As increasing emphasis is placed upon the role surface processes play in regulating tectonic behaviour, the need for accurate measurements of denudation rate has become paramount. The quantity and quality of denudation rate studies has grown with the advent of cosmogenic radionuclide techniques, capable of recording denudation rates over timescales of 100 to 1000000 years. This study seeks to utilise cosmogenic 10Be concentrations measured in alluvial sediments in order to further develop this method and to investigate rates of basin-wide denudation in the San Bernardino Mountains, an active orogen associated with the San Andreas Fault system. The theory which underpins measurements of basin-wide denudation rates with cosmogenic radionuclide analysis is evaluated in light of recent understanding of production mechanisms. Field testing of the assumptions required by the basinwide denudation rate model highlights the importance of sampling thoroughly mixed sediments. Denudation rates ranging over three orders of magnitude are measured by applying the cosmogenic radionuclide technique in thirty-seven basins throughout the San Bernardino Mountains. Results show a relationship between denudation rate and slope which provides quantification of the threshold slope angle in high relief granitic environments and suggests tectonic activity is the first order control of denudation rates in these mountains. Mean annual precipitation is shown to exert no significant influence over the rates measured in the San Bernardino Mountains. Questions concerning denudation rates recorded over differing timespans are addressed using the cosmogenic technique, (U-Th)/He thermochronometry, incision into dated horizons and modern day sediment flux data. This comparison reveals that a decrease in rates with distance from the San Andreas Fault has been consistent throughout the lifespan of the San Bernardino Mountains and provides further evidence that a tectonic mechanism is driving denudation in this region. The relevance of both spatial and temporal scale in geomorphic studies is considered in light of these results, highlighting the need for a greater appreciation of their role in the interpretation of basin-wide denudation rates.

Long term fluvial incision spanning the Late Cenozoic is recorded in many fluvial systems around the world by terrace landform sequences. The incision manifests itself as inset sequences of river terraces which form terrace staircases. The timing of the onset of incision and the rate incision then proceeds at is poorly constrained due to the difficulties in dating river terraces. This study applies the technique of cosmogenic exposure dating to a fluvial staircase, for the first time, in the Sorbas Basin, SE Spain. Cosmogenic exposure dating allows the timing of abandonment of the fluvial terraces to be calculated therefore recording periods of incision. Cosmogenic exposure dating and the profile method offer a viable way to date Early and Middle Pleistocene terrace deposits. Combined exposure and burial age’s approaches using paired isotopes allow for insights into terrace aggradation and fluvial incision timing. The fluvial deposits in the Sorbas Basin record 1.0 Ma of incision by the Río Aguas. The timing of aggradation and incision in the Sorbas basin has been linked to both tectonics and climate cycles. Terrace aggradation took place in glacial and interglacial periods. The abandonment of terrace surfaces occurred both at warming transitions and in interglacial periods. New uplift rates calculated for the Pleistocene fluvial system suggest that tectonic activity in the Sorbas Basin has been episodic. The south margin and centre of the Sorbas Basin has uplifted at a faster rate than the northern margin impacting on the rates of incision taking place in the fluvial systems. Overall tectonic uplift has increased the fluvial system sensitivity to climatic variations.

