Four prograding reef terraces (6, 15, 30, and 50 m) have been repetitively exposed to marine and freshwater alteration during the Pliocene and Pleistocene periods. Prolonged freshwater alterations have resulted in many diagenetic overprints that obscure early diagenetic products. This study investigates the sequence of the diagenetic processes and products in the terrace deposits using five long cores and 14 short cores taken from these different reef terraces. The lithologic changes in the cores were documented for reconstruction of the original depositional frameworks prior to embarking on a diagenetic study. Both textural and geochemical changes were examined within all four different terraces in order to characterized the diagenetic history. The textural changes observed in the cores and thin sections, provided preliminary evidence of the diagenetic environment. Through the use of X-ray diffractometry, stable isotopes (C and O), and trace element data, the interpretation of the diagenetic environment can be constrained. The reef terraces were deposited as as shallowing upward units following a down-stepping carbonate sequence. The lithology of the cores is dominated by reefal facies, which consist of the back reef, reef crest, front, and fore reef facies. The exposure surfaces, observed at various depths, constrained the interpretation of early diagenetic environments (met. vadose and phreatic). Three major diagenetic environments can be characterized from the cores, these are meteoric vadose, meteoric phreatic, and dolomitizaton. These diagenetis environments produced different geochemical signatures, which can be quantified through analysis of the stable isotopes and trace elements incorporated into the cements. The different reef terraces represent different duration of exposure, with the higher terraces having been exposed longer than the lower ones. This study enables the documentation and comparison of the processes and products of the meteoric diagenesis that occurred within these different terraces. In addition, this study also constrain the early dolomitization observed in sigmoidal reef deposits. In order to further quantify the process of early dolomitization, mineralogy, isotopes C and O, trace elements, and the Sr-isotopes were examined as well.

The Oligocene Brac Formation is the oldest part of the Bluff Group that is exposed on Cayman Brac. Sediments of the Brac Formation were deposited on a small, open bank in shallow marine waters. Today, the formation is composed of limestone, finely crystalline dolostone, and coarsely crystalline sucrosic dolostone. The Pollard Bay member, defined herein, comprises the sucrosic dolomite that is exposed only on the south coast of Cayman Brac. Changes in sea level and subsequent groundwater chemistry mediated a complex diagenetic evolution that is responsible for the lithological heterogeneity that now characterizes the formation. Field, petrographic, and geochemical analyses indicate that dolomitization was probably mediated by normal to slightly modified seawater. Multiphase dolomite crystals represent different stages of textural and geochemical maturity, and attest to time-transgressive dolomitization processes that evolved in various hydrologic regimes through time.

Thesis (Ph.D.) -- Memorial University of Newfoundland. / Typescript. Bibliography: leaves 446-492. Also available online.

Thesis (M.S.)--Baylor University, 2009. / Superscript: 6 and 3 in "106m3". Includes bibliographical references (p. 170-175).

