Anomalias biogeoquímicas expressivas têm sido reconhecidas em rochas marinhas neoproterozoicas depositadas em todos os continentes, não havendo similares ao longo do Fanerozoico. O interesse nesta Era aumentou nos últimos anos, especialmente em relação ao Ediacarano, período que precede a grande Explosão de Vida Cambriana e que abriga os primeiros organismos macroscópicos, conhecidos como Fauna de Ediacara. Assim, o entendimento das condições paleoambientais e paleoclimáticas, bem como o estabelecimento da cronologia dos eventos, é fundamental no entendimento da evolução da biota no planeta durante este período. As rochas da Faixa Paraguai Norte, na região de estudo, registram a ocorrência de duas glaciações, uma criogeniana e outra ediacarana (formações Puga e Serra Azul), separadas por uma espessa plataforma carbonática (Grupo Araras), que registra anomalias biogeoquímicas na água do mar ediacarano. Estas rochas foram depositadas na margem sudeste do Craton Amazônico, no intervalo de tempo entre a quebra do paleocontinente Rodínia e a colagem do Gondwana. O presente trabalho é apresentado na forma de artigos e apresenta estudos de: i) quimioestratigrafia isotópica (C, O, S e Sr) de detalhe nos carbonatos do Grupo Araras e da Formação Serra Azul; ii) proveniência (Sm-Nd) das rochas terrígenas das formações Puga e Serra Azul, bem como da base da Formação Raizama; e iii) geocronologia (Pb-Pb em carbonatos e K-Ar em clastos vulcânicos) da Formação Serra Azul. Os valores de \'delta\'\'POT.13 C\' evidenciaram duas anomalias negativas (ca. - 6%o) pósglaciais e um gradiente de até 2,5%o ao longo da bacia, no período interglacial. As razões \'ANTPOT.87 Sr\'/\'ANTPOT.86 Sr\' (entre 0.7074 e 0.7087) mostraram uma evolução coerente com a esperada para o oceano ediacarano. Os valores de \'delta\'\'POT.34 S\' obtidos nos sulfatos-traços dos carbonatos variaram de 22 a 61, enquanto que nas piritas variaram de 11 a 43%o, sendo os mais pesados já registrados no tempo geológico (acima de 48%o e 30%o, respectivamente). As idades modelo (\'T IND.DM\') Sm-Nd obtidas em rochas terrígenas das formações Puga, Serra Azul e Raizama encontram-se entre 1,6 e 2,2 Ga, mostrando contribuição variável, ao longo da seção, com predomínio de fontes localizadas a norte e a leste da bacia precursora da Faixa Paraguai. As idades K-Ar obtidas em clastos vulcânicos recuperados da Formação Serra Azul variaram de 730 a 1167 Ma, evidenciando uma fonte jovem, distinta do esperado para o Cráton Amazônico. A idade isocrônica Pb-Pb de 596 ± 26 Ma determinada em carbonatos da Formação Serra Azul corrobora sua correlação com a Glaciação Gaskiers, datada em 580 Ma. / Expressive biogeochemical anomalies have been recognized in Neoproterozoic marine rocks deposited worldwide, with no similar record throughout the Phanerozoic. The interest in this Era have been increased, especially on the Ediacaran time, the period that precedes the great CambrianLife Explosion, and houses the first macroscopic organisms, which are known as the Ediacaran Fauna. Thus, the understanding of paleoclimatic and paleoenvironmental conditions, associated with the establishment of the chronology of the events is crucial in the understanding the evolution of biota on the planet during this period. The rocks of northern Paraguay Belt in the study area record the occurrence of two glaciations, where one is Cryogenian and another is Ediacaran (Puga and Serra Azul formations). These glacial deposits are separated by a thick carbonate platform (Araras Group), which records biogeochemical anomalies in the Ediacaran seawater. These rocks were deposited in the southeastern margin of the Amazonian Craton, in the time interval between the breakup of the Rodinia Paleocontinent and the assemblage of the Gondwana. This work is composed by five articles, whose study scopes are: i) detailed isotope chemostratigraphy (C, O, S and Sr) in carbonates from the Araras Group and the Serra Azul Formation; ii) provenance (Sm-Nd) of the siliclastic rocks from the Puga and the Serra Azul Formations and the base of the Raizama Formation; and iii) geochronology (Pb-Pb in carbonate and K-Ar in volcanic clasts) from the Serra Azul Formation. The \'delta\'\'POT.13 C\' values showed two post-glacial negative anomalies (ca. - 6%o) and a gradient of up to 2.5%o along the basin, during interglacial period. The obtained \'ANTPOT.87 Sr\'/\'ANTPOT.86 Sr\' ratios (between 0.7074 and 0.7087) showed a consistent trend with that expected for the Ediacaran sea water. The trace sulfate extracted from obtained carbonates yielded \'delta\'\'POT.34 S\' values from 22 to 61%o, whereas the pyrites ranged between 11 and 43%o. These \'delta\'\'POT.34 S\' values are the heaviest ever recorded in geologic time (above 48 and 30, respectively). The Sm-Nd model ages (\'T IND.DM\') obtained from siliciclastic rocks from Puga, Serra Azul and Raizama formations range from 1.6 to 2.2 Ga, and indicate a variable contribution along the section, with predominant sources coming from areas at north and east of the precursor basin. Recovered volcanic clasts from the Serra Azul Formation yielded K-Ar ages between 730 and 1167 Ma, revealing a non expected young source for areas on the Amazon Craton. The Pb-Pb isochron age of 596 ± 26 Ma was determined in carbonates from the Serra Azul Formation and corroborates its correlation with Gaskiers Glaciation which was dated at 580 Ma.

The Late Paleozoic Ice Age represents a dynamic period in Earth system history recording a shift from icehouse to greenhouse conditions. Concomitant with this change was a series high-frequency, high-amplitude sea level fluctuations leading to the deposition of “Kansas type” cyclothems in the Mid-Continent, and a similar rhythmic expression of interbedded shales and carbonates in the Midland Basin. Stable isotope geochemistry is a particularly powerful tool when examining these mud-rich successions because changes in organic matter partitioning may be recorded first in δ13CDIC of sea-water and consequently in δ13Ccarb of marine rocks. The δ13Ccarb record may also illuminate early and late-stage diagenetic processes and associated destruction of organic matter. This study used high-resolution x-ray fluorescence (XRF) and δ13Ccarb measurements to analyze paleo-environmental conditions in two cores within the Midland Basin Wolfcamp Formation. Using this approach, the combination of more positive δ13Ccarb measurements and enrichment of redox-sensitive elements reflect conditions more favorable for organic matter enrichment in the distal core. Additionally, four (< 6 in.) early-diagenetic intervals have been identified representing prolonged periods of reduced or non-deposition based on sharp negative δ13Ccarb excursions. These horizons are proposed as potential chronostratigraphic tie-points between the two core localities.

The Lower to Middle Ordovician Garden City Formation and Pogonip Group are coeval successions of mixed carbonate and siliciclastic rocks deposited under normal marine conditions on a shallow carbonate ramp on the western margin of Laurentia. The Garden City Formation was deposited in the Northern Utah Basin and the Pogonip Group was deposited in the Ibex Basin. These two basins experienced different rates of thermal subsidence following Neoproterozoic rifting along the western margin of Laurentia resulting in significant thickness differences between rock units and varying lithologic expressions of eustatic change. This study provides a unique opportunity to examine the lithologic, geochemical, and paleontological responses to eustatic oscillations of two coeval sedimentary basins in Utah that formed under different tectonic settings and subsidence rates. The Garden City Formation is composed