Fibre reinforced structural members are currently being produced using the pultrusion process. The mechanical properties of these members are fundamentally different from those of conventional metallic ones. Therefore, the approximate theories which are suitable for designing the latter elements have to be revised before they are applied to pultrusions. An important aspect of the design of building frames is that of joints. The bolting technique is considered as the most suitable method for on-site jointing. Accordingly, experimental investigations are undertaken in order to establish the behaviour of bolted joints in pultrusions. Numerical and analytical methods are used to investigate the stresses in these joints. Single and two-bolt joints were the subject of experimental investigations. It is shown that materials with high percentage of axial fibres do not develop bearing failure. However, provided the end distance is sufficient, the resulting shear failure will be ductile. The load distribution in joints with two bolts is measured and it is found that it varies with the load on the joint. The theoretical investigations compare the use of the laminated plate theory with three dimensional analyses. Because the use of the laminated plate theory is found to be reasonably accurate, an improvement for the case of a symmetrical laminate is proposed where the laminated shell theory is used to model half the plate only. This technique is based on the assumption of a bi-linear variation of the stress through the thickness of the laminate. The effect of the fastener is an important part of the behaviour of the joints. Three dimensional analyses are performed to assess its effect. To avoid the complications of performing three dimensional analyses, a two dimensional model for considering the effect of the washer on the joint is devised. In addition, a method which avoids iteration when considering the effect of friction is formulated. A finite element formulation for the non-linear and failure behaviour of uniaxial composite materials is developed to investigate the behaviour of the joints. Finally, a closed form analytical formula for calculating the tangential stress around a hole in an infinite orthotropic plate loaded on the hole is generated to simplify the design procedures.

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La découverte du boson de Higgs en 2012 a été un des principaux succès du run 1 du LHC. Une ère de mesures de précision a alors débuté à la recherche de déviations par rapport au Modèle Standard (MS), qui seraient des indices quant à la physique au-delà du MS.Ce manuscrit s'intéresse en premier lieu à l'étalonnage du calorimètre électromagnétique de l'expérience ATLAS. L'étape finale de cet étalonnage utilise la distribution en masse du boson Z pour corriger l'énergie mesurée des électrons et des photons. Des recommandations pour le démarrage du run 2 ont été produites afin de fournir des constantes de correction pour aux premières analyses. Les corrections utilisant les données du run 2 ont également été mesurées. Les performances de l'étalonnage du run 1 ont été atteintes puis améliorées : l'incertitude systématique sur le terme constant de la résolution du calorimètre électromagnétique, dominante pour la mesure des couplages du boson de Higgs au run 1, a été divisée par 3. La mesure des couplages du boson de Higgs consiste en la mesure de la forme du signal résonnant sur un bruit de fond décroissant. Cette mesure est effectuée de manière corrélée entre différentes catégories, optimisées pour différents modes de production à travers l'identification d'objets produits avec le boson de Higgs. Les résultats ont été obtenus à partir de 36 fb$^{-1}$ de données récoltées en 2015 et 2016 à une énergie de $sqrt{s}$=13 TeV. Le rapport ($mu$) de la mesure de la section efficace inclusive du boson de Higgs sur sa valeur dans le MS a été mesuré. Aucune déviation significative par rapport au MS n'a été observée. $$mu = 0.99 pm 0.14$$Les rapports des principaux modes de production ont également été mesurés :$$mu_{ggH} = 0.80 pm 0.18$$$$mu_{VBF} = 2.1 pm 0.66$$$$mu_{VH} = 0.7 pm 0.85$$$$mu_{ttH+tH} = 0.5 pm 0.62$$ / The discovery of the Higgs boson was a major success of the run 1 of the LHC. The era of precision measurements began as any deviation from the expected Standard Model value would be a direct hint of new physics beyond the standard model. This thesis has a first focus on the calibration of the electromagnetic calorimeter of the ATLAS experiment. The final step of this calibration uses the knowledge of the line shape of the Z boson in order to correct the measured energy of electrons and photons. Recommendations for the beginning