Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2016-01-20T20:35:40Z No. of bitstreams: 1 JeanCarlosSilvaAndrade_TESE.pdf: 5351227 bytes, checksum: 6baecb9ca1efd3ecbe1d465cdf5fbe9b (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2016-01-21T17:57:45Z (GMT) No. of bitstreams: 1 JeanCarlosSilvaAndrade_TESE.pdf: 5351227 bytes, checksum: 6baecb9ca1efd3ecbe1d465cdf5fbe9b (MD5) / Made available in DSpace on 2016-01-21T17:57:45Z (GMT). No. of bitstreams: 1 JeanCarlosSilvaAndrade_TESE.pdf: 5351227 bytes, checksum: 6baecb9ca1efd3ecbe1d465cdf5fbe9b (MD5) Previous issue date: 2014-02-10 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPES / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico - CNPq / A demanda por materiais com alta homogeneidade obtidos a temperaturas relativamente baixas vem alavancando a busca por processos qu?micos substituintes do m?todo cer?mico convencional. Esse trabalho tem como objetivo a obten??o de pigmentos nanom?tricos encapsulados (core-shell) a base de TiO2, dopados com ?ons de metais de transi??o (Fe, Co, Ni, Al) atrav?s de 3 (tr?s) m?todos de s?ntese: precursores polim?ricos (Pechini); hidrotermal de microondas; e co-precipita??o associado ? qu?mica sol-gel. O estudo foi motivado pela simplicidade, rapidez e baixo consumo de energia caracter?sticos desses m?todos. Os sistemas de custos s?o acess?veis, pois que permitem atingir um bom controle da microestrutura, aliada a elevada pureza, com controle estequiom?trico e de fases permitindo obter part?culas de tamanho nanom?trico. As propriedades f?sicas, qu?micas, morfol?gicas, ?pticas e estruturais dos materiais obtidos foram analisadas utilizando diferentes t?cnicas de caracteriza??o de materiais. Os p?s pigmentantes foram testados na descolora??o e degrada??o utilizando um fotoreator, atrav?s da solu??o do corante remazol amarelo ouro (RNL), a partir da filtra??o destas, resultando na separa??o da solu??o filtrante e dos pigmentos, para posterior realiza??o de medidas de UV-Vis. As diferentes temperaturas de calcina??o adotadas ap?s a obten??o dos p?s, nos diferentes m?todos foram: 400 ?C a 1000 ?C. Utilizando uma concentra??o fixa de 10% (Fe, Al, Ni, Co) em massa em rela??o ? massa do tit?nio, viabilizando tecnologicamente e economicamente o estudo. Atrav?s da t?cnica de microscopia eletr?nica de transmiss?o (MET) foi poss?vel analisar e confirmar a forma??o estrutural das part?culas de pigmentos nanom?tricos encapsulados, apresentando di?metro dos p?s de TiO2 entre 20 nm e 100 nm, e espessura da camada recoberta de Fe, Ni e Co entre 2 nm e 10 nm. O m?todo de s?ntese mais eficiente entre os estudados no trabalho foi o co-precipita??o associado ? qu?mica sol-gel, no qual foram obtidos os melhores resultados, sem a necessidade da obten??o de p?s pelo processo de calcina??o / The demand for materials with high consistency obtained at relatively low temperatures has been leveraging the search for chemical processes substituents of the conventional ceramic method. This paper aims to obtain nanosized pigments encapsulated (core-shell) the basis of TiO2 doped with transition metals (Fe, Co, Ni, Al) through three (3) methods of synthesis: polymeric precursors (Pechini); hydrothermal microwave, and co-precipitation associated with the sol-gel chemistry. The study was motivated by the simplicity, speed and low power consumption characteristic of these methods. Systems costs are affordable because they allow achieving good control of microstructure, combined with high purity, controlled stoichiometric phases and allowing to obtain particles of nanometer size. The physical, chemical, morphological, structural and optical properties of the materials obtained were analyzed using different techniques for materials characterization. The powder pigments were tested in discoloration and degradation using a photoreactor through the solution of Remazol yellow dye gold (NNI), such as filtration, resulting in a separation of solution and the filter pigments available for further UV-Vis measurements . Different calcination temperatures taken after obtaining the post, the different methods were: 400 ? C and 1000 ? C. Using a fixed concentration of 10% (Fe, Al, Ni, Co) mass relative to the mass of titanium technologically and economically enabling the study. By transmission electron microscopy (TEM) technique was possible to analyze and confirm the structural formation nanosized particles of encapsulated pigment, TiO2 having the diameter of 20 nm to 100 nm, and thickness of coated layer of Fe, Ni and Co between 2 nm and 10 nm. The method of synthesis more efficient has been studied in the work co-precipitation associated with sol-gel chemistry, in which the best results were achieved without the need for the obtainment of powders the calcination process