Thesis (M.S.)--Rochester Institute of Technology, 2004. / Typescript. Includes bibliographical references (leaf 122).

A irradiação de dielétricos sólidos com feixes eletrônicos tem-se revelado uma poderosa ferramenta na investigação das características de armazenamento e condução de carga elétrica nesses materiais. O presente trabalho faz urna revisão dos resultados que se tem obtido no campo, discute uma equação de transporte para carga em excesso em isolantes amorfos e aplica-la a particulares montagens experimentais. Encontra-se que os efeitos de carga espacial não são em geral importantes para pequenas penetrações do feixe na amostra, mas desempenham papel essencial no caso de elétrons quase-trespassantes. Em particular, obtém-se satisfatória concordância com os resultados experimentais de Spear (1955). / Irradiation of solid dielectric with electron beams has been used as a powerful tool in investigations of charge storage and transport in such materials. The present work reviews some of the results that have been obtained in this area and discusses the formulation of a transport equation for excess charge in irradiated insulators. This equation is subsequently applied to various experimental set-ups . It is found that space charge effects p1ay an essential role in the establishment of stationary currents in samples subject to quasi- -penetrating electron beams. Such effects may, however, be neglected for low electron ranges. Theoretical results are in good agreement with experimental findings by Spear (1955).

TSDC (thermally stimulated depolarization current) is one of the most important and popular technique for investigating electret materials. TSDC technique can indicate the magnitude of polarization and depolarization, relaxation time, charge-storage, glass transition, and activation energy. To fully investigate polarization and relaxation for pure epoxy and filled epoxy materials, a TSDC system was built and verified by the research. The article describes the building processes and verification of the TSDC system. TSDC, TSPC, and TWC tests data for epoxy and filled epoxy samples are presented in the article. To compare TSDC technique with other related techniques, DEA (dielectric analysis), DMA (dynamic mechanical analysis), and DSC (differential scanning calorimetry) tests are introduced.

Ce travail de thèse s’inscrit dans la grande problématique de la récupération d’énergie. Il s’agit plus précisément de convertir de petites quantités d’énergie cinétique présentes dans un écoulement d’air en énergie électrique par l’intermédiaire d’un convertisseur électrostatique. L’énergie électrique convertie est ensuite destinée à alimenter des capteurs autonomes communicants pour le monitoring de structures, le suivi environnemental, le monitoring de santé…Le manuscrit comprend une étude des travaux antérieurs en récupération d’énergie des écoulements d’air, la compréhension physique des phénomènes de conversion électrostatique, de mécanique des fluides et d’aérodynamique à très faibles nombres de Reynolds, ainsi qu’une description des prototypes développés et des résultats expérimentaux obtenus.Les récupérateurs que nous avons développés se divisent en deux grandes catégories : (i) les récupérateurs rotatifs qui transforment l’énergie cinétique de l’air en énergie mécanique de rotation et (ii) les récupérateurs aéroélastiques qui puisent l’énergie cinétique du vent pour produire de l’énergie mécanique par oscillations périodiques. Ces deux types de récupérateurs ont été associés à des convertisseurs électrostatiques dédiés, polarisés par l’ajout d’électrets ou auto-polarisés par triboélectricité. Les récupérateurs d'énergie ont été optimisés et nous avons notamment montré l'intérêt de la conversion électrostatique pour des dispositifs de petites dimensions (quelques cm²) fonctionnant à faible vitesse (<3m/s). Les densités surfaciques de puissance atteignent 5µW/cm2@1m/s pour les récupérateurs rotatifs et de l'ordre de 10µW/cm2@10m/s pour les récupérateurs aéroélastiques. Les micro-générateurs ont finalement été combinés à des circuits de gestion d'énergie pour alimenter des capteurs autonomes communicants, validant la chaine complète de récupération d'énergie, montrant par la même occasion l'intérêt des circuits de gestion d'énergie actifs de type SECE (synchronous electric charge extraction) ou MPP (maximum power point). / This work is enshrined in the energy harvesting context. More specifically, the purpose is to convert small amounts of kinetic energy from airflows into electrical energy through an electrostatic converter. The electrical energy produced is then intended to supply low power sensors for structural health monitoring, environmental follow-up, human monitoring…The manuscript includes an overview of the state of the art on airflow energy harvesting, the physical understanding of electrostatic conversion phenomena, fluid mechanics, ultra-low Reynolds number aerodynamics, a description of the prototypes developed and the results obtained.The harvesters we have developed are divided into two families: (i) the rotational harvesters which transform the kinetic energy of airflows into mechanical energy of rotation and (ii) the aeroelastic harvesters which use wind energy to produce mechanical energy of periodical oscillations. These two types of harvesters have been associated to different electrostatic converters, polarized by the addition of electrets or self-polarized by triboelectricity. The energy harvesters have been optimized and we have demonstrated the benefit of the electrostatic conversion for small devices (a few cm2) operating at low speeds (<3m/s). The power densities reach 5µW/cm2@1m/s for rotational devices and in the range of 10µW/cm2@10m/s for aeroelastic devices. The micro-generators were finally combined with power management circuits to supply autonomous and communicating sensors. This last stage completes the energy harvesting chain and also shows the high benefit of active circuits (synchronous electric charge extraction, maximum power point).

