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Factors controlling the abundance and carbon isotopic composition of land-plant derived compounds in crude oils.Murray, Andrew P. January 1998 (has links)
This thesis describes a study in petroleum geochemistry and specifically of the application of Land-plant derived hydrocarbons to elucidating source matter type, depositional environment and thermal maturity of crude oils. Large volumes of petroleum have been generated from land-plant organic matter in many parts of the world, but especially in the Tertiary deltaic provinces of the USA, Canada, Africa, Southeast Asia, Australia and New Zealand. Compared to oils from other regions, these oils have a relatively complex pattern of biomarkers or molecular fossils, a feature reflecting the diversity of deltaic depositional environments and the advanced state of plant evolution during late Mesozoic and Tertiary time. The molecular and carbon isotopic composition of these oils is useful in identifying the character of their source beds and also in understanding the conditions that give rise to oil-prone sediments generally.Despite their widespread occurrence in oils and sediments, land-plant biomarkers have been used less frequently than compounds of algal origin as markers for source, depositional environment and thermal maturity. The present work sets out to extend the range of land-plant biomarker and isotope tools available to the petroleum geochemist and to provide a firmer foundation for some of the existing tools. A systematic study of the biomarker and n-alkane carbon-isotope composition of a set of late Mesozoic/Tertiary-age oils was carried out as a preamble to more focussed investigations. A comparison of the biomarker and n-alkane isotope data showed that parameters such as the oleanane/hopane ratio overestimate the higher plant contribution to marine deltaic oils. The abundance of bicadinane isomers was found to be much more variable than that of the oleananes, probably because of their close association with the highly resinous, dipterocarp hardwoods of ++ / Southeast Asia. However, small amounts of bicadinanes were found in an oil from outside the paleogeographic range of the dipterocarp family, indicating a more general source. Retention indices based on the regular hopane series were calculated for the main bicadinane and methyl bicadinane isomers and for a group of oleanoid triterpanes.Source rock depositional setting proved to be the primary control on the shape of the n-alkane isotope profile, with negatively sloping curves being characteristic of fluvio-deltaic and marginal lacustrine oils and flat or positively sloping curves typical of marine oils. The difference is probably related to the bacterial reworking of higher plant matter in the fluvio-deltaic environment. A slight isotopic anomaly at n-C(subscript)17 correlates with the abundance of algal-derived steranes and may indicate a minor marine contribution to the source of an fluvio-deltaic oil. A study of sediments from the South Sumatra Basin and New Zealand showed that the n-alkane isotope profile is determined mainly by source matter type and is little influenced by thermal maturity or depositional environment.Based on the results of the work described above, three aspects were chosen for further examination. These were: a) the factors controlling the carbon isotopic composition of n-alkanes and of resin-derived compounds in terrigenous oils; b) the influence of source, maturity and biodegradation on the abundance of bicadinanes, especially the effect of maturity on the isomer distribution, and c) the factors controlling the abundance of oleananes and rearranged oleananes in oils and Ancient sediments, especially the role of depositional environment.A preliminary study using sediments, from the Visayan Basin (Philippines) showed the bicadinane isomeric distribution to be sensitive to maturity. This suggested new maturity parameters which would be ++ / resistant to even severe biodegradation and largely immune to interference from diagenetic effects. A more detailed study of a marine-fluvio-deltaic depositional sequence from the South Sumatra Basin confirmed that the maturity indices based on bicadinanes and aromatic analogs were less subject to non-maturity influences than those based on the steranes and aromatic hydrocarbons. The values obtained for the bicadinane indices were compared with the maturity required for oil generation as estimated by kinetic modelling and with conventional maturity indicators such as sterane epimerisation and the methyl phenanthrene index. Values for several of the indices were also measured for 