La craie est définie comme étant une roche carbonatée microporeuse. Cette formation est largement exploitée en Mer du Nord pour ses hydrocarbures et constitue un aquifère dans le Bassin de Paris. Les propriétés réservoirs de la Craie (propriétés matricielles) varient considérablement comme Alam et al. (2011) le soulignent pour les craies de surface et de subsurface de Mer du Nord, avec des porosités de 4 à 52 %, des perméabilités de 0,01 à 100 mD et des vitesses des ondes P sur roche saturée de 2,4 à 4,4 km.s-1.Dans le secteur d'étude (Normandie, France), pris comme analogue de terrain, 114 échantillons (Cénomanien- Santonien) ont été prélevés dans le but d'illustrer l'hétérogénéité sédimentaire et pétrophysique de la Craie. Comme en Mer du Nord, les échantillons présentent une grande variabilité des propriétés pétrophysiques : porosités () de 6,1 à 46,5 %, perméabilités matricielles (K) très faibles (0,002 mD) jusqu’à des perméabilités atypiques et très fortes (470 mD, en l’absence de fractures) et des vitesses des ondes P sur échantillon saturé s'étalant selon une gamme très étendue (1,8 à 5,5 km.s-1). Cependant, l’origine de ces hétérogénéités est encore mal comprise. L'objectif de cette étude est donc de comprendre l’influence respective des facteurs contrôlant les propriétés pétrophysiques afin d'optimiser la modélisation de ce type de réservoir.Trois modèles sédimentaires ont ici été définis avec :(1) un modèle de rampes, subdivisé en modèle de rampe argileuse avec des porosités de 34,4 à 46,5 % et des valeurs de perméabilité de 0,02 à 3 mD, et en modèle de rampe carbonatée (mudstone à grainstone) avec des porosités de 26,1 à 46,5 % et des valeurs de perméabilité de 0,04 à 6 mD,(2) un modèle de contourite (mudstone à grainstone et micro-packstone) avec des porosités de 8,3 à 45,5 % et des valeurs de perméabilité de 0,05 à 477 mD,(3) un modèle de surface de hiatus (Soupground à Hardground) avec des porosités de 6 à 36,9 % et des valeurs de perméabilité de 0,002 à 36 mD.Une classification des microtextures, basée sur l’observation au MEB de quatre critères (contenu minéralogique, fraction biogénique, fraction micritique et fraction de ciment), est proposée. À partir de ces critères, deux groupes majeurs ont été définis avec les Pure chalk microtextures et Impure chalk microtextures. Le groupe des Pure chalk microtextures reflète l’intensité des modifications subies par la craie lors de la diagenèse (taux de diagenèse qu’elle soit précoce ou tardive). Une augmentation du taux de diagenèse induit une diminution de la porosité et une augmentation des vitesses de propagation des ondes acoustiques P. En effet, les transformations qui s’opèrent au cours de la diagenèse, d’une part, réduisent la taille des espaces intergranulaires et donc font diminuer la porosité, et d’autre part, renforcent les contacts entre grains, favorisant ainsi la propagation des ondes acoustiques. Pour le groupe des Impure chalk microtextures, la présence de particules insolubles dans la matrice n’affecte pas la porosité, mais diminue la perméabilité du fait de la réduction des tailles d’accès aux pores.Par conséquent, l’héritage sédimentaire et les transformations diagénétiques, qui affectent à différents degrés les faciès sédimentaires primaires, déterminent les propriétés réservoirs et sont donc la cause de la grande variabilité de ces dernières. De plus, la répartition spatiale de ces microtextures, dépendante des conditions de dépôt (e.g. climat, distance des côtes), et des modifications diagénétiques (précoces ou tardives), n’est pas aléatoire. À partir de l’extrapolation combinée des faciès et de l’empreinte diagénétique, il serait ainsi possible de visualiser la distribution des propriétés pétrophysiques sur les falaises, et donc de visualiser l'architecture des réservoirs dans la Craie. / Chalk is defined as a microporous reservoir rock. This formation is a prolific hydrocarbon-bearing reservoir in the North Sea and is one of the main aquifers in the Paris Basin. The heterogeneity of chalk in terms of petrophysical properties (both surface and subsurface) is illustrated by porosity ranging from 4 to 52 %, permeability from 0.01 to 100 mD, and P-wave velocity on water-saturated samples from 2.4 to 4.4 km.s-1 (Alam et al., 2011).In the study area (Normandie, France), taken as an outcrop analogue, 114 samples were collected (Cenomanian – Santonian). As in the North Sea fields, these samples show great petrophysical heterogeneity: total porosity () from 6.1 to 46.5 %, very low permeability (K; 0.002 mD) to atypical high permeability (477 mD; without fractures), and P-wave velocity on water-saturated samples ranging from 1.8 to 5.5 km.s-1. However, the origin(s) of this large variation in petrophysical parameters is poorly understood. Three sedimentary models are defined here for the chalk:(1) Ramp models, subdivided into argillaceous ramp model, with porosity from 34,4 to 46.5%, and permeability from 0.02 to 3 mD, and carbonate ramp model (mudstone to packstone), with porosity from 26.1 to 46.5%, and permeability from 0.04 to 6 mD,(2) Contourite model (mudstone to