Analisa-se no presente trabalho o problema das medidas de relaxação dielétrica a U.B.F. (Ultra Baixa Frequência). Propõe-se um modelo de ponte para tais medidas capaz de varrer o intervalo 10-3 Hz-10Hz, baseada na medida de fase conforme a discussão original de Van Turnhout e colaboradores. Analisa-se também os principais problemas experimentais com tal equipamento de U.B.F. e descreve-se a sua construção e funcionamento. Analisa-se também o modelo teórico de correlação entre medidas de U.B.F. e descarga de eletreto com correntes termo-estimulado. Em particular calculamos uma correção para a expressão integral dado por Van Turnhout e colaboradores que leva em conta a influência da energia de ativação na correlação entre as duas técnicas. Tal conversão é significante para valores da energia de ativação menor que 0,5eV e que ocorrem experimentalmente com frequência / In the present work we investigate the problem of U.L.F. (Ultra Low Frequency) dielectric relaxation. An experimental model is proposed for a bridge covering the range of 10-3Hz-10Hz, based on phase shift measurements originally proposed by Van Turhout and collaborators. We also analyze the main experimental problems with such U.L. F. measurements and describe its construction and performance. We have also investigated the theoretical correlation between U.L.F. dielectric relaxation and electret thermal stimulated currents. We calculate in particular, a correction for the integral expression given by Turnhout and collaborators that takes into account the value of the activation energy in the relation between the two techniques. The correction is important for values of the activation energy below 0,5eV, which occur frequently in dielectric relaxation processes

An array of electret-biased frequency-selective resonant microelectromechanical system (MEMS) acoustic sensors was proposed to perform analysis of stress pulses created during an impact between two materials. This analysis allowed classification of the stiffness of the materials involved in the impact without applying post-impact signal processing. Arrays of resonant MEMS sensors provided filtering of the incident stress pulse and subsequent binning of time-domain waveforms into frequency-based spectra. Results indicated that different impact conditions and materials yielded different spectral characteristics. These characteristics, as well as the resulting sensor array responses, are discussed and applied to impact classification. Each individual sensor element in the array was biased by an in situ charged electret film. A microplasma discharge apparatus embedded within the microsensor allowed charging of the electret film after all device fabrication was complete. This enabled electret film integration using high-temperature surface micromachining processes that would typically lead to discharge of traditionally formed electret materials. This also eliminated the traditional wafer-bonding and post-fabrication assembly processes required in conventional electret integration approaches. The microplasma discharge process and resulting electret performance are discussed within the context of the MEMS acoustic sensor array.

Analisa-se no presente trabalho o problema das medidas de relaxação dielétrica a U.B.F. (Ultra Baixa Frequência). Propõe-se um modelo de ponte para tais medidas capaz de varrer o intervalo 10-3 Hz-10Hz, baseada na medida de fase conforme a discussão original de Van Turnhout e colaboradores. Analisa-se também os principais problemas experimentais com tal equipamento de U.B.F. e descreve-se a sua construção e funcionamento. Analisa-se também o modelo teórico de correlação entre medidas de U.B.F. e descarga de eletreto com correntes termo-estimulado. Em particular calculamos uma correção para a expressão integral dado por Van Turnhout e colaboradores que leva em conta a influência da energia de ativação na correlação entre as duas técnicas. Tal conversão é significante para valores da energia de ativação menor que 0,5eV e que ocorrem experimentalmente com frequência / In the present work we investigate the problem of U.L.F. (Ultra Low Frequency) dielectric relaxation. An experimental model is proposed for a bridge covering the range of 10-3Hz-10Hz, based on phase shift measurements originally proposed by Van Turhout and collaborators. We also analyze the main experimental problems with such U.L. F. measurements and describe its construction and performance. We have also investigated the theoretical correlation between U.L.F. dielectric relaxation and electret thermal stimulated currents. We calculate in particular, a correction for the integral expression given by Turnhout and collaborators that takes into account the value of the activation energy in the relation between the two techniques. The correction is important for values of the activation energy below 0,5eV, which occur frequently in dielectric relaxation processes

No description available.