17 Tertiary-age oils from Southeast Asia, Papua New Guinea, New Zealand and Australia. The main bicadinane maturity indicator (BMI-1) continues to change into the oil window and hence is useful in ranking the relative maturity of oils as well as sediments. Values of BMI-1 for two oils having unusually low sterane maturities were found to be normal and, in the light of this observation, the conventional explanation for low sterane epimerisation of many Tertiary-age oils was critically evaluated.The oleananes, as markers for the angiosperms, provide valuable source and age information when present in an oil. Nevertheless, their abundance is not quantitatively related to the land plant input and indeed their presence results from a small "leak" in diagenetic processes leading primarily to aromatic oleanoids. Evidence is presented that contact of plant matter with seawater during early diagenesis enhances the expression of oleananes in a mature sediment or oil. Oleananes are absent or present at very low concentrations in samples from the base of an Eocene coal seam affected by post-depositional seawater intrusion. However, their abundance increases toward the top of the seam in correlation with ++ / % organic sulphur, dibenzothiophene/phenanthrene and the homohopane index. Similarly, in deltaic sediments from the South Sumatra Basin, oleanane/hopane is strongly correlated with indicators of marine influence such as C[subscript 27]/C[subscript 29] steranes and of oxic/anoxic conditions such as the homohopane index. In each case, increasing oleanane abundance is accompanied by a reduction in the extent of aromatisation and, for the South Sumatra Basin, the proportion of A-ring contracted oleananes. An angiosperm-derived Miocene coal from the Philippines, deposited under freshwater conditions, shows abundant aromatic oleanoids but no oleananes. These results show that oleananes need to be used with caution as age and source markers in fluvio- deltaic and lacustrine petroleum systems. On the other hand, their sensitivity to early diagenetic conditions may make them useful in locating effective source rocks in such systems.Compounds derived from plant resins are major components of some terrigenous oils. Although recent studies have elucidated the molecular structure of resinites, very little information was available on the carbon isotope composition of resinites prior to the present study. No carbon isotope studies of resin-derived compounds in oils had been performed. Hence, carbon stable isotope analyses were carried out on a set of modern and fossil resins of diverse origins and compound specific isotope analysis was used to characterise individual hydrocarbons in resin pyrolysates and oils derived from resinitic source matter. The results showed that "Class V' resinites derived from gymnosperms are enriched in the heavy carbon isotope compared with the angiosperm-derived "Class W' resinites. Furthermore, both the fossil resinites themselves and individual hydrocarbons derived from them are isotopically heavy compared with modern plant resins. The reasons for ++ / these differences and their implications for petroleum geochemical studies are discussed.
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Stable Carbon and Nitrogen Isotopic Studies of Devonian Land Plants -- An Indicator of Paleoclimate and Paleoenvironmental ChangesWan, Zhenzhu 16 October 2012 (has links)
No description available.
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Depth Profiles of Radiocarbon and Carbon Isotopic Compositions of Organic Matter and CO_2 in a Japanese Forest Area((2)Summaries of Research Using AMS)劉, 衛, LIU, Wei, 森泉, 純, MORIIZUMI, Jun, 山澤, 弘実, YAMAZAWA, Hiromi, 飯田, 孝夫, IIDA, Takao 03 1900 (has links)
タンデトロン加速器質量分析計業績報告 Summaries of Researches Using AMS 2005 (平成17)年度
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[en] RECONSTRUCTION OF PALEOENVIRONMENTS OF THE LATE QUATERNARY OF AMAZON AND NORTHEAST OF BRAZIL FROM THE MARINE CORE GEOB16202-2 USING AS PROXIES THE MOLECULAR DISTRIBUTION AND ISOTOPIC COMPOSITION (D13C AND DD) OF LONG-CHAIN N-ALKANES AND FATTY ACIDS / [pt] RECONSTRUÇÃO DE PALEOAMBIENTES DO QUATERNÁRIO TARDIO DA AMAZONIA E DO NORDESTE DO BRASIL A PARTIR DO TESTEMUNHO MARINHO GEOB16202-2 USANDO COMO INDICADORES A DISTRIBUIÇÃO MOLECULAR E COMPOSIÇÃO ISOTÓPICA (D13C E DD) DE N-ALCANOS E ÁCIDOS GRAXOS DE CADEIA LONGA25 January 2022 (has links)
