Thesis (Ph.D)--Mechanical Engineering, Georgia Institute of Technology, 2010. / Committee Chair: Samuel Graham; Committee Member: Bernard Kippelen; Committee Member: David McDowell; Committee Member: Sankar Nair; Committee Member: Suresh Sitaraman. Part of the SMARTech Electronic Thesis and Dissertation Collection.

Thesis (MScIng)--University of Stellenbosch, 2005. / Bibliography. Also available via the Internet.

Thesis (Ph. D.)--University of Canterbury, 2006. / Typescript (photocopy). "January 2006." Includes bibliographical references (p. [173]-182). Also available via the World Wide Web.

Thesis (MScEng)--University of Stellenbosch, 2005. / ENGLISH ABSTRACT: The calibration and field evaluation of an Insulator Pollution Monitoring Relay (IPMR) were the main aims of this research programme. A repeatable artificial wetting test method was developed after several modifications were made to the steam system, test chamber and the test routine. The IPMR was successfully calibrated with insulators that were artificially polluted according to the solid layer method. Linear and polynomial relationships were determined after curve-fitting techniques were performed on the results. The calibration showed that the IPMR is capable as a device relating the maximum conductivity during artificial wetting to the ESDD, a severity classification parameter. The IPMR was successfully used in a salt fog chamber to determine if the device is capable to evaluate the severity of an instantaneous pollution event. The IPMR was successfully installed at a natural pollution test site along the Cape west coast. The conductivity measurements with natural wetting showed good correlation to flashovers experienced. A rule of thumb, developed to indicate a possible risk of flashover, was based on observations made on the relationship between humidity and surface conductivity. The measured IPMR data was successfully applied to quantify the site severity according to the conductivity measurement with natural wetting. This calculated severity value could be used in the assessment of flashover probability of high voltage insulators. / AFRIKAANSE OPSOMMING: Die hoofdoel van die tesis was die kalibrasie en veldtoetse van 'n isolatorbesoedelingsmonitor (IPMR). 'n Herhaalbare nagebootste benatting-toetsmetode is ontwikkel na veranderings aan die stoomstelsel, toetsruimte en die toetsproses. Die IPMR is suksesvol gekalibreer met isolators wat besoedel was met 'n nagebootste besoedeling volgens die "solid layer method". Liniêre sowel as kwadratiese verwantskappe is ontwikkel na krommepassings op die resultate uitgevoer was. Die kalibrasie het gewys dat die IPMR in staat is om die maksimum geleidingsvermoë wat d.m.v. nagebootste benatting verkry is, met die ESDD, 'n besoedelingsklassifikasie, kan vergelyk. Die apparaat is ook suksesvol gebruik tydens soutmistoetse om te bepaal of dit in staat is om 'n skielike besoedelingsgebeurtenis te kan meet. Na die afhandeling van laboratorium werk is die apparaat by 'n natuurlike isolator besoedeling-toetsstasie langs die Kaapse weskus geïnstalleer. Die geleidingsvermoë metings met natuurlike benatting het goeie korrelasie getoon met isolator oorvonkings. 'n Skattingsmetode wat ontwikkel is om moontlike oorvonkings te voorspel, is gebaseer op waarnemings wat gemaak is van die humiditeit sowel as die oppervlakte geleidingsvermoë. Die IPMR se geleidingsvermoë metings met natuurlike benatting is aangewend om die besoedelingsgraad van die gebied te bepaal. Die bepaalde besoedelingsgraad kan verder gebruik word om die waarskynlikheid van die oorvonking van isolators vas te stel.

This thesis presents the study for the temperature-driven and current-driven metal-insulator phase transition (MIT) in Ca₂RuO₄ via home-built variable temperature Scanning Tunneling Microscope. Atomically resolved topography images along with temperature dependence of resistivity are taken verifying the quality of the single crystals used in this experiment. Tunneling spectra are measured under various temperatures across the Tmi = 357K, which clearly shows spectra evolution with temperature and the difference between the room- temperature insulator phase and the high-temprature metal phase. Compared with DMFT calculation, the STS indicates lattice structure plays a vital role in the phase transition. Same measurement is conducted on the crystals under a DC current, thanks to a custom designed sample holder. The evolution of the tunneling spectra with source current demon- strates similarity with the one of temperature-driven MIT. The comparison between the spectra taken at high-temperature metalic state and the high-current metalic state high- lights the similarity of these 2 phases, with both showing a DOS transfer from 1eV to lower energy, when compared with the ground state. Combined with a variety of other studies via transport, scattering technique and infrared thermal imaging, it is found that the local temperature dominates both temperature-driven and current-driven MIT. It is very likely that the current-driven is caused by the inevitable Joule heating generated by the current, indicating the high-current metallic phase might be the same with high-current metallic phase. Finally, surface roughness and autocorrelation length analysis suggests an inhomo- geneous surface topography stemmed from the coexistence of the insulating S* phase and conducting L* phase under current.

No description available.

A dissertation submitted to the Faculty of Engineering and the Built Environment, University of the Witwatersrand, in fulfilment of the requirements for the degree of Master of Science in Engineering Date submitted: 28 August 2015 / Many generator transformers were installed many years ago during the initial commissioning of Eskom’s power stations. Many of these transformers have started showing signs of significant ageing of the paper insulation and hence require regular monitoring. There are two methods that are currently being employed to assess the degree of ageing of the paper insulation in a generator transformer, which are paper sampling and furan level measurement. This dissertation investigates an alternative method of predicting the degree of ageing of the paper insulation instead of what is used currently. This method uses the Arrhenius equation that relates time and temperature to determine the degree of degradation of organic materials. The reliability of the Arrhenius estimation method is assessed by comparing the predicted DP (Degree of polymerisation) values with the measured DP values of the same transformer paper insulation. The results obtained showed that there is reasonable correlation between the DP values estimated from the Arrhenius equation and the DP values estimated from the measured furan levels. The accuracy of the prediction method is reduced when the oil temperature greatly differs from the paper insulation temperature. The application of the Arrhenius equation to estimate the ageing of paper insulation is a great milestone in the quest to predict the remaining life of a transformer. It is the only method available to do this prediction and using online temperature measurement on transformers makes the method more reliable. / MT 2017

