Text in English / There are limits on performance of processes and reactions set by material balances and by thermodynamics. The interaction of these theoretical limits and how they influence the behaviour of reactions and equipment is of interest to researchers and designers. This thesis looks at the conversion of biomass to gaseous products under various conditions, including a range of temperatures from ambient to 1500 ⁰C and in the presence or absence of oxygen. The limits of performance of the material balance can be represented as an Attainable Region (AR) in composition or extent space; we call this the MB-AR. The MB-AR represents all possible material balances that can be achieved for a given a set of feeds and set of possible products. The dimension of this space depends on the number of independent material balances. The extreme points of the MB-AR are of particular interest as these define the limiting compositions and the edges of the boundary of the MB-AR represent the limiting material balances. The MB-AR does not depend on temperature. The thermodynamic limits of performance of can be represented as an AR in the space of Gibbs Free Energy (G) and Enthalpy (H); this is called the G-H AR. The G-H AR is always two dimensional, no matter what the dimension of the MB-AR. Extreme points in the G-H AR are also extreme points in the MB-AR are; however not all extreme points in the MB-AR are extreme points in the G-H AR. The extreme points in the MB-AR are transformed by calculating G and H of the points at the condition of interest (reaction temperature and pressure). It is then necessary to find the convex hull in G-H space of this set of transformed points which gives us the boundary of the G-H AR. The extreme points in the G-H AR can be associated with material balances and the extreme point with the minimum G represents the global equilibrium or equivalently the most favoured material balance for the system. The edges of G-H AR are defined by the lines between neighbouring extreme points in the boundary of the G-H AR. These edges represent the limiting material balances in terms of defining the extremes of the G and H of the system. The G-H AR depends on the feed and products through the MB-AR, but also depends on temperature (and pressure). The set of points which are extreme points of both the MB-AR and the G-H AR changes with temperature. Geometrically, the transformed set of extreme points for the MB-AR moves in the GH space as temperature is changed and they move at different rates. Hence when finding the convex hull in the G-H space of the transformed extreme points of the MB-AR, G-H points become either boundary (extreme) points or move into the convex hull at different temperatures. Thus, the material balance which corresponds to the global minimum in G may change with temperature, as do the material balances which are associated with the edges of the G-H AR. Experiments are performed on biomass anaerobically at ambient temperature using microbes as the catalyst, and the products of this process are called biogas. The experiments were performed in a nitrogen plasma system on biomass at higher temperatures (400 ⁰C to 1000 ⁰C) also in the absence of oxygen, and this process would typically be referred to as pyrolysis. Oxygen was added to the plasma system and operated at temperatures between 700 ⁰C and 900 ⁰C, and this would typically be referred to as gasification. Thus, it was able to change the MB-AR by presence or absence of oxygen. By changing operating temperatures, the G-H AR is effectively changed with either the same or different MB-AR’s. The experiments show that in all cases, the product tends towards minimum G. Although this might not be surprising at the higher temperatures, minimizing G is not thought to be the driving force in microbial systems. An important insight from this is that if one were to try and make hydrogen only in a biological system, the system would need to have organisms that make hydrogen only. This is because the material balance that produces hydrogen has a lower change in G than the material balance that make methane. Thus, if there was a consortium of organisms and some of them could make methane, the methane producing organisms would dominate as they have the higher Gibbs Free Energy driving force. If the boundary of the G-H AR around the minimum G is fairly flat, or if many of the extreme points of the MB-AR lie close to the minimum G in the boundary of the G-H AR, then there are many material balances that will give the same G and H. Thus, there are a range of compositions with similar G and H and how one approaches the minimum G will determine the chemical composition of the product. This has important implications for the design, scale up and operation of equipment if a particular product is desired rather process efficiency. The low temperature anaerobic route to gasifying waste, using microbes as catalysts, has a very simple G-H AR, and the preferred products are CH4 and CO2, known as biogas. These units should be relatively stable to operate as none of the other products have G’s that are as negative as that of the biogas. Although not part of this thesis, small-scale anaerobic digesters were installed in communities and these do run easily and stably with fairly little intervention from the operator which seems to support our conclusion. We however could ask, why then have simple technologies, such an anaerobic digestion, not been widely adopted in Africa? To this end we worked with communities and spoke to people about their knowledge about the technology, their concerns and their possible interest in using new approaches to supply energy for cooking and lighting. We found that people were not aware of the technology but would be very interested in adopting a technology that supplied energy cheaply. To our surprise however, their major concern was around hygiene and safety, in that if the gas was made from “poo” how could the gas be clean and would cooking with it not contaminate the food and make people sick? This in hindsight is a very reasonable concern, although it had never occurred to us that this would be a perception. Engineers will have to work with social scientists and psychologist, amongst others, to address the concerns and needs of communities in order for sustainable technologies to be successfully adopted by communities. In summary, this thesis presents a tool for analysing biomass conversion to gaseous products in general, whether microbial or thermal. This tool gives insight into what is achievable, what the major factors are that affect the favoured product and how this can be manipulated to improve efficiency from an overall material and energy point of view. / Physics / D. Phil. (Physics)

