No description available.

No description available.

No description available.

No description available.

The oxygen permeation flux through the perovskite membrane made of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) has been measured as a function of both the temperature and the oxygen pressure gradient across the membrane. A simple model for the surface exchange fluxes was used to understand the mechanism of the oxygen transport. The limiting step of the oxygen transport was found to be the bulk diffusion for the BSCF perovskite at temperatures above 700 oC. Furthermore, the oxygen vacancy diffusion coefficient (Dv) can be deduced from the dependence of the oxygen permeation flux on the oxygen pressure gradient. From permeation measurement on the BSCF membrane tube, Dv is between 2.82×10-9 m2/s at 900 oC and 0.82×10-9 m2/s at 700 oC.

Pulsed field gradient (PFG) NMR is applied to measure self-diffusion coefficients of 1,3,5 tri-isopropyl-benzene in the particles of several industrial FCC catalysts having different systems of meso- and macropores. Relating these diffusivities to the self-diffusion coefficient of 1,3,5 tri-isopropyl-benzene in the liquid phase, the tortuosity factors for diffusion in the meso- and macropores of the particles were obtained. The values of the tortuosity factors were found to increase with a increasing volumetric fraction of the small (< 20 nm) meso- and macropores in the total intraparticle volume.

The impact of nanopore diffusion on the performance of adsorption separation processes is reviewed. Zeolite membrane processes and kinetically selective cyclic adsorption processes depend for their selectivity on differences in intracrystalline diffusion rates so these processes are designed to operate under conditions of intracrystalline diffusion control. In contrast, the performance of equilibrium based adsorption separation processes is adversely affected by diffusional resistance so in such processes the minimization of all resistances to mass transfer is a major design objective. Zeolite catalyzed reactions constitute a further important class of processes in which intrusion of diffusional resistance can be either advantageous or disadvantageous. Such effects are illustrated by considering in detail the conversion of methanol to light olefins (MTO) over SAPO34. Within the chemical process industries diffusion is important over a wide range of length scales. In this paper we focus only on diffusion at the nanometer scale since diffusional phenomena on this scale are critically important in adsorption separation processes as well as in many heterogeneous catalytic systems. Indeed membrane separations and molecular sieving adsorption processes (kinetic separations) are driven by differences in nanoscale diffusivities. For such processes the conditions of operation must therefore be selected so as to maximize the influence of nanoscale diffusion. This is true also for certain catalytic processes in which product selectivity can sometimes be improved by operating under conditions of diffusion control. More commonly, in equilibrium controlled adsorptive separations and in catalytic systems where activity rather than selectivity is the important feature, process performance is adversely affected by nanoscale diffusion, and in such systems it is obviously desirable to design the process in such a way as to minimize the intrusion of diffusional resistances. Some examples of both classes of process are discussed below.

With reference to molecular transport in manifold media of porous structure, a survey is given on the ample spectrum of diffusion phenomena under confinement. The presentation is mainly based on the evidence provided by pulsed field gradient NMR and by interference and IR microscopy. These "microscopic" techniques of diffusion measurement are particularly powerful for exploring the diverse features of molecular propagation in complex systems. The presented data cover the peculiarities of molecular diffusion under the regime of "intracrystalline" zeolitic diffusion, refer to deviations from normal diffusion and deal with the practically particularly important case where the overall diffusion process includes molecular propagation in the gas phase. In many cases, the reported experimental studies have been performed in immediate response to theoretical issues including single-file diffusion and sorption hysteresis. Simultaneously, they have given rise to new challenges for basic research correlating equilibrium and non-equilibrium phenomena of molecular propagation.

1H NMR imaging is a powerful technique for studying the diffusion of pure hydrocarbons (for example benzene and n-hexane) during their adsorption in or desorption from a fixed bed of zeolite crystallites. This technique is used to visualize the progression of the diffusing molecules in the zeolite bed and to determine their intracrystallite diffusion coefficients. More importantly, NMR imaging is today the only technique able to give the time dependence of the distribution of two gases during their competitive diffusion.

No description available.