This thesis treats the mass range of charmonium states and excited gluonic fields in two experiments, BESII and PANDA, and outlines a phenomenological model that connects them. In BESII, e+e– form a charmonium initial state, which is utilised as a source for secondary particles. The analysed channels, ψ´→ γK+K– and ψ´→ γπ+π–, give access to intermediate scalar states such as the two glueball candidates: f0(1500) and f0(1710). The f0(1710) is indeed observed in decay into both π+π– and K+K– and the f0(1500) is accepted as a necessary part of the π+π– signal at the moderate 5% level. In addition, we observe the two tensor states f2(1270) (in both channels) and f2´(1525) (in K+K–), but the need for the f2´(1525) is not firmly established. The region around 2 GeV/c2 is fitted with an f4(2050) and an f0(2200) in π+π–. This region is fairly flat in K+K– with a slight peak at the f0(2200). Branching ratios for all eight channels are given. A fit to the angular distribution of ψ´→ γ f2(1270) → γ π+π–gave two possible solutions for the relative importance of helicity projections zero, one and two. The future ppbar experiment PANDA is still in the development phase; important physics goals have been defined and we are now taking on the laborious task of constructing a detector that is able to fulfil them. A simulation investigation of a theoretically preferred JPC=1–+ charmonium hybrid (Hc) is presented: ppbar → Hcπ0/η, Hc → χc1 (π0π0)S–wave, χc1 → J/ψπ0, with a final state of seven photons and a lepton pair. To detect this channel next to full coverage of CM phase space is needed and as little material as possible before the electromagnetic calorimeter. A second simulation study of ppbar → ηc → γγ at PANDA, suggests that the channel should be possible to detect with a signal-to-background ratio of 5±1 and a detection efficiency of at least 10%. By assuming a constant matrix element we obtain a relation between the decay width for ψ → ppbar+m, which has been measured at BES for several cases, and the cross section for ppbar charmonium production in association with the same light meson, m (at for example PANDA). Cross sections of ~300–3000 pb were predicted for J/ψ production and ~30 pb for ψ' production. Isoscalars seem to be preferred to isovectors in J/ψ production, this might however be an artefact of simplifications within the model. A comparison with the only measured cross section, ppbar → J/ψπ0, suggests that the model is useful as a first estimate.

Buildings account for over 35% of the energy demand in OECD countries, making them a prime target for improvement. (EIA 2011) To help building owners reduce energy usage, ratings systems such as LEED have been developed. A prerequisite for certification is the demonstration of energy efficiency through computer modeling; however, the complex nature of building energy simulations too often leads to errors of up to 30% (Turner and Frankel 2008). One source of significant error can be the assumptions made of environmental conditions, which are often simplified to speed up simulations. To demonstrate the significance of active microclimate modeling, a building energy model combined with a microclimate model has been created in RadTherm, a commercial CAE thermal solver. Simulations are run using Passive House construction in three types of environments, and demonstrate an increase in energy demand over an annual time scale when microclimatic components are included. The increase in demand is less than 1%, however the decrease in radiant heat losses are up to 30%. Using the same methodology with revisions to the building construction and urban geometry, a larger increase in energy demand is expected.

