities between arable and non arable land uses (F1, 197 = 11.92, p=0.001). The arable land had 6.40 ± 5.29 stems ha-1 while non arable land had three times more at 19.63 ± 11.82 stems ha-1. However there was no significant difference in densities between the villages in the study area (F 3, 195 =1.063, p= 0.366). There was a significant difference between marula tree diameters between arable and non arable land (t 92, 107 = 1.69, p = 0.0401). The arable land had generally bigger tree diameters (31.2 ± 25.3 cm) than non arable land (26.5 ± 20.8 cm), suggesting a form of domestication through allowing marula to grow around homesteads and crop fields. The investigation of marula size class profiles shows a large proportion of smaller diameter trees and this indicates ongoing recruitment of trees into the population. A closer analysis of the smallest diameter class shows a higher proportion of saplings (> 6cm diameter) than of seedlings (< 4cm diameter). Fruit harvesting seems to have a low potential for any negative impact, compared to other uses of marula trees. However fruits have the highest economic return and therefore should be targeted for the commercialisation activities. The management of some destructive forms of marula tree use (such as harvesting for bark, firewood, and carving wood) however, do need to be monitored to limit negative impacts on the population. There is also a need to determine the annual quantity of harvestable marula fruits and also the sex ratio of marula trees (a dioecious species) on this particular site, as a prelude to developing sustainable harvesting quotas, so that harvesting rates do not exceed the capacity of populations to replace the individuals extracted. There are some non governmental organisations (NGOs) and local institutions that are working towards natural resources conservation in the area. Zvishavane water project (ZWP) and Phytotrade Africa are assisting the rural producers in marula commercialisation activities through providing information on processing, packaging and marketing. At a current value of US$1 kg-1of fruit, the 3200 ha study area is estimated to yield a total harvest of 1 120 000 kg of marula fruit per year, and this should translate to an approximate total value of $1 120 000 per year for the whole area. There is still a need to expand the supply of processed goods with added value to wider markets locally, nationally, and internationally. There is therefore an indication that marula products offer a promising economic alternative for the people in the rural areas of Zvishavane area and southern Africa as a whole. The cash injection earned from selling fresh marula products comes at a particularly crucial time of the year, when money is required for school fees, uniforms and books. However there is a need for long-term monitoring and evaluation of socio-economic and environmental impacts of marula commercialisation so as to achieve sustainable resource utilisation in the region.