A coated conductor is generally fabricated by depositing a high Tc superconducting layer onto a flexible metallic substrate, using intermediate buffer layers to prevent chemical interaction. In order for the superconductor to be capable of carrying a high current density, its grains must have good crystallographic alignment in order to avoid the presence of high angle grain boundaries. This can be ensured by transferring the texture from the substrate through epitaxial film growth. The main substrate considered in this thesis is a Ni-Fe alloy. When cold-rolled, NiFe develops a preferential orientation and upon annealing at an elevated temperature, undergoes primary recrystallisation to form grains with the cube texture {100}<001>. There crystallisation process and the texture of the tapes has been examined and various buffer layers have been fabricated. As silver does not react adversely with high temperature superconductors, it has been deposited onto Pd-buffered NiFe by DC sputtering and very sharp cube texture is obtained. Ceramic buffer layers, CeO2 and YSZ, have been deposited by RF sputtering, though an undesirable (111) oriented component accompanies the cube textured material. Also a technique has been developed to produce a suitably oriented native oxide of NiFe by a simple oxidation technique. Preliminary attempts to deposit YBCO films onto these buffer layers have shown that the quality of the metallic buffers is degraded by rapid inter-diffusion at elevated temperatures, but that cube textured material can be deposited on the oxide buffer layers. The percolative nature of current flow in such coated conductors has been considered through the development of a grain network model. As the texture of the superconducting layer is directly influenced by the underlying layers, measurements from the substrate and buffer layers are applied in order to model the orientations of the grains in a superconducting overlayer. The model calculates the critical current of coated conductors as a function of parameters such as length, width, grain size and texture, as well as examining factors such as cracks and highly misoriented grains.

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Superconductivity Centennial Conference 2011- EUCAS–ISEC–ICMC (18-23 Sep 2011, The Hague, The Netherlands)

Since the discovery of the high temperature superconductor YBa2Cu3O7-δ (YBCO), with transition temperature (Tc = 77 K), above liquid nitrogen point in 1987 many research projects have been dedicated to enhancing the high field performance of this material for practical applications. The 2nd generation YBCO-based coated conductors are believed to be the most promising approach for commercial applications including power transmission, motors, generators, and high field magnets. With the advances of nanotechnologies, different nanoengineering methods have been demonstrated to enhance the performance of YBCO thin films, include doping with 0-dimensional (0-D) self-assembled nanoparticles, 1-dimensional (1-D) nanorods, and 2-dimensional (2-D) nanolayers. Furthermore, dopants with ferromagnetic properties are also reported to provide enhanced pinning effects by Lorentz force, especially under high-applied magnetic fields. The principle of these methods is to generate high-density defects at the heterogeneous interfaces as artificial pinning centers in an effort to improve the flux-pinning properties. The morphology and dimensions of the nanoinclusions play an important role in pining enhancement. Optimized pinning structures are likely to be located at energetically favorable vortex cores, which form a triangular lattice with dimensions close to the YBCO coherence length ξ (ξab ~ 4 nm; ξc ~ 0.5 nm at 77 K.) However, it is challenging to achieve small dimensional nanodopants in the vapor deposited YBCO thin films. The purpose of this research is to utilize nanoengineering methods to produce optimized pinning structure in YBCO thin films. In this thesis, we systematically study the effects of different nanoinclusions on the flux-pinning properties of YBCO thin films. The 0-D ferromagnetic Fe2O3 and CoFe2O4 nanoparticles, 2-D CeO2 multilayers, and tunable vertically aligned nanocomposites (VAN) of (Fe2O3)x:(CeO2)1-x and (CoFe2O4)x:(CeO2)1-x systems are introduced into the YBCO matrix as artificial pinning centers. Results suggest that all nanoinclusions showed significant enhancement in the superconducting properties of YBCO. The ferromagnetic pinning centers dominate at high field and low temperature regimes, however, the defect pinning centers dominate at low field and high temperature regimes. The uniquely arranged VAN structure of alternating magnetic and non-magnetic nanophases, which incorporates both high defect density and tunable distribution of magnetic dopants, is believed to be an ideal solution for flux-pinning enhancement.

Since a superconductor has no resistance below a certain temperature and can therefore save a large amount of energy dissipated, it is a 'green' material by saving energy loss and hence reducing carbon emissions. Recently the massive manufacture of high-temperature superconducting (HTS) materials has enabled superconductivity to become a preferred candidate to help generation and transportation of cleaner energy. One of the most promising applications of superconductors is Superconducting Magnetic Energy Storage (SMES) systems, which are becoming the enabling engine for improving the capacity, efficiency, and reliability of the electric system. SMES systems store energy in the magnetic field created by the flow of direct current in a superconducting coil. SMES systems have many advantages compared to other energy storage systems: high cyclic efficiency, fast response time, deep discharge and recharge ability, and a good balance between power density and energy density. Based on these advantages, SMES systems will play an indispensable role in improving power qualities, integrating renewable energy sources and energizing transportation systems. This thesis describes an intensive study of superconducting pancake coils wound using second-generation(2G) HTS materials and their application in SMES systems. The specific contribution of this thesis includes an innovative design of the SMES system, an easily calculated, but theoretically advanced numerical model to analyse the system, extensive experiments to validate the design and model, and a complete demonstration experiment of the prototype SMES system. This thesis begins with literature review which includes the introduction of the background theory of superconductivity and development of SMES systems. Following the literature review is the theoretical work. A prototype SMES system design, which provides the maximum stored energy for a particular length of conductors, has been investigated. Furthermore, a new numerical model, which can predict all necessary operation parameters, including the critical current and AC losses of the system, is presented. This model has been extended to analyse superconducting coils in different situations as well. To validate the theoretical design and model, several superconducting coils, which are essential parts of the prototype SMES system, together with an experimental measurement set-up have been built. The coils have been energized to test their energy storage capability. The operation parameters including the critical current and AC losses have been measured. The results are consistent with the theoretical predictions. Finally the control system is developed and studied. A power electronics control circuit of the prototype SMES system has been designed and simulated. This control circuit can energize or discharge the SMES system dynamically and robustly. During a voltage sag compensation experiment, this SMES prototype monitored the power system and successfully compensated the voltage sag when required. By investigating the process of building a complete system from the initial design to the final experiment, the concept of a prototype SMES system using newly available 2G HTS tapes was validated. This prototype SMES system is the first step towards the implementation of future indsutrial SMES systems with bigger capacities, and the knowledge obtained through this research provides a comprehensive overview of the design of complete SMES systems.