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Effects of the Methyltrimethoxysilane Coupling Agent on Phenolic and Miscanthus Composites Containing Calcium Sulfite Scrubber MaterialJones, Sean Charles 01 May 2012 (has links)
The purpose of this research is to test the effects of methyltrimethoxysilane coupling agent on composite material containing calcium sulfite obtained from the Southern Illinois Power Co-operative. This scrubber material and the miscanthus plant are of interest due to their use in coal burning power plants to reduce toxic emission. When calcium sulfate is passed through coal fire gas emissions it absorbs mercury and sulfur. In these composites it is used as filler to reduce cost. Miscanthus is a source of both cellulose reinforcement and some natural resin. This plant has low care requirements, little mineral content, useful energy return, and positive environmental effects. Under investigation is whether a post-cure procedure or a silane coupling agent will positively impact the composite. Hot pressing alone may not be enough to fully cure the phenolic. It is hoped that the silane will increase the strength characteristics of the composite by enhancing adhesion between the calcium sulfite and phenolic resin. Possible effects on the miscanthus by the silane will also be tested. Phenolic is being utilized because of its recycling and biodegradable properties along with cost effectiveness in mass production. Composite mechanical performance was measured through 3-point bending to measure flexural strength and strain at breakage. A dynamic mechanical analyzer (DMA) was used to find thermomechanical properties. The post-cure was found to be effective, particularly on the final composite containing silane. When methyltrimethoxysilane was added to the miscanthus prior to fabrication, it was found to reduce flexural strength and density. However the addition of methyltrimethoxysilane to the calcium sulfite altered thermo-mechanical properties to a state more like pure phenolic, with added flexibility and thermal stability.
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Aplikace a vlastnosti silikonových zátěrů tkanin / Application and properties of silicone textile coatingsBernátová, Silvia January 2020 (has links)
The diploma thesis in the first part deals with a theoretical description of coating technologies, textile materials used in coatings, types of coated polymers and properties of coatings - especially adhesion. The experimental part of the work is devoted to the preparation of textile coatings from polyester fabric and coating based on addition silicone. Using the developed method of sample preparation for T-peel testing of the adhesive strength, the improvement of the adhesion of the coating by chemical adhesion with the support of adhesive agents was studied. The second method studied the change in compactness and adhesion of the coating to the fabric after shaking as a function of breathability. The influence of side reactions of reagents on silicone cohesion was studied by preparing dogbones for testing tensile-deformation properties. The research also included the characterization of silicone samples using ATR-FTIR, monitoring the weight gain and thickness of the fabric after coating, the feel and color stability of the applied fabric and observing the coating under an optical microscope.
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Silica Dispersion for Applications in Rubber ProcessingLaw, Yuk Yu 19 August 2013 (has links)
No description available.
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Pultruze biokompozitu na bázi lněných vláken / Pultrusion process of composite based on flax fibresHahn, Filip January 2015 (has links)
Theoretical part of master's thesis is focused on chemical treatments of natural fibers and their use as reinforcement material in polymer composites. Flax fibers were treated with two different silane coupling agents to improve their adhesion with polymer matrix. Nature of treatment was studied by using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). Composites based on both treated and untreated flax fibers were prepared by pultrusion.technique. Mechanical properties and water absorption of prepared composites were evaluated.
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Evaluation of Coal Surface Modification to Improve Coal-Plastic Composite StrengthChirume, Clive T. 01 June 2020 (has links)
No description available.
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Characterization of Dispersion and Residual Stress in Nanoparticle Reinforced Hybrid Carbon Fiber CompositesSelimov, Alex 01 January 2016 (has links)
Hybrid carbon fiber reinforced composites are a new breed of materials that are currently being explored and characterized for next generation aerospace applications. Through the introduction of secondary reinforcements, such as alumina nanoparticles, hybrid properties including improved mechanical properties and stress sensing capabilities can be achieved. In order to maximize these properties, it is necessary to achieve a homogeneous dispersion of particulate filler. Utilizing the photoluminescent properties of alumina, it is possible to compare local levels of particle concentration through emission intensities as a way to determine the effectiveness of the tested manufacturing parameters in increasing material homogeneity. Parameters of these photoluminescence emissions have been established to be stress dependent, which allows for in situ residual stress measurements. It is shown here that the application of silane coupling agents as particle surface treatments improves particle dispersion when compared to untreated samples. Reactive silane coupling agent (RSCA) treatments were found to provide for greater dispersion improvements when compared to non-reactive silane coupling agents (NRSCA). Higher resolution investigations into these samples found that treatment with a reactive coupling agent altered the stress state of particles concentrated around the fiber from a tensile stress state to a compressive stress state. This is proposed to result from bonding of the reactive groups on the coupling agent to the organic groups on the carbon fibers which adjusts the stress state of the particle. Future mechanical tests will verify the effects of the particle surface functionalization treatments on mechanical properties of the composites.
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INTERFACIAL MODIFICATION FOR THE REINFORCEMENT OF SILICONE ELASTOMER COMPOSITESVu, Bich Thi Ngoc 11 October 2001 (has links)
No description available.
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Creation of crosslinkable interphases in polymer blends by means of novel coupling agents / Erzeugung von vernetzbaren Grenzschichten in Polymerblends durch Einsatz neuartiger KopplungsagenzienSadhu, Veera Bhadraiah 14 August 2004 (has links) (PDF)
The goal of the work is to study possibilities for the modification of interface in immiscible polymer blends, which determine to a large degree of the blend properties. For this purpose novel coupling agents (named SCA) containing 2-oxazoline, 2-oxazinone, and hydrosilane reactive sites have been prepared. In blends of amino- functional and carboxylic acid terminated polymers the oxazoline and oxazinone units of the SCA react selectively with one of the polymers and, therefore, the SCA should locate at the interface. The remaining hydrosilane sites can now be used for further modification, e.g. for crosslinking. In the thesis we discussed the effect of the SCA on the morphology and thermal and rheological properties of blends based on carboxylic acid terminated polystyrene (PS) and amino-terminated polyamide 12 (PA) or poly(methyl methacrylate) (PMMA). The morphology of the blends and the location of the SCA strongly depends on the processing conditions. The crosslinkability of the interface could be proven by changes in the solubility behavior of the blends.
