MESHWR / Department of Hydrology and Water Resources

M.Sc. (Geology) / Most rural communities in developing countries rely on borehole water as their only source of water. Since borehole water comes from underground, it is often considered pure and clean, but this is frequently not the case. Groundwater contains certain amounts of trace elements that may become deleterious to human health. The objectives of this investigation were to assess the concentration levels of Potential Harmful Trace Elements (PHTEs) and their spatial distribution patterns in borehole water in the Greater Giyani area of Limpopo, South Africa, and the potential human health risks associated with this. The method of research comprised two phases: (I) In the first phase, I assessed the occurrence and distribution patterns of PHTEs in the boreholes of the Giyani area. A total of 29 water samples were collected from boreholes (including 15 community boreholes and 14 primary school boreholes) in the Greater Giyani area during the dry season (July/August 2012), and for comparison another 27 samples (including 15 community boreholes and 12 schools boreholes) from the same localities during the wet season (March 2013). The samples were analysed for the trace elements arsenic (As), cadmium (Cd), chromium (Cr), selenium (Se) and lead (Pb) using the Inductively Coupled Plasma Mass-Spectrometry (ICPMS) technique. In order to assess the groundwater quality, PHTEs concentrations were compared with the South African National Standard of Drinking water (SANS 241-1:2011). (II) In the second phase, I evaluated the geographic variation between PHTEs and associated human health effects. This involved acquisition of data on a total of 100 cancer cases recorded during the period 2011-2014 at Nkhensani Hospital. ArcGIS Spatial analyst tool was used to create thematic maps illustrating spatial distribution of clinical data and arsenic concentrations in boreholes.

Thesis (M.Sc.(Geology)) -- University of Limpopo, 2022 / The Limpopo Province is largely underlain by crystalline basement rocks, which are characterised by low porosity and permeability. The climate in this province is arid to semi-arid, with scarce surface water for domestic and industrial use. As a result, groundwater is the prime source of fresh water supply for various uses. The complex geology, the impacts of climate change and man-made interactions with groundwater and surface water are the main threat to the availability of a sustainable source of fresh water in the province. In addition, despite substantial research efforts conducted by academic institutions and government organisations, there is still a gap in understanding quantitatively the dynamics of the hydrological systems in large parts of the Limpopo Province. The present study is therefore focused on the investigation of hydrological stresses that are applied to groundwater and surface water in one of the catchments situated in the Limpopo Province. In this study, a three-dimensional steady-state numerical model of groundwater flow was carried out at Mogalakwena Subcatchment, which is situated in the western sector of the Limpopo Province. The area is situated approximately 40 km northwest of Mokopane and 50 km west of Polokwane town. The research aims to understand the dynamics of the exchange between surface water and groundwater, and to assess the influences of these processes on the sustainability of water supply in the area. Hydrologically, the area falls within the boundaries of the Mogalakwena River Catchment, which forms part of the Limpopo River Basin. Previous studies suggest that there is a continuous decline in groundwater levels in the study area due to extensive use of groundwater for mining, irrigation, and domestic purposes. Furthermore, continued climate changes have altered the rainfall events during the last couple of decades, which consequently had an impact on groundwater recharge, quality, and availability. In addition, the complex geology of the area has an impact on the aquifers’ productivity resulting in variability in borehole yields throughout the study area. To achieve the aims of the research project, a three-dimensional steady-state numerical model of groundwater flow was implemented using MODFLOW NWT and ModelMuse v graphical user interface. The model domain covers an area of 5896 sq. km and was discretised with a grid cell size of 200 m by 200 m. The MODFLOW Packages used include DIS, UPW, RCH, EVT, WEL, GHB, RIV and UZF as well as the ZONEBUDGET. The conceptual model of groundwater flow consists of two layers, and it was developed based on drillhole logs, hydrochemical data, environmental isotopes, geological, digital terrain models, and other spatial data relevant for the conceptualisation of boundary conditions and hydrological stresses. The results of the steady-state simulation of groundwater flow show that recharge contributes 99.6% of inflow, followed by river leakage (0.36%) and GHB (0.08%). Among the outflow components, surface runoff takes the lion’s share (83.3%), followed by evapotranspiration (16.6%) and river leakage 0.02%. The zone budget was implemented to evaluate the interaction between surface water and groundwater by quantifying the amount of water that flows from one zone to the other. This was achieved by assigning zone numbers to the objects that represent boundary conditions (e.g., aquifer, river and dam). Zone 1, 2 and 3 were assigned to the aquifer, river and dam, respectively. The results indicate that the rivers gain more water than they supply to the aquifer. Similarly, the Glen Alpine Dam gain more water from the aquifer than it supplies to the aquifer. This implies that the interaction between surface water bodies such as rivers and dams have a significant impact on the aquifer, which consequently partly contributed to the shortage of water in the area. A predictive analysis of the aquifer’s response to an increase in abstraction rate, evapotranspiration rate and a decrease in recharge was carried out to investigate the future fate of water availability in the study area. The results suggest that as recharge decreases, the river inflow slightly increases to compensate for the declining water level due to the river stage exceeding the piezometric surface. In addition, the decrease in recharge rate is accompanied by a slight decrease in both surface runoff and evapotranspiration rate. Thus, a decline in recharge causes a significant drop in piezometric surface relative to the evapotranspiration extinction depth, which ultimately decreases the rate of evapotranspiration. Similarly, a decrease in recharge rate lowers the depth of the water level below the river stage, which consequently triggers water vi exchange from Mogalakwena River to the aquifer. In general, the water balance shows that as recharge decreases by 20% or more, the outflows exceed the inflows resulting in a continuous drop in water level, which may ultimately risk the availability of groundwater in the area. / Council for Geoscience (CGs)

