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Thermotropic liquid crystalline polymers (TLCPs) have attracted great interest because of the combination of their promising properties, which includes high stiffness and strength, excellent processability, and outstanding chemical resistance. TLCPs exhibit inherently low viscosity relative to many other conventional thermoplastics. The low melt viscosity is detrimental to processes requiring high melt strength, such as extrusion blow molding, film blowing, thermoforming and multilayer coextrusion. Our laboratory has developed a unique method to increase the viscosity of TLCPs by first raising the temperature above the melting point (Tm) to exclude all solid crystalline structure, and then lowering the temperature below Tm to super cool the materials. Additionally, the super-cooling behavior of TLCPs allows them to be blended with other thermoplastics possessing lower processing temperatures. The initial focus of this dissertation is to investigate the processing temperature of a representative TLCP in the super-cooled state, using the methods of small amplitude oscillatory shear (SAOS), the startup of shear flow and differential scanning calorimetry (DSC). The TLCP used in this work is synthesized from 4-hydroxybenzoic acid (HBA), terephthalic acid (TA), hydroquinone (HQ) and hydroquinone derivatives (HQ-derivatives). The TLCP of HBA/TA/HQ/HQ-derivatives has a melting point, Tm, of around 280 oC. Once melted, the TLCP can be cooled 30 oC below the Tm while still maintaining its processability. As the TLCP was cooled to 250 oC, a one order magnitude increase in viscosity was obtained at a shear rate of 0.1 s- 1. Additionally, super cooling the TLCP did not significantly affect the relaxation of shear stress after preshearing. However, the recovery of the transient shear stress in the interrupted shear measurements was suppressed to a great extent in the super-cooled state. The second part of this work is concerned with the extrusion blow molding of polymeric blends containing the TLCP of HBA/TA/HQ/HQ-derivatives and high density polyethylene (HDPE), using a single screw extruder. The blends were processed at a temperature of 260 oC which is 20 oC below Tm of the TLCP such that the thermal degradation of HDPE was minimized. Bottles were successfully produced from the blends containing 10, 20 and 50 wt% TLCP. The TLCP/HDPE blend bottles exhibited an enhanced modulus relative to pure HDPE. However, the improvement in tensile strength was marginal. At 10 and 20 wt% TLCP contents, the TLCP phase existed as platelets, which aligned along the machine direction. A co-continuous morphology was observed for the blend containing 50 wt% TLCP. The preliminary effectiveness of maleic anhydride grafted HDPE (MA-g-HDPE) as a compatibilizer for the TLCP/HDPE system was also studied. The injection molded ternary TLCP/HDPE/MA-g-HDPE blends demonstrated superior mechanical properties over the binary TLCP/HDPE blends, especially in tensile strength. Consequently, it is promising to apply the ternary blends of TLCP/HDPE/MA-g-HDPE in the blow molding process for improved mechanical properties. Finally, this work tends to determine how the isothermal crystallization behavior of a TLCP can be adjusted by blending it with another TLCP of lower melting point. One TLCP (Tm~350 oC) used is a copolyester of HBA/TA/HQ/HQ-derivatives with high HBA content. The other TLCP (Tm~280 oC) is a copolyesteramide of 60 mol% hydroxynaphthoic acid, 20 mol% terephthalic acid and 20 mol% 4-aminophenol. The TLCP/TLCP blends and neat TLCPs were first melted well above their melting points, then cooled to the predetermined temperatures below the melting temperatures at 10 oC/min to monitor the isothermal crystallization. As the content of the low melting TLCP increased in the blends, the temperature at which isothermal crystallization occurred decreased. Comparing with neat TLCPs, the blend of 75% low melting TLCP crystallized at a lower temperature than the pure matrices, and the blend remained as a stable super-cooled fluid in the temperature range from 220 to 280 oC. Under isothermal conditions, differential scanning calorimetry (DSC) was not capable of reliably detecting the the low energy released in the initial stage of crystallization. In contrast, small amplitude oscillatory shear (SAOS) was more sensitive to detecting isothermal crystallization than DSC. / Ph. D.