grainstone and micro-packstone), with porosity from 8.3 to 45.5%, and permeability from 0.05 to 477 mD,(3) Softground to Hardground model, with porosity from 6 to 36.9%, and permeability from 0.002 to 36 mD.Each model has specific distribution in the porosity-permeability plot.A microtexture classification of the chalk is proposed, based on SEM observation of four groups of criteria (mineralogical content, biogenic fraction, micritic fraction and cement fraction). From these criteria, two major groups are defined: Pure chalk microtexture and Impure chalk microtexture. The Pure chalk microtexture group reflects the intensity of chalk modification during diagenesis (rate of diagenesis, whether early stage or not). An increase in the diagenetic rate induces a decrease in porosity and an increase in P-wave velocity. Diagenetic transformation induces a decrease in pore-space size, with better grain contact, explaining the decrease in porosity and the improved propagation of acoustic P-wave velocity. For Impure chalk microtexture group, the presence of insoluble particles in the matrix does not affect porosity but decreases permeability, due to the reduction of pore-throat size.The complex relationships between depositional inheritance and diagenetic transformation lead to variability in chalk petrophysical parameters. Spatio-temporal distribution of depositional facies and associated diagenetic transformation is not random; it depends on sedimentological condition (e.g. climate and distance to shore) and imprint of diagenetic processes (early or late stage). By extrapolating from the combined data on facies and diagenesis, the petrophysical properties of the entire cliff section can be characterised, and used to describe the reservoir architecture of the Chalk.

Les systèmes sédimentaires carbonatés forment à la fois des archives géologiques uniques des changements globaux-locaux des enveloppes externes de la Terre et renferment plus de 75 % des réserves d'hydrocarbure conventionnelles. Ils sont complexes et très difficiles à comprendre et à prédire. Cette complexité à toutes les échelles spatio-temporelles rend nécessaire l'intégration de méthodes naturalistes et quantitatives pour les étudier. La modélisation numérique basée processus permet de réduire les incertitudes des prédictions des propriétés des réservoirs carbonatés.Le manuscrit présente une méthode de modélisation itérative des systèmes carbonatés de la stratigraphie à la sismique en intégrant la diagenèse. Cette approche est basée sur le couplage de plusieurs outils numériques et par une démarche de travail combinant la sédimentologie, la diagenèse, la physique des roches et la simulation sismique.L’approche de modélisation développée permet ainsi d’intégrer un grand nombre de données multi-échelles et multidisciplinaire au sein d’un modèle facilement partageable entre toutes les disciplines en géosciences. L’intégration de ces nombreuses données est facilitée par un continuum du modèle entre les différentes échelles d’espace et de temps (du bassin au réservoir). La sismique synthétique ainsi obtenue n’est pas une simple convolution géométrique, elle intègre les propriétés sédimentologiques et diagénétiques, permettant une analyse de la signification stratigraphique des réflecteurs sismiques. Cette approche innovante intègre les méthodes naturalistes et quantitatives nécessaires à la compréhension et à la prédiction des systèmes carbonatés. / Carbonate sedimentary systems record both global and local geological changes of the outer envelope of the Earth and contain more than 75% of conventional hydrocarbon reserves. These carbonate systems show a great complexity at every spatial and temporal scales. To increase our ability to understand and predict such intricate natural systems, it is necessary to integrate naturalistic and quantitative methodological apporaches. Numerical process-based modeling (stratigraphic-sedimentary-diagenetic) reduces the uncertainty of prediction of carbonate reservoir properties. The manuscript presents a method of iterative modeling of carbonate systems from stratigraphy to seismic by integrating diagenesis. This approach is based on the coupling of numerical tools and a working approach combining sedimentology, diagenesis, rock physics and seismic simulation. Tests on case studies associated with scientific and industrial issues validated the method.The modeling approach that was developed during the thesis allows to integrate a large number of multi-scale and multidisciplinary data. Models can easily be shared between the disciplines of geosciences. The model continuum along different scales of space (from the basin to the reservoir) and time eases the integration of various data. The obtained synthetic seismic is not a simple geometric convolution, but an integration of sedimentological and diagenetic properties, which allows for an analysis of the stratigraphic significance of the seismic reflectors. This innovative approach integrates naturalistic and quantitative methods, which improve the understanding and prediction of carbonate systems and reservoirs.