MESHWR / Department of Hydrology and Water Resources / Siloam, a village in the Northern province of South Africa has groundwater reportedly characterised by concentration of fluoride greater than 1.5 mg/L permissible limit. Regional investigation has been done to determine the possible fluoride sources in the northern province of South Africa, but no localised investigation has been documented. The World Health Organization and South Africa National Standard permissible limit is 1.5 mg/L for a duration of time. Therefore, this study focuses on investigating the sources of fluoride in the groundwater of Siloam village in response to reported high incidences (80%) of dental fluorosis in Siloam village. This study also elaborates more on the hydrochemical and geochemical processes favouring the release of fluoride into the groundwater of Siloam village. Two (2) surface rocks, one (1) surface clay deposit, twelve (12) borehole cuttings and four (4) groundwater samples were used for this study. Temperature, total dissolved solids (TDS), conductivity (EC) and pH of the groundwater were determined using a combined multimeter because these parameters are proxy indicators of geogenic influence on groundwater fluoride concentration. Total fluoride in the groundwater samples and the leachates obtained during a leaching experiment were determined using Ion Chromatograph (IC) and Fluoride Ion Selective Electrode (FISE). X-ray fluorescence spectrometry is the most preferred method for rock analysis by earth scientists because it is faster and does not require ambiguous training on the part of the analyst, therefore, it is mostly the standard methods used in whole rock chemistry. Elemental composition and mineralogy were determined using X-ray Fluorescence (XRF) and X-ray diffraction (XRD), respectively. Clay, greywacke, argillaceous sedmients and basalt were analysed. Results obtained indicated that the groundwater fluoride concentration ranges from 3.92 to 4.95 mg/L, which are far above the WHO permissible limit and South African standard. Insitu temperature reading obtained ranges from 25 to 48°C thus classifying the groundwater to be hot and tepid. The groundwater pH ranges from 8.1 to 9.1 which indicates an alkaline water condition. The groundwater conductivity ranges from 330 to 730 μS/cm while the Total dissolved solids ranges from 130.12 to 423.07 mg/L. Groundwater proxy indicators showed geologic sources to be responsible for the high fluoride concentration in the groundwater of Siloam village. Hydrochemical investigation revealead that the mineralisation of groundwater in Siloam village is as a result of rock water interaction and the process of groundwater enrichment is through base ion exchange and reverse ion exchange. The dominant water type in the village was identified to be Na-Cl water type and the abundance of sodium (Na) is due to the heavy weathering of plagioclase of the parent rocks. Total fluoride content of the rocks and soils of the village ranges from 10 to 2000 mg/L. The leachable fluoride, however, ranged in concentration from 0.27 to 14.88 mg/L under induced temperature v and 0.05 to 10.40 mg/L without temperature. Mineralogical investigation revealed the abundance of smectite clay, which is known for its enrichment and leaching of fluoride into groundwater sources, thus, the research question and assumption about the possible source of fluoride and the assumption that fluoride increases downwards towards the aquifer were answered. Leaching experiments identified the main contributors of fluoride to groundwater in Siloam village as smectite clays and the muscovite present in the sandstone, greywacke and basalt. Time based leaching experiment, geochemical modelling and dating of different hydrogeological unit was recommended / NRF

