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STUDY OF OZONE NON-ATTAINMENT COUNTIES IN OHIO USING COMPREHENSIVE AIR QUALITY MODEL WITH EXTENSIONS/ANTHROPOGENIC PRECURSOR CULPABILITY ASSESSMENTSRINIVASAN, GANESH 13 July 2005 (has links)
No description available.
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Analysis and simulation of temporal and spatial variations of suspended particulates in the urban area, KaohsiungHuang, Yao-Tien 12 June 2005 (has links)
ABSTRACT
Although the fractions of station-days that the Pollutant Standard Index (PSI) exceed 100 (also referring to the episodes) in Kaohsiung City showed a decline trend from about 10.3% in 1995 to about 5.5% in 2002, the percentage of particulate PM10 events showed a increase trend: from 1.0 % in 2002 to 2.9 % in 2004. This study first statistically summarized the trends of PM10 concentrations using box plots for four air-quality monitoring stations in Kaohsiung during the period of 1997 to 2004, together with the t-test and F-test. The Comprehensive Air Quality Model with extensions (CAMx model) was then applied to analyze the source and the cause of the PM10 events.
The monthly averages of PM10 concentrations at four air-quality monitoring stations were 72.9 ¡V 81.7 £gg/m3 during the period of 1997 to 2004, highest at Hsiung-Kong and lowest at Nan-Chie. The long-term trend analyses show slightly decline results for yearly-averaged PM10 concentrations (1.05% at Nan-Chie, 1.38% at Tzuo-Yin, 1.51% at Chien-Chin, and 1.91% at Hsiung-Kong).
During 1997 to 2004, the PM10 episodes occurred most frequently, while the numbers of PM10 episodes decreased from south to north (i.e., Hsiung-Kong > Chien-Chin > Tzuo-Yin > Nan-Chie). The statistical tests using t-test for the mean and F-test for the variance with 95% confidence level show that the probability that the hourly PM10 concentrations differ insignificantly among the four stations is only about 42%. That is, the spatial difference of pollutant concentrations among four air-quality monitoring stations is rather significant in Kaohsiung.
The CAMx simulations show that contributions to ambient PM10 from stationary source is about 38.9% (NOx: 24.7%; SO2: 14.2%), 8.8% from mobile source (NOx: 7.4%; SO2: 1.4%), and 0.9% from fugitive emissions (SO2: 0.9%) in Kaohsiung. The contributions to ambient PM10 from the emissions in Kaohsiung Harbor are about 3.5%.
Keywords: Particulate matter, Trend analysis, Statistical test, CAMx model.
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Sustainable energy systems : the environmental footprints of electricity generation systems : mechanisms for managing electricity, water resources and air qualityAlhajeri, Nawaf Salem 03 October 2012 (has links)
This thesis examines the response of air pollutant emissions, water use and carbon emissions from electric power supply systems (electrical grids) to market forces and natural and human disruptions. Specifically, the response of electrical grid operation decisions to emissions pricing and other factors, such as drought restrictions, is examined. The grid of the Electricity Reliability Council of Texas (ERCOT) is used as a source of data, and as a spatial and temporal test-bed.
Price signals for NOx emissions have the potential to reduce NOx emissions from the ERCOT grid by up to 50%. In addition to lowering NOx, there are co-benefits to introducing NOx prices, including reductions in the emissions of SOx (24.9% to 70.9%), Hg (16.8% to 81.3%) and CO2 (8.7% to 21.1%). Water consumption was also decreased by 4.3% to 8.2%. The costs of redispatching electricity generation to reduce NOx emissions are, in many scenarios, comparable to conventional control costs. Higher CO2 prices produce many of the same changes in electricity generation as increases in NOx prices, but the simultaneous application of NOx and CO2 pricing produces complex effects.
Under stress, such as drought induced water scarcity, dispatching decisions have the potential to increase water availability in regions in which drought is a concern. This dispatching had relatively small impacts on total water consumption summed over all regions of the ERCOT grid. However, the dispatching scenarios resulted in net increases in NOx, SOx, and CO2 emissions rates summed over all regions of the grid, particularly in regions that were absorbing the electricity generation that was exported out of the drought impacted regions. The costs of electricity dispatching, per volume of water consumption reduced in the drought impacted region, was generally greater than the cost of implementing dry cooling in the same facilities at high electricity demand levels, but comparable to dry cooling at low to moderate demand levels.
