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1	Palladium(II)-catalysed total synthesis of naturally occurring pyrano[3,2-a]carbazole and pyrano[2,3-b]carbazole alkaloids Hesse, Ronny, Jäger, Anne, Schmidt, Arndt W., Knölker, Hans-Joachim 21 July 2014 (has links) (PDF) Seven naturally occurring pyranocarbazole alkaloids (pyrayafoline A–E, O-methylmurrayamine A and O-methylmahanine) have been obtained by total synthesis using a palladium(II)-catalysed oxidative cyclisation of a diarylamine to an orthogonally diprotected 2,7-dihydroxycarbazole as key step. Synthese Alkaloide Palladium Katalysator Carbazolalkaloide synthesis alkaloids palladium catalysis carbazole alkaloids ddc:540 rvk:VA 1120
2	Palladium(II)-catalysed total synthesis of naturally occurring pyrano[3,2-a]carbazole and pyrano[2,3-b]carbazole alkaloids Hesse, Ronny, Jäger, Anne, Schmidt, Arndt W., Knölker, Hans-Joachim 21 July 2014 (has links) Seven naturally occurring pyranocarbazole alkaloids (pyrayafoline A–E, O-methylmurrayamine A and O-methylmahanine) have been obtained by total synthesis using a palladium(II)-catalysed oxidative cyclisation of a diarylamine to an orthogonally diprotected 2,7-dihydroxycarbazole as key step. info:eu-repo/classification/ddc/540 ddc:540
3	Efficient iron-mediated approach to pyrano[3,2-a]carbazole alkaloids - first total syntheses of O-methylmurrayamine A and 7-methoxymurrayacine, first asymmetric synthesis and assignment of the absolute configuration of (−)-trans-dihydroxygirinimbine Gruner, Konstanze K., Hopfmann, Thomas, Matsumoto, Kazuhiro, Jäger, Anne, Katsuki, Tsutomu, Knölker, Hans-Joachim 02 April 2014 (has links) (PDF) Iron-mediated oxidative cyclisation provides an efficient approach to pyrano[3,2-a]carbazole alkaloids. Thus, improved routes to girinimbine and murrayacine as well as the first total syntheses of O-methylmurrayamine A and 7-methoxymurrayacine are reported. Asymmetric epoxidation of girinimbine led to (−)-trans-dihydroxygirinimbine and the assignment of its absolute configuration. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich. Übergangsmetallkomplexe Carbazolalkaloide wässrige Wasserstoffperoxidlösung organische Synthese Murraya euchrestifolia Orangenrauten Komplexbildungsreaktion Katalyse Epoxidierung transition-metal-complexes active carbazole alkaloids aqueous hydrogen-peroxide organic-synthesis murraya-euchrestifolia tricarbonyliron fragment catalytic complexation chemical taxonomy girinimbine epoxidation ddc:540 rvk:VA 1120
4	Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling – synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A Thomas, Claudia, Kataeva, Olga, Schmidt, Arndt W., Knölker, Hans-Joachim 02 December 2019 (has links) We describe the regioselective prenylation of 3-bromocarbazole by palladium(0)-catalysed cross coupling with a prenylstannane or a prenylboronate. The procedure is applied to the synthesis of precursors for biologically active carbazole alkaloids. info:eu-repo/classification/ddc/540 ddc:540
5	Efficient iron-mediated approach to pyrano[3,2-a]carbazole alkaloids - first total syntheses of O-methylmurrayamine A and 7-methoxymurrayacine, first asymmetric synthesis and assignment of the absolute configuration of (−)-trans-dihydroxygirinimbine Gruner, Konstanze K., Hopfmann, Thomas, Matsumoto, Kazuhiro, Jäger, Anne, Katsuki, Tsutomu, Knölker, Hans-Joachim January 2011 (has links) Iron-mediated oxidative cyclisation provides an efficient approach to pyrano[3,2-a]carbazole alkaloids. Thus, improved routes to girinimbine and murrayacine as well as the first total syntheses of O-methylmurrayamine A and 7-methoxymurrayacine are reported. Asymmetric epoxidation of girinimbine led to (−)-trans-dihydroxygirinimbine and the assignment of its absolute configuration. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich. info:eu-repo/classification/ddc/540 ddc:540

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