Os reservatórios lacustres do Grupo Lagoa Feia, seção rift da Bacia de Campos, margem Leste brasileira, tem mantido há décadas uma expressiva produção a partir de campos localizados em águas rasas. A descoberta de grandes acumulações na seção rift e sag (pré-sal) da Bacia de Santos reativou a exploração por reservatórios análogos na Bacia de Campos e em outras bacias marginais. Um estudo petrográfico e petrofísico sistemático foi executado sobre os reservatórios rift da Formação Coqueiros e sag da Formação Macabu do Norte da Bacia de Campos, com objetivo de caracterizar os principais controles sobre a gênese e evolução daqueles reservatórios não-convencionais e seus sistemas porosos. As principais petrofácies de reservatório reconhecidas foram grainstones e rudstones bioclásticos, arenitos ooidais argilosos e dolomitos na Formação Coqueiros, e crostas coalescentes e não-coalescentes de calcita fascicular, rudstones e grainstones intraclásticos e dolomitos na Formação Macabu. A evolução dos reservatórios bioclásticos foi controlada pelo balanço entre dissolução ou neomorfismo dos bioclastos aragoníticos de bivalves, favorecendo a geração de porosidade móldica pouco conectada, ou a preservação da porosidade interpartícula bem conectada, controlando a permeabilidade dos reservatórios. Os arenitos de oóides de argilas magnesianas sofreram dissolução e substituição por dolomita e sílica, o que gerou sistemas porosos altamente heterogêneos, compostos por poros móldicos, intercristalinos, vugulares e microcristalinos. O crescimento de agregados cristalinos arborescentes nas crostas coalescentes de calcita gerou porosidade de crescimento do arcabouço primária, que foi reduzida principalmente por cimentação dolomítica, ou alargada por dissolução, o que ampliou sua permeabilidade. Crostas nãocoalescentes de calcita mostram forte interação com argilominerais magnesianos, que preenchem interstícios, e/ou estão intercalados com as crostas. Sua porosidade está relacionada com a dissolução das argilas, o que produziu baixa permeabilidade. Rochas intraclásticas comumente mostram matriz argilosa, ou estão compactadas e cimentadas. Onde exibem porosidade interpartícula primária ou dissolução da matriz, podem ter boas porosidades e permeabilidades. A dolomitização heterogênea de ambas as Formações em alguns casos destruiu a porosidade primária ou eodiagenética, ou em outros gerou altos valores de porosidade e permeabilidade nos dolomitos. Relações de substituição e de compactação indicam que muitos dos processos diagenéticos ocorreram durante a eodiagênese, controlados principalmente pela instabilidade da aragonita nos reservatórios bioclásticos da Formação Coqueiros, e dos argilominerais magnesianos na Formação Macabu. Este estudo representa a primeira caracterização petrográfica publicada dos reservatórios carbonáticos não-convencionais do sag, e salienta a importância crucial dos estudos petrográficos sistemáticos para a compreensão e previsão da qualidade de reservatórios complexos. / Lacustrine carbonate reservoirs from the Lagoa Feia Group, rift section of Campos Basin, offshore eastern Brazil, have sustained for decades a significant production from shallow water oil fields. The discovery of giant accumulations in the rift and sag (pre-salt) section of the adjacent Santos Basin has reactivated the exploration for equivalent reservoirs in the Campos Basin and in other marginal basins. A systematic petrographic and petrophysical study was performed on the rift Coqueiros Formation and the sag Macabu Formation carbonates from the Lagoa Feia Group in northern Campos Basin, in order to characterize the main controls on the origin and evolution of those unconventional reservoirs and their pore systems. The main types of reservoir petrofacies recognized were grainstones and bioclastic rudstones, magnesian clay ooidal arenites and dolostones from the Coqueiros Formation; coalescent and non-coalescent crusts of fascicular calcite, intraclastic rudstones and grainstones, and dolostones from the Macabu Formation. The evolution of bioclastic reservoirs was controlled by the balance between dissolution and neomorphism of the aragonitic bivalve bioclasts, favoring the generation of poorly-connected