This PhD dissertation presents the exploration and development of two carbon materials, carbon nanotubes (CNTs) and carbon fiber (CF), as either key functional components or unconventional substrates for a variety of MEMS applications. Their performances in three different types of MEMS devices, namely, strain/stress sensors, vibration-powered generators and fiber solar cells, were evaluated and the working mechanisms of these two non-traditional materials in these systems were discussed. The work may potentially enable the development of new types of carbon-MEMS devices. Firstly, a MEMS-assisted electrophoretic deposition (EPD) technique was developed, aiming to achieve controlled integration of CNT into both conventional and flexible MEMS systems. Selective deposition of electrically charged CNTs onto desired locations was realized in the EPD process through patterning of electric field lines created by the microelectrodes fabricated using MEMS techniques. A variety of 2-D and 3-D micropatterns of CNTs with controllable thickness and morphology have been successfully achieved in both rigid and elastic systems at room temperature with relatively high throughput. Studies also showed that high surface hydrophobicity of the non-conductive regions in microstructures was critical to accomplish well-defined selective micropatterning of CNTs through this strategy. A patterned PDMS/CNT nanocomposite was then fabricated through the aforementioned approach, and was incorporated, investigated and validated in elastic force/strain microsensors. The gauge factor of the sensor exhibited a strong dependence on both the initial resistance of the device and the applied strain. Detailed analysis of the data suggests that the piezoresistive effect of this specially constructed bi-layer composite could be three folds, and the sensing mechanism may vary when physical properties of the CNT network embedded in the polymer matrix alter. The feasibility of the PDSM/CNT nanocomposite serving as an elastic electret was further explored. The nanocomposite composed of these two non-traditional electret materials exhibited electret characteristics with reasonable charge storage stability. The power generation capacity of the corona-charged nanocomposite has been characterized and successfully demonstrated in both a ball drop experiment and the cyclic mechanical load experiments. Lastly, in an effort to develop carbon-material-based substrates for MEMS applications, a carbon fiber-based poly-Si solar cell was designed, fabricated and investigated. This fiber-type photovoltaics (PV) takes advantage of the excellent thermal stability, electrical conductivity and spatial format of the CF, which allows CF to serve as both the building block and the electrode in the PV configuration. The photovoltaic effects of the fiber PV were demonstrated with an open-circuit voltage of 0.14 V, a short-circuit current density of 1.7 mA/cm2, and output power density of 0.059mW/cm2. The issues of this system were discussed as well.

A técnica de injeção de cargas por feixe eletrônico em materiais poliméricos pode ser utilizada como uma importante ferramenta no estudo das propriedades elétricas destes materiais. Fenômenos tais como a emissão eletrônica secundária, o transporte e armazenamento de portadores de carga no volume do material, fenômenos de injeção e condutividade induzida por radiação podem ser observados em películas finas de dielétricos lançando mão desta poderosa técnica. Neste trabalho, utilizamos um canhão de elétrons de energia variável (O a 10 keV) na irradiação de amostras de polianilinas, por nós sintetizadas, para o estudo da emissão secundária e de transporte no volume. Alguns experimentos foram também realizados com o poli(fluoreto de vinilideno), que é um polímero bem mais resistivo que as polianilinas. As medidas de emissão eletrônica foram feitas em circuito aberto, enquanto as medidas de transporte foram obtidas em circuito fechado. Neste segundo tipo de configuração, procuramos fazer uma análise do comportamento da corrente através da amostra pela observação de transientes rápidos (da ordem de 10 ms) de corrente gerados pela injeção de pacotes de carga de penetração bem definida a partir da superfície bombardeada. Propriedades elétricas intrínsecas como a condutividade do material e a permissividade elétrica, e extrínsecas como a condutividade na região irradiada foram utilizadas como parâmetros no ajuste dos resultados experimentais. / Charge injection in polymeric materials by electron beam is a powerful technique in the study of electrical properties of such materials. Secondary emission, transport and storage phenomena, as well as radiation-induced conductivity are among the subjects related to dielectrics that can be investigated. At present work we used an electron beam system (O to 10 keV) to irradiate polyaniline films, synthesized in our laboratory, and to perform studies of secondary emission and transport phenomena. Some experiments were also carried out with poly(viny1idene fluoride), a more resistivity polymer. Secondary emission measurements were carried out in an open-circuit configuration while the transport ones used a short circuit mode. Fast transient phenomena (about 10 ms) were also studied in details. Intrinsic electric properties, such as conductivity and dielectric constant, and extrinsic ones, like the induced conductivity in the irradiated region of the sample, were obtained in the fitting between the model and the experimental results.