The unique properties of diamond make it an excellent material for electronic and optical applications. It is particularly attractive for ultraviolet radiation dosimetry due to its intrinsic properties, which include biological tissue equivalence and visible blindness. Importantly, the advent of synthetic diamond, especially Chemical Vapour Deposition (CVD) diamond, has made it more economically viable for such applications. A thorough understanding of the electronic properties of diamond is needed before these applications can be fully explored. Consequently, this thesis investigates charge carrier trapping states in CVD polycrystalline diamond for the optimization of ultraviolet radiation dosimetry. / The technique of Thermally Stimulated Conductivity (TSC) is used to probe electrically active defects and is also applied for dosimetric read-out. A range of as-grown CVD polycrystalline diamond films are studied to determine attributes that favour dosimetric-related TSC. In doing so, we establish that dosimetric TSC in these films originate from defects at the grain boundaries with a correlation to high crystalline quality. / With this finding in hand, we then investigate the possibility of optimising diamond for dosimetry by controllably introducing extrinsic dosimetric defects using ion implantation. However, it is shown that these defects are not suitable for dosimetry and have a detrimental effect on the indigenous TSC signal. This study verifies the importance of crystalline quality on the indigenous dosimetric properties of CVD polycrystalline diamond. / The possibility of doping CVD diamond during growth is also investigated as a means for intentionally introducing extrinsic dosimetric defects. Sulphur is selected as the dopant based on the theoretical energy levels formed by this defect, and because the prospect of S doping in diamond remains an actively debated issue in the literature. We report for the first time defect levels extracted from TSC analysis of S-doped CVD diamond and find consistency with theoretical predications. In addition, the dominant TSC trap level in S-doped diamond shows promise for radiation dosimetry with certain properties exceeding many current radiation dosimeters. / The experimental results in this thesis lead to a deeper understanding of defect and trapping mechanisms in CVD polycrystalline diamond and establish attributes that favour TSC and related dosimetric properties in such films. This knowledge is fundamental to the realisation of diamond for ultraviolet dosimetry.

Thesis (M.S.)--Oregon State University, 2010. / Printout. Includes bibliographical references (leaves 42-45). Also available on the World Wide Web.

Thesis (M. Sc.)--University of Canterbury, 2006. / Typescript (photocopy). Includes bibliographical references (leaves 60-62). Also available via the World Wide Web.

A BF3 fast neutron dosimeter or long counter is constructed and calibrated for use with the Cockcroft-Walton accelerator and UTR-IO reactor at Virginia Polytechnic Institute. The counter consists of a paraffin cylinder 8 inches in diameter, having a BF3 proportional detector on the axis and a set of holes around the detector to improve the low energy response. External shields of paraffin, 3 inches thick, and boron-trioxide, 1/2 inch thick, enclose the paraffin cylinder. These shields serve to reduce the background effect and improve the high energy response. Calibration of the counter is accomplished using as neutron sources: plutonium-berylliwn and the induced reactions H2(d,n)He3 and H3(d,n)He4. Long counter efficiencies for both a 1 inch and 1/2 inch BF) tube yield a flat response over the energy range, 2.5 to 4 Mev whereas an approximately 60% decrease in efficiency is observed for a 14.1 Mev neutron. Count rate of long counter is expressed as a function of the incident neutron flux. Neutron fluxes, ranging from 0 to 1100 neutrons/cm2-second are monitored with the counter. / Master of Science

Call number: LD2668 .T4 1979 H364 / Master of Science / Mechanical and Nuclear Engineering

Thesis (M.S. in Electrical Engineering)--Naval Postgraduate School, September 2003. / Thesis advisor(s): Todd R. Weatherford, Andrew A. Parker. Includes bibliographical references (p. 39). Also available online.

Thesis (M.S.)--University of Texas at El Paso, 2008. / Title from title screen. Vita. CD-ROM. Includes bibliographical references. Also available online.

Thesis (Ph. D. in Physics)--Vanderbilt University, May 2009. / Title from title screen. Includes bibliographical references.

Thesis--University of Utrecht. / Bibliography: p. 89-92.

Thesis--University of Utrecht. / Bibliography: p. 89-92.