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Yes / With the technological advances in the field of building materials, there has been an increasing focus on the research of lightweight concrete made with coated aggregates for improving the durability of concrete. In this study, pumice aggregates were coated with cast-based polyester to obtain polymer-coated pumice aggregates (PCPA). Lightweight concretes were produced with different cement dosages (200, 250 and 300) and PCPAs at different ratios (0%, 50% and 100%). Physical properties, mechanical strength, thermal properties and internal structure analysis (SEM-EDS) of the produced concrete samples were performed. According to the RILEM functional classification of lightweight concrete, the test results showed that REF D300 and REF D250 dosage series are in the semi-load-bearing lightweight concrete class, and the other all series are in the insulation concrete class, and the produced concretes can be classified as lightweight insulation materials. It can also be used in non-load-bearing walls or as an alternative lightweight insulation material. / The first author wish to thank the support of Scientific and Technical Research Council (TUBITAK) BIDEB-2219 Postdoctoral Research (Project Number: 1059B192100644) and the second author also thank to the Düzce University.

Yes / Reverse roll coating is probably the most widely used coating operation, yet its full potential has not been exploited as it is shown in this paper which considers operation with a negative gap. We demonstrate through a wide range of experimental data that such operation can yield very thin and stable films with no ribbing or cascade instabilities when low viscosity fluids are used. Typically, stable film thickness less than 5μm can be obtained at speeds up to 150 m/min when a rubber roller is used at -100 μm gap with fluids of viscosity in the range 10-200 mPa.s. These film thicknesses can be made to decrease further down to 1 or 2 microns with a judicious choice of speed ratios (applicator to metering roller) and rubber hardness. Such new findings make this simple coating method an attractive roll to roll technique for application in the newer coating technologies, such as in the production of solar cells and plastic electronics. The data obtained in this study have been underpinned by a model based on the classical lubrication theory, well developed for such flow situations. Essentially it is shown that the film thickness non dimensionalised with respect to the set negative gap is controlled through a single parameter, the elasticity number Ne which combines all the operating parameters. Of course, this flow problem has complexities, particularly at high speed ratios and at zero gap so the data obtained here can serve as a basis for more comprehensive modelling of this classical fluid mechanic problem. / Films R&D Centre of Toyobo Co. Ltd., Otsu, Japan and the Thin Films Research Group of the University of Bradford, UK.

Yes / Tensioned web-roll coating is widely used but has surprisingly received little research attention. Here, a new semi-empirical model that predicts film transfer from applicator roller to web is developed and tested against data collected from a pilot coating line. The film transfer is found to vary linearly with web to applicator speed ratio S. Flow stability investigations revealed three types of defects: rivulets, air entrainment due to dynamic wetting failure and cascade, occurring at different values of S and capillary number Ca. Rivulets occurred at Ca< 0.4 and S> 0.71-0.81, air entrainment at Ca>0.4 and S>0.71-0.83 and cascades at S>1.1 for Ca up to 6. Web speeds at which dynamic wetting failure occurred were, for the same Ca, comparatively higher than those that occur in dip coating. The data show that such hydrodynamic assistance is due to the coating bead being confined, more so with increasing web wrap angle β. / The authors acknowledge the support of the Films R&D Centre of Toyobo Co. Ltd., Otsu, Japan and of the Thin Liquid Films Research Group of the University of Bradford, UK.

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Yes / Dynamic wetting failure was observed in the simple dip coating flow with a series of substrates, which had a rough side and a comparatively smoother side. When we compared the air entrainment speeds on both sides, we found a switch in behaviour at a critical viscosity. At viscosity lower than a critical value, the rough side entrained air at lower speeds than the smooth side. Above the critical viscosity the reverse was observed, the smooth side entraining air at lower speed than the rough side. Only substrates with significant roughness showed this behaviour. Below a critical roughness, the rough side always entrained air at lower speeds than the smooth side. These results have both fundamental and practical merits. They support the hydrodynamic theory of dynamic wetting failure and imply that one can coat viscous fluids at higher speeds than normal by roughening substrates. A mechanism and a model are presented to explain dynamic wetting failure on rough surfaces.