of fourteen lithotypes and the Pogonip Group is composed of eleven lithotypes. These lithotypes mainly represent depositional environments ranging from inner ramp and middle ramp with minor outer ramp deposits. Many lithologies appear to be storm influenced due to the presence of abundant rip-up clasts (intraclasts), fragmented bioclasts, and occasional mega-ripples. Other lithologies have been extensively bioturbated and burrowed. Nine stratigraphic sequences have previously been identified within the Pogonip Group. Eight equivalent, albeit compressed, sequences within the Garden City Formation were located using biostratigraphic and chemostratigraphic correlations, and increases in insoluble residues often found at the bases of sequence boundaries. Sequences are expressed as deepening-upward packages containing silty/sandy lowstand deposits that transition into wackestones and lime mudstone-rich highstand deposits. Several sequence boundaries appear to coincide with conodont and/or trilobite extinction events. Important sequence boundaries mark the Sauk III-m and Sauk IV-m transition and the Ibexian- Whiterockian Series boundary. Meter-scale cycles are common and likely related to Milankovitch cyclicity. Insoluble residue increases upsection at each location which may indicate a gradual overall drop in sea level due to the onset of the regressive upper portion of the Sauk III supersequence. Insoluble residue from the Pogonip Group ranges from 1.2 to 84.7 wt. % with an average of 16.0 wt. % ± 0.7 wt. %. Insoluble residue from the Garden City Formation ranges from 1.5 to 63.8 wt. % with an average of 13.4 wt. % ± 1.0 wt. %. New stable carbon isotope data (δ13C) from the Garden City Formation and the Pogonip Group range from -2.92 to 1.23 ‰ V-PDB and -2.19 to 0.56 ‰ V-PDB, respectively. Four distinct δ13C trends are recognized in both sections: 1) a drop in δ13C from positive values between 0.2-1.0 ‰ to negative values approaching -1.0 ‰ near the base of the Ordovician, 2) a 0.5 to 1.0 ‰ positive δ13C excursion near the top of the Rossodus manitouensis Zone, 3) a drop in δ13C values to near -2.0 ‰ through most of the Acodus deltatus –Oneotodus costatus Zone, and 4) a gradual increase in δ13C from - 2.0 ‰ to -1.0 ‰ throughout the remainder of the sections. δ13C of the Garden City Formation and the Pogonip Group appear to be correlative based on these distinct trends. This correlative relationship was verified by the lowest occurrence of conodont species Scolopodus filosus and Scalpellodus n. sp. A of the Low Diversity Interval which coincides with the positive δ13C excursion in both the Garden City Formation and the Pogonip Group. New δ13C data likely represent global primary seawater chemistry based on the correlation of similar δ13C trends from the Argentine Precordillera and western Newfoundland.

The first Isaac carbonate (FIC) is a mixed siliciclastic-carbonate base-of-slope succession in the Neoproterozoic Windermere Supergroup (WSG). Outstanding outcrop exposure at three study areas provided an excellent opportunity to observe the stratigraphic and isotopic evolution of an ancient deepwater mixed turbidite system. Based on lithological and stratal dimensions, the FIC can be subdivided into lower and upper parts suggesting temporal changes in patterns of sediment transport and deposition. δ13Ccarb also changes from -5.2‰ at the base of the FIC to 2.5‰ in the middle and then decreases to -6.3‰ at the top. Notably, the δ13Ccarb of primary cement in FIC strata is substantially more positive than most other Neoproterozoic deep-marine sections, suggesting the retention of their original shallow-marine isotopic signature. Nevertheless, this trend potentially correlates with the EN2 excursion in China and therefore the Gaskiers glaciation (~580 Ma), although better age control of WSG is needed to corroborate this correlation.