moldic porosity or the preservation of well-connected interparticle porosity, which controlled the permeability of the reservoirs. The magnesian clay (stevensite) ooidal arenites suffered dissolution and replacement by dolomite and silica, what generated highly heterogeneous pore systems, composed by moldic, intercrystalline, vugular and microcrystalline pores. The growth of crystal shrubs in coalescent calcite crusts generated growth-framework primary porosity, which was reduced mostly by dolomite cementation, or enlarged by dissolution, what enhanced their permeability. Non-coalescent calcite crusts usually show strong interaction with syngenetic magnesian clay minerals, which fill interstices and/or are interbedded with the crusts. Their porosity is related to dissolution of the clays, what generated poor permeability. Intraclastic rocks usually display clay matrix, or are compacted and cemented. Where they show interparticle primary porosity or matrix dissolution, they may have good porosities and permeabilities. The heterogeneous dolomitization of both formations, either destroyed the primary or early diagenetic porosity, or generated high porosity and permeability values in the dolostones. Relationships of replacement and compaction indicate that most of the diagenetic processes occurred during eodiagenesis, controlled mostly by the instability of the aragonite in the bioclastic Coqueiros reservoirs, and of the magnesian clay minerals in the Macabu Formation. This study represents the first published petrographic characterization of the unconventional sag carbonate reservoirs, and stresses the crucial importance of systematic petrographic studies for the understanding and prediction of the quality of complex reservoirs.

Processos diagenéticos controlam a porosidade e permeabilidade dos reservatórios de petróleo. Um estudo petrográfico sistemático de 71 arenitos e conglomerados da Formação Itabapoana (Aptiano), selecionadas de testemunhos de 13 poços na porção offshore da Bacia de Campos, Leste do Brasil, permitiu o reconhecimento dos principais constituintes primários, diagenéticos, tipos de poros e das relações temporais e espaciais entre eles. Essas rochas são contemporâneas aos extensos reservatórios lacustres do “Pré-Sal” atualmente em exploração. As rochas variam de arenitos muito finos a conglomerados, com predominância de arenitos muito grossos, e sua composição detrítica original corresponde a arcósios líticos e litarenitos feldspáticos, ricos em fragmentos de rochas vulcânicas (FRV). Argilominerais esmectíticos são os mais abundantes constituintes diagenéticos, relacionados principalmente à alteração de FRV, minerais pesados e biotita. A história térmica e de soterramento, e o fluxo de fluídos também exerceram um papel fundamental nos processos diagenéticos e na evolução da qualidade de reservatório. Os principais processos diagenéticos registrados foram a dissolução de FRV, feldspatos e minerais pesados, a autigênese de esmectitas, hematita, dolomita, calcita, zeolitas e óxidos de titânio cimentando e substituindo FRV, feldspatos, biotita e minerais pesados, a compactação mecânica e química, e a albitização dos feldspatos, principalmente dos plagioclásios. A porosidade primária intergranular foi fortemente reduzida pela compactação e cimentação por argilominerais esmectíticos, calcita, dolomita e zeolitas. Por outro lado, porosidade secundária foi gerada pela dissolução de constituintes primários e diagenéticos, e por faturamento. Futuros estudos específicos e detalhados, incluindo análises de microscopia eletrônica, difratometria de raios-X e isótopos estáveis, deverão contribuir para um melhor entendimento da distribuição espacial e temporal dos processos diagenéticos nessas rochas, de modo a embasar o desenvolvimento de modelos preditivos quanto à sua qualidade, que possam contribuir para reduzir os riscos envolvidos na sua exploração. / Diagenetic processes control the porosity and permeability of petroleum reservoirs. A systematic study of 71 sandstones and conglomerates of the Itabapoana Formation (Aptian), selected from the cores of 13 wells in the offshore portion of Campos Basin, eastern Brazil, allowed the recognition of the main