The purpose of this thesis is to provide a first look at the spatial and temporal distributions of dissolved organic material (DOM) off the Oregon coast of North America. While this paper is not a comprehensive examination of these distributions, several patterns are identified as promising candidates for continued research. Most of the data presented was acquired during a strong El Nino event. The DOM data is presented as dissolved organic carbon (DOC) and dissolved organic nitrogen (DON) and is accompanied by temperature, salinity, nitrate plus nitrite (N+N), ammonium, silicate, chlorophyll, total organic carbon (TOC), particulate organic carbon (POC), total nitrogen (TN), total organic nitrogen (TON), and zooplankton biomass measurements. During July 1997, we examined the distribution of DOM in the surface waters off the Oregon and Southern Washington coasts. Eleven east-west transects were sampled from nearshore waters to 190km offshore. DOC concentrations as high as 180 iM were observed in the Columbia River plume. Patterns in the DOC distribution were also associated with upwelling regions, an offshore coastal jet, and an oligotrophic water mass in the northern portion of our study area. Beginning with the July 1997 study and continuing until July 1998, samples were collected on weekly and seasonal time scales at station NH-05, located 9km offshore from Newport, Oregon. Various problems have limited our seasonal comparisons, but we were able to collect high quality data depicting the changes in organic matter partitioning during a phytoplankton bloom and its decline during a two month period from mid-July through mid-September in 1997. During the bloom, POC increased dramatically, but DOC decreased. Possible explanations for this decrease and for changes in the C/N ratio of the DOM during the bloom are explored. Suggestions for future research are presented in the final chapter. / Graduation date: 2000

Carbon and energy fluxes were measured with the eddy covariance technique above two semi-arid ecosystems, ponderosa pine and juniper/sagebrush, located in central Oregon. The two ecosystems have low LAI and a very open canopy structure. The energy closure was ~70-80% at both ecosystems, equivalent to an imbalance of 150-250 W m⁻² on cloudless summer days, when net radiation (R[subscript n]) was ~600-700 W m⁻². The lack of closure cannot be explained by the uncertainty of an estimate of available energy due to a single R[subscript n] sensor location. At the more open juniper/sagebrush ecosystem, a numerical model showed that spatial variation in R[subscript n], even for large differences in surface radiation temperature and reflection coefficient between ecosystem components (soil and vegetation), is less than 10% of measured R[subscript n]. The uncertainty in R[subscript n] at the two-layered ponderosa pine ecosystem with patches of young and old-growth trees is expected to be smaller than at the juniper ecosystem. Net carbon exchange (NEE) at the pine site strongly depends on environmental factors effecting carbon assimilation (A[subscript c]) and ecosystem respiration (R[subscript e]). A more detailed analysis of the carbon budget showed a strong negative response of carbon uptake to large vapor pressure deficits (VPD), whereas water vapor exchange (LE) was less affected. At large VPD the vegetation maintains a sustainable water flow through the soil-plant system by stomatal control of transpiration. The stomatal closure leads to limitation in A[subscript c], but LE is subject to a positive feedback from higher evaporative demand. Annual NEE of the ponderosa pine forest (200-300 gC m⁻²) was in the mid-range of reported NEE of temperate forest ecosystems, though, unusually, much of the annual carbon gain occurred during the fall through spring, because the relatively mild winters allowed carbon assimilation to occur and R[subscript e] rates were low. The information gathered at our ponderosa pine site during two years with contrasting climate suggests that the carbon uptake of the ponderosa pine ecosystem will be more sensitive to global climate change than the water vapor exchange. / Graduation date: 2000