of run 2 have been given to provide calibration constants for early analyses. Run 2 calibration constants have been computed and the performances of run 1 have been reached and improved : the systematic uncertainty on the resolution constant term of the electromagnetic calorimeter, which was dominant for the Higgs boson couplings measurement at run 1, has been divided by a factor 3.The measurement of the H boson couplings consists in measuring the shape of the resonant signal over a smooth decreasing background in categories optimized for various processes, by tagging the objects produced in association with the Higgs boson. The results are based on 36 fb$^{-1}$ of data recorded in 2015 and 2016 at $sqrt{s}$=13 TeV. The ratio of the measured production cross-sections of the Higgs boson over the SM expected value ($mu$) has been measured. No significant deviation with respect to the SM has been observed.$$mu = 0.99 pm 0.14$$The ratios of the main production processes have also been measured:$$mu_{ggH} = 0.80 pm 0.18$$$$mu_{VBF} = 2.1 pm 0.66$$$$mu_{VH} = 0.7 pm 0.85$$$$mu_{ttH+tH} = 0.5 pm 0.62$$

Die vorliegende Arbeit befasst sich mit dem Betriebsverhalten und den Auslegungsrichtlinien für ein hochtemperaturfähiges Übertragungselement aus Stahl für elastischen Klauenkupplungen. Im Grundlagenkapitel wurden hierfür zunächst aus den Eigenschaften und Auslegungsvorschriften handelsüblicher Klauenkupplungen wichtige Kenngrößen und Kennwerte bestimmt und relevante Aspekte der Tribologie und der Federtechnologie beleuchtet. Mittels FEM wird die Spannungsverteilung und das Verformungsverhalten des Übertragungselements bei Drehmomentbelastung untersucht und anhand einer Parameterstudie der Einfluss verschiedener Konstruktionsparameter analysiert. Zusätzlich werden Berechnungen und Simulationen zur Dämpfung und zur Betriebsfestigkeit durchgeführt. Die gewonnenen Erkenntnisse wurden anschließend durch experimentelle Untersuchungen mit statischer und dynamischer Belastung sowie durch Lebensdauerversuche und Betriebslastenversuche verifiziert und ergänzt. Hierbei wurden zu Vergleichszwecken auch handelsübliche Übertragungselemente aus TPE untersucht. Auf Basis der Untersuchungsergebnisse wurden anschließend Richtlinien für die Auslegung und den Betrieb des Übertragungselements abgeleitet. / The present work deals with the operating behaviour and the selection guidelines for a new high-temperature steel transmission element for elastic jaw couplings. In the state oft the art chapter, important parameters and characteristic values were first determined from the properties and selection specifications of commercially available claw couplings and relevant aspects of tribology and spring technology were highlighted. FEM is used to investigate the stress distribution and the deformation behaviour of the transmission element under torque loading and to analyse the influence of various design parameters. In addition, calculations and simulations for damping and fatigue strength are carried out. The knowledge gained was then verified and supplemented by experimental investigations with static and dynamic loads as well as by service life tests and operating load tests. For comparison purposes, commercially available transmission elements made of TPE were also investigated. Based on the test results, guidelines were then derived for the selection and operation of the new transmission element.

This study consists of four major areas of research. First, the relationship between and was extended to Lrl nil homoallylic couplings and was used to determine the relative degree of puckering in a series of dihydroaromatic carboxylic acids. Second, the effect of coupling contributions transmitted through space were examined by theoretical calculations of the intermediate neglect of differential overlap finite perturbation theory type (INDO-FPT) including selective overlap reduction experiments to determine the sign and magnitude of the major through-space contributions and the effect of the orientation of the substituent upon the vicinal carbon3 carbon coupling. Third, the dependence of the J upon substituent orientation in norbornanes was empirically investigated by the synthesis of a series of lactones and cyclic ethers whose conformation was rigid and known. Fourth, a large number of norbornanes substituted with methyls in the 1, 3, and 7 position and a carbon-13 labeled substituent in the 2 position were synthesized and studied in order to obtain a variety of vicinal C-C couplings; all the NMR parameters for this series of compounds were determined while the carbon13 labeled substituent was varied from methyl to methylene to carbinol to aldehyde and to carboxylic acid.