primary and diagenetic constituents, pore types, and of the space and time relations among them. These rocks are contemporaneous to the extensive lacustrine Pre-Salt carbonate reservoirs under exploration. The rocks range from very fine-grained sandstones to conglomerates, with predominance of very coarse-grained sandstones, and their original detrital composition corresponds to lithic arkoses and feldspathic litharenites, rich in volcanic rock fragments (VFR). Smectitic clay minerals are the most abundant diagenetic constituents, related mostly to the alteration of VRF, heavy minerals and biotite. The burial and thermal history and the flow of fluids also exerted a fundamental role on the diagenetic processes and on the of reservoir quality. The main diagenetic processes recorded were the dissolution of volcanic fragments, feldspars and heavy minerals, the authigenesis of smectites, hematite, dolomite, calcite, zeolites and titanium oxides in intergranular pores and replacing VRF, feldspars, biotite and heavy minerals, mechanical and chemical compaction, and the albitization of feldspars, mostly plagioclase. Primary intergranular porosity was strongly reduced by compaction and smectite, calcite, dolomite and zeolite cementation. On the other hand, secondary porosity was generated by the dissolution of primary and diagenetic constituents, and by fracturing. Future specific and detailed studies, including electron microscopy, X-ray diffraction and stable isotope analyses, shall contribute to a better understanding of the space and time distribution of diagenetic processes in these rocks, in order to support the development of predictive models of their quality that may contribute to the reduction of risks involved in their exploration.

A evolução diagenética de dois reservatórios turbidíticos terciários da porção offshore da Bacia do Espírito Santo, foi influenciada tanto por processos meteóricos como por processos relacionados a domos salinos adjacentes aos reservatórios, que tiveram diferente impacto sobre sua qualidade. A precipitação de pirita framboidal, dolomita microcristalina e siderita ocorreram sob condições eodiagenéticas marinhas. A percolação por água meteórica ocorreu ainda durante a eodiagênese, e promoveu extensiva caulinização (δ18OSMOW=+15.3‰ a +18.2‰; δDSMOW=-51‰ a -66‰) e dissolução de feldspatos, micas e intraclastos lamosos. Durante o progressivo soterramento da sequência (profundidades atuais: 2600-3000m) e consequente compactação, fluidos oriundos dos lutitos circundantes, modificados por reações com a matéria orgânica e carbonatos, deslocaram gradualmente os fluidos salobros marinhos-meteóricos, levando à precipitação de calcita poiquilotópica (valores médios: δ18OVPDB= -6.6‰; δ13CVPDB= -1.2‰). A composição dos fluidos mesodiagenéticos foi progressivamente modificada pela proximidade dos domos de sal, promovendo ubíqua albitização dos feldspatos e precipitação localizada de quartzo, calcita (valores médios: δ18O= -10.2‰; δ13C= -3.9‰) e dolomita em sela (valores médios: δ18O= -10.2‰; δ13C= -4.2‰). A análise de inclusões fluidas nos crescimentos de quartzo indicou que os fluidos precipitantes tinham salinidade predominantemente entre 9 e 13 % de NaCl (em peso) e temperaturas de homogeneização na faixa de 1050 a 1450 C Estes valores são mais altos do que aqueles esperados para o gradiente geotérmico normal da área. A distribuição da albitização dos feldspatos sugere que as fraturas ao longo das margens dos domos de sal atuaram como caminho preferencial para a circulação das salmouras quentes. Os valores de δ13C e δ18O dos cimentos de calcita e dolomita seguem um padrão de covariância, mostrando um declínio desde daqueles representativos da água do mar (~0%), para δ13C =-5.9‰ e δ18O = -10.9‰ para a calcita, e δ13C = -5.4‰ e δ18O = -11.7‰ para a dolomita, o que sugere a progressiva participação da descarboxilação térmica da matéria orgânica dos lutitos com o soterramento. A compactação mecânica foi mais importante do que a cimentação na redução da porosidade, e a dissolução de feldspatos foi o processo mais importante na geração de porosidade nos reservatórios. Apesar da proximidade dos domos de sal, a intensidade dos processos diagenéticos foi