Submitted by Claudinei Pracidelli (cpracide@ipen.br) on 2015-03-17T11:00:01Z No. of bitstreams: 0 / Made available in DSpace on 2015-03-17T11:00:01Z (GMT). No. of bitstreams: 0 / Neste trabalho foram analisados diferentes parâmetros geométricos para canais de fluxo em células a combustível tipo PEMFC e sua influência no desempenho do sistema, utilizando a fluidodinâmica computacional. Na análise dos modelos matemáticos, verificou-se que o modelo de aglomerado inundado descreve com maior fidelidade o comportamento de células a combustível, enquanto as equações de Butler-Volmer não consideram as perdas por transporte de massa. Foram avaliadas as seções transversais retangular, trapezoidal e em degrau. O modelo com canais de seção retangular apresentou desempenho elétrico ligeiramente superior, porém os canais com seção trapezoidal propiciam um melhor gerenciamento de água. Em todos os aspectos estudados, os canais com seção em degrau se comportaram de forma análoga aos canais com seção trapezoidal, porém sua construção é menos complexa. Também foram analisadas as configurações serpentina e interdigitada em células de 5 cm², e sua influência na uniformidade da densidade de corrente. Não foram observadas diferenças significativas quanto à eficiência elétrica entre células com as duas configurações. A configuração interdigitada propiciou distribuição mais uniforme de geração de corrente, pois os reagentes são fornecidos em alta concentração por uma maior área da célula. Assim, esta configuração é preferível para aumento de escala. / Dissertação (Mestrado em Tecnologia Nuclear) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP

Recent cooperative efforts between the University of Central Florida, the Florida Department of Environmental Protection, and the South Florida Water Management District explore the development of a two-dimensional, depth-integrated tidal model for the Loxahatchee River estuary (Southeastern Florida). Employing a large-domain approach (i.e., the Western North Atlantic Tidal model domain), two-dimensional tidal flows within the Loxahatchee River estuary are reproduced to provide: 1) recommendations for the domain extent of an integrated, surface/groundwater, three-dimensional model; 2) nearshore, harmonically decomposed, tidal elevation boundary conditions. Tidal simulations are performed using a two-dimensional, depth-integrated, finite element-based code for coastal and ocean circulation, ADCIRC-2DDI. Multiple variations of an unstructured, finite element mesh are applied to encompass the Loxahatchee River estuary and different spatial extents of the Atlantic Intracoastal Waterway (AIW). Phase and amplitude errors between model output and historical data are quantified at five locations within the Loxahatchee River estuary to emphasize the importance of including the AIW in the computational domain. In addition, velocity residuals are computed globally to reveal significantly different net circulation patterns within the Loxahatchee River estuary, as depending on the spatial coverage of the AIW.

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Two numerical models have been developed to describe the volumetric changes during solidification in pure metals and alloys and to predict shrinkage defects in the castings of general three-dimensional configuration. The first model is based on the full system of the Continuity, Navier-Stokes and Enthalpy Equations. Volumetric changes are described by introducing a source term in the Continuity Equation which is a function of the rate of local phase transformation. The model is capable of simulating both volumetric shrinkage and expansion. The second simplified shrinkage model involves the solution of only the Enthalpy Equation. Simplifying assumptions that the feeding flow is governed only by gravity and solidification rate and that phase transformation proceeds only from liquid to solid allowed the fluid flow equations to be excluded from consideration. The numerical implementation of both models is based on an existing proprietary general purpose CFD code, FLOW-3D, which already contains a numerical algorithm for incompressible fluid flow with heat transfer and phase transformation. An important part of the code is. the Volume Of Fluid (VOF) algorithm for tracking multiple free surfaces. The VOF function is employed in both shrinkage models to describe shrinkage cavity formation. Several modifications to FLOW-3D have been made to improve the accuracy and efficiency of the metal/mould heat transfer and solidification algorithms. As part of the development of the upwind differencing advection algorithm used in the simulations, the Leith's method is incorporated into the public domain twodimensional SOLA code. It is shown that the resulting scheme is unconditionally stable despite being explicit.

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Made available in DSpace on 2014-10-09T12:42:47Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:56:19Z (GMT). No. of bitstreams: 1 05234.pdf: 8658831 bytes, checksum: 5fdbfa575f19ac2ea95052849f7b67f1 (MD5) / Tese (Doutoramento) / IPEN/T / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP