Boltzmann's equation for binary chemical reactions has been solved by the modified moment method using the equivalent of the 13-moment approximations. It was found that the transport coefficients are nonlinear in the thermodynamic forces. This nonlinearity is at least quadratic. The rate coefficient also appears to be at least quadratic in fluxes. / The stability of the solutions of two coupled equations of change for the current under the influence of an electric field is examined. These equations are deduced from the structure of dissipative terms calculated in the modified moment method. Two steady state branches in current are found to bifurcate from the primary steady state branch as a critical field value E(,c) = 4.35 V/cm is crossed. The results are in good qualitative agreement with experiment. / The dynamical behaviour of the two coupled equations used above was also studied in order to establish the influence (if any) of the entropy production surface on the trajectory followed by the system. This aspect of the study proved to be difficult since the entropy production surface associated with the two equations used did not have sufficiently distinctive features. / In order to continue studies on the relationship between dynamical behaviour and the topography of the entropy production surface, the two basic equations used before were slightly modified, and new parameters were introduced. At the critical field value E(,c) = 1.48 V/cm, no secondary steady states bifurcated out of the unstable primary steady state as in the previous model. Rather, stable oscillations in current of more or less constant amplitude occurred. This may account for some of the current fluctuations observed in experiment. The entropy production surface associated with this pair of model equations consists of two intersecting locii of minima. It turns out that the trajectory follows these minimal regions for most of the orbit, crossing from one locus of minima to another either through the intersection near to the origin or by crossing a ridge of high entropy production. The average energy dissipated over this cycle turns out to be smaller than if the system had remained with the unstable steady state. / Out of the latter studies, the useful conjecture was made. Given the topography of the entropy production surface and the stability of the steady states, it is possible to qualitatively predict the dynamics of the system provided the entropy production surface has sufficiently distinctive features.

Cast Al-Si and Al-Si-Mg alloys containing up to 12.6 wt. pct. silicon and 1.0 wt. pct. magnesium were prepared. The changes in electrical conductivity/resistivity of these alloys due to strontium additions have been investigated and explained in terms of variations in microstructure. The conductivity behaviour of strontium-containing and strontium-free alloys was found to exhibit marked differences, depending on the silicon and magnesium contents and the rate of solidification. The electrical conductivity of single phase alloys containing less than 1.60 wt. pct. Si decreased with increasing silicon and magnesium levels. However, strontium had no effect on the conductivity of these solid solution alloys since it does not dissolve appreciably in the aluminum matrix or change the solid solubility of silicon and magnesium in aluminum. Silicon precipitation processes in the supersaturated solid solution alloys of Al-Si and Al-Si-Sr have been examined using the Johnson-Mehl-Avrami equation and found to be isokinetic. Strontium, however, retarded the growth rate of silicon precipitates. Strontium did not affect the kinetics of G.P. zone formation in Al-Si-Mg alloys but it suppressed the formation of stable Mg$ sb2$Si precipitates during subsequent aging at 175$ sp circ$C. Unlike the single phase alloys, two phase Al-Si and Al-Si-Sr alloys, in the range of 2.0 to 12.6 wt. pct. Si, exhibited different electrical conductivity behaviour. The strontium-containing alloys showed a higher conductivity than alloys with no strontium, and this conductivity difference increased as the silicon and magnesium contents were increased and the solidification rate was decreased. It has been demonstrated this difference is due to changes in the silicon morphology. Electron scattering at the interface between the aluminum matrix and the eutectic silicon phase contributes significantly more to the resistivity of unmodified alloys than that of modified alloys. In addition, the resistivity of

From measurements of thermal and electrical conductivities of 64 ocean sediment samples obtained from piston cores taken off the Oregon Coast, and from 37 water-saturated sandstone samples analyzed by Zierfuss and Van der Vliet (1956), as well as 51 thermal conductivities and water contents of ocean sediments analyzed by Ratcliffe (1960), this research shows that a useful relationship can be obtained giving thermal conductivity when electrical conductivity is known. Analysis of the data was made using theoretical concepts which have been known for many years to relate thermal and electrical conductivity to porosity. The results of this research may make possible a convenient determination of in situ thermal conductivity that would give the average conductivity in materials containing large variations in conductivity. / Graduation date: 1966

Electrical imaging of groundwater that interacts with surface watercourses provides detail on the extent of intervention needed to accurately manage both resources. It is particularly important where one resource is saline or otherwise polluted, where spatial quantification of the interacting resources is critical to water use planning and where losses from surface waterways need to be minimized in order to transport water long distances. Geo-electric arrays or transient electromagnetic devices can be towed along watercourses to image electrical conductivity (EC) at multiple depths within and beneath those watercourses. It has been found that in such environments, EC is typically related primarily to groundwater salinity and secondarily to clay content. Submerged geo-electric arrays can detect detailed canal-bottom variations if correctly designed. Floating arrays pass obstacles easily and are good for surveying constricted rivers and canals. Transient electromagnetic devices detect saline features clearly but have inferior ability to detect fine changes just below beds of watercourses. All require that water depth be measured by sonar or pressure sensors for successful elimination of effects of the water layer on the data. The meandering paths of rivers and canals, combined with the sheer volume of data typically acquired in waterborne surveys, results in a geo-referencing dilemma that cannot be accommodated using either 2D imaging or 3D voxel imaging. Because of this, software was developed by the author which allows users to view vertical section images wrapped along meandering paths in 3D space so that they resemble ribbons. Geo-electric arrays suitable for simultaneous imaging of both shallow and deep strata need exponentially spread receiver electrodes and elongated transmitter electrodes. In order to design and facilitate such arrays, signed monopole notation for arrays with iv segmented elongated electrodes was developed. The new notation greatly simplified generalized geo-electric array equations and led to processing efficiency. It was used in the development of new array design software and automated inversion software including a new technique for stable inversion of datasets including data with values below noise level. The Allen Exponential Bipole (AXB) array configuration was defined as a collinear arrangement of 2 elongated transmitter electrodes followed by receiver electrodes spaced exponentially from the end of the second transmitter electrode. A method for constructing such geo-electric arrays for use in rivers and canals was developed and the resulting equipment was refined during the creation of an extensive set of EC imaging case studies distributed across canals and rivers of the Australian Murray- Darling Basin. Man made and natural variations in aquifers connected to those canals and rivers have been clearly and precisely identified in more than 1000 kilometres of EC imagery.

Thesis (Ph.D.)--University of Wollongong, 2005. / Typescript. Includes bibliographical references.

Thesis (Ph. D.)--Ohio State University, 2008.

Thesis (M.S.)--University of Wisconsin--Madison, 1969. / eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

Thesis (Ph. D.)--Rutgers University, 2007. / "Graduate Program in Physics and Astronomy." Includes bibliographical references (p. 134-138).

Typescript. Includes vita and abstract. Includes bibliographical references (leaves 130-137). Abstract also available online in ProQuest, free to University of Oregon users.

Thesis (M. Sc.)--University of Alberta, 2010. / Title from pdf file main screen (viewed on July 15, 2010). A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirements for the degree of Master of Science in Materials Engineering, Department of Chemical and Materials Engineering, University of Alberta. Includes bibliographical references.