This thesis investigates the use of an avalanche Platinum Silicide (PtSi) Schottky Barrier Diode as a detector in fiber optic communication systems for the 1.3 to 1.5 mum spectral region. The avalanche process is used to amplify the signal prior to electrical interfacing in order to enhance the signal-to-noise ratio. The amount of multiplication is predicted by the impact ionization coefficients for electrons and holes, alpha and beta, respectively. By using PtSi Schottky diodes, where alpha > beta, pure electron injection can be accomplished by irradiating with photons of energy psi hnu Eg (where psi is the Schottky Barrier height and Eg is the bandgap of silicon), thus maximizing multiplication and minimizing noise. An alternative means for avalanching involves the quantum effects of impurity-band ionization. By using a heavily doped semiconductor and operating at low temperatures, one can achieve noise-free gain at lower electric field strengths. (Abstract shortened with permission of author.)

An experimental and theoretical analysis of the effects of ion bombardment on Schottky diodes is presented. The experimentally observed shifts in diode performance are compared to the conditions of ion exposure. These experiments show that Schottky diodes exposed to ion beams show decreases in effective barrier heights and ideality factors, as well as increased incidence of premature reverse breakdown. The change in barrier height is found to be proportional to the energy of the individual ions and the total number of ions delivered to the surface. A numerical simulation of the damage process and device performance is developed. The model considers only the effect of ion exposure on the potential distribution within the metal-semiconductor junction. Comparison of experimental and modelled barrier shifts shows fair agreement, suggesting that enhancement of tunnelling currents is the dominant mechanism for barrier lowering.

No description available.

No description available.

This dissertation is not only about the production of a building: it is rather a progressive report, which documents the process and development of my personal manifesto of the inter-relationships between: the social and physical effects of sport activities and people with disabilities, in public open spaces in the city. It aims to serve as an instrument to demonstrate the insight of my experiences, from taking a contemporary social issue (segregation of disabled people from the main society) and urban issues (lack of interests and abandonments of public park spaces in our city) into architectural theories. The research did not begin from a particular point towards a specific building type or programme; instead, I located the base of the research by reinterpreting a personal experience and looking into a specific social/contextual condition. It begins with an assessment of people with disabilities and the built environments in the form of interviews, surveys and academic research. The aim of this exercise is to provide first hand contact with disabled peoples’ needs and priorities. Then the theoretical research which revolves around the notion of public safety in the park - one of the major reasons which decrease the willingness of the public to use it. Together with the findings derived from site analysis and precedent studies, I will then consolidate the arguments by developing an experimental architectural prototype which directly aims to substantiate the theory, and the building structure itself will be the projector that materializes the programme into real context and thus gives justification to my manifesto.

Biopolymers from renewable resources are of interest for packaging applications as an alternative to conventional petroleum-based polymers. One of the major application areas for biopolymers is food packaging, where a candidate polymer should meet critical requirements such as mechanical and oxygen barrier performance, also in humid conditions. Starch has long been used in certain packaging applications, either in plasticized state or blended with other polymers. However, native starch has high sensitivity to water and low mechanical and barrier performance. Recently, wood-derived hemicelluloses have been extensively studied as oxygen barrier films, but suffer from low film-forming ability and mechanical performance. In the present study, xyloglucan (XG) from tamarind seed waste is explored as an alternative high-performance biopolymer in packaging applications. The obstacles of polysaccharides in terms of moisture sensitivity and processability are addressed in this thesis. In Paper I, film properties of XG were studied. XG has a cellulose backbone, but unlike cellulose, it is mostly soluble in water forming highly robust films. Moisture sorption isotherms, tensile tests and dynamic mechanical thermal analysis were performed. Enzymatic modification (partial removal of galactose in side chains of XG) was performed to study the effect of galactose on solubility and filmforming characteristics. XG films showed lower moisture sorption than starch. Stiffness and tensile strength were very high of the order of 4 GPa and 70 MPa respectively, with considerable ductility and toughness. The thermomechanical performance was very high with a softening temperature near 260 ºC. In Paper II, several plasticizers were studied in order to facilitate thermal processing of XG films: sorbitol, urea, glycerol and polyethylene oxide. Films of different compositions were prepared and studied for thermomechanical and tensile properties. Highly favorable characteristics were found with XG/sorbitol system. A large drop in glass transition temperature (Tg) of XG of the order of 100 ºC with 20 - 30 wt% sorbitol was observed with an attractive combination of increased toughness. In Paper III, XG was chemically modified and the structure-property relationship of modified XG studied. XG modification was performed using an approach involving periodate oxidation followed by reduction. The oxidation is highly regioselective, where the side chains of XG are mostly affected with the cellulose backbone well-preserved as noticed from MALDI-TOF-MS and carbohydrate analysis. Films were cast from water and characterized by dynamic mechanical thermal analysis, dynamic water vapor sorption, oxygen transmission analysis and tensile tests. Property changes were interpreted from structural changes. The regioselective modification results in new types of cellulose derivatives without the need for harmful solvents. In Paper IV, moisture durability of XG was addressed by dispersing montmorillonite (MTM) platelets in water suspension. Oriented bionanocomposite coatings with strong in-plane orientation of clay platelets were prepared. A continuous water-based processing approach was adopted in view of easy scaling up. The resulting nanocomposites were characterized by FE-SEM, TEM, and XRD. XG adsorption on MTM was measured by quartz crystal microbalance analysis. Mechanical and gas barrier properties were measured, also at high relative humidity. The reinforcement in mechanical properties and effects on barrier properties were remarkable, also in humid conditions. In Paper V, cross-linked XG/MTM composite was prepared with high clay content (ca. 45 vol%) by an industrially scalable “paper-making” method. Instead of using cross-linking molecules, cross-linking sites were created on the XG chain by selective oxidation of side chains. The in-plane orientation of MTM platelets were studied using XRD and FE-SEM. The mechanical properties and barrier performance were evaluated for the resulting 'nacre-mimetic' nanocomposites. The elastic modulus of cross-linked nanocomposites is as high as 30 GPa, one of the stiffest bionanocomposites reported. / <p>QC 20121107</p>