Since the 1900’s it has been known that microorganisms are capable of generating electrical power through extracellular electron transfer by converting the energy found organic compounds (Potter, 1911). Microbial fuel cells (MFCs) has garnered more attention recently, and have shown promise in several applications, including wastewater treatment (Yakar et al., 2018), bioremediation (Rosenbaum & Franks, 2014), biosensors (ElMekawy et al., 2018) desalination (Zhang et al., 2018) and as an alternative renewable energy source in remote areas (Castro et al., 2014). In MFCs catalytic reactions of microorganisms oxidize an electron donor through extracellular electron transfer to the anode, under anaerobic conditions, with the cathode exposed to an electron acceptor, facilitating an electrical current (Zhuwei, Haoran & Tingyue, 2007; Lovley, 2006). For energy production in remote areas a low cost and easily accessible feed stock is required for the MFCs. Sweet sorghum is a drought tolerant feedstock with high biomass and sugar yields, good water-use efficiency, established production systems and the potential for genetic improvements. Because of these advantages sweet sorghum stalks were proposed as an attractive feedstock (Rooney et al., 2010; Matsakas & Christakopoulos, 2013). Dried sweet sorghum stalks were, therefore, tested as a raw material for power generation in a MFC, with anaerobic sludge from a biogas plant as inoculum (Sjöblom et al., 2017a). Using sorghum stalks the maximum voltage obtained was 546±10 mV, the maximum power and current density of 131±8 mW/m2 and 543±29 mA/m2 respectively and the coulombic efficiency was 2.2±0.5%. The Ohmic resistances were dominant, at an internal resistance of 182±17 Ω, calculated from polarization data. Furthermore, hydrolysis of the dried sorghum stalks did not improve the performance of the MFC but slightly increased the total energy per gram of substrate. During the MFC operation, the sugars were quickly fermented to formate, acetate, butyrate, lactate and propionate with acetate and butyrate being the key acids during electricity generation. Efficient electron transfer between the microorganisms and the electrodes is an essential aspect of bio-electrochemical systems such as microbial fuel cells. In order to design more efficient reactors and to modify microorganisms, for enhanced electricity production, understanding the mechanisms and dynamics of the electron transport chain is important. It has been found that outer membrane C-type cytochromes (OMCs) (including omcS and omcZ discussed in this study) play a key role in the electron transport chain of Geobacter sulfurreducens, a well-known, biofilm forming, electro-active microorganism  (Millo et al., 2011; Lovley, 2008). It was found that Raman microscopy is capable of providing biochemical information, i.e., the redox state of c-type cytochromes (cyt-C) without damaging the microbial biofilm, allowing for in-situ observation. Raman microscopy was used to observe the oxidation state of OMCs in a suspended culture, as well as in a biofilm of an MFC. First, the oxidation state of the OMCs of suspended cultures from three G. sulfurreducens strains (PCA, KN400 and ΔpilA) was analyzed. It was found that the oxidation state can also be used as an indicator of the metabolic state of the cells, and it was confirmed that PilA, a structural pilin protein essential for long range electron transfer, is not required for external electron transfer. Furthermore, we designed a continuous, anaerobic MFC enabling in-situ Raman measurements of G. sulfurreducens biofilms during electricity generation, while poised using a potentiostat, in order to monitor and characterize the biofilm. Two strains were used, a wild strain, PCA, and a mutant, ΔOmcS. The cytochrome redox state, observed through the Raman spectra, could be altered by applying different poise voltages to the electrodes. This change was indirectly proportional to the modulation of current transferred from the cytochromes to the electrode. This change in Raman peak area was reproducible and reversible, indicating that the system could be used, in-situ, to analyze the oxidation state of proteins responsible for the electron transfer process and the kinetics thereof.

Solar photovoltaic (PV) is the fastest-growing energy resource. The price of energy generation from residential PV has dropped from $0.50 to $0.10 per kWh in the past decade. One challenge with this resource is that the amount of power available depends on the solar irradiance and temperature. Abrupt changes in solar irradiance can cause disturbances to the hosting electricity network and lead to voltage and frequency oscillations. The impact is more severe in a weak grid with high penetration of such resources. Evolving grid interconnection standards are imposing requirements to limit the impacts of these disturbances on the grid. Battery energy storage (BES) technology has also experienced a significant price drop (e.g., from $1100 to $156 per kWh for lithium-ion batteries) in the past decade. Therefore, complementary PV+BES solutions are increasingly considered. A BES of sufficient capacity equipped with appropriate controls can respond to both abrupt and long-term PV power variations. Properly formulating the problem and developing efficient control systems is crucial. These define the scope and objective of this research. This research develops two BES solutions. In the first one, the BES is co-located with the PV and connects to its dc output terminals. The BES controller ensures that the PV+BES system exhibits a desirable power ramp rate set by the user. In the second solution, the BES is not co-located with the PV. It detects the disturbances from their signatures on its locally measured signals and takes proper actions. An approach based on capacitor emulation combined with a droop mechanism is developed and optimally designed to provide dynamic and static supports. The BES can respond to the disturbances from more than one PV system and non-PV sources, such as load disturbances. The dissertation presents detailed modeling and control of the BES system. Optimal control techniques are developed to ensure robust and fast responses. For the simulation study, the proposed BES systems are implemented in a hybrid dc/ac study system and the effect on both dc and ac subsystems are investigated. The real-time results obtained by implementing the proposed controllers on laboratory-scale hardware prototypes are also presented.