Thesis (MScEng (Mechanical and Mechatronic Engineering))--University of Stellenbosch, 2010. / ENGLISH ABSTRACT: Large air‐cooled heat exchangers and condensers make use of fan arrays to provide cooling. The performance of the fan arrays are however negatively affected by distorted inlet conditions. Given the size of these fans, quantifying exactly what the detrimental effects are is practically impossible. This serves as motivation for developing a scaled multi‐fan testing platform that is able to mimic the behaviour of a full‐scale array but at a more measureable and manageable scale. This investigation was conducted in two parts. A Reynolds number investigation was conducted to determine what effect incorporating Reynolds number effects will have on the scaled fan performance. Computational fluid dynamics (CFD) was used to determine where turbulent transition onset occurs on the full‐scale fan blades and trip wires were then sized and positioned appropriately to recreate the same transition effect. From this initial investigation it was found that the trip wires have an allround negative impact on fan performance but when compensated for by increasing the blade angle, the tripped fan static pressure rise performance is comparable with the non‐tripped fan performance. This suggests that the Reynolds number effects may be ignored for this scaled fan testing investigation. Scaled equivalents of the fans in cooling arrays were tested in a three row multi‐fan array which, using symmetry, represents a typical bay in a full‐scale installation. Various platform heights were simulated and the corresponding decrease in system performance was compared to a model formulated to predict how fan volumetric effectiveness decreases with platform height. The model deviated from the test data at very low platforms heights. A replacement fan for the scaled equivalent fan was tested while installed as the edge fan of a multi‐fan array, the fan worst affected by any inlet disturbance, and was found to perform similarly to the scaled equivalent fan for most platform heights but exceeded the scaled equivalent fan’s performance for the lowest platform height and the most adverse conditions. This proves the effectiveness of the replacement fan as an edge fan. / AFRIKAANSE OPSOMMING: Groot lugverkoelde warmteruilers maak gebruik van waaier matrikse om verkoeling te voorsien. Die verrigting van die waaieropstelling word egter negatief beïnvloed deur versteurde inlaattoestande. Gegewe die grootte van hierdie waaiers is daar geen praktiese metode om die nadelige invloed van die versteurde inlaattoestande te kwantifiseer nie. Hierdie dien as motivering vir die ontwikkeling van ‘n multi‐waaier toetsplatform wat daartoe in staat is om die gedrag van die volskaal opstelling na te boots maar op ‘n baie meer meetbare en hanteerbare skaal. Hierdie ondersoek was uitgevoer in twee dele. ‘n Reynoldsgetal ondersoek was uitgevoer om te bepaal watter impak dit sal hê op die skaalwaaier verrigting indien die Reynolds getaleffekte ingesluit word in die toetswerk. Berekende vloeidinamka (BVD) was gebruik om te bepaal waar turbulente oorgang voorkom op die volskaal waaierlemme en pooitjiedrade was geselekteer en geposisioneer hiervolgens om dieselfde oorgang te herskep. Vanuit hierdie aanvanklike ondersoek was dit gevind dat die pooitjiedrade ‘n algehele afname in verrigting tot gevolg het, maar wanneer dit oorkom word deur die lemhoek op te stel, die gedrag en verrigting van die gepooitjiede waaier soortgelyk is aan die van die nie‐gepooitjiede waaier. Hierdie gedrag stel voor dat die Reynoldsgetalle maar geïgnoreer kan word vir hierdie skaalwaaier toetswerk. Gelykwaardige skaalwaaiers van die wat in bedryf is in volskaal opstellings was getoets in ‘n drie ry multi‐waaier opstelling wat, deur simmetrie, verteenwordigend is van ‘n tipiese straat in ‘n volskaal opstelling. Verskeie platformhoogtes was gesimuleer en die ooreenstemmende afname in stelsel verrigting was vergelyk met ‘n model wat geformuleer is juis om te voorspel hoe die volumetriese effektiwiteit afneem met platformhoogte. Die model wyk af van die toetsdata by baie lae platform hoogtes. ‘n Vervangingswaaier vir die aanvanklike geskalleerde waaier was getoets as ‘n randwaaier, die waaier wat die ergste benadeel word deur versteurde inlaattoetstande, in die multi‐waaier opstelling. Die vervangingswaaier het soortgelyk aan die aanvanklike waaier verrig vir meeste platformhoogtes, maar oortref die aanvanklike waaier se werksverrigting by die laagste platformhoogte en mees ongunstige toestande. Hierdie bewys die vermoëns van die vervangingswaaier as ‘n randwaaier.

Thesis (MScEng (Mechanical and Mechatronic Engineering))--University of Stellenbosch, 2011. / Please refer to full text to view abstract.

This thesis is a follow up on "SPARC fast reactor design: Design of two passively metal-fuelled sodium-cooled pool-type small modular fast reactors with Autonomous Reactivity Control" by Tobias Lindström (2015). In this thesis the two reactors designed by Lindström in said thesis were evaluated. The goal was to determine the reactors ability to load follow as well as the burnup of the neutron absorber used in the passive control system. To be able to determine the dynamic behaviour of the reactors the reactivity feedbacks of the cores were modelled using Serpent, a Monte Carlo simulation software for 3D neutron transport calculations. These feedbacks were then implemented into a dynamic simulation of the core, primary and secondary circulation and steam generator. The secondary circulation and feedwater flow were used to regulate steam temperature and turbine power. The core was left at constant coolant flow and no control rods were used. The simulations showed that the reactor was able to load follow between 100 % and 40 % of rated power at a speed of 6 % per minute. It was also shown that the reactor could safely adjust its power between 100 % and 10 % of rated power suggesting that load following is possible below 40 % of rated power but at a lower speed. Finally the reactors were allowed compensate for the variations in a week of the Latvian wind power production in order to show one possible application of the reactor.