The aim of this research is to study the formation mechanism of Barrier Layers (BL) in the western tropical Atlantic and their influence on the tropical Atlantic climate at both short and long timescales. Many Coupled General Circulation Models (CGCMs) tend to overestimate the salinity in the Atlantic warm pool or the Northwestern Tropical Atlantic (NWTA) and underestimate the surface salinity in the subtropical salinity maxima region. Most of these models also suffer from a seasurface temperature (SST) bias in the NWTA region, leading to suggestions that the upper ocean salinity stratification may need to be improved in order to improve the BL simulations and thus the SST through BL-SST-Intertropical Convergence Zone (ITCZ) feedbacks. We used a CGCM to perform a set of idealized numerical experiments to understand the sensitivity of the BL and consequently SST in the NWTA region to freshwater flux and hence the upper ocean salinity strati cation. We find that the BL of the western tropical Atlantic is quite sensitive to upper ocean salinity changes in the Amazon River discharge region and the subtropical salinity maxima region. The BL phenomenon is further manifested by the formation of winter temperature inversions in our model simulations. However, in the region of improved BL simulation, the SST response is not statistically significant. SST response to Tropical Cyclones (TCs) is studied for the Atlantic region using a high-resolution coupled regional climate model (CRCM) and observational data sets. The presence of a BL, defined as the layer below the mixed layer that separates the base of the isothermal layer from the base of the isohaline layer, is found to modulate the SST response. The amplitude of TC-induced surface cooling is reduced by more than 35 percent in the presence of a BL, as a consequence of the weak thermal stratification. Furthermore, in locations when the BL exhibits a temperature inversion, TC-induced mixing can result in weak surface warming. BLs considerably reduce the rightward bias for tropical storms, but the effect is less conspicuous for TCs. The enthalpy flux into the atmosphere at the air-sea interface is enhanced by 16 percent and the increase in upper ocean potential energy due to TC-induced mixing is reduced by 25 percent in the presence of BLs. The results from the coupled model are supported by an observational analysis performed using re-analysis data sets, as well as data from Argo floats and TRMM satellite. As previous modeling and observational studies have indicated that the surface cooling caused by TC-induced mixing acts as a negative feedback for its intensity, results from our study suggest that BLs may have potential implications for TC intensity prediction.

Abstract The behaviors of the TaNx barrier layer that placed between the Cu metal and GaAs have been studied by using X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. The TaNx and Cu films were deposited on GaAs sequentially with RF magnetron sputter. With a 250 nm thick TaNx barrier layer, the Cu metal can be impeded from reacting with GaAs substrate at 575¢Jannealed for one hour. Within an As or Ga overpressure environment condition, the failure temperature still occurred below 600¢J. The failure of TaNx diffusion barrier layer for preventing the reaction of the Cu and GaAs was originated for the dissociation of the GaAs itself at 580¢J. The outgoing As atoms increased the deterioration speed of the TaNx film and reduced its blocking ability.

Thesis (M. Arch.)--University of Hong Kong, 1995. / Includes bibliographical references (leaves 29-30).

This dissertation documents the research involved in determining an appropriate response for the design of a building which serves to provide tools for empowerment and independence for blind and partially sighted people. Primary and secondary data collection methods are used. Secondary data collection forms the majority of information gathered focusing on precedent and case studies. The studies investigate how buildings are currently occupied, discussing the differences between buildings that have been specifically designed for the visually impaired and those that have not. Analysis observes the problems that exist and what solutions have been proposed to overcome these. Design criteria can focus on detail design exclusively; however the building in its entirety can be custom-designed to meet the needs of the visually impaired user. This dissertation explores architecture as a sensory experience, highlighting findings that can be used when designing buildings specifically for visually impaired users. The visually impaired rely heavily on their senses enabling them to interpret their surroundings. This research includes an exploration into the use of the senses within the built environment and how we as sighted designers can understand, interpret and contribute to a visually impaired person's experience of the built environment. The research concludes on an appropriate response to designing for visually impaired people. Conclusions are drawn and a design brief for a facility for a Society for the Blind derived. / Thesis (M.Arch.)-University of KwaZulu-Natal, Durban, 2008.