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Epoxidation of alkenes by dimethyldioxirane kinetics, activation parameters and solvent studies /Crow, Brian Shelton. January 2005 (has links)
Thesis (Ph. D.)--Georgia State University, 2005. / Title from title screen. Al Baumstark, committee chair; Paul Franklin, David Boykin, Markus Germann, committee members. Electronic text (136 p. : charts (some col.)) : digital, PDF file. Description based on contents viewed June 7, 2007. Includes bibliographical references (p. 130-136).
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Development of enzyme-based screening methodology for combinatorial catalysis identification of novel chiral salens for the hydrolytic kinetic resolution of epoxides /Dey, Sangeeta. January 2007 (has links)
Thesis (Ph.D.)--University of Nebraska-Lincoln, 2007. / Title from title screen (site viewed Feb. 17, 2009). PDF text: viii, 383 p. : ill. (chiefly col.) ; 49.9 Mb. UMI publication number: AAT 3294904. Includes bibliographical references. Also available in microfilm and microfiche formats.
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The influence of thermohumid conditions on compression-after-impact properties of fibre-reinforced laminate materialsAziz, Roslan Abd January 2000 (has links)
Advance composite materials based mainly on epoxy resins are being used in increasing amounts in aerospace components due to their high strength:weight ratio. Such components have to survive in a range of temperature and humid environments in different parts of the world. The current generation of epoxy resins used in high performance fibre reinforced laminates absorb moisture from the atmosphere. Moisture absorption by the epoxy resins leads to a reduction in glass transition temperature and to a softening of the resin with a loss of resin stiffness and strength. In certain applications the components have to survive low impacts from dropped tools and rough handling during maintenance. Low energy impacts of this nature are considered potentially dangerous mainly because the damage might be left undetected. Even where no visible impact damage is observed at the surface, matrix cracking and interlaminar failure can occur, and the load carrying properties of the composite components is considerably reduced. A compression after impact (CAI) test is widely used in industry as the major screening parameters for materials selection. The aim of the work reported in this thesis was to determine the influence of thermohumid conditions on CAI properties and to assess the degradation behaviour of composite laminates under these thermohumid conditions.
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Application of oxo reaction to two sugar epoxidesKalra, Rajinder Mohan January 1967 (has links)
Methyl 2,3-anhydro-4,6-0-benzylidene- α-D-mannopyranoside was allowed to react with carbon monoxide and methanol in the presence of dicobalt octacarbonyl at elevated temperatures and pressures. The resulting product mixture contained unreacted epoxide, methyl 3-0-methyl-α -D-altropyranoside and methyl 4,6-0-benzylidene- α-D-altropyranoside.
Methyl 2,3-anhydro-4,6-0-benzylidene- α-D- mannopyranoside was allowed to react with carbon monoxide (990 p.s.i.) and hydrogen (910 p.s.i.) in the presence of dicobalt octacarbonyl at 140°. The resulting product mixture contained two products. The n.m.r. indicated that the epoxide ring had not been opened. In one product, the benzylidene ring was completely removed and in the other component the benzylidene ring had been partially altered.
When Brigl's anhydride was allowed to react with carbon monoxide (910 p.s.i.) and hydrogen (990 p.s.i.) in the presence of dicobalt octacarbonyl at 106° for 30 minutes, the resulting product mixture contained one major product and two minor products. The minor product was presumed to be a sugar and the major product (75-80%) had been characterized as 2,6-anhydro-D-glycero-D-gulo-heptitol. / Science, Faculty of / Chemistry, Department of / Graduate
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Microwave effects on the curing, structure properties and decomposition of epoxy resinsBolasodun, Babatunde January 2011 (has links)
Comparative studies were carried out on the curing kinetics, physical and mechanical properties of conventionally and microwave cured epoxy resins. Epoxy resins Araldite LY 5052 and DLS 772 were used for this study. 4 4' Diaminodiphenyl sulfone was used as a hardener in the preparation of both systems. Nuclear magnetic resonance and gel permeation chromatography were used to identify the chemical structure of the resins. Differential scanning calorimetry was used to monitor the curing kinetics of conventionally cured epoxy samples while a microwave heating calorimeter was used to monitor the curing kinetics of microwave cured epoxy samples 'in situ'. These studies were carried out under non-isothermal and isothermal conditions. For both conditions, there was a significant increase in the fractional conversion of the microwave cured samples compared to the conventionally cured samples. The curing reactions for samples cured using microwave heating took place over a smaller temperature range. Higher reaction rates were observed in the samples cured using microwave heating.There were some differences in the kinetic parameters of the non-isothermal curing reactions of samples cured using microwave and conventional heating. For the Araldite LY 5052 / 4 4' DDS epoxy system, the microwave cured samples had higher activation energy than conventionally cured samples, while for the Araldite DLS 772 / 4 4' DDS epoxy system, the microwave cured samples had lower activation energy. The activation energies of the microwave isothermal curing of both Araldite LY 5052 / 4 4' DDS and Araldite DLS 772 / 4 4'DDS epoxy systems were lower than the activation energies of the conventionally cured samples.Infrared spectroscopy showed that the curing reaction followed the same path during conventional and microwave heating. It also revealed that the reaction rate of the microwave cured samples was higher than the conventionally cured samples.For both epoxy systems, the microwave cured samples had a higher glass transition temperature (Tg) , higher cross-link density (v) and lower molecular weight between cross-links. These showed that the microwave cured samples had a more compact network structure than the conventionally cured samples, which is an indication of better mechanical properties.A microwave reaction system was used to successfully dissolve conventional and microwave cured samples of Araldite DLS 772 / 4 4' DDS epoxy system. The chemical structure of the decomposed product was determined.
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Epoxidized Sucrose Soyate as a Primary Binder in ParticleboardNorris, Andrew James January 2018 (has links)
Wood composites industry has been growing for decades. However, wood composites have been associated with some health concerns due to the presence of formaldehyde. A promising bio-based resin Epoxidized Sucrose Soyate (ESS) was investigated as a potential primary binder in particleboards. The goal of this research was to find a strong and durable resin for wood composites. Several ESS-MDI based formulas were found that were able to match the performance criteria for particleboard. / North Dakota Soybean Council
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The reactions of phosphodiesters with epoxides : model studies to understanding the interaction of PAH epoxides with nucleic acidsDi Raddo, Pasquale. January 1983 (has links)
No description available.
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Epoxy/aluminum interphasesFondeur, Fernando January 1992 (has links)
No description available.
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PROCESSING OF NANOCOMPOSITES BASED ON EPOXY AND CARBON NANOTUBESNARASIMHADEVARA, SUHASINI 27 September 2005 (has links)
No description available.
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Hygrothermal response of graphite/epoxy composites /Chen, Rong-Sheng January 1987 (has links)
No description available.
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