Yes / This experimental study of forward gravure coating considers the effects of operating variables on air entrainment, ribbing instabilities and the thickness of the film formed. The data show that this coating method can yield very thin films of thickness of order of 15 - 20% at most of the equivalent cell depth of a gravure roller. Air free and non ribbed stable uniform films can however only be obtained in a narrow window of operating conditions at very low substrate capillary number (CaS ~ 0.02) equivalent to substrate speeds typically less than 20m/min. The paper draws a similarity with flow features observed with smooth forward roll coating and slide coating. It is shown that the onset of ribbing and the flux distribution between the gravure roller and the substrate at the exit of the nip obey approximately the same rules as in smooth forward roll coating, whereas the onset of air entrainment actually corresponds to a low-flow limit of coatability similar to that observed in slide coating.

A superhydrophobic coating can be produced using a hydrophobic material textured with surface roughness on the micro-/nano-scale. Such a coating on the outside of a submersible body may result in reduced skin-friction drag due to a trapped layer of air in the coating. However, this layer may become unstable when subjected to elevated hydrostatic pressures, and a coating’s performance is compromised beyond a certain threshold (critical pressure). This thesis presents a numerical model for predicting the pressure tolerances of superhydrophobic coatings comprised of randomly deposited hydrophobic particles or fibers. We have also derived a set of force-balance-based analytical equations for predicting critical pressure in surfaces with ordered roughness, and compared our numerical model against it, observing reasonable agreement. The numerical model was then applied in a large parameter study, predicting critical pressure for coatings with a given set of microstructure properties.

"Catalytic growth of Carbon Nanotubes (CNT) provides important advantages of controlling their diameters and possibly chirality. Our work involved growing CNT on model and supported catalyst by catalytic decomposition of carbon source such as benzene, methane and propylene. On supported catalyst, iron nitrate was deposited on alumina and reduced to form metallic iron clusters. These were reacted at 700 - 950 C under varying benzene concentrations. Multi Walled CNT (MWNT) grew below 800 C and Single Wall CNT (SWNT) are observed at 850 C and above as confirmed by TEM and Raman. Model catalysts were studied by producing CNT from ferrocene which acted as the carbon and catalyst source on Silica/Si (100). Large yield of MWNT was observed at 900 C. MWNT grew perpendicular to the model support as seen by SEM. In another model catalyst study, iron salt clusters were deposited on silica/Si (100) by spin coating, controlling their diameters by solution concentration and speed of spinning. Agglomeration of clusters at high temperatures produces only MWNT on silica/Si (100). Cluster agglomeration can be reduced with strong support metal interaction such as with alumina. We deposited alumina on silica/Si (100) by atomic layer deposition, with conformal coatings on surface and low relative roughness. Alumina film was stable under reaction temperatures of 900 C. Cluster deposition on alumina by spin coating was difficult because of different surface acidity compared to silica. Clusters on alumina did not agglomerate at high reaction temperatures. We report effect of parameters such as the temperature of reaction, conditions of pretreatment such as reduction and oxidation of catalyst precursor, type of precursor, type of carbon source, and type of support material on growth of CNT. The role of spin coating in controlling the diameter of salt clusters deposited is discussed. We also report deposition of alumina on top of silica/Si (100) by atomic layer deposition and the effect of deposition and calcination temperatures on the alumina film integrity."

The effects of coating formulation on thermal characteristics of coating layers were systematically studied for xerographic toner fusion on coated papers. Model coatings were formulated using three types of ground calcium carbonate and one kaolin pigments, each mixed with 6, 10, 18, and 25 pph of styrene butadiene latex binder. Porosity was found to be a key parameter for coating thermal conductivity adjustment, and was determined by the latex concentration. The particle size distribution and morphology of pigments also affect the overall thermal characteristics of coating layers. Print qualities on model coated papers were evaluated by print gloss measurement, toner adhesion test, and pair-wise visual ranking, and it was proved that print gloss is reduced with increasing bulk thermal conductivity of coating layers. The coating layer consisted of Covercarb HP pigment and 10 pph of latex was found to have the best performance in the three print quality evaluation tests.