There are many problems associated with the use of fossil fuels to produce fuels and chemicals, and lignocellulosic biomass stands as a promising alternative fuel/chemical feedstock. Large scale processing of biomass will likely take place in high temperature liquid water due to the low vapor pressure and polar nature of carbohydrates. However, little is known about the material stability of these catalysts in high temperature aqueous phase environments. This dissertation aims to investigate the structural integrity of some common catalytic materials under typical biomass reforming conditions. There are 3 main objectives of this study: 1) identify potentially stable candidates from commonly used materials, 2) understand the mechanism(s) by which these catalysts degrade, 3) design/modify catalysts in an effort to increase their hydrothermal stability. The two main materials investigated in this work are zeolites (faujasite, ZSM-5) and γ-Al2O3 as these are commonly used as catalysts and catalyst supports. A number of physicochemical techniques were used to characterize the materials as a function of treatment time at conditions relevant for biomass reforming. For zeolites, the major findings are that ZSM-5 framework is highly stable whereas faujasite stability depends on the Si/Al ratio, where silicon rich materials are less stable. For γ-Al2O3 based catalysts, it was found that the alumina support hydrates and undergoes a phase transformation to form crystalline boehmite (AlOOH) with a subsequent loss in surface area and Lewis acid sites. When metal particles are present on the support, the phase change kinetics are slowed. The role of metal precursor on the stability of γ-Al2O3 supported catalysts was also explored, and it was found that the precursor used in catalyst synthesis changes the boehmite formation kinetics and also affects alumina support dissolution. The final thrust aims to stabilize a Pt/γ-Al2O3 catalyst by depositing silicon on the catalyst surface. The silicon modification is effective in protecting the catalyst from boehmite formation upon exposure to hot liquid water while also stabilizing metal particles against sintering. Additionally, an increase in turnover number for hydrogen production via aqueous phase reforming of sorbitol was observed.

Thesis (M.S.)--Oregon State University, 2008. / Printout. Includes bibliographical references (leaves 103-106). Also available on the World Wide Web.

In recent years, proponents of 'green and clean fuel' have argued that the costs of overreliance on fossil fuels could be reduced through transition to biofuels such as bio-ethanol. Global biofuel discourses suggest that any transition to biofuel invariably results in significant benefits, including energy independence, job creation, development of agro-industrial centres at local level and high revenue generations for the state with minimum negative impacts on the environment. With many risks and costs associated with traditional 'dirty' fuels, it is likely that many countries, particularly African countries, will move towards the 'green and clean fuel' alternative. However, until recently research has arguably paid limited attention to the local livelihood impacts related to land acquisition for biofuel development or the policy frameworks required to maximise biofuel benefits. With regards to biofuel benefits, some recent studies suggest that the much bandied potential for greater tax revenue, lowered fuel costs and wealth distribution from biofuel production have all been perverted with relatively little payoff in wage labour opportunities in return (e.g. Richardson, 2010; Wilkinson and Herrera, 2010). Based on work done in Chisumbanje communal lands of Zimbabwe (Thondhlana, 2015), this policy brief highlights the local livelihood impacts of biofuel development and discusses policy implications of the findings. By highlighting the justifications of biofuel development at any cost by the state, the study sheds some light on the conflicts between state interests and local livelihood needs.

No description available.

Thesis (M.S.)--Mississippi State University. Department of Forestry. / Title from title screen. Includes bibliographical references.

Raw biomass material is bulky, high in void fraction, and very low in transportation efficiency. Furthermore, biomass dissipates quickly in harsh environments of high heat furnaces because of its relatively low calorific value (BTU/lb) and has grinding or size degradation properties highly dissimilar from commonly-used fossil fuels like coal. Therefore, the development of transformational technologies are necessary to convert raw biomass into high-value and useful products of high hardness and calorific value without requiring excessive process energy. This thesis investigates the sustainability of densified biomass fuels. In addition, a procedure that converts raw biomass from agro/forest industry waste into a fuel source known as semi-carbonized densified biomass (SCDB) is shown to have the necessary performance qualities that are conducive to applications involving the harsh conditions of high heat furnaces. The SCDB is produced at temperatures between 115-230°C and pressures between 8-25 MPa. The raw biomass is transformed into a densified fuel source with maximum compressive strengths between 60-200 MPa and calorific values between 18-23 MJ/kg, which are essential to operating in high heat furnace environments. The procedural steps and equipment used to manufacture this densified fuel source are outlined in detail along with experimental results and discussions of initial testing.

