Este trabalho de mestrado tem como objetivo o desenvolvimento de uma arquitetura denominada PEESOS-Cloud para realização de experimentos em sistemas orientados a serviços capaz de verificar a carga de trabalho. Possíveis problemas durante a geração de carga em ambientes de experimentos foram identificados e sumarizados. Com base nesses problemas e limitandose às características dos sistemas distribuídos, dois módulos e um modelo para geração de carga foram desenvolvidos e associado à PEESOS-Cloud. Uma avaliação experimental foi realizada demonstrando a efetividade da proposta em atuar na avaliação de sistemas orientados a serviços. Para isso, cenários de experimentos foram definidos variando o ambiente de execução da arquitetura. Assim, o desempenho de uma aplicação sintética oferecida como serviço foi estudada e avaliada. Os resultados mostraram como a arquitetura proposta permite identificar a característica da carga de trabalho e verificar seu impacto sobre avaliação de um sistema alvo. Além disso, como uma carga de trabalho descaracterizada infere em uma avaliação de desempenho inconsistente. Por outro lado, como essa mesma carga de trabalho, sujeita a condições específicas, pode subsidiar uma avaliação de desempenho sólida. / This master thesis aims at developing an architecture called PEESOS-Cloud for conducting experiments in the service oriented systems capable of respecting the workload. Possible problems during the generation of load experiments environments were identified and summarized. Based on these problems and limited to the characteristics of distributed systems, two modules and a model for load generation were developed and associated with PEESOS-Cloud. An experimental evaluation was performed demonstrating the effectiveness of the proposal of acting in the evaluation of service-oriented systems. For this, experiments scenarios were defined by varying the architecture of execution environment. Thus, the performance of a synthetic application offered as a service has been studied and evaluated. The results showed how the proposed architecture allows us to identify the characteristics of the workload. In addition, uncharacterized workload can provide an inconsistent performance evaluation. On the other hand, as the same workload, subject to specific conditions, can support a solid performance evaluation.

Este trabalho de mestrado tem como objetivo o desenvolvimento de uma arquitetura denominada PEESOS-Cloud para realização de experimentos em sistemas orientados a serviços capaz de verificar a carga de trabalho. Possíveis problemas durante a geração de carga em ambientes de experimentos foram identificados e sumarizados. Com base nesses problemas e limitandose às características dos sistemas distribuídos, dois módulos e um modelo para geração de carga foram desenvolvidos e associado à PEESOS-Cloud. Uma avaliação experimental foi realizada demonstrando a efetividade da proposta em atuar na avaliação de sistemas orientados a serviços. Para isso, cenários de experimentos foram definidos variando o ambiente de execução da arquitetura. Assim, o desempenho de uma aplicação sintética oferecida como serviço foi estudada e avaliada. Os resultados mostraram como a arquitetura proposta permite identificar a característica da carga de trabalho e verificar seu impacto sobre avaliação de um sistema alvo. Além disso, como uma carga de trabalho descaracterizada infere em uma avaliação de desempenho inconsistente. Por outro lado, como essa mesma carga de trabalho, sujeita a condições específicas, pode subsidiar uma avaliação de desempenho sólida. / This master thesis aims at developing an architecture called PEESOS-Cloud for conducting experiments in the service oriented systems capable of respecting the workload. Possible problems during the generation of load experiments environments were identified and summarized. Based on these problems and limited to the characteristics of distributed systems, two modules and a model for load generation were developed and associated with PEESOS-Cloud. An experimental evaluation was performed demonstrating the effectiveness of the proposal of acting in the evaluation of service-oriented systems. For this, experiments scenarios were defined by varying the architecture of execution environment. Thus, the performance of a synthetic application offered as a service has been studied and evaluated. The results showed how the proposed architecture allows us to identify the characteristics of the workload. In addition, uncharacterized workload can provide an inconsistent performance evaluation. On the other hand, as the same workload, subject to specific conditions, can support a solid performance evaluation.

