A second law analysis of compression ignition engine was completed using a thermodynamic engine cycle simulation. The major components of availability destruction and transfer for an entire engine cycle were identified and the influence of mode of combustion, injection timing and EGR on availability balance was evaluated. The simulation pressure data was matched with the available experimental pressure data gathered from the tests on the Isuzu 1.7 L direct injection diesel engine. Various input parameters of the simulation were changed to represent actual engine conditions. Availability destruction due to combustion decreases with advanced injection timing and under premixed compression ignition (PCI) modes; but it is found to be insensitive to the level of EGR. Similarly, trends (or lack of trends) in the other components of availability balance were identified for variation in injection timing, EGR level and mode of combustion. Optimum strategy for efficient combustion processes was proposed based on the observed trends.

The goal of this study is to assess conventional and low temperature dual fuel combustion in light- and heavy-duty multi-cylinder compression ignition engines in terms of combustion characterization, performance, and emissions. First, a light-duty compression ignition engine is converted to a dual fuel engine and instrumented for in-cylinder pressure measurements. The primary fuels, methane and propane, are each introduced into the system by means of fumigation before the turbocharger, ensuring the airuel composition is well-mixed. Experiments are performed at 2.5, 5, 7.5, and 10 bar BMEP at an engine speed of 1800 RPM. Heat release analyses reveal that the ignition delay and subsequent combustion processes are dependent on the primary fuel type and concentration, pilot quantity, and loading condition. At low load, diesel-ignited propane yields longer ignition delay periods than diesel-ignited methane, while at high load the reactivity of propane is more pronounced, leading to shorter ignition delays. At high load (BMEP = 10 bar), the rapid heat release associated with diesel-ignited propane appears to occur even before pilot injection, possibly indicating auto-ignition of the propane-air mixture. Next, a modern, heavy-duty compression ignition engine is commissioned with an open architecture controller and instrumented for in-cylinder pressure measurements. Initial diesel-ignited propane dual fuel experiments (fumigated before the turbocharger) at 1500 RPM reveal that the maximum percent energy substitution (PES) of propane is limited to 86, 60, 33, and 25 percent at 5, 10, 15, and 20 bar BMEP, respectively. Fueling strategy, injection strategy, exhaust gas recirculation (EGR) rate, and intake boost pressure are varied in order to maximize the PES of propane at 10 bar BMEP, which increases from 60 PES to 80 PES of propane. Finally, diesel-ignited propane dual fuel low temperature combustion (LTC) is implemented using early injection timings (50 DBTDC) at 5 bar BMEP. A sweep of injection timings from 10 DBTDC to 50 DBTDC reveals the transition from conventional to low temperature dual fuel combustion, indicated by ultra-low NOx and smoke emissions. Optimization of the dual fuel LTC concept yields less than 0.02 g/kW-hr NOx and 0.06 FSN smoke at 93 PES of propane.

The performance characteristics of a diesel fuel piloted syngas compression ignition engine are presented in this thesis. A stock Hatz 1D81 engine was converted to operate in dual fuel mode through the elimination of the governor system and addition of an in-cylinder pressure transducer and custom intake system to facilitate the mixing of the gaseous fuel and combustion air. The engine was run on a Superflow water brake dynamometer and benchmarked with diesel to compare against manufacturer specifications. This was followed by dual fuel operation on methane and syngas, with the results being compared through performance characteristics. When operated on methane, the engine attained higher peak in-cylinder pressures along with higher torque, power, and thermal efficiency values for equal equivalence ratios. It was necessary to use greater amounts of syngas to reach comparable results with methane due to the lower energy content of syngas. The ignition delay was greater for syngas, and the onset of knock occurred earlier with syngas in comparison to methane. The heat release, Q, was comparable for both fuels and the exhaust gas emissions were significantly lower for operation with syngas. With emphasis on clean engine operation, syngas operation proved to be viable due to its renewable nature, significantly lower exhaust gas emissions, equal heat release characteristics, and larger useable operating range when compared to methane. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2012-05-28 15:02:49.227

Controlling ignition timing and flame stabilization is one of the most outstanding challenges limiting the development of modern, efficient and low-emission compression ignition engines (CIEs). In this study, the role of turbulence on two-stage ignition dynamics and subsequent flame stabilization at diesel engine conditions is assessed by performing direct numerical simulations in a simplified inflow-outflow premixed configuration. The thermochemical conditions are chosen to match those of the most reactive mixture in the Engine Combustion Network’s n-dodecane Spray A flame (temperature of 813 K, pressure of 60 atm, equivalence ratio of 1.3, and with 15% vol. O2 in the ambient gas). Inflow velocities 4 to 16 times larger than the laminar flame speed are considered. As a result, in the absence of turbulence, ignition and flame stabilization are controlled by advection and chemistry, diffusion being negligible. Ignition delays match those of the homogeneous reactor and both the cool flame, due to low-temperature chemistry (LTC), and the hot flame, due to high-temperature chemistry (HTC), are spontaneous ignition fronts. Turbulence alters this picture in two ways. First, the second-stage (HTC) ignition delay is increased considerably, in contrast with the first-stage (LTC) ignition delay, which remains virtually unaffected. Second, a sufficiently high turbulence intensity makes the cool spontaneous ignition front transition to a cool deflagration which moves upstream to the inlet, while the hot flame is pushed downstream, still stabilized by spontaneous ignition. The latter phenomenon is caused by the reduced reactivity of LTC products as the cool flame transitions from spontaneous ignition to deflagration. Further increasing the turbulence intensity leads to both cool and hot flames transitioning to deflagrations. For the hot flame, the mechanism governing this transition is the increase in magnitude of progress variable gradient under increased turbulence or reduced inflow velocity, while in cool flames it is mainly due to the reduction in chemical source terms. In addition to turbulence intensity, the role of inflow velocity, integral length scale, and oxygen concentration level on this transition is assessed and modeling challenges are discussed. Finally, a chemical explosive mode analysis is provided to further characterise the ignition and transition phenomena. The present results highlight important fundamental roles of turbulence expected to modulate CIE combustion dynamics.