Envelopes with low thermal performance are common characteristics in European historic buildings resulting in insufficient thermal comfort and higher energy use compared to modern buildings. There are different types of applications for the European historic buildings such as historic churches, historic museums, historic theatres, etc. In historic buildings refurbished to offices, it is vital to improve thermal comfort for the staff. Improving thermal comfort should not increase, preferably reduce, energy use in the building. The overall aim in this research is to explore how to improve thermal comfort in historic buildings without increasing, preferably reducing, energy use with the application of non-intrusive methods. This is done in form of a case study in Sweden. Thermal comfort issues in the case study building are determined through a field study. The methods include field measurements with thermal comfort equipment, data logging on BMS, and evaluating the occupant’s perception of a summer and a winter period indoor environment using a standardized questionnaire. According to questionnaire and thermal comfort measurements results, it is revealed that the summer period has the most dissatisfied occupants, while winter thermal comfort is satisfactory – but not exceptionally good. Accordingly, natural heat sinks could be used in form of NV, as a non/intrusive method, in order to improve thermal comfort in the building. For the historic building equipped with mechanical ventilation, NV strategy has the potential to both improve thermal comfort and reduce the total electricity use for cooling (i.e. electricity use in the cooling machine + the electricity use in the ventilation unit’s fans). It could decrease the percentage of exceedance hours in offices by up to 33% and reduce the total electricity use for cooling by up to 40%. The optimal (maximum) NV rate (i.e. the potential of NV strategy) is dependent on the thermal mass capacity of the building, the available NV cooling potential (dependent on the ambient air temperature), COP value of the cooling machine, the SFP model of the fans (low SFP value for high NV rate is optimal), and the offices’ door scheme (open or closed doors).

No description available.

Deep geological repository (DGR) for disposal of high-level radioactive waste (HLW) is designed to rely on successive superimposed barrier systems to isolate the waste from the biosphere. This multiple barrier system comprises the natural geological barrier provided by the repository host rock and its surrounding and an engineered barrier system (EBS). The EBS represents the synthetic, engineered materials placed within the natural barrier, comprising array of components such as waste form, waste canisters, buffer materials, backfill and seals. The buffer will enclose the waste canisters from all directions and act as a barrier between canisters and host rock of the repository. It is designed to stabilise the evolving thermo-hydro-mechanical-chemical stresses in the repository over a long period (nearly 1000 years) to retard radionuclides from reaching biosphere. Bentonite clay or bentonite-sand mix have been chosen as buffer materials in EBS design in various countries pursuing deep geological repository method. The bentonite buffer is the most important barrier among the other EBS components for a geological repository. The safety of repository depends to a large extent on proper functioning of buffer over a very long period of time during which it must remain physically, chemically and mineralogically stable. The long term stability of bentonite buffer depends on varying temperature and evolution of groundwater composition of host rocks in a complex way. The groundwater in the vicinity of deep crystalline rock is often characterized by high solute concentrations and the geotechnical engineering response of bentonite buffer could be affected by the dissolved salt concentration of the inflowing ground water. Also during the initial period, radiogenic heat produced in waste canisters would radiate into buffer and the heat generated would lead to drying and some shrinkage of bentonite buffer close to canister. This could alter the dry density, moisture content and in turn the hydro-mechanical properties of bentonite buffer in DGR conditions. India has variety of bentonite deposits in North-Western states of Rajasthan and Gujarat. Previous studies on Indian bentonites suggest that bentonite from Barmer district of Rajasthan (termed as Barmer-1 bentonite) is suitable to serve as buffer material in DGR conditions. Nuclear power agencies of several countries have identified suitable bentonites for use as buffer in DGR through laboratory experiments and large scale underground testing facilities. Physico-chemical, mineralogical and engineering properties of Kunigel VI, Kyungju, GMZ, FoCa clay, MX-80, FEBEX and Avonseal bentonites have been extensively studied by Japan, South Korea, China, Belgium, Sweden, Spain, Canada. It is hence essential to examine the suitability of Barmer-1 bentonite as potential buffer in DGR and compare its physico-chemical and hydromechanical properties with bentonite buffers identified by other countries. The significant factors that impact the long-term stability of bentonite buffer in DGR include variations in moisture content, dry density and pore water chemistry. With a view to address these issues, the hydromechanical response of 70 % Barmer-1 bentonite + 30 % river sand mix (termed bentonite enhanced sand, BES specimens) under varying moisture content, dry density and pore water salt concentration conditions have been examined. The broad scope of the work includes: 1) Characterise the physico-chemical and hydro-mechanical properties of Barmer-1 bentonite from Rajasthan, India and compare its properties with bentonite buffers reported in literature. 