Thesis (MScEng (Industrial Engineering))--University of Stellenbosch, 2010. / ENGLISH ABSTRACT: The world is facing an energy crisis with worldwide energy consumption rising at an alarming rate. The effects that fossil fuels have on the environment are also causing concern. For these two reasons the world is determined to find ‘cleaner’, renewable and sustainable energy sources. The Cape Winelands District Munisipality (CWDM) area has been identified as the study area for a bioenergy project. The CWDM project aims to determine the possibility of producing bioenergy from lignocellulosic biomass, and transporting it as economically as possible to a number of electricity plants within the study area. From the CWDM project a number of research topics were identified. The aim of this thesis is to determine the best location for one or more processing plants that will maximise the potential profit through the entire system. This is achieved by minimising the overall life cycle cost of the project. It takes into account costs from establishing and maintaining the crops, harvesting, transportation, conversion and generation; with a strong focus on the transport costs. In conjunction with a Geographical Information Systems (GIS) specialist and taking into account various factors such as electricity demand, heat sales and substation locations, 14 possible plant locations were identified. The possible supply points for each of the 14 plant locations were then analysed by GIS again to yield data in terms of elevation, road distances and slope. The transport costs were calculated using the Vehicle Cost Schedule (VCS) from the Road Freight Association (RFA) and fuel consumption calculations. It takes into account slope, laden and unladen transport and considers different transport commodities. These calculations together with the other associated costs of the life cycle are then combined with the results of the GIS into an EXCEL file. From this a transportation optimisation model is developed and the equivalent yearly life cycle cost of each of the 14 demand points are minimised by means of LINGO software. Initially runs were done for 2.5 MW capacity plants. From the high profit areas identified here, a single area was chosen and further runs were done on it. These runs were performed to determine the effect of different plant capacities on the life cycle costs, as well as how it affects the farm gate price that can be paid to the farmer. It also determined the effect of farmer participation at different plant capacities. The results indicate that it is currently possible to pay a farmer between R 300.00 and R 358.00 for a ton of biomass. It also revealed that with higher participation from farmers in the CWDM project, lower costs and higher farm gate prices will result, since the transport costs will be lower. Although all the costs within the life cycle are variable over time, the transport cost is the only cost that varies spatially and this will have a major effect on the overall system cost. The thesis found that generating electricity from woody biomass is feasible for all areas that were considered as well as for all variations considered during the sensitivity analysis. For the recommended plant size of 5 MW the transport of logs will be optimum. / AFRIKAANSE OPSOMMING: Die tempo waarteen energieverbruik wêreldwyd styg is ʼn rede tot kommer. Die nadelige effek wat fossiel brandstowwe op die omgewing het, is ook ʼn probleem. Hierdie twee redes is hoofsaaklik wat die wêreld dryf om ‘skoner’ hernieubare en volhoubare energie bronne te vind. Die Kaapse Wynland Distrik Munisipaliteit (KWDM) area is identifiseer as ʼn studie area vir ʼn bio-energie projek. Die doel van die KWDM projek is om die vervaardiging van bio-energie vanaf plantasies, die vervoer van hierdie bome sowel as die prosessering koste by die fabriek te bepaal en te evalueer. Vanuit die KWDM projek het `n aantal tesisse ontwikkel waarvan hierdie een is. Die doel van hierdie tesis is om die beste posisie vir een of meer prosesserings fabrieke te bepaal wat die potensiële wins van die KWDM projek sal maksimeer. Dit is ook gemik daarop om die ekwivalente jaarlikse oorhoofse lewenssiklus koste van die projek te minimeer. Dit neem die vestiging en onderhoud van gewasse, oeskostes, vervoerkostes en proseskostes in ag, met ʼn spesifiek fokus op die vervoerkoste. In samewerking met `ʼn “Geographical Information Systems” (GIS) spesialis en deur verskeie faktore, soos elektrisiteitsverbruik, inkomste vanaf hitte verkope en substasie posisies, in ag te neem is 14 moontlike fabriek posisies identifiseer. Verder is die moontlike voorsienings areas van elk van die 14 fabriek posisies weer deur GIS analiseer om resultate in terme van hoogte bo seespieël, padafstand en helling te verkry. Die vervoerkostes is verkry vanaf die “Vehicle Cost Schedule” (VCS) van die “Road Freight Association” (RFA), asook berekeninge wat die brandstof verbruik in ag neem. Hierdie kostes sluit in die effek van gradiënt, gelaaide en ongelaaide vervoer sowel as verskillende vervoer produkte. Hierdie berekeninge sowel as die ander kostes in die siklus en die resultate van GIS is kombineer in ʼn EXCEL leer. Hierdie data word dan gebruik om ʼn LINGO model te ontwikkel en die oorhoofse lewenssiklus koste van elk van die 14 fabriek posisies te minimeer. Optimering is gedoen vir 2.5 MW kapasiteit fabrieke. Uit die beste areas is een area identifiseer en verdere lopies is daarop gedoen. Die doel van hierdie lopies is om die effek van verskillende fabriekskapasiteit op die lewensiklus koste te bepaal, asook die effek daarvan op die prys wat aan die boer betaal word vir hout. Hierdie lopies is ook gebruik om die effek van boer deelname te bepaal. Die resultaat dui aan dat dit tans moontlik is om ʼn boer tussen R 300.00 en R 358.00 te betaal vir ʼn ton biomassa. Dit het ook gewys dat hoe meer boere deelneem aan hierdie projek hoe laer is die oorhoofse lewensiklus koste en hoe hoër is die prys wat betaal kan word vir hout aangesien die vervoerkoste laer sal wees. Alhoewel al die lewensiklus kostes veranderlik is oor tyd, is dit net die vervoerkoste wat ʼn ruimtelike komponent ook het en dit sal ʼn groot effek op die oorhoofse lewenssiklus koste hê. Die tesis bevind dat dit lewensvatbaar is vir alle areas in die studie om elektrisiteit op te wek vanaf hout biomassa, selfs al word die uiterse variasie in die sensitiwiteitsanalise gebruik. Vir die aanbeveling van ʼn 5 MW fabriek sal die goedkoopste vervoer opsie boomstompe wees.