Gasoline and gasoline-like fuels (naphtha) have high volatility, which results in flash boiling spray in gasoline engines when operated at throttling or low load conditions. Flash boiling can achieve better atomization, thus benefit fuel evaporation and fuel-air mixing. However, when flash boiling occurs, spray morphology, and fuel distribution are dramatically varied from the injectors' intentional design. This difference will affect the performance of combustion and emissions. Thus it is essential to investigate the spray collapse phenomenon regarding varied conditions. The currently developing gasoline compression ignition (GCI) engines, also has throttled stoichiometric spark ignition operation mode, which inevitably has flash boiling possibility. However, there is a lack of research on flash boiling spray with a GCI injector, which has a large designed cone angle. This work aims to understand the spray collapse phenomenon and fill the gap in GCI flash boiling spray. Simultaneous side-view diffused back illumination (DBI) and front-view mie-scattering are used to capture the liquid spray development. Simultaneous shadowgraph from side and front view are used for recording the liquid+vapor phase spray development. Criteria for distinguishing different spray regimes have been established from these results. It shows this GCI injector is more resistant to collapse than the other conventional gasoline direct injection (GDI) injectors reported in the literature. A combination of DBI and space-time tomographic algorithm is validated in this work, achieving 3D reconstruction of the spray volume development from non-flashing to collapsed spray regime at low cost. The 3D results help elucidate the spray collapse procedure and provide validation data for CFD simulation. Structured laser illumination planar imaging (SLIPI) is firstly implemented in flash boiling spray study in this work to suppress the multiple scattering effect. Reconstructed 3D results from slice sweeping by SLIPI methods exposes the hollow structure in the spray's collapsed central jet, which has not been reported previously by other methods. Different spray motion types are summarized for the transitional and collapsed spray regime from the SLIPI slice and confirmed by the particle image velocimetry (PIV) technique.

A 12.9 L heavy duty compression ignition engine was tested with strategies for dual fuel optimization. The effects of varied intake manifold pressure as well as split-injection strategies at a load of 5 bar BMEP and 85 PES were observed. These results were used to allow testing of split-injection strategies at a higher load of 10 bar BMEP at 70 PES that were void of MPRR above 2000 kPa/CAD. The split-injection strategies at 5 bar BMEP showed that lower BSNOx can be achieved with minimal drop in FCE. Varying intake manifold pressure revealed that combustion occurs earlier in a cycle with increasing intake manifold pressure and indirectly increasing FCE. A load of 10 bar BMEP at 70 PES should only use split-injection strategy to maintain load without high MPRR as efficiency drops with dependency on the second injection.

On-board hydrogen and syngas production is considered as a transition solution from fossil fuel to hydrogen powered vehicles until problems associated with hydrogen infrastructure, distribution and storage are resolved. A hydrogen- or syngas-rich stream, which substitutes part of the main hydrocarbon fuel, can be produced by supplying diesel fuel in a fuel-reforming reactor, integrated within the exhaust pipe of a diesel engine. The primary aim of this project was to investigate the effects of intake air enrichment with product gas on the performance, combustion and emissions of a diesel engine. The novelty of this study was the utilisation of the dilution effect of the reformate, combined with replacement of part of the hydrocarbon fuel in the engine cylinder by either hydrogen or syngas. The experiments were performed using a fully instrumented, prototype 2.0 litre Ford HSDI diesel engine. The engine was tested in four different operating conditions, representative for light- and medium-duty diesel engines. The product gas was simulated by bottled gases, the composition of which resembled that of typical diesel reformer product gas. In each operating condition, the percentage of the bottled gases and the start of diesel injection were varied in order to find the optimum operating points. The results showed that when the intake air was enriched with hydrogen, smoke and CO emissions decreased at the expense of NOx. Supply of nitrogen-rich combustion air into the engine resulted in a reduction in NOx emissions; nevertheless, this technique had a detrimental effect on smoke and CO emissions. Under low-speed low-load operation, enrichment of the intake air with a mixture of hydrogen and nitrogen led to simultaneous reductions in NOx, smoke and CO emissions. Introduction of a mixture of syngas and nitrogen into the engine resulted in simultaneous reductions in NOx and smoke emissions over a wide range of the engine operating window. Admission of bottled gases into the engine had a negative impact on brake thermal efficiency. Although there are many papers in the literature dealing with the effects of intake air enrichment with separate hydrogen, syngas and nitrogen, no studies were found examining how a mixture composed of hydrogen and nitrogen or syngas and nitrogen would affect a diesel engine. Apart from making a significant contribution to existing knowledge, it is 3 believed that this research work will benefit the development of an engine-reformer system since the product gas is mainly composed of either a mixture of hydrogen and nitrogen or a mixture of syngas and nitrogen.

