Ester liquids including natural ester and synthetic ester are considered as potential substitutes for mineral oil, due to their good biodegradability and high fire points. Although these liquids have been widely used in distribution and traction transformers, research efforts are required for the purposes of design and manufacture of high voltage and large power transformers which are filled by esters. Indeed, it would be risky to apply esters in large power transformers without thorough understandings of their behaviours in large gaps and/or when combined with pressboard insulation. Therefore, investigations of creepage discharges along the surface of pressboard in esters are vitally important and their behaviours should be compared with those of mineral oils. This thesis is aimed to investigate the creepage discharges along pressboard in esters and mineral oil under ac divergent electric field. Apparent charges, current signals and images of streamer channels were obtained synchronously to identify whether and how the introduction of pressboard surface would influence the inception and propagation of discharges as compared to tests in open gap. When over-stressed by higher voltages, the surface tracking along the pressboard-ester interface, triggered by sustaining creepage discharges, was studied and the evolutions of accompanying creepage discharge patterns were investigated. In these experiments, both esters and mineral oil impregnated pressboards were comparatively studied. The test results indicated that at the inception stage, the presence of pressboard or any other solid types in different liquids under test do not influence the PD inception voltages; in the propagation stage, solid surface tends to promote the development of discharges, especially those occurring in negative half cycles, and shifts more discharges towards the zero-crossing phase angles. This discharge promotion effect is much more evident in esters than in mineral oil, probably because of higher discharge intensity in esters and higher viscosity of esters. The space charge effect and the residual low density channel effect are proved as the mechanisms best explaining the influences of solids on creepage discharges. Under higher voltages, it was found that the impregnated pressboard is susceptible to discharge erosion characterized by “white and carbonized tree-shaped marks”, due to intense discharges occurring on or near the pressboard surface. The “white mark” appears at a lower voltage and propagates more easily on ester impregnated pressboard. The gaseous “white mark” channels will attract the subsequent discharges to follow the same discharge routes; the accumulative energy dissipation in these channels will then result in the carbonization of the channels. Once formed, the surface tree-shaped mark can continue to grow even under reduced voltage levels until it bridges the gap and causes the final flashover.

Dans le présent travail, nous abordons une problématique essentielle liée aux accessoires des lignes électriques et plus particulièrement au connecteur à perforation d’isolant (TTDC 45501 FA), commercialisé par la société Sicame située à Arnac-Pompadour (Corrèze). Ce produit permet d’effectuer des dérivations de courant en moyenne tension gainé HTA entre 15 et 25kV. Cependant, il devient nécessaire de concevoir une nouvelle génération de connecteurs capable de fonctionner à une tension de 52 kV en raison de la constante augmentation des besoins en électricité. En réalité, le principal souci concernant ces produits réside dans l’apparition de décharges partielles dans le volume constitué par la matière isolante (polyamide 6 chargée à 50% en poids de fibres de verre). Ces décharges engendrent un vieillissement prématuré du produit sous l’action conjuguée d’une atmosphère corrosive (brouillard salin) et d’un champ électrique. Ainsi, l’objectif de la présente thèse est de faire, dans un premier temps, un choix approprié de matériaux isolants parmi des polymères thermoplastiques, thermodurcissables époxydes ou élastomères en EPDM, capables de résister à plusieurs contraintes : thermique, électrique, mécanique, chimique et climatique. La partie expérimentale concerne, tout d’abord, la mesure de la tension de contournement, de l’activité des décharges partielles se propageant à la surface des matériaux isolants et de la tension de claquage, en tension alternative (A.C.). Pour cela, des échantillons polymères qui comportent des surfaces planes ou des surfaces pourvues de protubérances ont été moulés en vue de comparer leur comportement diélectrique en présence d’atmosphères polluées de type brouillard salin; ces mesures sont nécessaires pour effectuer un choix approprié du matériau à intégrer dans le connecteur. Par la suite, l’étude et la caractérisation optique et électrique de décharges glissantes, se propageant en surface de divers matériaux polymères, en tension impulsionnelle (L.I.) pour les deux polarités (positive et négative) et pour deux types de champ électrique (normal et tangentiel) sont présentées pour le cas d’une interface solide/air. La mesure de la longueur finale des décharges glissantes et la visualisation de l’onde de courant sont les deux paramètres principaux pour différencier les caractéristiques des matériaux utilisés. L’ensemble des résultats de mesures a permis de sélectionner les résines époxydes cyclo-aliphatiques (CEP) comme candidates potentielles pour la conception d’une nouvelle génération de connecteurs. De plus, la simulation du champ électrique, à l’aide du logiciel Flux 2D/3D, sur le connecteur électrique (TTDC 45501FA) a permis d’aboutir à la proposition d’un prototype de connecteur présentant une nouvelle géométrie et pouvant fonctionner à 52kV. / In the present study, we deal with an essential problem related to electrical lines accessories and more particularly to piercing connectors (TTDC 45501FA) commercialized by a private company named Sicame and which is located in Arnac-Pompadour (Corrèze, France). This product/accessory is designed to provide power diversions on medium voltage live lines HVA operating between 15 and 25kV. However, it becomes required to design a new generation of piercing connectors able to operate on 52kV live lines because of the electrical power demands that are steadily increasing. Actually, the main concerns about these products are the occurrence of partial discharges within the insulating material volume (polyamide 6 containing 50%wt of glass fibers). Most of the time, these discharges induce an early ageing process of the accessory under the combined effects of a corrosive environment (as salt fog) and an electric field threshold. Thus, the main objective of the present Ph.D. thesis is to carry out an appropriate choice of insulating materials among several tested polymers such as thermoplastics and thermosetting epoxy resins and EPDM elastomers that are capable of withstanding several constraints: thermal and electrical and mechanical and chemical conditions. The experimental section is focusing on the measurements of flashover voltage and partial discharges activity propagating on polymeric surfaces and breakdown voltage within material bulks under A.C voltage. That is why polymeric samples with plane surfaces and textured surfaces are molded to compare their resistance to partial discharges when being subjected to polluted environments such as salt fog; these measurements are necessary to choose the suitable materials for the required application to be integrated in the new generation of connectors. Then, the optical and electrical characterization results of creeping discharges propagating on several polymeric surfaces under lightning impulse (L.I.) voltage with its both polarities (positive and negative) and for two kinds of applied electric field (normal and tangential) are presented in the case of solid/air interfaces. Final length measurements of creepage discharges are the main parameter for distinguishing material properties. The whole obtained results (under AC and LI voltages) allow us to point out the cycloaliphatic epoxy resins as potential candidates to the conception of a new generation of piercing connectors. In addition, the electric field simulation and modelling of the TTDC 45501FA connector by using the Flux 2D/3D software seems to be helpful to design a connector prototype which exhibits a new geometry and is able to reach a voltage level that equals 52kV.