Concern for the environment and a need for more efficient energy generation have sparked a growing interest throughout the world in renewable fuels. In order to reduce emissions that negatively contribute to global warming, especially CO2, enormous efforts are being invested in technologies to reduce our impact on the environment. Biomass is an option that is considered CO2 friendly due to the consumption of CO2 upon growth. Co-firing biomass with coal offers economic advantages because of reduced capital costs as well as other positive impacts, such as NOx and SOx emission reductions. However, due to the large average particle size of biomass, issues arise such as poor flame stability and poor carbon burnout. Larger particles can also result in longer flames and different heat transfer characteristics. Oxygen enrichment is being investigated as a possible solution to mitigate these issues and enable co-firing in existing facilities. An Air Liquide designed burner was used in this work to explore the impact of oxygen enrichment on biomass flame characteristics, emissions, and burnout. Multiple biomass fuels were used (medium hardwood, fine hardwood, and straw) in conjunction with multiple burner configurations and operating conditions. Exhaust ash samples and exhaust NO were collected for various operating conditions and burner configurations. All operating parameters including O2 addition, swirl, and O2 location could be used to reduce LOI but whenever LOI was reduced, NO increased producing an NO-LOI trade-off. Starting with high LOI, various parameters such as O2 addition and increased swirl could be used to reduce LOI with only small increases of NO. As O2 or swirl increased further, small decreases in LOI were obtained only with large increases in NO. This behavior was captured through NO-LOI trade-off curves where a given configuration or operating condition was deemed better when the curve was shifted toward the origin. Global enrichment or O2 addition to the secondary stream and O2 addition to the primary stream produced better trade-off results than center O¬2 injection. Straw produced NO-LOI trade-off curves just as the wood particles but the curve was shifted further from the origin, likely due to the higher nitrogen content of the straw. Flame characterization results showed that small amounts of O2 in the center improved flame attachment and stability while increasing flame temperature and pyrolysis rates.

Biomass is one of the renewable energy sources being used widely for power generation. This research work includes developing a comprehensive model for a biomass based power generation system as well as analyzing the technical, economical, and environmental impacts. The research objectives include modeling of the system, stability studies, and sensitivity analysis using MATLAB/Simulink. A mathematical model for the gas turbine has been developed and successfully interconnected with the distribution network. Transient stability of the power system has been carried out for four bus and six bus test case systems. Maximum rotor speed deviation, oscillation duration, rotor angle, and mechanical power have been taken as the stability indicators to analyze the system characteristics. Additionally, the sensitivity of the system to the changes of gas turbine parameters has been investigated under balanced and unbalanced fault scenarios. The economical and environmental impacts of the biomass have been analyzed using HOMER software developed by the National Renewable Energy Laboratory (NREL). The net present cost of the four biomass resources namely agricultural resources, forest residues, animal waste, and energy crops were obtained and the comparison of the costs of the biomass fuels as well as the diesel have been carried out. To investigate the environmental impact, carbon emissions of the different biomass fuels have been explored using HOMER.