Este trabalho trata do estudo do transporte atmosférico de emissões de queimadas na região Amazônica e Centro-Oeste do Brasil. Em consequência da queima de biomasa, gases (CO IND.2, CO, CH IND.4, etc.) e partículas são emitidas para a atmosfera, os quais podem provocar mudanças no equilíbrio climático e biogeo químico do planeta Terra, em várias escalas. O estudo é realizado por meio de simulação numérica dos movimentos da atmosfera utilizando o modelo atmosférico RAMS (Regional Atmospheric Modeling System). São utilizados os métodos Lagrangiano e Euleriano. No método Langrangiano o transporte é estudado por meio do cálculo de trajetórias cinemáticas 3d de massas de ar, utilizando o campo de vento simulado, na escala resolvida. A posição inicial das massas de ar é obtida a partir de mapas de queimadas detectadas por sensores a bordo de satélites como o AVHRR da série NOAA. Uma metodologia simples que contabiliza os efeitos de processos convectivos úmidos da escala sub-grade na velocidade vertical da parcela de ar para modelo atmosféricos de baixa resolução, é introduzida no modelo de trajetórias. No método Euleriano, é resolvida a equação de conservação de massa dos principais elementos emitidos. Para tanto é introduzido um modelo de fontes emissoras de gases/partículas associadas à queimadas em floresta tropical e cerrado da América do Sul, distribuídas espacial e temporalmente através da assimilação diária de mapas de posição de queimadas produzidos por sensoriamento remoto. Os termos de advecção na escala resolvida e o transporte turbulento na escala sub-grade são resolvidos utilizando as parametrizações próprias do modelo RAMS. É introduzida uma parametrização do transporte sub-grade associado às circulações úmidas e profundas não resolvidas explicitamente pelo modelo, devido a baixa resolução espacial. Termos sumidouros associados a processos genéricos de remoção/transformação de gases/partículas são ) também parametrizadas e inseridos na equação de conservação de massa. A metodologia é aplicada a um estudo de caso ocorrido no mês de julho de 1993. São modelados o transporte turbulento na camada limite planetária, os efeitos transientes associados à entrada de frentes frias vindo do sul do continente e à convecção na bacia Amazônica no transporte convectivo de poluentes, bem como o transporte associado aos sistemas de larga escala. São observados padrões de exportação continental de poluentes, com saídas ocorrendo a noroeste da América do Sul em direção ao oceano Pacífico, e a sudeste em direção ao oceano Atlântico. / A study about the atmospheric transport f biomass burning emissions in the Amazon and the Central of Brazil is presented. Gases (CO IND.2, CO, CH IND.4, etc.) and particles emitted to the atmosphere due the biomass burning are responsible for the climatic and biogeochemical budget changes in the Earth planet, in many scales. This study is carried out through a numerical simulation of the atmospheric motions using the atmospheric models RAMS (Regional Atmospheric Modeling System). Lagragian and Eulerian methods are used. In the Lagrangian method the transport is studied through 3D kinematic air mass trajectories calculation, using simulated wind fields, in a resolved scale. The initial position of the air masses is obtained from biomass burning spots maps, derived from satellite sensors (AVHRR from NOAA series). A simple methodology to take into account the sub-grid effects of wet convective process in the vertical velocity of the air parcels, for low resolution atmospheric models is introduced in the trajectory model. In the Eulerian method the mass conservation equation is resolved for the main elements emitted. A model of gases and particles sources emissions is introduced associated with biomass burning in South America tropical forest and savanna, spatially and temporally distributed and daily assimilated, according to the biomass burning spots defined by remote sensing. The advection in a resolved scale and turbulent transport, in a sub-grid parameterization associated to wet and deep circulation not explicitly resolved by the model due its low spatial resolution is introduced. Sinks associated with generic process of removal/transformation of gases/particles are parameterized and introduced in the mass conservation equation. The methodology is applied to a case study on July 1993. The turbulent transport in the planetary boundary layer the transient effects in the convective transport of pollutants associated with cold fronts from the south and convection in the Amazon basin and the transport associated with the large scale systems are modeled. Patterns of pollutant exportation are observed with a corridor to the Pacific Ocean in the South America Northwest and another in the Southeast to the Atlantic Ocean.

