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Thesis (M.S. in environmental engineering)--Washington State University, May 2009. / Title from PDF title page (viewed on May 14, 2009). "Department of Civil and Environmental Engineering." Includes bibliographical references (p. 71-74).

Thesis (Ph. D.)--Civil and Environmental Engineering, Georgia Institute of Technology, 2006. / Dr. Jennifer Michaels, Committee Member ; Dr. Jacek Jarzynski, Committee Member ; Dr. Jianmin Qu, Committee Member ; Dr. Laurence J. Jacobs, Committee Chair ; Dr. Kimberly E. Kurtis, Committee Co-Chair.

Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references (leaves 506-525). Available also in a digital version from Dissertation Abstracts.

The City of Saskatoon is responsible for maintaining approximately 1,100 km of roads including locals, collectors, arterials, and freeways. With the aged state of the road infrastructure, increasing budget constraints limit the City’s ability to maintain existing road infrastructure to an acceptable level of service and to construct new road infrastructure. The infrastructure demands related to urban growth within the City of Saskatoon have caused a shrinking aggregate supply and increasing aggregate demand. In turn, growing demand and dwindling resources for aggregate are resulting in rapid increases to road construction costs. Aggregate sources are a non-renewable resource in Saskatchewan. Therefore, road designers do not have an endless supply of quality aggregates. With limitations of the road building industry and the foreseeable economic growth projected for the City of Saskatoon, it is reasonable to expect that the unit costs of providing conventional pavement structures will continue to increase in Saskatoon. Presently, the primary conventional road building materials include well graded granular base material, subbase, crushed rock and a wearing surface of either conventional hot mix asphalt concrete (HMAC) or Portland cement concrete (PCC). To ensure long term pavement performance, quality aggregate sources are needed in all road design structural layers. Recent years have seen an increased need for substructure drainage systems, therefore increasing the need for high quality crushed rock. City of Saskatoon, like other urban centers, generates significant stock piles of concrete rubble annually. The primary objective of this research was to compare PCC material properties to those of conventional granular materials under realistic field state conditions. The second objective of this research was to validate the economic feasibility of using recycled PCC material within City of Saskatoon road structure through test section design and field test sections’ structural performance. Conventional and mechanistic material characterization was completed for recycled PCC well graded base course and recycled PCC drainage rock derived from PCC rubble, as well as conventional City granular base and drainage rock aggregates from typical City of Saskatoon stockpiles. Conventional testing completed on the samples included physical properties as required by COS aggregate specifications. Micro-Deval testing was also completed to compare the mechanical breakdown of the aggregates tested. Based on the results of the conventional tests performed, the recycled PCC well graded base and the recycled PCC drainage rock were found to meet COS base and drainage rock specifications, respectively. The recycled PCC well graded base material, recycled PCC drainage rock, COS granular base, and recycled PCC well graded base stabilized with different percentages of cement and slow setting type one (SS-1) asphalt emulsion were the research materials mechanistically tested. These materials were mechanistically tested using triaxial frequency sweep characterization to derive the mechanistic material constitutive relations across all the materials. Five repeat samples were gyratory compacted and tested at room temperature using the rapid triaxial testing. To characterize climatic durability, all the samples were moist cured for 28 days, characterized using the rapid triaxial test; then vacuum saturated and then characterized again using the rapid triaxial test. The mechanistic properties measured for the PCC material showed better climatic durability compared to those measured for the virgin aggregates, particularly after climatic durability testing. Prior to vacuum saturation, the conventional COS granular base had a peak dynamic modulus of 457 MPa. Under the same testing conditions, recycled PCC well graded base unstabilized had a stiffness of 1081 MPa; the stabilized PCC samples with two percent cement had a dynamic modulus of 1542 MPa. The radial micro strain and Poisson’s ratio were reduced for well graded PCC materials both unstabilized and stabilized compared to the conventional COS granular base. The conventional granular base had a peak radial micro strain of 194 compared to the untreated recycled PCC well graded base peak radial micro strain of 54 at the same testing parameters of low stress state at a testing frequency of 10 Hz prior to vacuum saturation. The conventional COS granular base samples failed under high deviatoric stress state at a 0.5 Hz testing frequency prior to vacuum saturation, whereas the PCC materials survived all testing frequencies and stress states. However, after vacuum saturation, the unstabilized recycled PCC well graded base samples failed under high stress state under a 10 Hz testing frequency. To validate field structural performance, two road structures within the City of Saskatoon were used as test sections in which recycled PCC drainage rock was used as a structural drainage layer. The first test section was constructed in the east bound lane of Marquis Drive, and the second was completed at the University of Saskatchewan. Prior to construction of both the Marquis Drive and North Road test sections, both sections were tested for peak surface deflections using the heavy weight deflectometer. Segment 1 of Marquis Drive had an average pre construction surface deflection of 1.85 mm under a primary weight limit. Section 1 of North Road had an average pre construction surface deflection of 1.17 mm under primary weight limit. After construction was complete on both test sections using recycled materials including a PCC drainage layer, HWD testing showed post construction peak deflections were significantly lower than the deflections measured pre construction. Recycled PCC well graded base material performed well in mechanistic laboratory analysis. However, the material was not field tested in this research. Mechanistic laboratory and field analysis indicated that recycled PCC drainage rock aggregates met structural performance requirements. The capital cost analysis showed that using recycled PCC drainage rock can reduce the overall cost of road rehabilitation projects when compared to using conventional virgin aggregates, particularly crushed drainage rock. The Marquis Drive section had a cost savings of $89,000, and the University of Saskatchewan section had a cost savings of $75,800 when recycled materials were used in lieu of virgin aggregates to rehabilitate the pavement structure. In addition, no PCC was disposed of in the landfill, saving the City of Saskatoon tipping fees and extending the life of the landfill. This research showed that the crushed PCC rubble is both technically and economically feasible to use as high quality aggregates in City of Saskatoon streets. Based on the findings of this research, the City of Saskatoon should pursue the use of recycled PCC rubble aggregates in urban road construction.