2) Examine the influence of variations in dissolved salt concentration (of infiltrating solution), dry density and moisture content of compacted BES specimens on their hydro-mechanical response; the hydro-mechanical properties include, swell pressure, soil water characteristic curve (SWCC), unsaturated hydraulic conductivity, moisture diffusivity and unconfined compression strength. Organization of thesis: After the first introductory chapter, a detailed review of literature is performed to highlight the need for detailed characterisation of physico-chemical and hydromechanical properties of Barmer-1 bentonite for its possible application in DGR in the Indian context. Further, existing literature on hydro-mechanical response of bentonite buffer to changes in physical (degree of saturation/moisture content, dry density) and physico-chemical (solute concentration in pore water) is reviewed to define the scope and objectives of the present thesis in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. Chapter 4 characterises Barmer-1 bentonite for physico-chemical (cation exchange capacity, pore water salinity, exchangeable sodium percentage) and hydro-mechanical properties, such as, swell pressure, saturated permeability, soil water characteristic curve (SWCC) and unconfined compression strength. The properties of Barmer-1 bentonite are compared with bentonite buffers reported in literature and generalized equations for determining swell pressure and saturated permeability coefficient of bentonite buffers are arrived at. Chapter 5 describes a method to determine solute concentrations in the inter-lamellar and free-solutions of compacted BES (bentonite enhanced sand) specimens. The solute concentrations in micro and macro pore solutions are used to examine the role of osmotic flow on swell pressures developed by compacted BES specimens (dry density 1.50-2.00 Mg/m3) inundated with distilled water and NaCl solutions (1000-5000 mg/L). The number of hydration layers developed by the compacted BES specimens on inundation with salt solutions in constant volume swell pressure tests is controlled by cation hydration/osmotic flow. The cation hydration of specimens compacted to dry density of 2.00 Mg/m3 is mainly driven by matric suction prevailing in the clay microtructure as the number of hydration layers developed at wetting equilibrium are independent of the total dissolved solids (TDS) of the wetting solution. Consequently, the swell pressures of specimens compacted to 2.00 Mg/m3 were insensitive to the salt concentration of the inundating solution. The cation hydration of specimens compacted to dry density of 1.50 Mg/m3 is driven by both matric suction (prevailing in the clay micro-structure) and osmotic flow as the number of hydration layers developed at wetting equilibrium is sensitive to the TDS of the wetting solution. Expectedly, the swell pressures of specimens compacted to 1.50 Mg/m3 responded to changes in salt concentration of the inundating solution. The 1.75 Mg/m3 specimens show behaviour that is intermediate to the 1.50 and 2.00 Mg/m3 series specimens. Chapter 6 examines the influence of initial degree of saturation on swell pressures developed by the compacted BES specimens (dry density range: 1.40- 2.00 Mg/m3) on wetting with distilled water from micro-structural considerations. The micro-structure of the bentonite specimens are examined in the compacted and wetted states by performing X-ray diffraction measurements. The initial degree of saturation is varied by adding requisite amount of distilled water to the oven-dried BES mix and compacting the moist mixes to the desired density. The montmorillonite fraction in the BES specimens is responsible for moisture absorption during compaction and development of swell pressure in the constant volume oedometer tests. Consequently, it was considered reasonable to calculate degree of saturation based on EMDD (effective montmorillonite dry density) values and correlate the developed swell pressure values with degree of saturation of montmorillonite voids (Sr,MF). XRD measurements with compacted and wetted specimens demonstrated that if specimens of density series developed similar number of hydration layers on wetting under constant volume condition they exhibited similar swell pressures, as was the case for specimens belonging to 1.40 and 1.50 Mg/m3 series. With specimens belonging to 1.75 and 2.00 Mg/m3 series, greater number of hydration layers were developed by specimens that were less saturated initially (smaller initial Sr,MF) and consequently such specimens developed larger swell pressures. When specimens developed similar number of hydration layers in the wetted state, the compaction dry density determined the swell pressure. Chapter 7 examines the influence of salt concentration of infiltrating solution (sodium chloride concentration ranges from 1000- 5000 mg/L) on SWCC relations, unsaturated