A fast response method for detection of light-off in gaseous flames and liquid spray flames has been developed. The method used chemiluminescent signals from the 2Σ - ²π OH system centered at 309 nm and the ²Δ - ²π CH system centered at 430 nm to indicate the presence of a flame. Spectral scans (performed on gaseous methane, liquid hexane and liquid Jet-A aircraft fuel) from 280 nm to 610 nm indicated that these two species produced the strongest signals available for flame detection. As their light is emitted in the ultraviolet spectrum, using the OH and CH radicals will potentially provide a good signal-to-noise ratio since, in combustion chambers, most of the broadband background emissions are in the infrared and visible wavelengths. These scans also showed that the hexane and Jet-A gave OH and CH signals of approximately equal intensity. The transient histories of OH and CH were investigated by performing light-off ignition tests and intermittent light-off ignition tests. These various flame conditions showed that both signals were good indicators of flame presence, showing on average, a response time of better than 3 milliseconds. It was found that when the Hydrogen to Carbon ratio of the fuel was decreased, the CH signal strength increased as a percentage of OH signal intensity. Finally, the output signal intensity was found to be sensitive to both the flame image magnification and to the part of the flame observed. / Master of Science

One or the characteristics of all anthracite coal, with its low volatile content, is its ability to burn completely in a small volume. Another characteristic and disadvantage of local, semi-anthracite coal is its high ash content. It is the authors' belief that local, semi-anthracite coal can be burned most effectively for domestic heating if the furnace design allows for these characteristics. With these facts in mind, it was decided that the Anthratube had excellent possibilities as a domestic unit for burning local coal. The Anthratube, by its compactness, takes full advantage of the first characteristic; with its ash-removing grate, it overcomes to a great extent the disadvantage of the second characteristic. The purpose of this thesis was, then, to determine whether or not various sizes of local, semi-anthracite coal from the Merrimac seam could be successfully burned in the Anthratube. The coal used for this investigation was obtained from the Great Valley Anthracite Corporation located at McCoy, Virginia. 1. Pea size, local coal can be burned very successfully in the Anthratube. Overall boiler efficiencies of the unit with this size coal are high over a wide range of loads. Of the sizes of coal burned, pea size is most suitable for the Anthratube. 2. Buckwheat size, local coal canoe burned in the Anthratube with good results. The overall boiler efficiencies obtained with this size of coal are good, although not as high as those obtained with the pea coal. 3. The performance of the Anthratube with rice size, local coal is inferior to that achieved with pea and buckwheat sizes. The output of the unit is seriously limited when using this size. 4. Culm size, local coal cannot be burned in the Anthratube. / M.S.

A thesis submitted to the Faculty of Engineering, University of the Witwatersrand, Johannesburg, in fulfillment of the requirements for the degree of Doctor of Philosophy. / A theoretical and experimental treatment of fire processes in fuel-Lined, ventilated passages is presented. Initially a radially well mixed axial flow condition is considered. Experiments are first performed in non-stratified flow conditions where fire propagation and gas temperature histories are acquired from liquid and solid fuelled fires. Theory and experiment;display transient fire propagation for typical duct fire scenarios where initial fuel mass Loading is constant with respect to duct length. ( Abbreviation abstract ) / AC2017

Lean combustion is increasingly employed in both ground-based gas turbines and aircraft engines for minimizing NOx emissions. Operating under lean conditions increases the risk of Lean Blowout (LBO). Thus LBO proximity sensors, combined with appropriate blowout prevention systems, have the potential to improve the performance of engines. In previous studies, atmospheric pressure, swirl flames near LBO have been observed to exhibit partial extinction and re-ignition events called LBO precursors. Detecting these precursor events in optical and acoustic signals with simple non-intrusive sensors provided a measure of LBO proximity. This thesis examines robust LBO margin sensing approaches, by exploring LBO precursors in the presence of combustion dynamics and for combustor operating conditions that are more representative of practical combustors, i.e., elevated pressure and preheat temperature operation. To this end, two combustors were used: a gas-fueled, atmospheric pressure combustor that exhibits pronounced combustion dynamics under a wide range of lean conditions, and a low NOx emission liquid-fueled lean direct injection (LDI) combustor, operating at elevated pressure and preheat temperature. In the gas-fueled combustor, flame extinction and re-ignition LBO precursor events were observed in the presence of strong combustion dynamics, and were similar to those observed in dynamically stable conditions. However, the signature of the events in the raw optical signals have different characteristics under various operating conditions. Low-pass filtering and a single threshold-based event detection algorithm provided robust precursor sensing, regardless of the type or level of dynamic instability. The same algorithm provides robust event detection in the LDI combustor, which also exhibits low level dynamic oscillations. Compared to the gas-fueled combustor, the LDI events have weaker signatures, much shorter durations, but considerably higher occurrence rates. The disparity in precursor durations is due to a flame mode switch that occurs during precursors in the gas-fueled combustor, which is absent in the LDI combustor. Acoustic sensing was also investigated in both the combustors. Low-pass filtering is required to reveal a precursor signature under dynamically unstable conditions in the gas-fueled combustor. On the other hand in the LDI combustor, neither the raw signals nor the low-pass filtered signals reveal precursor events. The failure of acoustic sensing is attributed in part to the lower heat release variations, and the similarity in time scales for the precursors and dynamic oscillations in the LDI combustor. In addition, the impact of acoustic reflections from combustor boundaries and transducer placement was addressed by modeling reflections in a one-dimensional combustor geometry with an impedance jump caused by the flame. Implementing LBO margin sensors in gas turbine engines can potentially improve time response during deceleration transients by allowing lower operating margins. Occurrence of precursor events under transient operating conditions was examined with a statistical approach. For example, the rate at which the fuel-air ratio can be safely reduced might be limited by the requirement that at least one precursor occurs before blowout. The statistics governing the probability of a precursor event occurring during some time interval was shown to be reasonably modeled by Poisson statistics. A method has been developed to select a lower operating margin when LBO proximity sensors are employed, such that the lowered margin case provides a similar reliability in preventing LBO as the standard approach utilizing a more restrictive operating margin. Illustrative improvements in transient response and reliabilities in preventing LBO are presented for a model turbofan engine. In addition, an event-based, active LBO control approach for deceleration transients is also demonstrated in the engine simulation.