Thesis (MScEng (Electrical and Electronic Engineering))--University of Stellenbosch, 2009. / ENGLISH ABSTRACT: From a systems operation and design perspective, it is important to understand the behaviour of HVDC system insulation when presented with high voltage transients, such as induced by lightning and switching operations. Therefore, this thesis investigates the design, operation and performance of a circuit arrangement that can be used in high voltage laboratories to generate impulse voltage waveforms superimposed on a dc bias voltage. The circuit arrangement consists of an impulse generator and a dc source that supplies continuous dc voltage to stress the test object, which can be any type of insulator, i.e. composite, porcelain, glass, gap arrangements, etc. The composite waveform obtained from the test arrangement is used experimentally to investigate the impulse flashover of insulators. For modelling and analysis purposes, the test circuit was transformed to a Laplace equivalent in order to derive the applicable nodal voltage equations. After substitution of circuit parameter values, the voltage equations are then transformed to time domain equations that predict the time-domain behaviour of the circuit. To validate this mathematical approach, the voltage waveforms obtained with this mathematical model is compared with the waveforms measured under laboratory conditions and also with waveforms simulated with HSPICE software. These comparisons are performed using graphical representations. Good correlation was obtained and the results are presented in this thesis. The final stage of this thesis discusses the application of the designed test arrangement for flashover and withstands tests on a silicon rubber insulator. The determination of the flashover values is done by using the existing statistical methods. The insulator was tested under dry conditions and also under polluted wet conditions for both positive and negative impulses compared to the DC bias voltage polarity. The results show that the dc bias voltage does not affect the total voltage flashover of the insulator significantly. It was also observed that wetting affects the flashover for negative impulse more severely, while the influence of wetting is minimal with positive impulse voltages / AFRIKAANSE OPSOMMING: Vanuit ‘n stelselbedryf en ontwerp perspektief, is dit is belangrik om die gedrag van HSGS stelsels te verstaan wanneer dit onderwerp word aan hoogspanning oorgangsverskynsels soos veroorsaak deur weerlig en skakeloperasies. Daarom ondersoek hierdie tesis die ontwerp, werking en werkverrigting van ‘n stroombaanopstelling wat gebruik kan word in hoogspanningslaboratoriums om impulsspannings gesuperponeer op gelykspanning voorspannings op te wek. Die stroombaan bestaan uit ’n impulsgenerator en ‘n gs-bron wat die langdurige gs-spanning voorsien aan die toetsvoorwerp, wat enige tipe isolator kan wees. bv. porselein, glas, gapings, ens. Die saamgestelde golfvorm wat met die toetsopstelling verkry word, is eksperimenteel gebruik om die impulsoorvonking van isolators te ondersoek. Vir die doel van modellering and analise, is die stroombaan na ‘n Laplace ekwivalent getransformeer om die toepaslike knooppunt spanningsvergelykings af te lei. Na substitusie van die stroombaan parameter waardes, word die spanningsvergelykings getransformeer na die tydgebied vergelykings wat die tydgebied gedrag van die stroombaan voorspel. Om die wiskundige benadering te toets, word die spanningsgolfvorms wat met die wiskundige model voorspel word, vergelyk met golfvorms wat onder laboratorium toestande gemeet is en ook met golfvorms wat met HSPICE programmatuur gesimuleer is. Hierdie vergelykings word gedoen met behulp van grafiese voorstellings. Goeie korrelasie is verkry en die resultate word in die tesis gegee. Die finale stadium van hierdie tesis bespreek die toepassing van die ontwerpte toetsopstelling vir oorvonk- en weerstaantoetse op ‘n silikonrubber isolator. Die bepaling van die oorvonkwaardes word gedoen deur bestaande statistiese metodes te gebruik. Die isolator is onder droë en nat besoedelde toestande gedoen, vir beide positiewe sowel as negatiewe impulse met verwysing na die GS voorspan spanning. Die resultate toon dat die gsvoorspanning nie die oorvonkspanning van die isolator beïnvloed nie. Dit is ook waargeneem dat die benatting die oorvonking neer beïnvloed met ‘n negatiewe impuls terwyl die invloed minimaal is met positiewe impulsspannings.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The worldwide increase in the popularity of high voltage direct current (HVDC) power transmission application has led to questions regarding the performance of high voltage alternating current (HVAC) insulators when energized under HVDC excitation. These questions have led researchers conduct numerous research projects worldwide. A particular question NamPower (the power utility in Namibia) has faced is: how do these insulators perform and age when energized under HVDC excitation in heavily polluted environments? This question was only partly answered by some insulator ageing tests conducted under laboratory conditions for HVDC excitation. However, the natural ageing tests on insulators, which are preferred, have to date been confined predominantly to HVAC excitation voltages. Thus, this research was initiated to investigate the natural ageing performance of insulators under both HVAC and HVDC excitations, when subjected to harsh marine pollution environments. This research project involved performance and ageing tests on three identical sets of line insulators made from different insulator materials, energised under HVAC and both polarities HVDC excitations respectively. The tests were conducted at Koeberg insulator pollution test station (KIPTS), which is a natural marine pollution insulator test station located near Cape Town, along the west coast of South Africa, approximately 50 m from the sea. The set of insulators consisted of EPDM silicone alloy rubber, HTV silicone rubber, RTV silicone rubber coated porcelain, Porcelain and Glass insulators. The HVAC excitation voltage was chosen as 12.7 kV r.m.s. phase-to-ground and it was decided to use a HVDC excitation voltage equal to this value. The research results showed that the insulators made from HTV silicone rubber performed better than the insulators made from EPDM silicone alloy rubber under all excitation voltages. It is also showed that RTV silicone rubber coated porcelain insulators performed better than Glass and Porcelain insulators under all excitation voltages. / AFRIKAANSE OPSOMMING: Die wêreld wye toename in gewildheid van hoë spanning gelyk stroom (HSGS) krag transmisie aplikasie het gelei na vrae oor die effektieweteit van hoë spanning wissel stroom (HSWS) insolators in HSGS aplikasies. Hierdie vrae het gelei na baie navorsings projekte. Een vraag waarmee NamPower (die krag voorsienings maatskapy in Namibia) gekonfronteer was, was hoe gaan die insolators wat onderworpe is aan ’n HSGS toevoer reageer in ’n baie besoedelde omgewing. Hierdie vraag was slegs gedeeltelik beantwoord deur verouderings toetse op insolators wat gedoen is in ’n labaratorium met ’n HSGS toevoer. Inteendeel, die meeste natuurlike verouderings toetse op insolators, soos verkies, is meestal gedoen met ’n HSWS toevoer. Om hierdie rede was hierdie navorsing begin om natuurlike verouderings toetse te doen op insolators onderworpe beide aan HSWS en HSGS toevoere binne ’n marien besoedelde omgewing. Hierdie navorsings projek gaan oor prestering en verouderings toetse op drie, identiese, transmissie lyn insolator stelle, wat onderskeidelik onderworpe was aan HSWS en beide polariteite HSGS toevoere. Die toetse was gedoen by Koeberg insolator besoedeling toets stasie (KIBTS) wat naby Kaapstad geleë is langs die weskus van Suid Africa omtrent 50 m van die see. ’n Stel toets insolators bestaan uit EPDM silikon allooi rubber, HTV silikon rubber, RTV silikon rubber bedekte porselein, Porselein en Glas insolators. Die HSWS waarde waarmee die insolators getoets was, was 12.7 kV w.g.k., fase-na-grond, en dit was besluit om ’n HSGS waarde gelyk aan hierdie spannings waarde te gebruik. Die navorsings resultate wys dat insolators wat gemaak is met HTV silikon rubber presteer beter as insolators wat met EPDM silikon allooi rubber gemaak is onder al die verskillende toevoere. Dit wys ook dat RTV silikon rubber bedekte porselein presteer beter as Porselein en Glas insolators onder al die verskillende toevoere.