Les molécules-aimants ou Single–Molécule Magnets (SMM) ont attiré une attention croissante au cours des dernières années en raison de leur potentiel attrayant en tant que dispositifs de stockage magnétique à haute densité. Beaucoup d'efforts ont été faits pour améliorer la performance magnétique de ces molécules à l’aide des techniques de chimie de coordination.Dans cette thèse, le travail est organisé en deux parties principales. La première partie est constituée des chapitres 2 et 3 qui se concentrent principalement sur les familles Lanthanide-radicaux zéro- et mono-dimensionnelles. La deuxième partie contient les chapitres 4 et 5, ou des ligands diamagnétiques sont utilisés afin concevoir des matériaux multifonctionnels.Dans la première partie, neuf radicaux TEMPO-R (R représente le substituant) sont utilisés. Leur structure cristalline, ainsi que leurs propriétés magnétiques ont été caractérisées. Dans le chapitre 2, quatre radicaux (TEMPO-OCH3, TEMPO-NH2 TEMPO-Acetamido et TEMPO-OCH2CCH) sont utilisés pour synthétiser des complexes zéro-dimensionnels, dont trois présentent des propriétés de SMM. Dans le cas particulier de TEMPO-OCH3, un très rare comportement de SMM avec lanthanides légers est observé (CeIII, PrIII et NdIII). La première SMM à base de PrIII est ainsi reportée. Dans le chapitre 3, l'objectif est de concevoir des SMM organisés mono-dimensionnellement dans l’empilement cristallin. Cinq autres radicaux sont utilisés: TEMPO-Méthacrylate, TEMPO-OCOPh, TEMPO-oxo, TEMPO-OH et TEMPO-CN. Parmi toutes les chaînes obtenues, [Pr(hfac)3(H2O)(TEMPO-OH)]n (17), [Dy(hfac)3-TEMPO-OH)]n (18) et [Tb(hfac)TEMPO-CN)]n (22) sont identifiés comme SMM. 22 présente la relaxation magnétique la plus lente parmi tous les SMM 4f-2p obtenues dans cette thèse, avec une d'hystérèse magnétique à basse température. Son analogue à base GdIII (23) présente une des plus grandes valeurs d'échange dans les composés de Gd-2p. Enfin un très rare exemple de réseau bidimensionnel 4f-2p de formule [(Ce(hfac)3)3(Oxo-TEMPO)4]n (15) est obtenu. Dans la deuxième partie, une chaine de dimère est obtenue par réaction d'un ligand carboxylique photo-commutable avec des sels d’ions LnIII. La photo-sensibilité du ligand sous irradiation UV a été testée et des mesures magnétiques en solution ont été entreprises. En outre, un composé de type Metal-Organic-Framework (MOF) présentant un comportement de SMM de {[Dy2(o-PDA)3(H2O)2]2H2O}n (28) a été conçu et caractérisé. Une interaction ferromagnétique Ln-Ln a été observée dans ce MOF-SMM et le dopage diamagnétique démontre que, contrairement à ce qui est observé sur [Ln(AZO)3(DMSO)(H2O)]2•4DMSO, cette interaction favorise le comportement de SMM. / Single-molecule-magnet (SMM) has attracted increasing attention in recent years due to their appealing potential for high-density storage devices. Much effort has been made to improve the magnetic performance through flexible coordination chemistry strategy.In this thesis, the work is organized in two main parts. The first part is constituted of chapter 2 and chapter 3, primarily focus on the Ln-Radical families aiming at designing zero-dimensional and one-dimensional single-molecule-magnet (SMM). The second part contains chapter 4 and chapter 5, in which the ligands are replaced by diamagnetic ones for the purpose of designing the multifunctional materials.In the first part, nine TEMPO-R (R represents the substituent) radicals are employed to construct zero-dimensional and one-dimensional complexes. These kinds of compounds were prepared by reactions in the dichloromethane/n-heptane co-solvents between the precursor [Ln(hfac)3(H2O)2] and TEMPO radicals. Subsequently their molecular structure as well as magnetic properties have been characterized and described. In chapter 2, four radicals (TEMPO-OCH3, TEMPO-NH2 TEMPO-Acetamido and TEMPO-OCH2CCH) are used to synthesize monometallic or dimetallic complexes, among which three are successful to construct the SMM. For the special case of TEMPO-OCH3 a rare light lanthanide ions (CeIII, PrIII and NdIII) SMM behavior is reported. The PrIII derivative is the first PrIII-based SMM ever reported. In chapter 3, the target is to design SMM in one dimension by using another five radicals: TEMPO-Methacrylate, TEMPO-OCOPh, TEMPO-oxo, TEMPO-OH and TEMPO-CN. Among all the