Anomalias biogeoquímicas expressivas têm sido reconhecidas em rochas marinhas neoproterozoicas depositadas em todos os continentes, não havendo similares ao longo do Fanerozoico. O interesse nesta Era aumentou nos últimos anos, especialmente em relação ao Ediacarano, período que precede a grande Explosão de Vida Cambriana e que abriga os primeiros organismos macroscópicos, conhecidos como Fauna de Ediacara. Assim, o entendimento das condições paleoambientais e paleoclimáticas, bem como o estabelecimento da cronologia dos eventos, é fundamental no entendimento da evolução da biota no planeta durante este período. As rochas da Faixa Paraguai Norte, na região de estudo, registram a ocorrência de duas glaciações, uma criogeniana e outra ediacarana (formações Puga e Serra Azul), separadas por uma espessa plataforma carbonática (Grupo Araras), que registra anomalias biogeoquímicas na água do mar ediacarano. Estas rochas foram depositadas na margem sudeste do Craton Amazônico, no intervalo de tempo entre a quebra do paleocontinente Rodínia e a colagem do Gondwana. O presente trabalho é apresentado na forma de artigos e apresenta estudos de: i) quimioestratigrafia isotópica (C, O, S e Sr) de detalhe nos carbonatos do Grupo Araras e da Formação Serra Azul; ii) proveniência (Sm-Nd) das rochas terrígenas das formações Puga e Serra Azul, bem como da base da Formação Raizama; e iii) geocronologia (Pb-Pb em carbonatos e K-Ar em clastos vulcânicos) da Formação Serra Azul. Os valores de \'delta\'\'POT.13 C\' evidenciaram duas anomalias negativas (ca. - 6%o) pósglaciais e um gradiente de até 2,5%o ao longo da bacia, no período interglacial. As razões \'ANTPOT.87 Sr\'/\'ANTPOT.86 Sr\' (entre 0.7074 e 0.7087) mostraram uma evolução coerente com a esperada para o oceano ediacarano. Os valores de \'delta\'\'POT.34 S\' obtidos nos sulfatos-traços dos carbonatos variaram de 22 a 61, enquanto que nas piritas variaram de 11 a 43%o, sendo os mais pesados já registrados no tempo geológico (acima de 48%o e 30%o, respectivamente). As idades modelo (\'T IND.DM\') Sm-Nd obtidas em rochas terrígenas das formações Puga, Serra Azul e Raizama encontram-se entre 1,6 e 2,2 Ga, mostrando contribuição variável, ao longo da seção, com predomínio de fontes localizadas a norte e a leste da bacia precursora da Faixa Paraguai. As idades K-Ar obtidas em clastos vulcânicos recuperados da Formação Serra Azul variaram de 730 a 1167 Ma, evidenciando uma fonte jovem, distinta do esperado para o Cráton Amazônico. A idade isocrônica Pb-Pb de 596 ± 26 Ma determinada em carbonatos da Formação Serra Azul corrobora sua correlação com a Glaciação Gaskiers, datada em 580 Ma. / Expressive biogeochemical anomalies have been recognized in Neoproterozoic marine rocks deposited worldwide, with no similar record throughout the Phanerozoic. The interest in this Era have been increased, especially on the Ediacaran time, the period that precedes the great CambrianLife Explosion, and houses the first macroscopic organisms, which are known as the Ediacaran Fauna. Thus, the understanding of paleoclimatic and paleoenvironmental conditions, associated with the establishment of the chronology of the events is crucial in the understanding the evolution of biota on the planet during this period. The rocks of northern Paraguay Belt in the study area record the occurrence of two glaciations, where one is Cryogenian and another is Ediacaran (Puga and Serra Azul formations). These glacial deposits are separated by a thick carbonate platform (Araras Group), which records biogeochemical anomalies in the Ediacaran seawater. These rocks were deposited in the southeastern margin of the Amazonian Craton, in the time interval between the breakup of the Rodinia Paleocontinent and the assemblage of the Gondwana. This work is composed by five articles, whose study scopes are: i) detailed isotope chemostratigraphy (C, O, S and Sr) in carbonates from the Araras Group and the Serra Azul Formation; ii) provenance (Sm-Nd) of the siliclastic rocks from the Puga and the Serra Azul Formations and the base of the Raizama Formation; and iii) geochronology (Pb-Pb in carbonate and K-Ar in volcanic clasts) from the Serra Azul Formation. The \'delta\'\'POT.13 C\' values showed two post-glacial negative anomalies (ca. - 6%o) and a gradient of up to 2.5%o along the basin, during interglacial period. The obtained \'ANTPOT.87 Sr\'/\'ANTPOT.86 Sr\' ratios (between 0.7074 and 0.7087) showed a consistent trend with that expected for the Ediacaran sea water. The trace sulfate extracted from obtained carbonates yielded \'delta\'\'POT.34 S\' values from 22 to 61%o, whereas the pyrites ranged between 11 and 43%o. These \'delta\'\'POT.34 S\' values are the heaviest ever recorded in geologic time (above 48 and 30, respectively). The Sm-Nd model ages (\'T IND.DM\') obtained from siliciclastic rocks from Puga, Serra Azul and Raizama formations range from 1.6 to 2.2 Ga, and indicate a variable contribution along the section, with predominant sources coming from areas at north and east of the precursor basin. Recovered volcanic clasts from the Serra Azul Formation yielded K-Ar ages between 730 and 1167 Ma, revealing a non expected young source for areas on the Amazon Craton. The Pb-Pb isochron age of 596 ± 26 Ma was determined in carbonates from the Serra Azul Formation and corroborates its correlation with Gaskiers Glaciation which was dated at 580 Ma.

