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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
381

The electrolytic production of peroxydisulfuric acid using periodically reversed direct current and alternating current superimposed on direct current

Fan, Sin-Chou January 1956 (has links)
It was the purpose of this investigation to study the effect of varying the direct to reverse time ratio of periodically-reversed, direct current from 1.0 to 20.0 at an anode current density of 4.5 amperes per square centimeter, and to study the effect of alternating current of 60, 240, and 500 cycles per second, 0.2 to 4.5 amperes per square centimeter, superimposed on direct current on the electrolytic production of peroxydisulfuric acid. Electrolyses of 200 milliliters of sulfuric acid of specific gravity 1.4, at a temperature of 5 to 10 °C were performed with direct current. The anode current density was varied. The surface area of platinum anode and lead cathode was 2.0 and 221.8 square centimeters, respectively. For one hour of electrolysis, the yields were 7.9, 14.0, 20.2, and 22.9 grams of peroxydisulfuric acid at the anode current density of 1.5, 3.0, 4.5, and 6.0 amperes per square centimeter, respectively. The current efficiencies corresponding to these anode current densities were 85.0, 77.0, 61.5, and 53.4 per cent. The results showed that the yield was increased and the current efficiency was decreased with increase in the anode current density. Electrolysis of the same concentration and volume of sulfuric acid using periodically-reversed, direct current yielded 14.2 grams at an anode current density of 4.5 amperes per square centimeter and at a temperature of 5 to 8 °C. The time of electrolysis was one hour and the time ratio of direct to reverse electrolysis was 20. The current efficiency obtained under these conditions was 42.6 per cent. Decreasing the direct to reverse time ratio gave lower yields and current efficiencies. Apparently, there is no advantage in using periodically-reversed, direct current over the use of direct current for this reaction under the above experimental conditions. Electrolyses of 200 milliliters of sulfuric acid of the same concentration were performed with 60 cycles per second, alternating current superimposed on direct current. The direct current density was 4.5 amperes per square centimeter for the ten tests, but the surface area of the platinum anode was changed from two to one square centimeter and the direct current was decreased from 9.0 to 4.5 amperes. The current efficiency decreased sharply from 61.5 to approximately 31.0 per cent as the ratio of peak alternating to direct current increased from zero to 0.2 and then it remained constant until the ratio reached one. The current efficiency decreased suddenly to almost zero when the ratio was greater than one. The same sulfuric acid was electrolyzed under the same experimental conditions with 240 and 500 cycles per second, alternating current superimposed on direct current. Both direct and alternating anode current densities were varied. The direct current density was 2.2 and 4.5 amperes per square centimeter. The current efficiencies obtained during these tests were almost the same as that obtained with 60 cycles per second, alternating current within a specific limit of the ratio of peak alternating to direct current. The ratio of peak alternating current to direct current at which the current efficiencies suddenly dropped to zero was 0.75 for 240 cycles per second, and 0.5 for 500 cycles per second, instead of one for 60 cycles per second, superimposed alternating current. The platinum anode was activated and dissolved into the sulfuric acid when the ratio of peak alternating to direct current was greater than 1.0, 0.75, and 0.5 for 60, 240, and 500 cycles per second, alternating current superimposed on direct current. Apparently, there is no advantage in using alternating current superimposed on direct current over the use of direct current for electrolytic production of peroxydisulfuric acid. / Master of Science
382

Physical processes along the southern continental shelf and slope of Western Australia

Mohd Akhir, Mohd Fadzil January 2010 (has links)
The circulation along the south coast of Western Australia was examined using field data and numerical modelling. Physical processes in this region, particularly along the continental shelf and slope regions, were poorly understood due to a paucity of field measurements. Data were collected during a research cruise on RV Southern Surveyor (04/2006) during April 2006 consisting of 18 CTD transects from Twilight Cove (126oE) to Cape Leeuwin (115oE) and was augmented by shipborne ADCP data. The field data set provided a detailed understanding of three major current systems: Leeuwin Current (LC), Leeuwin Undercurrent (LU) and Flinders Current (FC). The LC along the south coast exhibits different characteristics when compared to that along the west coast. The LC flows into the colder and lower salinity subantarctic environment of the south coast. This is evident in a strong geopotential gradient off the south-west corner of Australia (Cape Leeuwin) resulting in rapid acceleration of the LC as it reaches a maximum velocity in this region. Numerical modelling studies, using the Regional Ocean Modelling System (ROMS) indicated that wind stress is an important component of the dynamics in this region. This was identified when comparing summer and winter conditions when the winds act in opposite directions, from north-westerly to southeasterly respectively. Along the shelf break and slope, the Flinders Current (FC) interacts with LC. As the dominant current, the FC serves both as a surface and as an undercurrent, transporting sub Antarctic mode water (SAMW). This interconnection the FC and LU can be seen clearly from the salinity, temperature and velocities within the depth range 200-700m postulating a connection between subsurface waters off Tasmania (origin of the Flinders Current) and the tropical Indian Ocean through the Flinders and Leeuwin Undercurrents.
383

A HIGH VOLTAGE D.C. PULSE SYSTEM AND ASSOCIATED ATHERMAL, IN VITRO EXPERIMENTS (POWER, SHORT, SYNERGISM).