This thesis is about modelling of the combustion and emissions of dual fuel HCCI engines for design of “engine combustion system”. For modelling the combustion first the laminar flamelet model and a hybrid Lagrangian / Eulerian method are developed and implemented to provide a framework for incorporating detailed chemical kinetics. This model can be applied to an engine for the validation of the chemical kinetic mechanism. The chemical kinetics, reaction rates and their equations lead to a certain formula for which the coefficients can be obtained from different sources, such as NASA polynomials [1]. This is followed by study of the simulation results and significant findings. Finally, for investigation of the knock phenomenon some characteristics such as compression ratio, fuel equivalence ratio, spark timing and their effects on the performance of an engine are examined and discussed. The OH radical concentration (which is the main factor for production of knock) is evaluated with regard to adjustment of the above mentioned characteristic parameters. In the second part of this work the specification of the sample engine is given and the results obtained from simulation are compared with experimental results for this sample engine, in order to validate the method applied in AVL Fire software. This method is used to investigate and optimize the effects of parameters such as inlet temperature, fuels ratio, diesel fuel injection timing, engine RPM and EGR on combustion in a dual fuel HCCI engine. For modelling the dual fuel HCCI engine AVL FIRE software is applied to simulate the combustion and study the optimization of a combustion chamber design. The findings for the dual fuel HCCI engine show that the mixture of methane and diesel fuel has a great influence on an engine's power and emissions. Inlet air temperature has also a significant role in the start of combustion so that inlet temperature is a factor in auto-ignition. With an increase of methane fuel, the burning process will be more rapid and oxidation becomes more complete. As a result, the amounts of CO and HC emissions decrease remarkably. With an increase of premixed ratio beyond a certain amount, NOX emissions decrease. With pressure increases markedly and at high RPM, knock phenomenon is observed in HCCI combustion.

Student Number : 9707408V - MSc(Eng) research report - School of Mechanical, Industrial and Aeronautical Engineering - Faculty of Engineering and the Built Environment / This research is an investigation into the performance and combustion characteristics of a two-cylinder, four-stroke compression ignition engine fuelled on diesel and then on dimethyl ether (DME). Baseline tests were performed using diesel. The tests were then repeated for dimethyl ether fuelling. All DME tests were performed at an injection opening pressure of 210 bar, as recommended for diesel fuelling. The tests were all carried out at constant torque with incremental increases in speed and an improved method of measuring the DME flow rate was devised. It was found that the engine’s performance characteristics were very similar, regardless of whether the engine was fuelled on diesel or DME. Brake power, indicated power and cylinder pressure, during the highest loading condition of 55 Nm, were virtually identical for diesel and DME fuelling, with the most significant finding being that the engine was more efficient when fuelled on DME than when fuelled with diesel. Another interesting finding was that the energy release of diesel decreases with increasing load, whilst the energy release of DME increases with increasing load. At the highest loading condition of 55 Nm, the energy release of DME was approximately 210 joules higher than that of diesel. This investigation concluded that DME may definitely be a suitable substitute fuel for diesel.

With the depletion of petroleum based fuels and the corresponding concerns of national energy security issues, natural gas as an alternative fuel in IC engine applications has become an attractive option. Natural gas requires minimum mixture preparation, and is chemically stable, both of which make it a suitable fuel for homogeneous charged compression ignition (HCCI) engines. Compared to petroleum based fuels, natural gas produces less green-house emissions. However, natural gas is hard to auto-ignite and therefore requires a higher compression ratio, some amount of intake heating, or some type of pre-ignition. In addition, natural gas usually has large differences in fuel composition from field to field, which adds more uncertainties for engine applications. The current study determines the auto-ignition characteristics, engine performance, and nitric oxides emissions as functions of major operating parameters for a natural gas fueled HCCI engine, and determines differences relative to gasoline fueled HCCI engines which have been studied for many years. These tasks have been done using both zero- and multi-dimensional engine simulations. By zero-dimensional simulation, the effects of varying equivalence ratios, engine speeds, compression ratio, EGR level, intake pressure and fuel compositions are determined and analyzed in detail. To be able to account for the in-cylinder inhomogeneous effect on the HCCI combustion, multi-zone models coupled with cold-flow CFD simulations are employed in addition to the single-zone model. The effects of non-homogeneous temperature and equivalence ratio stratification on the ignition timing, combustion phasing, and emissions formation have been studied and discussed. Finally, the preliminary two-dimensional axial-symmetric CFD simulations have been conducted to study the in-cylinder temperature and the species distributions, which provide better visualization of the natural gas auto-ignition process.