O presente trabalho apresenta um estudo de quimioestratigrafia isotópica (C, O, Sr) de detalhe, realizado numa sucessão carbonática de idade ediacariana da porção extremo norte da Faixa Paraguai, Estado do Mato Grosso. A pesquisa se justifica já que durante o Neoproterozóico a Terra sofreu profundas mudanças climáticas, as quais foram registradas em enigmáticas sucessões compostas de depósitos glaciais recobertos por rochas carbonáticas de clima quente. Estudos recentes mostram que ocorreram, pelo menos, três glaciações neste período, denominadas Sturtiana (ca. 725 Ma), Marinoana (ca. 635 Ma) e Gaskierana (580 Ma). Na tentativa de estabelecer uma correlação global entre as sucessões depositadas neste período, os geopesquisadores têm usado diversas ferramentas, principalmente a quimioestratigrafia isotópica de C, O e Sr. Na região de estudo, ocorrem diamictitos da Formação Puga recobertos por rochas carbonáticas do Grupo Araras, sobre a qual se depositam os diamictitos e carbonatos da Formação Serra Azul, definida neste trabalho. A sucessão carbonática do Grupo Araras apresentou valores de d13C variando de ? 1,7? (base) a + 4? (topo) e razões 87Sr/86Sr entre 0,7075 (na base) e 0,7084 (no topo). Estes valores são semelhantes àqueles encontrados em outras sucessões carbonáticas Marinoanas. Os calcários da Formação Serra Azul apresentaram um valores de d13C entre ? 7,5% e ? 3,2% e razões 87Sr/86Sr de ca. 0,7086, típicas das sucessões carbonáticas Gaskieranas. Os resultados isotópicos obtidos neste trabalho, associados às evidências sedimentológicas, sugerem que na história geológica de deposição da Faixa Paraguai ocorreram, pelo menos, duas importantes glaciações. / This work presents a detailed isotopic (C, O, and Sr) chemostratigraphic study carried out on the Ediacaran carbonate succession from the northernmost part of the Paraguay Belt, in Mato Grosso, Brazil. The importance of this study is related to the Earth´s profound climate changes that took place during the Neoproterozoic, which have been recorded by enigmatic sequences composed of glacial deposits immediately overlain by carbonate rocks typical of warm climate. At least three glaciations are recognized: Sturtian (ca. 725 Ma), Marinoan (ca. 635 Ma), and Gaskiers (580 Ma). In order to correlate worldwide the successions deposited in this period and to understand the complex depositional environments, isotopic tools, especially chemostratigraphy, have been widely used. In the study area diamictites of the Puga Formation are overlain by carbonates of the Araras Group, and these, in turn, are covered by diamictites and carbonates of the Serra Azul Formation, which is defined here. The Araras Group carbonates exhibited d13C values between ? 1.7? at the base and + 4 ? at the top and 87Sr/86Sr ratios ranging from 0.7075 at the base to 0.7084 at the very top. These values are similar to those of post-glacial, non-cap Marinoan carbonate successions. The limestones of the Serra Azul Formation yielded d13C values between ? 7.5 and ? 3.2 ?, and 87Sr/86Sr ratios of ca. 0.7086, typical of post-Gaskiers cap carbonates. These isotopic results, together with sedimentological evidence, suggest that two important glaciations occurred during the depositional history of the northernmost Paraguay Belt.