moderada, já que não ocorreu autigênese de ilita, e a cimentação de quartzo foi limitada. Estas características podem estar relacionadas com o soterramento relativamente recente destes reservatórios. Este estudo mostra que a predição da diagênese e qualidade de reservatórios relacionados a domos de sal é uma função de múltiplas variáveis, incluindo as dimensões dos domos, o regime térmico regional da bacia, a condutividade térmica e de fluidos, e a composição mineral e propriedades geomecânicas dos reservatórios e litologias associadas. / The diagenetic evolution of two tertiary turbidite reservoirs from the offshore portion of the Espírito Santo Basin, eastern Brazil, was influenced by meteoric and salt dome-related processes, which had different impact on their quality. Marine eogenetic processes included the precipitation of framboidal pyrite, microcrystalline dolomite and siderite. Meteoric water influx during eodiagenesis occurred in response to relative sea-level falls that promoted extensive kaolinization (δ18O=+15.3‰ to +18.2‰; δD= -51‰ to -66‰) and dissolution of framework silicate grains. During progressive burial (present depths – 2600 m – 3000 m), connate marine fluids modified by reactions with organic matter and carbonates presented in the surrounding mudrocks gradually displaced brackish fluids generated by the meteoric influx and led to concretionary cementation by poikilotopic calcite (average δ18O= -6.6‰; δ13C= -1.2‰). Mesogenetic fluids were progressively modified by the proximity of salt domes, which led to ubiquitous feldspar albitization and localized quartz, calcite (average δ18O= -10.2‰; δ13C= -3.9‰) and saddle dolomite precipitation (average δ18O= -10.2‰; δ13C= -4.2‰). Fluid inclusion analysis in quartz overgrowths indicate that the precipitating fluids had salinities predominantly in the range 9-13 wt% NaCl equivalent and temperatures largely in the 105 – 145oC range These values are higher than those expected considering the normal geothermal gradient for the area. The distribution of feldspar albitization suggests that the fracture systems along the salt domes margins acted as preferential pathways for such hot, saline diagenetic fluids. Isotopic values for calcite and dolomite cements follow a co-variance trend of decreasing δ13C and δ18O from close to marine (~0‰) towards negative values (δ13C and δ18O down to -5.9‰ and -10.9‰ for calcite; -5.4‰ and -11.7‰ for dolomite), suggesting increasing contribution from thermal decarboxylation with increasing temperature and depth. Mechanical compaction was more important than cementation in reducing depositional porosity, and the dissolution of framework silicate grains is the most important processes for enhancing reservoir quality. Despite the proximity to the salt domes, the intensity of the influenced diagenetic processes is relatively mild, as illite authigenesis is lacking, and quartz cementation is limited, features that may be related to the recent burial of the reservoirs.

A evolução diagenética de dois reservatórios turbidíticos terciários da porção offshore da Bacia do Espírito Santo, foi influenciada tanto por processos meteóricos como por processos relacionados a domos salinos adjacentes aos reservatórios, que tiveram diferente impacto sobre sua qualidade. A precipitação de pirita framboidal, dolomita microcristalina e siderita ocorreram sob condições eodiagenéticas marinhas. A percolação por água meteórica ocorreu ainda durante a eodiagênese, e promoveu extensiva caulinização (δ18OSMOW=+15.3‰ a +18.2‰; δDSMOW=-51‰ a -66‰) e dissolução de feldspatos, micas e intraclastos lamosos. Durante o progressivo soterramento da sequência (profundidades atuais: 2600-3000m) e consequente compactação, fluidos oriundos dos lutitos circundantes, modificados por reações com a matéria orgânica e carbonatos, deslocaram gradualmente os fluidos salobros marinhos-meteóricos, levando à precipitação de calcita poiquilotópica (valores médios: δ18OVPDB= -6.6‰; δ13CVPDB= -1.2‰). A composição dos fluidos mesodiagenéticos foi progressivamente modificada pela proximidade dos domos de sal, promovendo ubíqua albitização dos feldspatos e precipitação localizada de quartzo, calcita (valores médios: δ18O= -10.2‰; δ13C= -3.9‰) e