Thesis (M. Sc. (Geology)) -- University of Limpopo, 2021 / The Glentig, Alma and Swaershoek Formations were deposited after the emplacement of the Bushveld igneous complex (BIC). The sediments accumulated in what is termed as the proto-basin of the Waterberg Group. The Glentig Formation is an unconformity-bounded formation that is overlain by the Swaershoek and Alma Formations of the Waterberg Group. This study revisited the stratigraphy and put perception on the petrography, lithofacies, provenance, paleoweathering, tectonic setting and source rock characteristics of the lower parts of Waterberg Group (Swaershoek and Alma Formations) and Glentig Formation. The methodologies employed in achieving the aforementioned goals include stratigraphical analysis, petrographical and modal composition analyses, lithofacies analysis and geochemical analysis. In the study area (northeast of Modimolle town), the Glentig Formation lies or bounded between the Swaershoek Formation and Schrikkloof Formation of the Rooiberg Group. The Glentig, Swaershoek and Alma Formations attained a maximum thickness of about 400 m, 300 m and 190 m, respectively. Based on the stratigraphical analysis, the Swaershoek, Alma and Glentig Formations can be correlated. The basis for the correlation rests solemnly on the similarities in the lithological characteristics that can be found in the three formations. Six facies were identified based on lithofacies analysis. The lithofacies are grouped into 2 facies association (FA1 and FA2). The two facies associations are FA1: Conglomerate and massive sandstone, and FA2: Cross-bedded sandstone, and planar cross-bedded sandstone. Sedimentological characteristics of the identified facies associations are interpreted as debris flow, and longitudinal and transverse bars (fluvial channel deposits). Petrography and modal composition analyses indicate that the detrital components of the sandstones are dominated by monocrystalline quartz, feldspar and lithic fragments. The sandstones of the Swaershoek, Alma and Glentig Formations can be classified as subarkosic arenite and lithic arkosic arenite. Also, provenance analysis indicates that the sandstones are derived from both felsic igneous provenance and intermediate igneous provenance. The modal composition analysis and geochemical tectonic setting discrimination diagrams show that the sediments are from both the passive and active continental margin tectonic settings. Also, the geochemical data of major and trace elements suggested that the studied formations have been derived from the same provenance source area. The indices of weathering indicated that the studied rocks have been subjected to moderate to the high degree of chemical weathering. Keywords: Geology, geochemistry, Glentig, Swaershoek, Alma, Waterberg Group, South Africa / Mining Qualification Authority (MQA)

M.Sc. / Please refer to full text to view abstract

A Dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the Degree of Master of Science in Geology. Johannesburg 2013 / The Nyl River floodplain, located in the Limpopo Province, is one of the few active sedimentary basins that exist within the South African interior, providing a unique opportunity to study the effect of climate change on fluvial systems. Progradation of tributary fans into the Nyl/Mogalakwena River has raised the surface by 30 m and forced the course of the river westwards towards the Waterberg. Periods of progradation deposited thick sequences of coarse-grained sediments with sand- to gravel-sized mean grain sizes and coarsely-skewed populations in the distal reaches of the tributary fans. These periods were interspersed with periods of relative non-deposition, when active sedimentation on the fan ceased and shallow lakes (or vleis) developed in the trunk river, resulting in deposition of fine-grained, organic-rich, floodplain sediment layers with silt-sized mean grain sizes and finely-skewed distributions in the extreme outer reaches of the tributary fan. The alternating progradational sequences and non-deposition events produced interlayered floodplain and fan deposits in the furthest reaches of the tributary fans along the banks of the Nyl/Mogalakwena River. Incised river cuts within the Rooisloot tributary fan were dated using OSL and 14C techniques. For OSL samples, the SAR protocol was used to measure the equivalent dose and the burial dose was determined using the CAM and MAM. Emission counting methods, including TSAC, GM-beta counting and HRGS were used to determine the dose-rate. The OSL ages ranged from 99 years to 3884 years, constraining the sampled deposits within the late Holocene. Although the 14C ages agreed with this range, carbon contamination of the samples resulted in inverted and overestimated ages. Based on stratigraphic relationships the non-deposition events have been dated at approximately 750–800 years ago, 600 years ago, 475 years BP and 100–150 years ago and two major periods of aggradation at ~ 800–1000 years ago and ~ 500–700 years ago. The rate of aggradation (0.29 cm/year) calculated implies that the entire 30 m deposit could have been deposited in 9 000 years. However, an independent study by McCarthy et al. (2011) proved that tributary sedimentation began prior to 220 ka. Therefore, in order to deposit 30 m of sediment over 220 ka, either the mid – late Quaternary sedimentation rate was lower than the recent past (Late Holocene) or the system periodically undergoes extensive erosion in order to flush the accumulated sediment from the tributary fan system.