The newest geochemical and sedimentological studies of the Libkovice Member in the Most Basin revealed existence of a sedimentary cyclicity that is controlled by the change of Earth's orbital parameters and the shape of its orbit. The main objective of this study is to verify the hypothesis whether there is also a similar cyclical record in strata underlying the Libkovice Member. This interval located in top of the Holešice Member consists of lacustrine sediments of a smaller extent represented by the so-called Břešťany Clays. The aim of the diploma thesis was a geochemical analysis of the concentration of selected elements measured by a mobile XRF device from the drilling cores in the stratigraphic interval between the roof of the Main Coal and the base of the Libkovice Member. Also made was a litological description of boreholes and sedimentary texture of selected clay samples. A mineralogical analysis was performed using the X-ray diffraction method. Usefulness of the XRF mobile device was proven especially for the heavier elements (e.g., Fe and Sr) and less for the lighter elements K and Ti. Nevertheless, it was possible to assign the analysed sediments to the already published chemostratigraphic subdivision of the Most Basin and to confirm its validity. The Břešťany Clays horizon was identified...

Cryptic trends in the trace element chemistry of Fe-Ti oxide minerals have been used to elucidate the magmatic processes responsible for the formation of Fe-Ti-V deposits in the Rivière Bell Complex layered mafic-ultramafic intrusion near Matagami, Quebec, Canada. Although metamorphism at greenschist-amphibolite facies conditions has modified the primary igneous compositions of magnetite and ilmenite, their Cr and V contents appear to have been unaffected. Chemostratigraphic variations of these elements in Fe-Ti oxides therefore remain valid tracers of magmatic differentiation, even in metamorphosed settings. Injections of compositionally evolved, Fe-Ti oxide-laden magma into a more primitive ferrogabbroic host are presumably responsible for sharp decreases in the Cr and V concentrations of Fe-Ti oxides that coincide with lithostratigraphic changes from predominantly disseminated gabbros to ultramafic sequences closely interlayered with massive oxides. These injections highlight the multistage magmatic history of the layered series of the Rivière Bell Complex and its vanadium ore horizons.

An important episode of carbon sequestration, Oceanic Anoxic Event 1a (OAE-1a), characterizes the Lower Aptian worldwide, and is mostly known from deeper-water settings. The present work of two Lower Aptian deposits, Madotz (N Spain) and Curití Quarry (Colombia), is a multiproxy study that includes fossil assemblages, microfacies, X-ray diffraction bulk and clay mineralogy, elemental analyses (major, minor, trace elements), Rock-Eval pyrolysis, biomarkers, inorganic and organic carbon content, and stable carbon isotopes. The results provide baseline evidence of the local and global controlling environmental factors influencing OAE-1a in shallow-water settings. The data also improve our general understanding of the conditions under which organic-carbon-rich deposits accumulate. The sequence at Madotz includes four intervals (Unit 1; Subunits 2a, 2b and 2c) that overlap the times prior to, during and after the occurrence of OAE-1a. The Lower Unit 1(3m thick) is essentially siliciclastic, and Subunit 2a (20m) contains Urgonian carbonate facies that document abruptly changing platform conditions prior to OAE-1a. Subunit 2b (24.4 m) is a mixed carbonate-siliciclastic facies with orbitolinid-rich levels that coincides with OAE-1a δ13C stages C4-C6, and is coeval with the upper part of the Deshayesites forbesi ammonite zone. Levels with pyrite and the highest TOC values (0.4-0.97%), interpreted as accumulating under suboxic conditions, and are restricted to δ13C stages C4 and C5. The best development of the suboxic facies is at the level representing the peak of the transgression. Subunit 2c, within δ13C stage C7, shows a return of the Urgonian facies. The 23.35-m section at Curití includes a 6.3-m interval at the base of the Paja Formation dominated by organic-rich marlstones and shales lacking benthic fossils and bioturbation, with TOC values as high as 8.84%. The interval overlies a level containing reworked and phosphatized assemblages of middle Barremian to lowest Aptian ammonites. The range of values and the overall pattern of the δ13Corg (-22.05‰ to -20.47‰) in the 6.3m-interval is comparable with Lower Aptian δ13C stage C7. Thus, conditions of oxygen depletion at this site also occurred after Oceanic Anoxic Event-1a, which developed between carbon isotope stages C3 and C6. Both sites, Madotz and Curití, attest to the importance of terrigenous and nutrient fluxes in increasing OM productivity that led to episodic oxygen deficiency.

No description available.