[pt] A distribuição molecular e as composições isotópicas estáveis (d13C, dD) de n-alcanos e ácidos graxos saturados foram investigadas em um testemunho sedimentar marinho (GeoB16202-1, 773cm) coletado na bacia do rio Parnaíba para determinar as fontes da matéria orgânica terrestre depositada durante os últimos 23000 anos. As composições isotópicas de carbono dos n-alcanos e ácidos graxos foram consideradas para inferir mudanças na vegetação de acordo com a variabilidade climática, enquanto as composições de hidrogênio forneceram informações sobre eventos milenares na hidrologia regional e sua relação com as forçantes climáticas globais. Os n-alcanos de cadeia longa (n-Nonacosano C29 e n-Hentriacontano C31) e os ácidos graxos saturados C26 (ácido hexacosanoico) e (ácido montânico) C28 foram os compostos mais abundantes determinados, sugerindo contribuições importantes de material de origem terrestre. Os valores mais negativos de d13C para C29 e C31 (-27,3 a -33,2 % VPDB – Vienna Pee Dee Belemnite) indicam uma predominância geral de vegetação C3 ao longo do testemunho. A composição isotópica de carbono dos ácidos graxos de cadeia longa (d13C de -27,3 e -34,5 % VPDB) variou em uma faixa semelhante e exibiu uma distribuição altamente correlacionada com os alcanos de cadeia longa, o que sugere uma origem comum e confirma o uso do d13C de ácidos graxos como indicador de paleovegetação. O dD dos n-alcanos de cadeia longa (-115 a -159 % SMOW – Standard Mean Ocean Water) variou em uma faixa mais positiva do que a composição dos ácidos graxos (-123 e -163 % SMOW) e ambos os sinais apresentam correlação positiva. O d13C de n-alcanos de cadeia longa e ácidos graxos sugere a expansão de plantas C3 e o dD sugere maior precipitação durante os eventos Heinrich Stadial1 (HS1) e Younger Dryas (YD), o que é consistente com estudos prévios que atribuem um regime de chuvas mais intenso no Nordeste do Brasil durante esses períodos. A distribuição molecular e a composição isotópica (d13C e dD) do ácido palmítico C16 revelam que os ácidos graxos de cadeia curta são provenientes de uma combinação de material ressintetizado e / ou uma mistura de matéria orgânica marinha / terrestre, enquanto os ácidos graxos C26 e C28 originam-se de plantas terrestres. A menor correlação entre o dD dos ácidos graxos e dD dos n-alcanos sugere que a assinatura isotópica de hidrogênio de ambos os grupos de compostos é afetada por diferentes processos que precisam ser investigados mais profundamente. / [en] Molecular distribution and stable isotopic compositions (d13C, dD) of n-alkanes and saturated fatty acids were investigated in a marine sediment core (GeoB16202-1, 773cm) collected in Parnaíba river basin to determine the sources of terrestrial organic matter deposited during the last 23000 years. The carbon isotopic compositions of n-alkanes and fatty acids were considered to infer vegetation changes according with climatic variations, while the hydrogen compositions provided information about millenary events in regional hydrology and its relationship with the global climate forcings. Long-chain n-alkanes (n-Nonacosane C29 and n-Hentriacontane C31) and saturated fatty acids C26 (hexacosanoic acid) and C28 (montanic acid) were the most abundant compounds determined, suggesting important contributions from terrestrial sources. The most negative values of d13C for C29 and C31 (-27.3 to -33.2 % VPDB – Vienna Pee Dee Belemnite) indicate a general predominance of C3 vegetation along the core. The carbon isotopic composition of the long-chain fatty acids (d13C of -27.3 and -34.5 % VPDB) varied in a similar range and exhibited a distribution highly correlated with the long-chain n-alkanes, which suggests a common origin and confirms the use of d13C from fatty acids as a paleovegetation proxy. The dD of the long-chain n-alkanes (-115 to -159 % SMOW– Standard Mean Ocean Water) varied in a more positive range than the composition of the fatty acids (-123 and -163 % SMOW) and both signs were positively correlated. The d13C of long-chain n-alkanes and fatty acids suggests expansion of C3 plants and the dD suggests greater precipitation during the Heinrich Stadial1 (HS1) and Younger Dryas (YD) events, which is consistent with previous studies that attribute a regime of more intense rainfall in Northeast of Brazil during these periods. Molecular distribution and isotopic compositions (d13C and dD) of palmitic acid (C16 ) reveal that the short-chain fatty acids correspond a combination of resynthesized material and/or a mixture of marine/terrestrial organic matter, while terrestrial plants are the principal sources of the fatty acids C26 and C28. The lower correlation between dD of fatty acids and dD of n-alkanes suggests that the hydrogen isotope signature of both groups of compounds is affected by different processes that need to be further investigated.
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