MENVSC / Department of Ecology and Resource Management / Some boreholes in South Africa which serve as a source of drinking water for rural communities are reported to have high fluoride concentration, much above the WHO guideline of 1.5 mg/L. This study aimed at activating aluminosilicate clay soil mechanochemically, modifying aluminosilicate clay soil with Al-oxide and fabricating porous ceramic granules using Al-oxide modified mechanochemically activated aluminosilicate clay soil/ mechanochemically activated clay soil/ corn starch and evaluating their performances in defluoridation of groundwater. The raw clay materials were mechanochemically activated for 5, 10, 15 and 30 minutes for physicochemical transformation of the solid aggregate. The morphology of the samples showed the honeycomb structure. The surface area analyses of samples using Brunauer–Emmett–Teller (BET) gave the highest surface area of 50.5228 m2/g at 30 min activation time. Hence, the optimum activation time was 30 min. The Fourier Transform Infrared (FT-IR) analysis showed increase in the absorbance of FT-IR by Si-O-H groups at 510 cm-1 with increasing milling time. This is evidence that more surface Si-O-H groups were available at higher particle surface area that would be necessary to interact with fluoride. X-ray diffraction (XRD) analyses revealed that, at 30 minutes milling time, the peak broadening is intensified whereas the reflection peak intensities decreased. The X-ray fluorescence spectrometry (XRF) results for 30 minutes milling time showed that silica and alumina were the highest components in the clay soil. Using the activated clay in batch defluoridation of fluoride-spiked water, a maximum fluoride removal of 41% was achieved at a pHe of 2.41. The initial fluoride concentration was 9 mg/L while the sorbent dosage was 0.6 g/100 mL and the contact time being 30 minutes. The adsorption data fitted to both Langmuir and Freundlich isotherms. The adsorption data fitted only the pseudo-second-order kinetic, showing chemisorption. Optimization of Al3+ concentration for modification was carried out by modifying the mechanochemical activated aluminosilicate clay soil with different concentrations of Al3+ from which the optimum modification was achieved with 1.5 M. Characterisation studies on the Al-oxide modified mechanochemically activated aluminosilicate clay soil by SEM, BET, FT-IR, XRD and XRF, analyses were carried out to determine the resultant changes in physicochemical properties of the adsorbent owing to modification. The SEM image of Al-oxide modified mechanochemically activated clay soil showed many small pores and honey-comb structure on the surface of different images. The BET surface area and the BDH adsorption cumulative area of the Al-oxide modified mechanochemically activated v aluminosilicate clay soil were more than double those for the raw clay soil. There was also an increase in pore volume of the Al-oxide modified mechanochemically activated aluminosilicate clay soil. The FT-IR spectra showed that there was increase in the absorbance by the Si-OH, H-O-H, Al-O-H and Si-O-Al. The equilibrium pH of solution was higher than the point-of-zero charge (pHpzc) implying that fluoride removal occurred at solution pH > pHpzc where the net surface charge of the mechanochemically activated clay aluminosilicate soil was negative.The efficiency of 1.5 M Al-oxide modified aluminosilicate clay soil to remove fluoride from water was studied and found to be 96.5 % at pHe 6.86, contact time of 30 minutes and dosage of 0.3 g/100 mL for 10 mg/L fluoride solution at 200 rpm shaking speed. The result shows that Al-oxide modified mechanochemically activated aluminosilicate clay soil is effective for defluoridation. The adsorption data fitted to both Langmuir and Freundlich isotherms. The adsorption data fitted only the pseudo-second-order kinetic, showing chemisorption. Al-oxide modified mechanochemically activated aluminosilicate clay soil was tested for fluoride removal on field water and the percentage fluoride removal was 96.5 % at the dosage of 0.6 g/100 mL with the pHe of 6.48. The optimum Al-oxide modified mechanochemically activated aluminosilicate clay soil/ mechanochemically activated clay soil/ corn starch mixing ratio for fabrication of porous ceramic granules was determined by varying ratios and temperature. The optimum ratio found was 20:5:1.The porous ceramic granules were characterised using SEM, BET, FT-IR, XRD and XRF. SEM analysis showed that the porous ceramic granules have the porous structure of the organic foam template. The porous ceramic granule showed an increase in pore surface area and volume as compared to mechanochemically activated aluminosilicate clay soil. The FT-IR showed the presence of a strong broad bending and stretching vibrations band at about 993 cm-1 which shows the presence of Si–O–Si bonds. Mineralogical characterisation showed the presence of quartz, albite, horneblende and microcline as the main minerals of the calcined porous ceramic granules. The major oxides of the porous ceramic granules as shown by XRF analysis were SiO2, Al2O3, MnO and Na2O. The porous ceramic granules reduced the concentrations of fluoride in the water from 10 to 3.31 mg/L. The optimum adsorption capacity was 0.6648 mg/g at a pHe of 6.32 and the percentage fluoride removal was 66.9 % at an adsorbent dosage of 1.0063 g/100 mL and a temperature of 600 ⁰C. The porous ceramic granules were tested for fluoride removal on field water and the percentage fluoride removal was 45.4 % at the dosage of 1.0009 g/100 mL with the pHe of 7.87. Mechanochemically activated aluminosilicate clay soil showed higher adsorption capacity at acidic pH, therefore it is recommended that future work should focus on improving their adsorption capacity at wider range of pH. The porous ceramic granules can also be evaluated in column dynamic flow experiments.