permeability and moisture diffusivity of compacted BES specimens. Analysis of the experimental and Brooks and Corey best fit plots revealed that infiltration of sodium chloride solutions had progressively lesser influence on the micro-structure and consequently on the SWCC relations with increase in dry density of the compacted specimens. The micro-structure and SWCC relations of specimens compacted to 1.50 Mg/m3 were most affected, specimens compacted to 1.75 Mg/m3 were less affected, while specimens compacted to 2.00 Mg/m3 were unaffected by infiltration of sodium chloride solutions. Variations in dry density of compacted bentonite impacts the pore space available for moisture flow, while, salinity of wetting fluid impacts the pore structure from associated physico-chemical changes in clay structure. Experimental results showed that the unsaturated permeability coefficient is insensitive to variations in dry density and solute concentration of wetting liquid, while, the effective hydraulic diffusivity is impacted by variations in these parameters. Chapter 8 summarises the major findings of the study.

Deep geological repository (DGR) for disposal of high-level radioactive waste (HLW) is designed to rely on successive superimposed barrier systems to isolate the waste from the biosphere. This multiple barrier system comprises the natural geological barrier provided by the repository host rock and its surrounding and an engineered barrier system (EBS). The EBS represents the synthetic, engineered materials placed within the natural barrier, comprising array of components such as waste form, waste canisters, buffer materials, backfill and seals. The buffer will enclose the waste canisters from all directions and act as a barrier between canisters and host rock of the repository. It is designed to stabilise the evolving thermo-hydro-mechanical-chemical stresses in the repository over a long period (nearly 1000 years) to retard radionuclides from reaching biosphere. Bentonite clay or bentonite-sand mix have been chosen as buffer materials in EBS design in various countries pursuing deep geological repository method. The bentonite buffer is the most important barrier among the other EBS components for a geological repository. The safety of repository depends to a large extent on proper functioning of buffer over a very long period of time during which it must remain physically, chemically and mineralogically stable. The long term stability of bentonite buffer depends on varying temperature and evolution of groundwater composition of host rocks in a complex way. The groundwater in the vicinity of deep crystalline rock is often characterized by high solute concentrations and the geotechnical engineering response of bentonite buffer could be affected by the dissolved salt concentration of the inflowing ground water. Also during the initial period, radiogenic heat produced in waste canisters would radiate into buffer and the heat generated would lead to drying and some shrinkage of bentonite buffer close to canister. This could alter the dry density, moisture content and in turn the hydro-mechanical properties of bentonite buffer in DGR conditions. India has variety of bentonite deposits in North-Western states of Rajasthan and Gujarat. Previous studies on Indian bentonites suggest that bentonite from Barmer district of Rajasthan (termed as Barmer-1 bentonite) is suitable to serve as buffer material in DGR conditions. Nuclear power agencies of several countries have identified suitable bentonites for use as buffer in DGR through laboratory experiments and large scale underground testing facilities. Physico-chemical, mineralogical and engineering properties of Kunigel VI, Kyungju, GMZ, FoCa clay, MX-80, FEBEX and Avonseal bentonites have been extensively studied by Japan, South Korea, China, Belgium, Sweden, Spain, Canada. It is hence essential to examine the suitability of Barmer-1 bentonite as potential buffer in DGR and compare its physico-chemical and hydromechanical properties with bentonite buffers identified by other countries. The significant factors that impact the long-term stability of bentonite buffer in DGR include variations in moisture content, dry density and pore water chemistry. With a view to address these issues, the hydromechanical response of 70 % Barmer-1 bentonite + 30 % river sand mix (termed bentonite enhanced sand, BES specimens) under varying moisture content, dry density and pore water salt concentration conditions have been examined. The broad scope of the work includes: 1) Characterise the physico-chemical and hydro-mechanical properties of Barmer-1 bentonite from Rajasthan, India and compare its properties with bentonite buffers reported in literature. 