Located beyond the southern limit of glaciation in Britain, the upland granitic terrain of Dartmoor, south-west England, has been exposed to long intervals of intense periglacial activity during the Pleistocene. This region has been significant in debates about appropriate models of long-term landscape change, most notably two-phase versus single-phase models of landform evolution, and the development of tors. However, given the previous lack of quantitative techniques capable of constraining denudation and specific process rates, and thereby testing developmental models for these features, there remains much uncertainty in the interpretation of the classic landforms of the region. This study measures concentrations of the cosmogenic nuclide 10Be produced in-situ in quartz within the upper few metres of the Earth surface. These reflect the history of near-surface exposure to cosmic radiation of sampled material, and allow for the interpretation of exposure age and/or erosion rates of the land surface. This research utilises these cosmogenic nuclide values to evaluate geomorphological processes and investigate key aspects of landform development. These include the formation of tors in non-glaciated regions, the development of regolith and boulderfields under periglacial conditions, and the derivation of catchment-averaged denudation rates. This study provides the first quantitative measurement of erosion on tor surfaces in Dartmoor, with typical rates of 14-45 mm ka-1. These are relatively high and comparable to other components of the landscape. In addition, there is no clear relationship of cosmogenic nuclide concentration to tor dimensions. It is shown that the tors are dynamic landforms and simple, two-stage development is an inappropriate model. Catchment-averaged denudation rates are derived and these long-term rates of 20-94 mm ka-1 are significantly higher than modern, short-term values. Finally, downslope transport in a palaeo-periglacial blockslope is investigated using 10Be concentrations. This variety of landforms and scale of investigation facilitates an integrated approach to the understanding of catchment-scale erosional dynamics. In addition, the complex nature of landform development that is evident in the area provides challenges to the application of in-situ cosmogenic nuclides and highlights both the potential and limitations of the technique.

Applications of in situ cosmogenic nuclides to problems in Quaternary geology require increasingly accurate and precise knowledge of nuclide production rates. Production rates depend on the terrestrial cosmic-ray intensity, which is a function of the elevation and geomagnetic coordinates of a sample site and the geomagnetic field intensity. The main goal of this dissertation is to improve the accuracy of cosmogenic dating by providing better constraints on the spatial variability of production rates.In this dissertation I develop a new scaling model that incorporates the best available cosmic-ray data into a framework that better describes the effects of elevation and geomagnetic shielding on production rates. This model is based on extensive measurements of energetic nucleon fluxes from neutron monitor surveys and on more limited data from low-energy neutron surveys. A major finding of this work is that neutron monitors yield scaling factors different from unshielded proportional counters. To verify that the difference is real I conducted an airborne survey of low-energy neutron fluxes at Hawaii (19.7° N 155.5° W) to compare with a nearby benchmark neutron monitor survey. Our data confirm that the attenuation length is energy dependent and suggest that the scaling factor for energetic nucleons is 10% higher between sea level and 4000 m than for low-energy neutrons at this location. An altitude profile of cosmogenic 36Cl production from lava flows on Mauna Kea, Hawaii, support the use of neutron flux measurements to scale production rates but these data do not have enough precision to confirm or reject the hypothesis of energy-dependent scaling factors.

This work aims to study the behavior of the western margin of the Greenland Ice Sheet during a period of pronounced ice retreat roughly 10,000 years ago, after the end of the last glacial period. It explores the efficiency of subglacial erosion, the spatial dynamics of ice retreat, and the rates of ice retreat. To address these questions, I use the radionuclides 10Be and 26Al, which form in rocks due to the bombardment of cosmic rays, only after the rocks have been exposed from underneath retreating ice. These nuclides can be used as a geologic dating technique to explore exposure history. Before applying this dating technique to address geological questions, it was critical to first perform methodological development. My work in the University of Vermont‘s new Cosmogenic Nuclide Laboratory served to improve the precision and efficiency of the pre-existing laboratory methods. New methodological advances ensured that samples from Greenland, which contained only low concentrations of 10Be and 26Al, could be used to yield meaningful results about ice behavior. Cosmogenic nuclide dating was applied at two sites along the ice sheet margin in central-western Greenland. At both of these sites, I collected paired bedrock and boulder samples in a transect normal to and outside of the present-day ice sheet margin. Samples were collected from a variety of elevations at numerous locations along the transects, thus providing three-dimensional coverage of the field area. After isolating the mineral quartz from the rocks, and isolating the elements Be and Al from the quartz, isotopic analysis was performed using accelerator mass spectrometry to quantify the relative abundances of the radionuclides against their respective stable isotopes. The southern study site, Ilulissat, is located on the western coast of Greenland at a latitude of 69N. Much previous work has been conducted here due to the presence of one of the largest ice streams in the northern hemisphere, Jakobshavn Isbræ. My work in Ilulissat demonstrated that subglacial erosion rates were high during previous glacial periods, efficiently sculpting and eroding the landscape. Ice retreat across the land surface began around 10,300 years ago, and the ice sheet retreated behind its present-day margin about 7,600 years ago. Ice retreat occurred at a rate of about 100 meters per year. My work in this area suggests that retreat in the large ice stream set the pace and timing for retreat of the neighboring ice sheet margin. The northern site, Upernavik, is located on the western coast of Greenland at a latitude of 73N. Little research has been conducted here in the past. Unlike in Ilulissat, my work here shows that the ice sheet did not efficiently erode the landscape, especially at high elevations, during previous glacial periods. This is likely because the ice was thinner, and therefore had a colder base, than the ice in Ilulissat. My work suggests that ice cover was lost from this area very rapidly, likely at rates of about 170 meters per year, in a single episode around 11,300 years ago. Comparison between the two study sites reveals that ice characteristics can vary appreciably over relatively small distances.