Experimental data on SuperCritical-Water (SCW) cooled bundles are very limited. Major problems with performing such experiments are: 1) small number of operating SCW experimental setups and 2) difficulties in testing and experimental costs at very high pressures, temperatures and heat fluxes. However, SuperCritical Water-cooled nuclear Reactor (SCWRs) designs cannot be finalized without such data. Therefore, as a preliminary approach experiments in SCW-cooled bare tubes and in bundles cooled with SC modeling fluids can be used. One of the SC modeling fluids typically used is Freon-12 (R-12) where the critical pressure is 4.136 MPa and the critical temperature is 111.97ºC. These conditions correspond to a critical pressure of 22.064 MPa and critical temperature of 373.95ºC in water. A set of experimental data obtained in a Freon-12 cooled vertical bare bundle at the Institute of Physics and Power Engineering (IPPE, Obninsk, Russia) was analyzed. This set consisted of 20 cases of a vertically oriented 7-element bundle installed in a hexagonal flow channel. To secure the bundle in the flow channel 3 thin spacers were used. The dataset was obtained at equivalent parameters of the proposed SCWR concepts. Data was collected at pressures of about 4.65 MPa for several different combinations of wall and bulk-fluid temperatures that were below, at, or above the pseudocritical temperature. Heat fluxes ranged from 9 kW/m2 to 120 kW/m2 and mass fluxes ranged from 440 kg/m2s to 1320 kg/m2s. Also inlet temperatures ranged from 70ºC – 120ºC. The test section consisted of fuel elements that were 9.5 mm in diameter with the total heated length of 1 m. Bulk-fluid and wall temperature profiles were recorded using a combination of 8 different thermocouples.The data was analyzed with respect to its temperature profile and heat transfer coefficient along the heated length of the test section. In a previous study it was confirmed that there is the existence of three distinct regimes for forced convention with supercritical fluids. (1) Normal heat transfer; (2) Deteriorated heat transfer, characterized by higher than expected temperatures; and (3) Improved heat transfer, characterized by lower than expected temperatures. All three regions were observed for the 7 rod bundle experiments. This work compares the experimental data to predictions based upon current 1-D correlations for heat transfer in supercritical fluids. Results show that no current 1-D correlation was able to accurately predict heat transfer coefficients within ±50%. A parametric analysis of the data was also completed to determine if continuity in the experiment was present. Results of this study show that two distinct regions are present in the data. For cases with a mass flux below 1200 kg/m2s wall temperature profiles appear to be normal while in cases with mass flux above 1200 kg/m2s temperature given by the wall thermocouples were higher than normal. This phenomenon occurred regardless of heat flux-to-mass flux ratios. / UOIT

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Made available in DSpace on 2014-10-09T12:26:10Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:10:22Z (GMT). No. of bitstreams: 1 00951.pdf: 4937591 bytes, checksum: 160731d29ec9edf1fc78d0034f24638b (MD5) / Thesis (Doctorate) / IPEN/T / Massachusetts Institute of Technology - Cambridge, Mass - MIT

Every year wildfires threaten or destroy ecological habitats, man-made infrastructure and people’s lives. Additionally millions of dollars are spent each year trying to prevent and control these fires. Ideally if a wildfire can be detected before it rages out of control it can be extinguished and avoid large scale devastation. Traditional manned fire lookout towers are neither cost effective nor particularly efficient at detecting wildfire. It is proposed that temporal filtering can be used to isolate the signals created at the beginnings of potential wildfires. Temporal filtering can remove any background image and any periodic signals created by the camera movement. Once typical signals are analyzed, digital filters can be designed to pass fire signals while blocking the unwanted signals. The temporal filter passes only fire signals and signals generated by moving objects. These objects can be distinguished from each other by analyzing the objects mid and long wave energy profile. This algorithm is tested on 17 data sources and its results analyzed.

The Master’s thesis dealing with air-cooled condensers is split into four sections. The first section shows an overview of air cooling, introduction into air-cooled condensers of A-frame shape and finned tubes. The second section deals with heat transfer on the steam side and deals with trapped incondensables on the steam side of ACC. The third section deals with heat transfer on the air side, shows a brief overview of fans and selected problems on the air side. In the last section the simplified thedmodynamic calculation of air-cooled condenser is shown.