Patchy particles are patterned particles with at least one well-defined patch that can have highly directional and strongly anisotropic interactions with other particles or surfaces. Multiple theoretical studies point to interesting self-assembly of these particles into superstructures and, as a result, a multitude of possible applications. However, reliable synthetic methods for patchy particles, especially at the sub-micron level, are still a challenge and an active area of research. This work presents a novel synthesis route for making patchy particles at the sub-micron level that involves the use of capillary condensation. Colloidal silica particles of various sizes were synthesized and ordered into closely-packed arrays via evaporative self-assembly. Various chemical agents were capillary condensed into the voids of this assembly which, due to the face-centered cubic structure of the crystallized colloidal silica, produced distinct \patches" on the particle surface. The patches on these particles were successfully functionalized with gold nanoparticles. This method was shown to provide control over the patch size by modifying the silica particle radius, which thermodynamically changes the amount of capillary condensation. The patchy nature of the resultant particles was confirmed using infrared spectroscopy, scanning electron and optical microscopies, energy dispersive x-ray analysis and zeta potential measurements.

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We have obtained spectra of 10 vibrational bands of the Cs₂ (2)³∏_u ← ϰ³∑⁺₉ system. The molecules were formed in a supersonic free jet expansion, and were excited by light from a single mode CW dye laser. The total laser induced fluorescence was measured at 90° to the incident light and molecular beam, using a photomultiplier. Using a slit system to image a selected part of the interaction region, we have reduced the Doppler width to about 350MHz. We have been able to resolve the discrepancy between the different vibrational band positions given in two previous papers. Our vibrational bands show broad rotational contours, but we have not been able to resolve individual rotational lines. We have also obtained rotationally resolved spectra of the bandhead region of 22 vibrational bands of the Β¹∏₉ ← X¹∑⁺_u system. We found that the frequencies of the bandheads agreed with the bandhead positions deduced from the Dunham coefficients of a previous work. We have developed a theoretical model of the rotational structure and intensity distribution, taking into account optical pumping and the small solid angle subtended by the detector. By fitting this model to the experimental spectrum of the v' = 3,u∿ = 0 band using least squares optimization, we were able to extract rotational constants and line positions. We found that these line positions were in good agreement with those from the previous work. We have discussed how such spectroscopic data may be used in a determination of the s-wave scattering length of caesium, and we have reviewed the validity of the scattering length and other pararneterisations of low energy Cs-Cs interactions.

This thesis develops and evaluates a method to simulate energy consumption and water production for a novel sorption dehumidication pro-cess. The system consists of a chamber comprising a hygroscopic materialand a heating device. The process consists of an adsorption phase anda regeneration phase. For both the regeneration phase and the adsorp-tion phase the model considers the heat distribution by thermal diusionand convection and the water transport by diusion and convection. Forthe regeneration phase the radiation is also considered since the radia-tive power increases with temperature to the power of four. Further, amodel for the condensation process is implemented and a model for thecondensation is suggested. To model the properties of the hygroscopicmaterials, the adsorption curves for SiO2 and AlO2 are investigated. Themodel were evaluated by comparing the simulated values with experimen-tal measurements.The results from the the simulation of the regeneration phase showsa good agreement with experimental data for the power and the energyconsumption even though the simulated values are a bit underestimated,about 10%. The water production is simulated to be about 25% higherthan the measured values. This discrepancy could be explained by aleakage of water vapour that was found in the experimental set up, whichis not considered in the model. This could also explain the underestimatedenergy consumption since the condensation energy in the system is toogreat. To improve the accuracy for the model the water leakage wouldneed to be implemented. The overestimation of water seemed to be thesame for the measurements from the same apparatus.For the adsorption phase a developed model, from an article for ad-sorption in silica, was implemented and tuned for the specic system. Thesimulations are in good agreement with the measurements but could betested further for more certainty.

An experimental study has been performed to investigate the condensation on the inner surface of open cavities located on horizontal and vertical surfaces of a refrigerator to simulate ice dispensers, water dispensers, electronic display slots, and door handles, etc. Cavity size, cavity depth and insulation thickness were variable parameters. Cavities were located on fresh food and freezer compartments to study two different boundary conditions. Level of condensation was put into a scale based on visual observation for condensed water droplets on the cavity surface. As a practical tool for design engineers, insulation thickness was plotted as a function of cavity depth indicating the level of condensation. Similar cavity geometries were tested on both freezer and fresh food compartments. Aluminum foil attached behind the inner surface of a cavity located on the fresh food door helped to decrease the level of condensation significantly. However, condensation can not be avoided for the cavities located on the freezer compartment deeper than critical values. Forming radius at the corners and on the edges of cavities decreased condensation on these regions. The effects of air circulation on condensation inside and outside the refrigerator were also investigated for some cavities. Particle Image Velocimetry (PIV) method was used to visualize non-disturbed air flow pattern over the cavity and at the cavity opening. High convective heat transfer at the cavity center was strongly associated with relatively high air velocity. Temperature distribution and flow pattern were analyzed by a CFD Programme. Condensation due to relatively low temperatures at the corners and on the edges was associated with conductive heat transfer in multiple directions and insufficient air circulation on these regions.

The Double-TOP trap is a new type of magnetic trap for neutral atoms, and is suitable for Bose-Einstein condensates (BECs) and evaporatively cooled atoms. It combines features from two other magnetic traps, the Time-averaged Orbiting Potential (TOP) and Ioffe-Pritchard traps, so that a potential barrier can be raised in an otherwise parabolic potential. The cigar-like cloud of atoms (in the single-well configuration) is divided halfway along its length when the barrier is lifted. A theoretical model of the trap is presented. The double-well is characterised by the barrier height and well separation, which are weakly coupled. The accessible parameter space is found by considering experimental limits such as noise, yielding well separations from 230 [mu]m up to several millimetres, and barrier heights from 65 pK to 28 [mu]K (where the energies are scaled by Boltzmann�s constant). Potential experiments for Bose-Einstein condensates in this trap are considered. A Double-TOP trap has been constructed using the 3-coil style of Ioffe-Pritchard trap. Details of the design, construction and current control for these coils are given. Experiments on splitting thermal clouds were carried out, which revealed a tilt in the potential. Two independent BECs were simultaneously created by applying evaporative cooling to a divided thermal cloud. The Double-TOP trap is used to form a linear collider, allowing direct imaging of the interference between the s and d partial waves. By jumping from a double to single-well trap configuration, two ultra-cold clouds are launched towards a collision at the trap bottom. The available collision energies are centred on a d-wave shape resonance so that interference between the s and d partial waves is pronounced. Absorption imaging allows complete scattering information to be collected, and the images show a striking change in the angular distribution of atoms post-collision. The results are compared to a theoretical model, verifying that the technique is a useful new way to study cold collisions.

Thesis (Ph.D.)--McMaster University (Canada), 1994. / Source: Dissertation Abstracts International, Volume: 56-08, Section: B, page: 4324. Adviser: P. Harrison.

Thesis (Ph. D.)--Ohio State University, 2007. / Title from first page of PDF file. Includes bibliographical references (p. 187-192).

Thesis (Ph.D.)--Michigan State University. Dept. of Physics and Astronomy, 2008. / Title from PDF t.p. (viewed on Mar. 27, 2009) Includes bibliographical references (p. 95-102). Also issued in print.

Thesis (Ph. D.)--University of Texas at Austin, 2008. / Vita. Includes bibliographical references.