This research aims to understand the natural and human influences on erosion in three tributary watersheds to the Mekong River, Yunnan Province, China and to assess the utility of a novel application of isotopic indicators of erosion. It explores how erosion varies through time and space as a function of physical characteristics of the landscape, tectonic forces, and human alteration of the landscape for forestry and agriculture. To accomplish these goals, I use four sediment-associated radionuclides: in situ 10Be, meteoric 10Be, 210Pbex, and 137Cs. These isotopes accumulate in or on sediment grains, and each accumulates to a different depth on the landscape and has a different half-life. Thus, the isotopes can be used to track sediment as it moves across Earth's surface, each providing unique insight into processes occurring over a certain time period (from ~50 to 50,000 years) or eroding to a certain depth on the landscape. The studied watersheds range from 22° to 27° N latitude, and from 200 to 2500 km2 in area. I collected 54 samples of river-borne sediment within the three study watersheds, and measured the concentration of each isotope in every sample. In addition to the measured isotopic concentrations, I utilize on over 20 years of daily sediment yield data at the outlet of each watershed, hillslope steepness, normalized channel steepness (ksn), contemporary land-use data, elevation, and 56 years of mean annual precipitation data (MAP). Long-term erosion rates scale with topographic parameters in two of the three study basins, indicating that topography, or the underlying tectonic forces responsible for topography, control erosion rates over the past 6,000 to 50,000 years. Isotopic data also show that contemporary erosion is higher in cultivated areas than un-cultivated areas, a direct result of agricultural practices. Contemporary sediment yield, however, has not increased notably due to land-use change; however, under-representation of large stochastic events and sediment trapped by agriculture have reduced sediment yield relative to the long-term average in two of the studied watersheds. Overall, the data imply changes in contemporary erosion that are consistent with Chinese policies that promoted deforestation from the 1950's to the late 1980's and conservation from the late 1990's to present. This proves to be a significant finding, as the result of the top-down approach China has taken with conservation policy has been widely called into question in previous studies. While each isotope has the potential to provide unique information regarding erosional processes, in situ 10Be and 210Pbex proved to be the most useful, while meteoric 10Be was the most challenging to utilize. Though interpretation is complex, measuring all four isotopes on the same sediment samples helps to fully realize the potential of in situ 10Be to estimate background erosion by simultaneously allowing for assessment of contemporary and human induced erosion.