chains, [Pr(hfac)3(H2O)(TEMPO-OH)]n (17), [Dy(hfac)3-TEMPO-OH)]n (18) and [Tb(hfac)3(TEMPO-CN)]n (22) are identified as chains of SMM. 22 exhibits the slowest magnetic relaxation among all the 4f-2p SMMs obtained in this thesis, with a small opening of magnetic hysteresis. Its analogue of [Gd(hfac)3(TEMPO-CN)]n (23) even exhibits one of the largest exchange values in Gd-2p compounds. Last a very rare example of bidimensional 4f-2p network of formula [(Ce(hfac)3)3(Oxo-TEMPO)4]n (15) is obtained.In chapter 4, the salt of a photo-switchable carboxylic ligand was reacted with LnIII ions to afford a chain-like arrangement of dinuclear complexes of formula [Ln(AZO)3(DMSO)(H2O)]2•4DMSO. Photo-sensitivity of the ligand under the irradiation of UV has been tested together with magnetic measurements in solution. In chapter 5, a Metal-Organic-Framework (MOF) (28) has been designed and characterized. Ln-Ln ferromagnetic interaction has been observed and diamagnetic doping highlight that, contrary to what observed on [Ln(AZO)3(DMSO)(H2O)]2•4DMSO, this interaction promote SMM behavior in a so-called MOF-SMM.

Doctor of Philosophy / Department of Physics / Yurii Maravin / This dissertation describes a comprehensive study of the Zgamma [to] eegamma/mumugamma/nu[bar]nugamma process. The data have been collected with the D0 detector at the Fermilab Tevatron p[bar]p collider with the center-of-mass energy of 1.96 TeV, and correspond to up to 3.6 fb[superscript]-1 of integrated luminosity. Firstly, in this study we perform a measurement of the Zgamma production cross section. The measured cross sections in both llgamma (l = e or mu) and nu[bar]nugamma channels are the most precise cross sections measured at hadron colliders to date, and they agree within uncertainties with the theoretical calculations to the next-to-leading order. We claim the first observation of the Zgamma [to] nu[bar]nugamma process at hadron colliders at 5.1 standard deviations statistical significance. We also conduct a search for anomalous Zgamma processes. Such anomalous Zgamma processes, where a Z boson couples to a photon, result in an increased cross section and an enhancement of the production of high-energetic photons. Thus, an observation of this kind might possibly indicate the presence of new physics. Having found no excess of data over the SM expectations, we set the most restrictive 95% C.L. limits on the anomalous trilinear Zgammagamma and ZZgamma gauge couplings (ATGC) at hadron colliders to date: |h[subscript]30[superscript]gamma| < 0.033, |h[subscript]40[superscript]gamma| < 0.0017, |h[subscript]30[superscript]Z| < 0.033, and |h[subscript]40[superscript]Z| < 0.0017, which mark almost three times improvement over the most recent results published to date. Three out of four current limits improve on the LEP limits, and are the tightest limits on ATGC in the world. Finally, we performed a search for narrow vector and scalar resonances that decay to Zgamma. Many extensions of the SM predict such resonances, thus making this search a test of the gauge sector of the SM. We found no significant deviation of data from the SM predictions, and hence we set 95% C.L upper limits on the production cross section of the resonances.

Doctor of Philosophy / Department of Physics / Yurii Maravin / In this Dissertation I present a detailed study of ppbar->WZ production using fully leptonic decays of W and Z bosons with electrons and muons in the final state. Data used for the study were collected by the D0 detector at the Fermilab proton-antiproton collider with a center-of-mass energy of 1.96 TeV and correspond to 4.1 fb[surepscript]-1 of integrated luminosity. The most precise measurement of the WZ production cross section is obtained and found to be in a good agreement with the standard model prediction. I also present a search for new phenomena in the WZ production by investigating the coupling between W and Z bosons and by searching for new charged particles that can decay into WZ boson pair. No evidence for new physics is found, and the most stringent limits are set on the anomalous WWZ coupling parameters and masses of charged resonances. This result also sets the stringest limit on one of the possible sources of electroweak symmetry breaking, a low-scale Technicolor with a typical heavy techni-pion hypothesis.