In many problems in dynamical systems one is interested in the identification of sets which have qualitatively different fates. The finite-time Lyapunov exponent (FTLE) method is a general and equation-free method that identifies codimension-one sets which have a locally high rate of stretching around which maximal exponential expansion of line elements occurs. These codimension-one sets thus act as transport barriers. This geometric framework of transport barriers is used to study various problems in phase space transport, specifically problems of separation in flows that can vary in scale from the micro to the geophysical. The first problem which we study is of the nontrivial motion of inertial particles in a two-dimensional fluid flow. We use the method of FTLE to identify transport barriers that produce segregation of inertial particles by size. The second problem we study is the long range advective transport of plant pathogen spores in the atmosphere. We compute the FTLE field for isobaric atmospheric flow and identify atmospheric transport barriers (ATBs). We find that rapid temporal changes in the spore concentrations at a sampling point occur due to the passage of these ATBs across the sampling point. We also investigate the theory behind the computation of the FTLE and devise a new method to compute the FTLE which does not rely on the tangent linearization. We do this using the 925 matrix of a probability density function. This method of computing the geometric quantities of stretching and FTLE also heuristically bridge the gap between the geometric and probabilistic methods of studying phase space transport. We show this with two examples. / Ph. D.

Beryllium-7 is a cosmogenic radionuclide produced in the atmosphere through the spallation of nitrogen and oxygen nuclei by cosmic-ray-produced neutrons and protons. It is carried in the atmosphere attached to aerosols and is deposited on land and ocean surfaces by wet and dry deposition processes. Beryllium-7 decays by electron capture to lithium-7 and has a half-life of approximately 53 days. It is a potentially useful radionuclide for studying different natural processes. This thesis presents a collection of scientific papers on the occurrence of beryllium-7 in the natural environment, particularly in the Southeast Queensland region of Australia. It shows the results of experimental measurements and discusses their implications. Overall, this thesis contributes to advancing our understanding of the distribution and behaviour of beryllium-7 in the natural environment and provides a foundation for the development of nuclear techniques for the evaluation of environmental problems.

Conselho Nacional de Desenvolvimento Científico e Tecnológico / O manto polar antártico retêm informação paleoclimatologica por entres suas camadas de neve e gelo. O gelo antártico tem revelado a base de dados paleoclimática de maior resolução para os últimos 800 mil anos. Os padrões de transporte atmosférico refletem a composição e a fonte do particulado encontrado na neve e no gelo do continente Antártico. Estando relacionado a processos climáticos, as características desse transporte alteram em quantidade e qualidade as espécies químicas que se depositam sobre o manto de gelo. Dessa forma, o estudo dos depósitos de particulado ao longo das camadas de neve/gelo na Antártica pode sugerir mudanças nos padrões de transporte atmosférico. Atualmente a comunidade científica discute as diferenças de padrões climáticos entre o leste e o oeste antártico. Enquanto de forma geral observa-se instabilidade no setor oeste, o clima da antártica oriental demonstra relativa estabilidade climática. Neste estudo, analisamos dois testemunhos de gelo recente de duas regiões com características climáticas diferentes do continente Antártico. No Platô Detroit situado na Península Antártica (6410′S/0600′O), analisamos a variabilidade de Black Carbon (BC) ao longo de 20 metros de neve. O BC encontrado na Península Antártica apresentou baixas concentrações comparáveis as encontradas no gelo do Artico período pré-industrial. Nossos resultados sugerem que sua variabiliade corresponde à sazonalidade dos períodos de queimada nos continentes do Hemisfério Sul. No interior do continente Antártico, analisamos o particulado em geral por um processo de microanálise ao longo de um testemunho de 40 metros extraído em Mont Johns (79o55′S/09423′O). Encontramos uma tendência negativa na deposição de poeira mineral (AlSi) entre 1967 e 2007. Nossos resultados sugerem que esta tendência seja resultado de um crescente isolamento atmosférico da região central do continente antártico pelo aumento da intensidade dos ventos ao redor da Antártica. Este aumento na intensidade dos ventos reflete por sua vez o resfriamento da alta atmosfera no centro antártico causado pela depleção da camada de ozônio na região. Adicionalmente, amostras de diferentes microambientes de Patriot Hills (8018′S/08121′O) foram coletadas de maneira asséptica para análise microbiológica. As amostras foram cultivadas em meio R2 e paralelamente o DNA total extraído foi sequenciado pela técnica de pirosequenciamento. Os resultados preliminares desta analise mostram grande riqueza de espécies dos mais variados grupos. Os resultados deste trabalho caracterizam três diferentes parâmetros relacionados a deposição atmosférica em duas áreas pouco exploradas e de grande interesse científico do continente antártico. / The antarctic ice cap stores paleoclimatological information within layers of snow and ice. Antarctic ice has revealed the higher resolution paleoclimactic database for the last 800 kyr. Atmospheric transport plays a fundamental role on the composition and sources of particulate matter found in the Antarctic ice. It has been related to several climatic processes that changes the quantity and quality of exogenous aerosols reaching Antarctica. Therefore, studies of the particulate matter deposits along the snow/ice layers may suggest changes on atmospheric transport patterns. This work, analyze two recent ice cores from two climatic distinct regions of the Antarctic continent. One retrieved from Detroit Plateau/Antarctic Peninsula (6410′S/0600′W), in which we have analyze Black Carbon (BC) deposition and variability along 20 meters of snow. BC found in the Antarctic Peninsula showed low concentrations (varing between 0,014 and 3,733ppb), comparable to the concentrations found on Arctic ice dated from before the industrial revolution period. Our results suggest that peaks of BC detected correspond, mostly, to biomass burning seasons in the South Hemisphere, not speficically from South America. The second one, of 40 m, was retrieved from Central-West Antarctica, Mont Johns (79o55′S/094 23′W), in which we analyzed the mineral dust abundance thought M.E.V. E.D.X. technique. In this study we found negative trends in mineral dust (inferred from Fe, Ti and AlSi) deposition between 1967 and 2007, in contrast to similar works in Sub-antarctic regions. We demonstrate that this trend is a consequence of the persistent atmospheric isolation that encloses the Central and East Antarctic regions due to the increasing winds around Antarctica within this period. It has been documented that westerlies intensification reflect the upper atmosphere cooling above Central Antarctica caused by the stratospherical ozone layer depletion. As part of the polar site characterization, we additionally have performed sampling for microbiological purpose from distinct microenvironments at Patriot Hills (8018′S/08121′W). Samples were cultivated on R2 media and at the same time total DNA on samples was extracted and sent to a pyrosequencing analysis. Preliminary results show richness and diversity of bacterial species distributed on five phyla.