2) Examine the influence of variations in dissolved salt concentration (of infiltrating solution), dry density and moisture content of compacted BES specimens on their hydro-mechanical response; the hydro-mechanical properties include, swell pressure, soil water characteristic curve (SWCC), unsaturated hydraulic conductivity, moisture diffusivity and unconfined compression strength. Organization of thesis: After the first introductory chapter, a detailed review of literature is performed to highlight the need for detailed characterisation of physico-chemical and hydromechanical properties of Barmer-1 bentonite for its possible application in DGR in the Indian context. Further, existing literature on hydro-mechanical response of bentonite buffer to changes in physical (degree of saturation/moisture content, dry density) and physico-chemical (solute concentration in pore water) is reviewed to define the scope and objectives of the present thesis in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. Chapter 4 characterises Barmer-1 bentonite for physico-chemical (cation exchange capacity, pore water salinity, exchangeable sodium percentage) and hydro-mechanical properties, such as, swell pressure, saturated permeability, soil water characteristic curve (SWCC) and unconfined compression strength. The properties of Barmer-1 bentonite are compared with bentonite buffers reported in literature and generalized equations for determining swell pressure and saturated permeability coefficient of bentonite buffers are arrived at. Chapter 5 describes a method to determine solute concentrations in the inter-lamellar and free-solutions of compacted BES (bentonite enhanced sand) specimens. The solute concentrations in micro and macro pore solutions are used to examine the role of osmotic flow on swell pressures developed by compacted BES specimens (dry density 1.50-2.00 Mg/m3) inundated with distilled water and NaCl solutions (1000-5000 mg/L). The number of hydration layers developed by the compacted BES specimens on inundation with salt solutions in constant volume swell pressure tests is controlled by cation hydration/osmotic flow. The cation hydration of specimens compacted to dry density of 2.00 Mg/m3 is mainly driven by matric suction prevailing in the clay microtructure as the number of hydration layers developed at wetting equilibrium are independent of the total dissolved solids (TDS) of the wetting solution. Consequently, the swell pressures of specimens compacted to 2.00 Mg/m3 were insensitive to the salt concentration of the inundating solution. The cation hydration of specimens compacted to dry density of 1.50 Mg/m3 is driven by both matric suction (prevailing in the clay micro-structure) and osmotic flow as the number of hydration layers developed at wetting equilibrium is sensitive to the TDS of the wetting solution. Expectedly, the swell pressures of specimens compacted to 1.50 Mg/m3 responded to changes in salt concentration of the inundating solution. The 1.75 Mg/m3 specimens show behaviour that is intermediate to the 1.50 and 2.00 Mg/m3 series specimens. Chapter 6 examines the influence of initial degree of saturation on swell pressures developed by the compacted BES specimens (dry density range: 1.40- 2.00 Mg/m3) on wetting with distilled water from micro-structural considerations. The micro-structure of the bentonite specimens are examined in the compacted and wetted states by performing X-ray diffraction measurements. The initial degree of saturation is varied by adding requisite amount of distilled water to the oven-dried BES mix and compacting the moist mixes to the desired density. The montmorillonite fraction in the BES specimens is responsible for moisture absorption during compaction and development of swell pressure in the constant volume oedometer tests. Consequently, it was considered reasonable to calculate degree of saturation based on EMDD (effective montmorillonite dry density) values and correlate the developed swell pressure values with degree of saturation of montmorillonite voids (Sr,MF). XRD measurements with compacted and wetted specimens demonstrated that if specimens of density series developed similar number of hydration layers on wetting under constant volume condition they exhibited similar swell pressures, as was the case for specimens belonging to 1.40 and 1.50 Mg/m3 series. With specimens belonging to 1.75 and 2.00 Mg/m3 series, greater number of hydration layers were developed by specimens that were less saturated initially (smaller initial Sr,MF) and consequently such specimens developed larger swell pressures. When specimens developed similar number of hydration layers in the wetted state, the compaction dry density determined the swell pressure. Chapter 7 examines the influence of salt concentration of infiltrating solution (sodium chloride concentration ranges from 1000- 5000 mg/L) on SWCC relations, unsaturated permeability and moisture diffusivity of compacted BES specimens. Analysis of the experimental and Brooks and Corey best fit plots revealed that infiltration of sodium chloride solutions had progressively lesser influence on the micro-structure and consequently on the SWCC relations with increase in dry density of the compacted specimens. The micro-structure and SWCC relations of specimens compacted to 1.50 Mg/m3 were most affected, specimens compacted to 1.75 Mg/m3 were less affected, while specimens compacted to 2.00 Mg/m3 were unaffected by infiltration of sodium chloride solutions. Variations in dry density of compacted bentonite impacts the pore space available for moisture flow, while, salinity of wetting fluid impacts the pore structure from associated physico-chemical changes in clay structure. Experimental results showed that the unsaturated permeability coefficient is insensitive to variations in dry density and solute concentration of wetting liquid, while, the effective hydraulic diffusivity is impacted by variations in these parameters. Chapter 8 summarises the major findings of the study.