Hibbard, John Arthur, 1959- January 1986 (has links)
No description available.
384

One dimensional theoretical and experimental analysis of the dark current in an indium-antimide hybrid photovoltaic focal plane array

Chen, Hao, 1958- January 1988 (has links)
A one-dimensional analytical model of dark current has been developed to facilitate the investigation and analysis of dark current from gate-controlled photovoltaic InSb arrays. The applied gate voltage is an essential parameter in the model. The expressions relating this parameter to surface potential are derived separately for the cases of accumulation and depletion at the surface of n-type InSb material under the gate. In addition, the measured dark current is compared with that from the analytical model, and the discrepancy is discussed in terms of the intrinsic carrier concentration, surface recombination velocity, and geometry of the array. The components of dark current are mainly associated with surface state generation-recombination, field induced tunneling, and the depletion region from the bulk and surface. The experimental results are obtained at temperatures between 30K and 40K.
385

Langmuir circulations in a coastal environment during CBLAST

Elge, Murat 09 1900 (has links)
Approved for public release; distribution is unlimited / Langmuir circulations in a coastal environment at an inner shelf site with strong tidal forcing were examined using a 4-month observation of high-resolution velocity profiles during the ONR-sponsored CBLAST-Low air-sea interaction experiment. Because of their potential contributions to mixing processes in the surface boundary layer, Langmuir circulations are important for naval operations such as ASW, MCM and Amphibious operations in littoral waters. A detection algorithm for upwelling / downwelling velocities due to Langmuir circulations was developed. Analyses focused on long-fetch, unstratified water column conditions with locally developed seas. The observations showed that strong Langmuir circulations greatly reduced water column shear arising from the tidally forced bottom boundary layer, while there was no significant effect from the strong tidal boundary layer on the formation of Langmuir cells. Long fetch conditions had the strongest vertical velocities with Langmuir number 0.1-0.4, while short fetch conditions have weaker vertical velocities with Langmuir number greater than 0.5. Cell vertical velocities were correlated with the water friction velocity, but penetration depths did not depend on forcing mechanisms. Spacing and penetration depths were correlated for increasing wind speed and wave heights whereas this correlation was not seen for constant high wind speed and wave heights. / Lieutenant Junior Grade, Turkish Navy
386

Cuspate shoreline morphology

McWilliams, Brandon K. 06 1900 (has links)
Large beach cusps with wavelengths O(200m), sometimes termed mega-cusps, were measured along 18km of the Southern Monterey Bay coastline from October 2004 to April 2005 to investigate the cuspate shoreline response to rip current systems. Monterey Bay is a unique location for the study of rip current systems, which has with well defined rips that are present all year long, a large dune erosional rate, and incident wave energy that is primarily shore-normal with a large alongshore gradient. Contours of the coastline were extrapolated from the surveys using an all-terrain vehicle equipped with Kinematic GPS. Cusp spacing was inferred from the data using a zero up-cross technique and found to be O(230m) for low wave energy beaches and O(250m) for high wave energy beaches. Migration rates of the cusps were found to be 1-5m/day owing to the quasi-uniform erosion of the dune system. Cusps were found to be semi-permanent features with length scales dependant upon the local wave climate.
387

The impact of harmonic distortion on power transformers operating near the thermal limit

26 February 2009 (has links)
M.Ing. / The study looks into the impact of harmonic distortion on power-plant equipment in general, and then focuses on the impact it has on power transformers operating near the thermal limit. The feasibility of the study is firstly evaluated and then the theory on harmonics and transformer losses is analysed. The study had been narrowed down to power transformers due to the high numbers of failures nationally and internationally attributed to unknown causes. A transformer model is then developed through theoretical considerations. Finally, a case study is done on the capability of a fully loaded transformer under harmonics conditions evaluated through transformer capability calculations and the proposed transformer model. Thereafter the transformer model developed is verified with measured results. The main impact of harmonic current distortion on power transformers is an increase in the rated power losses that results in a temperature rise inside the power transformer. The heat build-up can lead to degradation of insulation, which can shorten the transformer’s life and lead to eventual breakdown. The harmonic current distortion impacts transformer losses – namely, ohmic losses, the winding eddy current losses and other stray losses. All of these harmonic effects on transformer losses are verified theoretically, mathematically and practically. The harmonic impact on the transformer capability is then evaluated through a numerical example of a transformer feeding a harmonic load. The transformer capability is determined via two methods – namely, harmonic capability calculations in the standard “IEEE Recommended Practice for Establishing Transformer Capability when Supplying Nonsinusoidal Load Currents”, [11] and a proposed transformer model derived from theoretical and mathematical analysis. The results show that an increase in the winding eddy current losses can decrease the maximum permissible nonsinusoidal load current substantially. If the load current of the transformer is derated accordingly it translates into a loss of the output power capacity of the power transformer. The standard recommended capability calculations for winding eddy current losses are conservative and not satisfactorily accurate. This results in a large loss of power capacity. The proposed transformer model includes a parameter that estimates the winding eddy current loss in the transformer that results in a smaller loss in power capacity. Furthermore, it was shown that the harmonic current distortion levels could exceed the permissible levels although the harmonic voltage distortion levels are within acceptable levels. The proposed transformer equivalent model is thereafter practically verified with experimental results of papers published by M.A.S. Masoum, E.F. Fuchs and D.J. Roesler, [19], [20] and [29].
388