dolomita em sela (valores médios: δ18O= -10.2‰; δ13C= -4.2‰). A análise de inclusões fluidas nos crescimentos de quartzo indicou que os fluidos precipitantes tinham salinidade predominantemente entre 9 e 13 % de NaCl (em peso) e temperaturas de homogeneização na faixa de 1050 a 1450 C Estes valores são mais altos do que aqueles esperados para o gradiente geotérmico normal da área. A distribuição da albitização dos feldspatos sugere que as fraturas ao longo das margens dos domos de sal atuaram como caminho preferencial para a circulação das salmouras quentes. Os valores de δ13C e δ18O dos cimentos de calcita e dolomita seguem um padrão de covariância, mostrando um declínio desde daqueles representativos da água do mar (~0%), para δ13C =-5.9‰ e δ18O = -10.9‰ para a calcita, e δ13C = -5.4‰ e δ18O = -11.7‰ para a dolomita, o que sugere a progressiva participação da descarboxilação térmica da matéria orgânica dos lutitos com o soterramento. A compactação mecânica foi mais importante do que a cimentação na redução da porosidade, e a dissolução de feldspatos foi o processo mais importante na geração de porosidade nos reservatórios. Apesar da proximidade dos domos de sal, a intensidade dos processos diagenéticos foi moderada, já que não ocorreu autigênese de ilita, e a cimentação de quartzo foi limitada. Estas características podem estar relacionadas com o soterramento relativamente recente destes reservatórios. Este estudo mostra que a predição da diagênese e qualidade de reservatórios relacionados a domos de sal é uma função de múltiplas variáveis, incluindo as dimensões dos domos, o regime térmico regional da bacia, a condutividade térmica e de fluidos, e a composição mineral e propriedades geomecânicas dos reservatórios e litologias associadas. / The diagenetic evolution of two tertiary turbidite reservoirs from the offshore portion of the Espírito Santo Basin, eastern Brazil, was influenced by meteoric and salt dome-related processes, which had different impact on their quality. Marine eogenetic processes included the precipitation of framboidal pyrite, microcrystalline dolomite and siderite. Meteoric water influx during eodiagenesis occurred in response to relative sea-level falls that promoted extensive kaolinization (δ18O=+15.3‰ to +18.2‰; δD= -51‰ to -66‰) and dissolution of framework silicate grains. During progressive burial (present depths – 2600 m – 3000 m), connate marine fluids modified by reactions with organic matter and carbonates presented in the surrounding mudrocks gradually displaced brackish fluids generated by the meteoric influx and led to concretionary cementation by poikilotopic calcite (average δ18O= -6.6‰; δ13C= -1.2‰). Mesogenetic fluids were progressively modified by the proximity of salt domes, which led to ubiquitous feldspar albitization and localized quartz, calcite (average δ18O= -10.2‰; δ13C= -3.9‰) and saddle dolomite precipitation (average δ18O= -10.2‰; δ13C= -4.2‰). Fluid inclusion analysis in quartz overgrowths indicate that the precipitating fluids had salinities predominantly in the range 9-13 wt% NaCl equivalent and temperatures largely in the 105 – 145oC range These values are higher than those expected considering the normal geothermal gradient for the area. The distribution of feldspar albitization suggests that the fracture systems along the salt domes margins acted as preferential pathways for such hot, saline diagenetic fluids. Isotopic values for calcite and dolomite cements follow a co-variance trend of decreasing δ13C and δ18O from close to marine (~0‰) towards negative values (δ13C and δ18O down to -5.9‰ and -10.9‰ for calcite; -5.4‰ and -11.7‰ for dolomite), suggesting increasing contribution from thermal decarboxylation with increasing temperature and depth. Mechanical compaction was more important than cementation in reducing depositional porosity, and the dissolution of framework silicate grains is the most important processes for enhancing reservoir quality. Despite the proximity to the salt domes, the intensity of the influenced diagenetic processes is relatively mild, as illite authigenesis is lacking, and quartz cementation is limited, features that may be related to the recent burial of the reservoirs.