With strict environmental regulations, gas turbine emissions have been heavily constrained. This requires operating conditions wherein thermo-acoustic flame instabilities are prevalent. During this process the combustor acoustics and combustion heat release fluctuations are coupled and can cause severe structural damage to engine components, reduced operability, and inefficiency that eventually increase emissions. In order to develop an engine without these problems, there needs to be a better understanding of the physics behind the coupling mechanisms of this instability. Among the several coupling mechanisms, the “velocity coupling” process is the main focus of this thesis. The majority of literature has treated axisymmetric disturbance fields which are typical of longitudinal acoustic forcing and axisymmetric excitation of ring vortices. Two important non-axisymmetric disturbances are: (1) transverse acoustics, in the case of circumferential modes of a multi-nozzle annular combustor and (2) helical flow disturbances, seen in the case of swirling flow hydrodynamic instabilities. With significantly less analytical treatment of this non-axisymmetric problem, a general framework is developed for three-dimensional swirl-stabilized flame response to non-axisymmetric disturbances. The dynamics are tracked using a level-set based G-equation applicable to infinitely thin flame sheets. For specific assumptions in a linear framework, general solution characteristics are obtained. The results are presented separately for axisymmetric and non-axisymmetric mean flames. The unsteady heat release process leads to an unsteady volume generation at the flame front due to the expansion of gases. This unsteady volume generation leads to sound generation by the flame as a distributed monopole source. A sound generation model is developed where ambient pressure fluctuations are generated by this distributed fluctuating heat release source on the flame surface. The flame response framework is used to provide this local heat release source input. This study has been specifically performed for the helical flow disturbance cases to illustrate the effects different modes have on the generated sound. Results show that the effects on global heat release and sound generation are significantly different. Finally, the prediction from the analytical models is compared with experimental data. First, a two-dimensional bluff-body stabilized flame experiment is used to obtain measurements of both the flow and flame position in time. This enables a local flame response comparison since the data are spatially resolved along the flame. Next, a three-dimensional swirl-stabilized lifted flame experiment is considered. The measured flow data is used as input to the G-equation model and the global flame response is predicted. This is then compared with the corresponding value obtained using global CH* chemilumenescence measurements.

Thesis: M.S., Massachusetts Institute of Technology, Department of Mechanical Engineering, 1981 / Includes bibliographical references. / by Mark Charles Sellnau. / M.S. / M.S. Massachusetts Institute of Technology, Department of Mechanical Engineering

Indiana University-Purdue University Indianapolis (IUPUI) / Pipe bombs are a common form of improvised explosive device, due in part to their ease of construction. Despite their simplistic nature, the lethality of pipe bombs should not be dismissed. Due to the risk of harm and their commonality, research into the pipe bomb deflagration process and subsequent chemical analysis is necessary. The laboratory examination of pipe bomb fragments begins with a visual examination. While this is presumptive in nature, hypotheses formed here can lead to subsequent confirmatory exams. The purpose of this study was to measure the mass and velocity of pipe bomb fragments using high speed video. These values were used to discern any trends in container type (PVC or black/galvanized steel), energetic filler (Pyrodex or double base smokeless powder), and ambient temperature (13°C and -8°C). The results show patterns based on container type, energetic filler, and temperature. The second stage of a laboratory exam is chemical analysis to identify any explosive that may be present. Legality calls for identification only, not quantitation. The purpose of this study is to quantitate the amount of explosive residue on post-blast pipe bomb fragments. By doing so, the instrumental sensitivities required for this type of analysis will be known. Additionally, a distribution of the residue will be mapped to provide insight into the deflagration process of a device. This project used a novel sampling technique called total vaporization solid phase microextraction. The method was optimized for nitroglycerin, the main energetic in double base smokeless powder. Detection limits are in the part per billion range. Results show that the concentration of residue is not uniform, and the highest concentration is located on the endcaps regardless of container type. Total vaporization solid phase microextraction was also applied to automotive racing samples of interest to the National Hot Rod Association. The purpose of this project is two-fold; safety of the race teams in the form of dragstrip adhesive consistency and monitoring in the form of fuel testing for illegal adulteration. A suite of analyses, including gas chromatography mass spectrometry, infrared spectroscopy, and evaporation rate, were developed for the testing of dragstrip adhesives. Gas chromatography mass spectrometry methods were developed for both nitromethane based fuel as well as racing gasolines. Analyses of fuel from post-race cars were able to detect evidence of adulteration. Not only was a novel technique developed and optimized, but it was successfully implemented in the analysis of two different analytes, explosive residue and racing gasoline. TV-SPME shows tremendous promise for the future in its ability to analyze a broad spectrum of analytes.