Thesis (Ph. D.)--University of Texas at Austin, 2008. / Vita. Includes bibliographical references.

The global warming has increased with unprecedented levels during the last couple of decades and the trend is uprising. The construction industry is responsible for nearly 10% of all carbon emissions, mainly due to the increasing global population and the large demand for housing and civil infrastructure. Concrete, which is the most used construction material worldwide, is found in every type of building as it provides long term structural stability, support and its main constituent cement, is very cheap. Consequently, due to the raising concerns of high average temperatures, the research community started investigating new, innovative methods for substituting cement with 'greener' materials whilst at the same time improving the intrinsic properties of concrete. However, the manufacturing complications and logistics of these materials make them unfavourable for industrial applications. A novel and truly revolutionary method of enhancing the performance of concrete, thus allowing for decreased consumption of raw materials, lies in nanoengineering the cement crystals responsible for the development of all mechanical properties of concrete. Graphene, a two-dimensional sheet of carbon atoms arranged in a hexagonal lattice, is the most promising nanomaterial for composites' reinforcement to this date, due to it's exceptional strength, ability to retain original shape after strain, water impermeability properties and non-hazardous large scale manufacturing techniques. I chose to investigate the addition of liquid-phase exfoliated graphene suspensions for concrete reinforcement, aiming to improve the fundamental mechanical properties of the construction material and therefore allowing the industry to design buildings using less volume of base materials. First, the method of liquid exfoliation of graphene was developed and the resulting water suspensions were fully characterised by Raman spectroscopy. Then, concrete samples were prepared according to British standards for construction and tested for various properties such as compressive and flexural strength, cyclic loading, water impermeability and heat transport. A separate, in-depth, study was carried out to understand the formation and propagation of micro-structural cracks between the concrete's internal matrix planes, and graphene's impact on total fracture capacity and resistance of concrete. Lastly, multiple experiments were performed to investigate the microcrystallinity of cement hydration products using X-Ray diffraction. In general, all experimental results show a consistent improvement in concrete's performance when enhanced with graphene on the nanoscale level. The nanomaterial improves the mechanical interlocking of cement crystal, thus strengthening the internal bonds of the composite matrix. This cheap and highly scalable method for producing and mixing graphene with concrete turns it into the first truly applicable method for industrial applications, with a real potential to have positive impact on the global warming by decreasing the production of concrete.