This dissertation presents results from three studies that address major scientific questions in glacial geology and paleoclimatology for the late Pleistocene and Holocene using relatively new geochemical and statistical techniques. Each of the studies attempts to answer a longstanding question in the respective field using geochemical or statistical methods that have not been applied to the problem thus far. A longstanding question in glaciology is the nature and mechanism of the so- called "Heinrich events" of the last ~60 ka. These massive iceberg discharge events into the North Atlantic from the partial breakup of the Laurentide Ice Sheet are identified from distinct ice rafted debris and detrital carbonate layers in marine sediment cores. The mechanism associated with the initiation of these events is commonly thought to be related to internal ice sheet instabilities. However, Heinrich events consistently occur following a long cooling trend that culminates in an extreme cold event, thus suggesting a possible triggering mechanism by climate. Recent modeling work has proposed an oceanic mechanism associated with ocean warming, but no physical evidence has been made available to date. To test this ocean-warming hypothesis, we measured temperature sensitive trace metals and stable isotopes in benthic foraminifera from a sediment core collected in the western North Atlantic that spans the last six Heinrich events and compared our results to climate model simulations using CCSM3. Our results show subsurface warming occurred prior to or coeval with nearly all of the Heinrich events of the last ~60 ka, thus implicating subsurface ocean warming as the main trigger of these rapid breakups of the Laurentide Ice Sheet. In the field of glacial geology a longstanding question has been the timing of alpine glacial advances during the Holocene. A number of studies have interpreted several Holocene glacial advances in western North America, but age control is based largely on relative dating techniques, which have been shown to be in error by up to 10,000 yrs in some cases. Based on 124 ¹⁰Be surface exposure ages from twenty cirque moraines in ten mountain ranges across western North America, glacier were retreating from moraine positions during the latest Pleistocene or earliest Holocene and not throughout the Holocene epoch as previously assumed, thus requiring a refined interpretation of Holocene glacial activity in western North America and the associated climate forcing. In the field of paleoclimatology a question regarding how global temperature varied over the entirety of the Holocene epoch has remained to be answered for some time. While many temperature reconstructions exist for the last 2000 years, a full Holocene temperature stack does not exist, despite its potential utility of putting modern climate change into a full interglacial perspective. Based on a global composite of 73 proxy based temperature record, a Holocene temperature stack was constructed and used to demonstrate that a general cooling of ~1°C has occurred from the early to mid Holocene and that centennial and millennial scale variability is modest. We account for both temperature calibration and chronologic uncertainties using a Monte Carlo based approach. Our results are consistent with prior reconstructions of the last 2000 years and now allow for a full Holocene temperature perspective for evaluation with present and future climate change. / Graduation date: 2011 / Access restricted to the OSU Community, at author's request, from May 5, 2011 - May 5, 2012

The main objective of this dissertation is to improve the knowledge of glacial chronology and paleoclimate of Turkey during the Late Quaternary. The 36Cl cosmogenic exposure ages of moraines show that Last Glacial Maximum (LGM) glaciers were the most extensive ones in Turkey in the last 22 ka (ka=thousands years), and they were closely correlated with the global LGM chron (between 19±23 ka). LGM glaciers started retreating 21.3±0.9 ka (1σ) ago on Mount Erciyes, central Turkey, and 20.4±1.3 ka ago on Mount Sandiras, southwest Turkey. Glaciers readvanced and retreated by 14.6±1.2 ka ago (Late Glacial) on Mount Erciyes and 16.2±0.5 ka ago on Mount Sandiras. Large Early Holocene glaciers were active in Aladaglar, south-central Turkey, where they culminated at 10.2±0.2 ka and retreated by 8.6±0.3 ka, and on Mount Erciyes, where they retreated by 9.3±0.5 ka. The latest glacial advance took place 3.8±0.4 ka ago on Mount Erciyes. Using glacier modeling together with paleoclimate proxy data from the region, I reconstructed the paleoclimate at these four discrete times. The results show that LGM climate was 8-11oC colder than today (obtained from paleotemperature proxies) and wetter (up to 2 times) on the southwestern mountains, drier (by ~60%) on the northeastern ones and approximately the same as today in the interior regions. The intense LGM precipitation over the mountains along the northern Mediterranean coast was produced by unstable atmospheric conditions due to the anomalously steep vertical temperature gradients on the Eastern Mediterranean Sea. In contrast, drier conditions along the southern Black Sea coast were produced by the partially ceased moisture take-up from the cold or frozen Black Sea and prevailing periglacial conditions due to the cold air carried from northern hemisphere's ice sheets. Relatively warmer and moister air from the south and overlying cold and dry air pooled over the northern and interior uplands created a boundary between the wet and dry LGM climates somewhere on the Anatolian Plateau. The analysis of Late Glacial advances suggests that the climate was colder by 4.5-6.4oC based on up to 1.5 times wetter conditions. The Early Holocene was 2.1oC to 4.9oC colder on Mount Erciyes and up to 9oC colder on Aladaglar, based on twice as wet as today's conditions. The Late Holocene was 2.4-3oC colder than today and the precipitation amounts approached the modern levels. Glaciers present on Turkish mountains today are retreating at accelerating rates and historical observations of the retreat are consistent with the behavior of other glaciers around the world.