M.Sc. / Please refer to full text to view abstract

The UG3 at Modikwa Platinum Mine occurs as a platiniferous, planar chromitite seam. It is stratigraphically located in the Upper Critical Zone of the Eastern Bushveld Complex. Field work study comprise of underground mapping, sampling, surface mapping, borehole core logging, microprobing and microscopic investigations carried out at the Rhodes University. The UG3 at the Modikwa Platinum Mine is about 22cm thick chromitite seam underlain by a white fine grained anorthosite and overlain by a brown medium grained feldspathic pyroxenite. It is an incomplete cyclic unit consisting of chromite and feldspathic pyroxenite. The UG3 reef at the Modikwa Platinum Mine lease area represents a Platinum Group Metal resource of 300 million tons of ore at an in situ grade of 2.5g/t. Under the current market conditions the UG3 reef remains unprofitable to mine in an underground operation due to the operational cost involved. However, it has been illustrated that the UG3 chromitite seam can increase profit margins in an open pit operation provided it is mined together with the economic UG2 chromitite seam. The extraction of the UG3 as ore in the four Modikwa UG2 open pits would result in a combined operating cash profit of R330 million. The UG3 chromitite seam is platiniferous. The platinum-group minerals (PGM) range in size from less than 10μm to about 70μm. The PGMs are associated with sulphides and are both located in the interstitial silicates and are concentrated in the chromitite seam. The PGMs show a strong preference to contact boundaries of the silicate grains, the chromite grains and the sulphide phases. In some instances, they are enclosed within the chromite grains in association with sulphides. The general sulphide assemblage comprises pentlandite and chalcopyrite whereas, the PGMs assemblage comprises cooperite, ferroplatinum, laurite, FeRhS and PtRhS.

MESHWR / Department of Hydrology and Water Resources / See the attached abstract below