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Preparation And Characterization Of Glass Fiber Reinforced Poly(ethylene Terephthalate)Altan, Cansu 01 July 2004 (has links) (PDF)
Glass fiber reinforced poly(ethylene terephthalate), GF/PET has excellent potential for future structural applications of composite materials. PET as a semi-crystalline thermoplastic polyester has high wear resistance, low coefficient of friction, high flexural modulus and superior dimensional stability make it a versatile material for designing mechanical and electromechanical parts.
Glass fibers are currently used as strength giving material in structural composites because of their high strength and high performance capabilities. In order to obtain high interfacial adhesion between glass fiber and polymer, glass fibers are treated with silane coupling agents.
The objective of this study is to produce GF/PET composites with varying glass fiber concentration at constant process parameters in a twin screw extruder. Also, by keeping GF content constant, it is aimed to observe the effects of process parameters such as screw speed and feed rate on structural properties of the composites. Another objective of the study is to investigate the influence of different coupling agents on the morphological, thermal and mechanical properties and on fiber length distributions of the composites.
Tensile strength and tensile moduli of the GF/PET composites increased with increasing GF loading. There was not a direct relation between strain at break values and GF content. The interfacial adhesion between glass fiber received from the manufacturer and PET was good as observed in the SEM photograps. Degree of crystallinity values increased with the addition of GF. Increasing the screw speed did not affect the tensile strength of the material significantly. While increasing the feed rate the tensile strength decreased. The coupling agent, 3-APME which has less effective functional groups than the others showed poor adhesion between glass fiber and PET. Therefore, lower tensile properties were obtained for the composite with 3-APME than those of other silane coupling agents treated composites. Number average fiber length values were reduced to approximately 300& / #61549 / m for almost all composites prepared in this study.
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Desenvolvimento e caracterização de um composito hibrido de polipropileno homopolimero e micro fibra de silica amorfa e fibra de madeira, utilizando agente de acoplagem / Development and characterization of a hybrid composites polypropylene homopolymer and micro fiber amorphous silica and powder's wood using coupling agentsSato, Alex Kazuo 12 March 2008 (has links)
Orientador: Lucia Helena Innocentini Mei / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Quimica / Made available in DSpace on 2018-08-12T10:58:35Z (GMT). No. of bitstreams: 1
Sato_AlexKazuo_M.pdf: 2098023 bytes, checksum: 44db955a219d9ed4ecd602a6d9c1ea7d (MD5)
Previous issue date: 2008 / Resumo: Um dos grandes desafios que enfrentamos neste novo século de avanços tecnológicos é o desenvolvimento de novos materiais que atendam as necessidades pré-requeridas no que diz respeito às propriedades mecânicas e térmicas das peças e seu custo, reunindo assim uma excelente relação de custo beneficio. Este trabalho visou o estudo de um compósito híbrido termoplástico, usando polipropileno como matriz polimérica associado a uma micro fibra de sílica
amorfa (MFSA) e uma fibra natural originada da madeira, para se testar a viabilidade de sua utilização na área dos materiais de engenharia. Foram testadas várias formulações com diferentes proporções de MFSA e de fibra de madeira, bem como compósitos com e sem agentes de acoplamento, funcionalizados com anidrido maleico. A eficiência desses agentes e as propriedades térmicas, mecânicas e morfológicas das diferentes formulações foram avaliadas por meio de testes de resistência à tração, impacto Izod, dureza Shore D, HDT, Vicat e por calorimetria e microscopia eletrônica de varredura dos compósitos obtidos. Os resultados mostraram que o compósito híbrido de homo polipropileno carregado como micro fibra de sílica amorfa e fibra de madeira, auxiliada com o agente de acoplagem estudado, possui boas propriedades térmicas e mecânicas em relação aos compósitos de polipropileno contendo cargas minerais, utilizados hoje em aplicações automobilísticas. Os resultados obtidos abrem novas possibilidades de estudo e apontam os compósitos híbridos como opções interessantes em aplicações práticas na área automobilística, com seus respectivos testes no produto final, como montabilidade e desempenho do produto em campo. / Abstract: One of the great challenges that we face in this new century of technological advances is the development of new materials that meet the pre-required needs regarding to thermal and mechanical properties of parts and their cost thus, leading to an excellent relationship of cost benefit analysis. This work aimed the study hybrid thermoplastic polypropylene composites, using a polymeric matrix combined with a micro fiber of amorphous silica (MFSA) and a natural fiber origined from wood. In this study different proportions of filled composites as well as composites with and without a coupling agent with maleic anydride functionality were tested. The effectiveness of these agents in the different formulations of the
composites obtained was evaluated through mechanical and thermal resistance
since the transfer of mechanical efforts of the matrix for the filled depends on the
efficiency of the accession interfacial between the two components. The results showed that the hybrid composites of homo polypropylene filled with amorphous silica micro fiber and wood fiber together with coupling agent with maleic functionality, has good thermal and mechanical properties in relation to polypropylene composites filled with mineral reinforcement used today in automobile applications. From the above findings, new opportunities can be opened for study in practical applications in a product for automotive application with their tests at the final product, as assembly and performance of the product on the final application. / Mestrado / Ciencia e Tecnologia de Materiais / Mestre em Engenharia Química
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