The magnitude of global sediment flux from streams to the oceans over the last 5 Ma is poorly quantified, yet important for predicting future fluxes and deciphering the relative control of tectonic uplift, climate change, vegetation, and related feedback mechanisms on landscape evolution. Despite numerous proxy studies on global sediment delivery to the oceans, it remains uncertain whether bulk sedimentation increased, decreased, or remained approximately constant across one of the most significant global climate changes: the Plio-Pleistocene transition. New developments and strategies in the application of cosmic-ray-produced isotopes, in part developed by this thesis, provide records of pre-historic denudation of confined fluvial catchments in Texas and Yukon. Non-glaciated, tectonically passive regions were targeted in contrast to other studies on modern sedimentation rates in order to isolate the climate influence from glacial and tectonic controls. The results suggest that average catchment temperature, and surficial processes and other factors such as vegetation cover associated with temperature, are the primary controls on the variation in landscape denudation in regions lacking tectonics and direct glacial cover. Specifically, warmer temperatures yield higher denudation rates, both at the scale of glacial-interglacial climate change and over the Plio-Pleistocene transition. The implication is that stream sediment flux to the ocean from tropical and temperate regions was higher during the Pliocene than in the Quaternary. However, this may have been balanced by an increase in sediment flux from regions covered by warm-based glaciers during glacial periods, or by increased temporary continental storage during interglacial periods.

This research is an integrated geological and geomorphological study into the Denton Hills area. The study area is part of the foothills to the Transantarctic Mountains, which divides East and West Antarctica, allowing an opportunity to investigate glacial events from both sides. As the study area is ice-free, it has allows good examination of the bedrock geology and has preserved geomorphological features allowing them to be examined and sampled. Comprehensive geological map and geomorphological maps have been produced, extending the knowledge into the spatial distribution of units and features. Both the geological and geomorphological maps reveal a complex history of evolution. The original geological units have been subjected to deformation and intrusion of large plutons. The geomorphological mapping shows ice has flowed in alternate direction through the valleys, and the valleys have had long periods where they have been occupied by large proglacial lakes. As the Antarctic ice sheets expanded they flowed into the valleys either from the west, the Royal Society Range draining the East Antarctic Ice Sheet or from the east, McMurdo Sound. Ice would flow from McMurdo Sound when the West Antarctic Ice Sheet expanded causing the grounding line of the ice sheet to move north through the Ross Sea. Surface exposure dating completed during the study has correlated the timing of glacial events to global cycles. The dating confirmed the presence of the large proglacial lake during the Last Glacial Maximum in the Miers Valley, which drained about 14 ka. The Garwood Glacier has also been directly linked to the Last Glacial Maximum with a moraine forming about 22 ka. The dating has also shown that during the Last Glacial Maximum there was little fluctuation in the size of glaciers draining the East Antarctic Ice Sheet, with features being date to the onset of the Last Glacial Maximum.