With the pressure on the construction industry to lower CO2 emissions it has become increasingly important to utilise materials that supplement Portland cement (CEM I) in concrete. These include additions such as ground granulated blast-furnace slag (GGBS) and fly ash, which have found greater use due to the benefits they provide to many properties of the material (in addition to environmental impact). While studies have investigated these materials in binary blends with CEM I, little work has examined the effect of combining materials in ternary blend concretes. A wide-ranging study was, therefore, set up to examine this for the range of more commonly available additions. This thesis reports on research carried out to investigate the effects of cement combinations based on CEM I / GGBS with either fly ash or limestone. The experimental programme investigated these materials in both paste and concrete and covered fresh properties, compressive strength, permeation and durability properties (using standard water curing for the latter three) and considered, for the hardened properties, how these may be balanced with environmental cost. The mixes covered a range of w/c ratios (0.35. 0.50 and 0.65), which was the main basis of comparison, and combinations of CEM I with GGBS (at levels of 35%, 55% and 75%), and fly ash and LS part-replacing this (at levels of 10 to 20 % and 10 to 35% respectively), after consideration of the relevant standards and related research. The initial phase of the study examined the characteristics of the materials, which indicated that they conformed to appropriate standards and were typical of those used in the application. Studies with cement paste (0.35 and 0.50 w/c ratio) indicated that there were reductions in water demand with the use of addition materials (binary and ternary) compared to CEM I. The setting times of the cement pastes were also affected, generally increasing with GGBS level for the binary mixes, although the effect was influenced by w/c ratio. Whilst fly ash and limestone delayed setting at the higher w/c ratio, the opposite occurred as this reduced, compared to the binary mixes. It was also found that the yield stress increased with GGBS level and further with the addition of ternary materials (particularly limestone) compared to CEM I. The superplastiser (SP) dosage requirement in concrete was found to decrease with increasing w/c ratio, and ternary additions reduced this compared to binary and CEM I concrete with the effect most noticeable at low w/c ratio. Early strength development was less than CEM I for binary concretes and differences increased with GGBS level. Improvements with the introduction of fly ash compared to the binary concretes were noted with increasing GGBS levels and w/c ratio. In general, the addition of LS gave reduced early strength for all concretes. Although at the 35% GGBS level binary concretes achieved similar strength to those of CEM I, the others generally gave reductions at all ages to 180 days, with differences increasing with GGBS level. However, with increasing w/c ratio and GGBS level improved strength development of ternary concretes, was noted compared to those of CEM I from 28 days. Permeation (absorption (initial surface absorption and sorptivity) and permeability (water penetration and air permeability)) and durability properties (accelerated carbonation and chloride ingress) of the test concrete were also investigated. At 28 days, for low GGBS levels, the binary concretes gave reduced absorption properties compared to CEM I, while the reverse occurred at high level. The effect of the ternary concretes gave further improvements at the lower GGBS levels and with increasing w/c ratio and curing time compared to CEM I. At the higher GGBS level the effect of the ternary additions was less noticeable but, in the case of limestone, improvements were still seen with increasing w/c ratio compared to CEM I. Similar effects were noted for the sorptivity results. The air permeability results gave higher values at 28 days for the binary and ternary concretes compared to CEM I, but significant improvements in the long-term at the lower GGBS level across the range of w/c ratios compared to CEM I concrete. Similar trends were found with water penetration tests. Accelerated carbonation increased with GGBS level for binary concretes compared to CEM I. These differences increased further with the introduction of fly ash and LS, particularly the former. In contrast rapid chloride tests indicated improvements with increasing GGBS levels compared to CEM I and further benefits with the inclusion of fly ash and limestone. Embodied CO2 (ECO2) was calculated based on published British Cement Association (BCA) values for each component of the mix and was shown to reduce with increasing w/c ratio and addition level in concrete. For concrete of an equal strength of 40N/mm2 the ECO2 could be almost halved (reduced from 343 kg/m3 for the CEM I to 176 kg/m3) for the ternary concretes at higher GGBS levels. These combination concretes also gave enhanced durability with regard to chloride ingress and at the lower w/c ratio comparable properties to CEM I in the case of carbonation. Overall, the results suggest that there is potential for ternary concretes to be used in the concrete industry given their ability to reduce ECO2, without compromising strength, permeation and durability properties of concrete.

Thesis (MEngSc)--University of Melbourne, Dept. of Chemical and Biomolecular Engineering, 2010. / Typescript. Includes bibliographical references (p. 105-110)

The work is focused on the possible use of secondary raw materials of the energy industry in the construction industry, particularly in concrete applications, where as the main raw material of the binder composition are used solid fluidized bed combustion residues - filter and ground. The aim of this work is to prepare concrete or concretes based on solid residues from fluidized bed combustion, that will fulfill or at least approximately approach by their parameters to commonly used concretes based on portland cement. The experimental part is divided into several chapters, at first the results of analyzes of feedstock and solid residues from fluidized bed combustion, portland cement and calcium hydroxide. Other chapters describe proposals for alternative binders, concrete, characterization and testing. Mainly were observed changing properties of the prepared concretes by changing the ratio of binders and aggregates. In tests were evaluated mainly mechanical properties and phase composition.