Finally, while changes in total emissions can be used as a surrogate for air quality impacts, actual changes in air pollutant concentrations, such as ozone, exhibit complex spatial and temporal patterns in response to redispatching, including the creation of hot spots of elevated concentrations. / text
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Assessing the sustainability of transportation fuels : the air quality impacts of petroleum, bio and electrically powered vehiclesAlhajeri, Nawaf Salem 22 October 2010 (has links)
Transportation fleet emissions have a dominant role in air quality because of their significant contribution to ozone precursor and greenhouse gas emissions. Regulatory policies have emphasized improvements in vehicle fuel economy, alternative fuel use, and engine and vehicle technologies as approaches for obtaining transportation systems that support sustainable development. This study examined the air quality impacts of the partial electrification of the transportation fleet and the use of biofuels for the Austin Metropolitan Statistical Area under a 2030 vision of regional population growth and urban development using the Comprehensive Air Quality Model with extensions (CAMx). Different strategies were considered including the use of Plug-in Hybrid Electric Vehicles (PHEVs) with nighttime charging using excess capacity from electricity generation units and the replacement of conventional petroleum fuels with different percentages of the biofuels E85 and B100 along or in combination. Comparisons between a 2030 regional vision of growth assuming a continuation of current development trends (denoted as Envision Central Texas A or ECT A) in the Austin MSA and the electrification and biofuels scenarios were evaluated using different metrics, including changes in daily maximum 1-hour and 8-hour ozone concentrations, total area, time integrated area and total daily population exposure exceeding different 1-hour ozone concentration thresholds. Changes in ozone precursor emissions and predicted carbon monoxide and aldehyde concentrations were also determined for each scenario.
Maximum changes in hourly ozone concentration from the use of PHEVs ranged from -8.5 to 2.2 ppb relative to ECT A. Replacement of petroleum based fuels with E85 had a lesser effect than PHEVs on maximum daily ozone concentrations. The maximum reduction due to replacement of 100% of gasoline fuel in light and heavy duty gasoline vehicles by E85 ranged from -2.1 to 2.8 ppb. The magnitude of the effect was sensitive to the biofuel penetration level.
Unlike E85, B100 negatively impacted hourly ozone concentrations relative to the 2030 ECT A case. As the replacement level of petroleum-diesel fuel with B100 in diesel vehicles increased, hourly ozone concentrations increased as well. However, changes due to the penetration of B100 were relatively smaller than those due to E85 since the gasoline fraction of the fleet is larger than the diesel fraction. Because of the reductions in NOx emissions associated with E85, the results for the biofuels combination scenario were similar to those for the E85 scenario.
Also, the results showed that as the threshold ozone concentration increased, so too did the percentage reductions in total daily population exposure for the PHEV, E85, and biofuel combination scenarios relative to ECT A. The greatest reductions in population exposure under higher threshold ozone concentrations were achieved with the E85 100% and 17% PHEV with EGU controls scenarios, while the B100 scenarios resulted in greater population exposure under higher threshold ozone concentrations. / text
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Propojení atmosferické chemie/aerosolů s regionálními klimatickými modely / Coupling atmospheric chemistry/aerosols to regional climate modelsHuszár, Peter January 2010 (has links)
Title: Coupling atmospheric chemistry/aerosols to regional climate models Author: Peter Huszár Department: Department of Meteorology and Environment Protection Supervisor: doc. RNDr. Tomáš Halenka, CSc. Supervisor's e-mail address: tomas.halenka@mff.cuni.cz Abstract: In this thesis, the connections between air quality and climate are studied. For this purpose, regional climate model RegCM3 and chemistry transport model CAMx has been coupled offline with one- and two-way interaction. Our work represents a first attempt to connect RegCM3 not only with CAMx, but with any other chemistry transport model. As a first step, an offline one way couple of RegCM3 and CAMx has been developed, meaning that the climate model drives the transport, emission, chemical transformation and deposition of species while the radiative feedbacks of gases and aerosols are not considered. A meteorological interface has been developed at our department in order to convert the meteorological data generated by RegCM3 to fields required by CAMx. For those parameters that are essential for CAMx but the regional climate model does not supply them, diagnostic methods were implemented into this interface. Further, it is used to calculate biogenic emissions. Regarding anthropogenic emissions, a simple utility has been developed to...
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