L’obiettivo di questo lavoro è guidare il docente attraverso la letteratura esistente, gli strumenti già in uso e si propone di fornire una modellizzazione per la pratica didattica delle lingue straniere ad alunni sordi. Nel primo e nel secondo capitolo si raccolgono, analizzano e definiscono le basi teoriche di riferimento per la didattica delle lingue a soggetti sordi. Nello specifico, si definiscono il quadro della glottodidattica speciale, i principi di bisogno speciale e specifico e le linee guida per la didattica in contesti di disabilità, procedendo con l’inclusione della sordità tra le esigenze a cui riferirsi con tali strumenti. Il terzo e il quarto capitolo rappresentano l’applicazione concreta dei modelli esposti con l’applicazione del modello SOMA al mondo della sordità e la costruzione del Profilo Glottomatetico Funzionale dell’alunno sordo. Nell’ultimo capitolo si presenta la proposta operativa di didattica dell’inglese ai sordi, partendo dall’analisi e la scelta dei materiali più accessibili, passando per la progettazione fino ad arrivare alla strutturazione specifica del lavoro di classe. / This work aims to guide the foreign language teacher trough the literature on special education needs and deafness, the available tools, and the modeling for everyday practice to encourage the inclusion of deaf students until now considered not teachable. In the first and second chapters, the theoretical approaches to deaf students learning are presented in the contexts of special language teaching, special education, and disabilities. The third and fourth chapters represent the application of those principles to include deaf students in the language classroom activities following the operational models usually used for different learning disabilities. The last chapter offers the concrete model that may guide teachers from their deaf students' needs analysis and the correct material choice for them, passing through the learning project management to get to the specific class lessons, in collaboration with support staff members.

This dissertation argues that Russia’s confrontation with modernity generated a series of sociocultural paradigm crises that gave rise to a modernist grotesque aesthetic tradition, uniting over forty years of artistic production into a coherent literary movement. While close reading the work of Fyodor Sologub (The Petty Demon [Мелкий бес]), Andrei Bely (Petersburg [Петербург]), Evgenii Zamyatin (At World’s End [На куличках]), and Velimir Khlebnikov (“The Crane” [Журавль]), I argue that prerevolutionary modernist writers utilized grotesque modes of representation to depict a world where the former cornerstones of pre-modern Russian identity are fracturing under the pressures of modernity. In contrast to extant scholarship, I argue the 1917 Revolution is not a fundamental break in Russia’s experience of the crisis of modernity, but an extension, and an exacerbation of it. Though discourses of Russian identity formation will be rapidly recodified around the Soviet project, the same underlying grotesque aesthetic devices used by pre-revolutionary authors are taken up by a new generation of Soviet-era modernists. Mikhail Zoshchenko’s parody in Michel Sinyagin (Мишель Синягин) elicits skepticism about yesterday’s unenlightened masses becoming today’s new Tolstoys. Andrei Platonov’s anomalous depictions of the Russian periphery in his Juvenile Sea (Ювенильное море) are still inhabited by monsters, too far from Soviet nodes of power to be assimilated into the national ideological project. And Konstantin Vaginov (in the novel Goat Song [Козлиная песнь]) and Evgenii Shvarts (in the play The Shadow [Тень]) capture the prevalence of superfluous intellectuals with ruptured psyches, frustrated by their unsuccessful attempts to adapt to the new Soviet reality.