MENVSC / Department of Hydrology and Water Resources / See the attached abstract below

Thesis (M.Sc. (Statistics)) -- University of Limpopo, 2022 / Water is a precious natural resource and one of the most vital substance for sustainability of life . The increase in water evaporation is a major prob lem where factors such as high temperature and minimum rainfall are the contributing factors. The aim of the study was to perform time series mod elling of water evaporation from the selected dams in the Limpopo province South Africa. A daily evaporation time series data was used in the study with variables such as temperature and rainfall. Daily water evaporation rate time series data was differenced to make the data series stationary and Dickey-Fuller test was used to test the stationarity of the data series. The Autoregressive Conditional Heteroskasticity (ARCH) and Generalized Au toregressive Conditional Heteroskasticity (GARCH) model was performed on the water evaporation time series data from the selected dams. Vec tor Autoregression (VAR) was used to determine the relationship between the variables evaporation, rainfall and temperature. Identification of time series models was done using the autoregressive integrated moving average (ARIMA). The best ARIMA models were selected based on the autocor relation function (ACF) and partial autocorrelation function (PACF), and the smallest value of Bayseian Information (BIC). The best models selected for each dam are: Mokolo dam, ARIMA (1, 1, 2) model; Ga-Rantho dam, ARIMA (1, 1, 2) model; Leeukraal DeHoop dam, ARIMA (1, 1, 1) model and Luphephe dam, ARIMA (2, 1, 3) model. The correlation coefficient, coefficient of determinant (R2 ) and root mean square (RMSE) were used to determine the performance of the model. The water evaporation time series data from the selected dams was forecasted using the best selected ARIMA models from the selected dams and then predicted for the next 3 years, where the results showed a positive constant water evaporation rate.

MESMEG / Department of Mining and Environmental Geology / See the attached abstract below

MESHWR / Department of Hydrology and Water Resources / See the attached abstract below