Uma câmara de ionização sólida / A solid ionization chamber

Freitas, Marcilio de 13 June 1984 (has links)
Assumindo elétrons e buracos se movimentando em suas bandas próprias e centros de recombinação independente para ambos, Hughes e Sokel calcularam as características e distribuição de cargas para o oxido de chumbo (PbO) quando este se encontra sob radiação. O cálculo também inclui a corrente de difusão e segundo os autores, esta possui um importante papel em muitos aspectos. Neste trabalho a característica para o PbO foi recalculado sem considerar a contribuição da corrente de difusão e essencialmente foi obtido o mesmo resultado. Foram desenvolvidos aproximações para baixo e alto campo. Em seguida, foram assumidos iguais parâmetros para ambos portadores (isto é, iguais mobilidades, tempos de captura, coeficientes de recombinação e densidades de centros de captura) e obtido as características para 18 combinações de três conjuntos de parâmetros convenientemente definidos. Aproximações de campo baixo e campo alto foram também derivadas para este caso / Assuming electron and hole bands and independent recombination centers or both carriers, Hughes and Sokel calculated the characteristics and charge distributions for lead oxide PbO under irradiation. The calculation also included the diffusion current and it was asserted that such a current was important in some aspects. In this work the characteristic for PbO was recalculated without the diffusion component and essentially the same result was obtained. Side this; approximations were derived for low and high fields. Next, assuming equal parameters for both carriers (that is, equal mobilities, trapping times, recombination rates and density of trap), characteristics were obtained for 18 combinations of three conveniently defined set of parameters. Low and high field approximation were also derived for this case
389

A System for Detecting the Position of a Molten Aluminum Metal-Front within a Precision Sand Mold

Foley, Brian M. 10 January 2009 (has links)
Manufacturers of cast metal parts are interested in the development of a feedback control system for use with the Precision Sand-Casting (PSC) process. As industry demands the ability to cast more complex geometries, there are a variety of challenges that engineers have to address. Certain characteristics of the mold, such as thick-to-thin transitions, extensive horizontal or flat surfaces, and sharp corners increase the likelihood of generating defective casts due to the turbulent metal-flow during fills. Consequently, it is critical that turbulent flow behavior within the mold be minimized as much as possible. One way to enhance the quality of the fill process is to adjust the flow rate of the molten metal as it fills these critical regions of the mold. Existing systems attempt to predict the position of the metal level based on elapsed time from the beginning of the fill stage. Unfortunately, variability in several aspects of the fill process makes it very difficult to consistently predict the position of the metal front. A better approach would be to embed a sensor that can detect the melt through a lift-off distance and determine the position of the metal-front. The information from this sensor can then be used to adjust the flow rate of the aluminum as the mold is filled. This thesis presents the design of a novel non-invasive sensor monitoring system. When deployed on the factory floor, the sensing system will provide all necessary information to allow process engineers to adjust the metal flow-rate within the mold and thereby reduce the amount of scrap being produced. Moreover, the system will exhibit additional value in the research and development of future mold designs.
390

Density currents in circular wastewater treatment tanks

LaLiberte, David M. 01 January 1990 (has links)
Deviations from ideal flow and settling occur in circular wastewater treatment tanks because of tank geometry, flow conditions, and density currents caused by variations in suspended solids concentration and temperature distributions. Thermally induced density currents were investigated in this study. Under winter, low flow conditions, measurements were made of vertical and radial temperature distributions in the circular chlorination tank at Lake Oswego, Or., and in the circular primary and secondary clarifiers at Bend, Or. Thermistor arrays were used to collect the data which exhibited both vertically well-mixed and a two-layer flow regime. Inlet geometry and suspended solids in the secondary clarifiers caused a warm bottom inflow and apparent thermal instability. Meteorological measurements were also made. The calculated winter heat loss values indicated that convective mixing may have inhibited particle sedimentation in the clarifiers.

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