Conselho Nacional de Desenvolvimento Científico e Tecnológico / O manto polar antártico retêm informação paleoclimatologica por entres suas camadas de neve e gelo. O gelo antártico tem revelado a base de dados paleoclimática de maior resolução para os últimos 800 mil anos. Os padrões de transporte atmosférico refletem a composição e a fonte do particulado encontrado na neve e no gelo do continente Antártico. Estando relacionado a processos climáticos, as características desse transporte alteram em quantidade e qualidade as espécies químicas que se depositam sobre o manto de gelo. Dessa forma, o estudo dos depósitos de particulado ao longo das camadas de neve/gelo na Antártica pode sugerir mudanças nos padrões de transporte atmosférico. Atualmente a comunidade científica discute as diferenças de padrões climáticos entre o leste e o oeste antártico. Enquanto de forma geral observa-se instabilidade no setor oeste, o clima da antártica oriental demonstra relativa estabilidade climática. Neste estudo, analisamos dois testemunhos de gelo recente de duas regiões com características climáticas diferentes do continente Antártico. No Platô Detroit situado na Península Antártica (6410′S/0600′O), analisamos a variabilidade de Black Carbon (BC) ao longo de 20 metros de neve. O BC encontrado na Península Antártica apresentou baixas concentrações comparáveis as encontradas no gelo do Artico período pré-industrial. Nossos resultados sugerem que sua variabiliade corresponde à sazonalidade dos períodos de queimada nos continentes do Hemisfério Sul. No interior do continente Antártico, analisamos o particulado em geral por um processo de microanálise ao longo de um testemunho de 40 metros extraído em Mont Johns (79o55′S/09423′O). Encontramos uma tendência negativa na deposição de poeira mineral (AlSi) entre 1967 e 2007. Nossos resultados sugerem que esta tendência seja resultado de um crescente isolamento atmosférico da região central do continente antártico pelo aumento da intensidade dos ventos ao redor da Antártica. Este aumento na intensidade dos ventos reflete por sua vez o resfriamento da alta atmosfera no centro antártico causado pela depleção da camada de ozônio na região. Adicionalmente, amostras de diferentes microambientes de Patriot Hills (8018′S/08121′O) foram coletadas de maneira asséptica para análise microbiológica. As amostras foram cultivadas em meio R2 e paralelamente o DNA total extraído foi sequenciado pela técnica de pirosequenciamento. Os resultados preliminares desta analise mostram grande riqueza de espécies dos mais variados grupos. Os resultados deste trabalho caracterizam três diferentes parâmetros relacionados a deposição atmosférica em duas áreas pouco exploradas e de grande interesse científico do continente antártico. / The antarctic ice cap stores paleoclimatological information within layers of snow and ice. Antarctic ice has revealed the higher resolution paleoclimactic database for the last 800 kyr. Atmospheric transport plays a fundamental role on the composition and sources of particulate matter found in the Antarctic ice. It has been related to several climatic processes that changes the quantity and quality of exogenous aerosols reaching Antarctica. Therefore, studies of the particulate matter deposits along the snow/ice layers may suggest changes on atmospheric transport patterns. This work, analyze two recent ice cores from two climatic distinct regions of the Antarctic continent. One retrieved from Detroit Plateau/Antarctic Peninsula (6410′S/0600′W), in which we have analyze Black Carbon (BC) deposition and variability along 20 meters of snow. BC found in the Antarctic Peninsula showed low concentrations (varing between 0,014 and 3,733ppb), comparable to the concentrations found on Arctic ice dated from before the industrial revolution period. Our results suggest that peaks of BC detected correspond, mostly, to biomass burning seasons in the South Hemisphere, not speficically from South America. The second one, of 40 m, was retrieved from Central-West Antarctica, Mont Johns (79o55′S/094 23′W), in which we analyzed the mineral dust abundance thought M.E.V. E.D.X. technique. In this study we found negative trends in mineral dust (inferred from Fe, Ti and AlSi) deposition between 1967 and 2007, in contrast to similar works in Sub-antarctic regions. We demonstrate that this trend is a consequence of the persistent atmospheric isolation that encloses the Central and East Antarctic regions due to the increasing winds around Antarctica within this period. It has been documented that westerlies intensification reflect the upper atmosphere cooling above Central Antarctica caused by the stratospherical ozone layer depletion. As part of the polar site characterization, we additionally have performed sampling for microbiological purpose from distinct microenvironments at Patriot Hills (8018′S/08121′W). Samples were cultivated on R2 media and at the same time total DNA on samples was extracted and sent to a pyrosequencing analysis. Preliminary results show richness and diversity of bacterial species distributed on five phyla.