PhDENV (Geology) / Department of Mining and Environmental Geology / The study focused on the geology, structural setting and mineralisation of copper-sulphide deposits in the Musina area, located in the Central Zone of the Limpopo Mobile Belt of South Africa. The Messina copper deposits are located in the eastern part of Limpopo Province near the border with Zimbambwe. The deposits stretch from northeastern to southwestern direction for about 15 km. Previous copper mining in the area took place at Artonvilla, Messina, Harper, Campbell and Lilly copper deposits. The current study, however, focused on two main deposits, Campbell and Artonvilla. The origin, nature and mode of formation of the Cu-sulphide deposits in the Musina area have not been established with certainty. Two principal hypotheses on the origin of the Messina copper sulphide deposits have been proposed, viz; a magmatic-hydrothermal model, and meteoric waters model. Consequently, the mode of formation and mineralisation style of the Messina Cu-sulphide deposits remain contentious. Therefore, the main objective of the study was to investigate the nature and mode of formation of Cu-sulphide deposits in the Musina area. Different research methods have been applied in the current study so as to unpack the contradictory positions on the genesis of the Messina copper deposits. This included fieldwork, remote sensing data acquisition, laboratory work, and data analysis and interpretation. Fieldwork involved soil geochemical survey as well as rock and ore sampling within the study area. A total of 295 soil samples, 33 rock specimens and 21 ore samples were collected for laboratory investigation. Laboratory work consisted of a range of methods that included; geochemical analysis, petrographic and cathodoluminescence microscopy, ore mineralogy and ore microscopy, fluid inclusion geothermometry and isotope geochemistry. The work was done in different laboratories including: Mining and Environmental Geology Laboratory, Unviersity of Venda; Department of Geology Laboratory, University of Johannesburg; MINTEK Laboratory in Johannesburg; Société Générale de Surveillance Laboratory in Johannesburg, South Africa; Department of Applied Geology, Geoscience Institute, Göttingen University, Germany and Department of Geology, University of Georgia, Athens, United States of America. Remote sensing data was acquired from Southern Mapping Company, Johannesburg, South Africa. Interpretation of Remote sensing data was done at the University of Applied Sciences, Oswestfalen-Lippe, Germany. Data analysis and interpretation of laboratory results involved the use of: Desktop ArcGIS 10.4.1 for geochemical data interpretation; ENVI 5.1 and ArcGIS 10.4.1 Softwares for remote sensing data; and Triplot version 4.1.2 software for ternary plot for compositional variation of rocks. Soil geochemical survey revealed geochemical anomalies for Pb, Zn, Cu, As and Ni over the known copper deposits in the area as well as over six other areas that have not been associated with any sulphide mineralisation. Such new anomalous areas have been identified as target areas for future exploration of sulphide ore mineralisation. Petrographic studies of the rocks confirmed the host rocks to be amphibolite-quartz granulite, biotite-garnet-quartz granulite, amphibolite, quartzite, hornblende gneiss, quartzo-feldspathic gneiss, potassium-feldspathic gneiss and cal-silicate gneiss. These rocks were subjected to hydrothermal alteration during ore mineralisation within the area. It was further noted that epidote alteration was quite intensive in ore samples, while in unmineralised rock samples it was less intensive. Remote sensing data interpretation revealed spatial distribution and intensity of epidote alteration within the study area and in places coincided either with the known copper deposits or structural features, thus led to the identification of target areas for future mineral exploration in the Musina area. The current study established that the process of ore mineralisation in the Messina copper deposits took place in two distinct phases: first the formation of garnet, graphite, magnetite and hematite during regional metamorphism of the Limpopo Mobile Belt; and secondly, sulphide ore mineralisation resulting in the formation of copper ore comprising, veined, disseminated and brecciated ores. Sulphide ore mineralisation consisted mainly of pyrite, chalcopyrite, sphalerite, bornite, chalcocite and minor pyrrhotite and galena as well as traces of pentlandite, tennantite, mollybdenite, cobaltite and tetrahedrite. This confirms that the Messina copper deposits had complex sulphide ore mineralisation that is typical of hydrothermal mode of ore mineralisation from a magmatic source. The study further establishes the paragenitic sequence of ore mineralisation, comprising four stages: Stage I (Garnet- graphite – Fe oxides); stage II (Quartz- pyrite); stage III (Pyrite- sphalerite - chalcopyrite); and stage IV (Carbonates). Stage III represented the main stage of sulphide ore mineralisation in the area, while Stage IV comprising calcite, dolomite and ankarite marked the final stage of hydrothermal ore mineralisation. Paragenetic sequence identified three generations of quartz; first generation being associated with garnet, graphite, magnetite and hematite, second generation with pyrite and third generation with pyrite, sphalerite and chalcopyrite. Previous studies, however, indicated that there was only one generation of quartz that formed at the temperature between 210o to 150°C, but the current study established that the entrapment temperature of first generation quartz ranges from 315o to 200°C; second generation quartz from 235o to 135°C and third generation quartz from 240o to 115°C. At the same time, sulphur isotope investigation of chalcopyrite-pyrite pair from Campbell deposit registered a temperature of 359°C. The study therefore concluded that the temperature of ore formation within the Messina copper deposits ranged between 359°C and 115°C. The presence of halite and calcite as daughter minerals within the fluid inclusions was noted and this apparently is indicative of high salinity of fluid inclusions, which is considered as a product of direct exolution of crystalizing magma. Raman spectroscopy revealed the composition of gases in the fluid inclusions to be CH4 and N2 with 80% and 20% composition respectively, however, some inclusions were gas-poor. The presence of gases in the fluid inclusions is an indication that there was boiling at the time of entrapment. A narrow range of 34S values of -0.5 to 0.5‰ obtained in this study further confirms the magmatic source of Sulphur as Sulphur from the host rock was found to have high 𝛿34S value of 8.2‰. A genetic model for copper ore mineralisation within Musina area is proposed. The deposits are of polymetallic vein type that are genetically associated with porphyry copper deposits. According to this model, copper ore bodies were formed from hydrothermal fluids originating from magma and were epigenetic in nature. Geological structures in the area acted as conduits for hydrothermal fluids that resulted in the alteration of the host rocks and mineralisation of copper sulphide ore. Thus, the Messina coper deposits are of magmatic hydrothermal origin although the apparent location of a batholith is still unknown and the study recommends further viii research work on the location of the batholith that is presumed to have been the magmatic source. The study further recommend dating of later rocks as well as orebody s it is essential for understanding the process of ore formation in this area. For further exploration, areas that have undergone “moderate” to “high” degree of epidote alteration and lie in close proximity to geological structures such as faults and thrust folds that could have acted as conduits for hydrothermal fluids and resulted in sulphide ore mineralisation and registered high geochemical anomalies for Pb, Zn, As and Ni should be targeted. In support of further mineral exploration within the study area, the study recommend a detailed geostatistical application for the purpose of delineating homogeneous areas based on the combination of lineaments, interpolated soil geochemical maps and thematic maps. / NRF