MESMEG / Department of Mining and Environmental Geology / This dissertation focused on the assessment of borehole yields within the Nzhelele- Makhado area, which is located in the northern part of South Africa within the Vhembe District Municipality of Limpopo Province. The aim of the study was to identify factors that influence the yields of water supply boreholes within the study area. This information will be used to improve the groundwater resource knowledge required in assessing the potential of groundwater resources in augmenting the Nzhelele Regional Water Supply Scheme. The study area is mostly underlain by the ‘hard rock’ formations of the Soutpansberg Group, which practically has no primary porosity. The groundwater is residing mainly within the weathered and fractured or discontinuities, considered being secondary porosities. Due to the complexity of the underlying fractured and hard rock aquifer systems and the fact that most of the boreholes drilled in the area were not scientifically sited, the study area is dominated by very low yielding boreholes. Majority (48%) of the boreholes were drilled into the Nzhelele formation due to the fact that it occupies the central, relatively flat and low lying sections of the study area. The variations in average yields in boreholes drilled in different formations within the study area is relatively low suggesting that the difference in lithology of different formations do not to have any major influence in the yields of boreholes. The topographical settings of the area do not have any influence in the borehole drilling depths and yields. The high borehole yields in shallow boreholes located in mountainous areas is due to local groundwater systems, which recharges and discharges locally. Mapped lineaments are slightly low yielding (average yield of 0.32 l/s) compared to the faults (average yield of 0.43 l/s) within the study area. Boreholes drilled along the NE-SW trending lineaments support double the yields (0.41 l/s) on average of those along the SE-NW (0.28 l/s) and W-E (0.20 l/s) trending lineaments. The high yields in boreholes closer to non-perennial streams compared to perennial rivers is due to the fact that non-perennial streams are comprised of thick layer of overburden capable of supporting high yielding boreholes, whereas the overburden along the perennial rivers are washed away during rainy season leaving bedrock exposed or covered with thin layer of sediments. The proximity to the young faults trending SE-NW and dry non-perennial streams has proved to be the most the favourable areas for development of high yielding boreholes in the study area, compared to lithological difference and topographical settings of the area. However, it should be noted that there are no simple relationship between various factors that control the yield of the boreholes in the area. Despite the similarities in some factors that influence borehole productivity on a regional scale such as faults and drainage systems, the complexity of the weathered-fractured aquifer system suggests an over-riding influence of local features, which results in significant variations in yield and response to abstraction. / NRF

MSc (Chemistry) / Department of Chemistry / Surface water is used for domestic and agricultural activities in Musina region and other surrounding areas. This is because of the shortage of potable water. As a result, the people living in the region and its surrounding areas are potentially exposed to hazardous contaminants that may be present in the surface water. It is therefore important to ascertain the quality of the surface water in the region. Surface water samples were collected from Mutale, Nwanedi, Tshipise and Nzhelele rivers. The samples were analysed for anions such as fluoride (F-), chloride (Cl-), nitrate (NO3-), phosphate (PO43-), sulphate (SO42-); cations such as aluminium (Al), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), sodium (Na) and trace metals such as lithium (Li), vanadium (V), chromium (Cr), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), molybdenum (Mo), cadmium (Cd), thallium (Tl) and lead (Pb) by using analytical techniques such as IC, ICP-OES and ICP-MS. The same samples were also investigated for other parameters such as pH, temperature, EC, TH, TDS, Na % and SAR. The WHO (2008), SANS 241 (2006) and Canadian guideline (2017) were used as a water quality guideline for drinking purposes. Higher concentrations of Li, V, Cr, Ni, Cu, Zn, Al, Ca, Mg, K and Na in river water were detected in rainy season, whereas higher concentrations of As, Mo, K and Fe were recorded in dry season. The concentration of F-, Cd, Tl and Pb showed low contamination level in river samples. The results demonstrated that Tshipise river water was contaminated with high concentration of parameters: TDS (1864.0.8-3372.8 mg L-1), EC (2960.3-5270 mS cm-1), F- (6.403-8.419 mg L-1), SO42- (289.657-326.598 mg L-1), Na (836.690-922.810 mg L-1) and As (10.017-11.267 μg L-1) and relative to the (WHO) water guidelines. Nwanedi river also showed higher values of EC (298.0-699.0) mS cm-1 and TDS (190.3-447.5) mg L-1. In this study, the results indicated that water from Tshipise and Nwanedi river is not suitable for human consumption based on the guidelines of drinking water. The results also indicated that the soil sample had abundance of Ca, Al, Mn and Fe with concentration ranging from 0.13-10595, 0.0084-4.16, 0.0455-1116.5, 2.4-287404 mg Kg-1 respectively. / NRF