No description available.

Exploring the concepts of long range aerial transport of microorganisms is the main motivation of this study. For this purpose we use theories and concepts of dynamical systems in the context of geophysical fluid systems. We apply powerful notions such as finite-time Lyapunov exponent (FTLE) and the associated Lagrangian coherent structures (LCS) and we attempt to provide mathematical explanations and frameworks for some applied questions which are based on realistic concerns of atmospheric transport phenomena. Accordingly, we quantify the accuracy of prediction of FTLE-LCS features and we determine the sensitivity of such predictions to forecasting parameters. In addition, we consider the spatiotemporal resolution of the operational data sets and we propose the concept of probabilistic source and destination regions which leads to the definition of stochastic FTLE fields. Moreover, we put forward the idea of using ensemble forecasting to quantify the uncertainty of the forecast results. Finally, we investigate the statistical properties of localized measurements of atmospheric microbial structure and their connections to the concept of local FTLE time-series. Results of this study would pave the way for more efficient models and management strategies for the spread of infectious diseases affecting plants, domestic animals, and humans. / Ph. D.

This thesis provides the measurements of 222Rn exhalation rates, 210Pb deposition rates and excess 210Pb inventories for locations in and around Ranger Uranium Mine and Jabiru located within Kakadu National Park, Australia. Radon-222 is part of the natural 238U series decay chain and the only gas to be found in the series under normal conditions. Part of the natural redistribution of 222Rn in the environment is a portion exhales from the ground and disperses into the atmosphere. Here it decays via a series of short-lived progeny, that attach themselves to aerosol particles, to the long lived isotope 210Pb (T1/2 = 22.3 y). Attached and unattached 210Pb is removed from the atmosphere through wet and dry deposition and deposited on the surface of the earth, the fraction deposited on soils is gradually transported through the soil and can create a depth profile of 210Pb. Here it decays to the stable isotope 206Pb completing the 238U series. Measurements of 222Rn exhalation rates and 210Pb deposition rates were performed over complete seasonal cycles, August 2002 - July 2003 and May 2003 - May 2004 respectively. The area is categorised as wet and dry tropics and it experiences two distinct seasonal patterns, a dry season (May-October) with little or no precipitation events and a wet season (December-March) with almost daily precipitation and monsoonal troughs. November and April are regarded as transitional months. As the natural processes of 222Rn exhalation and 210Pb deposition are heavily influenced by soil moisture and precipitation respectively, seasonal variations in the exhalation and deposition rates were expected. It was observed that 222Rn exhalation rates decreased throughout the wet season when the increase in soil moisture retarded exhalation. Lead-210 deposition peaked throughout the wet season as precipitation is the major scavenging process of this isotope from the atmosphere. Radon-222 is influenced by other parameters such as 226Ra activity concentration and distribution, soil porosity and grain size. With the removal of the influence of soil moisture during the dry season it was possible to examine the effect of these other variables in a more comprehensive manner. This resulted in categorisation of geomorphic landscapes from which the 222Rn exhalation rate to 226Ra activity concentration ratios were similar during the dry season. These results can be extended to estimate dry season 222Rn exhalation rates from tropical locations from a measurement of 226Ra activity concentration. Through modelling the 210Pb budget on local and regional scales it was observed that there is a net loss of 210Pb from the region, the majority of which occurs during the dry season. This has been attributed to the fact that 210Pb attached to aerosols is transported great distance with the prevailing trade winds created by a Hadley Circulation cell predominant during the dry season (winter) months. By including the influence of factors such as water inundation and natural 210Pb redistribution in the soil wet season budgeting of 210Pb on local and regional scales gave very good results.