Thesis (MSc)--Stellenbosch University, 2004. / ENGLISH ABSTRACT: Polydimethylsiloxane (PDMS) compounds are utilized in outdoor high voltage insulation due to their low weight, vandalism resistance, better anti-contamination performance and their superior hydrophobic nature. Under severe environmental conditions and over prolonged service time, however, the hydrophobic surface can gradually become hydrophilic and then recover with adequate resting period. In this study, room temperature vulcanized (RTV) PDMS samples were prepared with different formulations and then exposed to corona discharge to evaluate its effect. The influence of different additives, such as different types and amount of fillers and additionally added low molar mass silicone oils, on the hydrophobicity recovery of the material was investigated. The effects of two types of corona treatment were also evaluated. Hydrophobicity recovery of corona and UV-C aged PDMS samples was evaluated by means of static contact angle measurements. Positron annihilation spectroscopy (PAS) gave important information on the micro structural change after corona treatment of RTV PDMS as well as naturally aged high temperature vulcanized (HTV) PDMS samples. The different formulations of the RTV PDMS samples and the effect of the additives were studied with this technique. The formation of a thin, highly crosslinked inorganic silica-like (SiOx) layer was confirmed even at the early stage of degradation. It was also possible to estimate the thickness of the silica-like layer formed during corona exposure that is responsible for the loss and recovery of hydrophobicity. The surface hardness and hydrophilicity change of PDMS samples due to corona treatment were studied simultaneously with force distance measurements by atomic force microscopy (AFM). The adhesive force calculated from the pull-off force-distance curves showed that the adhesive force between the probe and the sample decreased with increasing corona treatment time, indicating hydrophobicity recovery. In addition to this, the increase in hardness after corona exposure provides indirect evidence of the formation of a silica-like layer. In all cases the hydrophilicity and the surface hardness of the PDMS samples increased directly after corona treatment and recovered with time. Two types of FTIR spectroscopy were used to analyse the surface of the polymer. / AFRIKAANSE OPSOMMINGS: Polidimetielsiloksaan (PDMS) word in buitelug hoogspanninginsulasie gebruik as gevolg van sy lae massa, weerstand teen vandalisme, verbeterde anti-kontaminasie werkverrigting en superieure hidrofobiese karakter. Die hidrofobiese oppervlakte kan egter gelydelik hidrofillies word onder uiterste omgewingsomstandighede en oor langdurige dienstyd. PDMS materiaal herstel egter nadat dit genoeg rustyd toegelaat is. Kamertemperatuur-gevulkaniseerde (KTV) PDMS met verskillende formulasies is in hierdie studie voorberei, aan korona ontlading blootgestel, geëvalueer en vergelyk. Die invloed van bymiddels soos verskillende tipes en hoeveelhede vuiler, asook addisionele lae molekulêre massa silikoonolie, op die herstel van hidrofobisiteit van die materiaal is ondersoek. Twee verskillende metodes van korona behandeling is ook geëvalueer. Die herstel van hidrofobisiteit van korona en UV-C verouderde PDMS monsters is met statiese kontakhoekmeting geëvalueer. Positronvernietigingspektroskopie (PVS) is 'n kragtige tegniek wat belangrike inligting oor die mikrostrukturele verandering van korona behandelde van KTV PDMS sowel as natuurlik-verouderde hoë temperatuur gevulkaniseerde (HTV) PDMS monsters gee. Die verskillende formulasies van die KTV PDMS monsters, sowel as die effek van die vullers, is met behulp van hierdie tegniek ondersoek. Die vorming van 'n dun, hoogskruisgebinde, anorganiese silika-agtige (SiOx) laag op die PDMS oppervlak, selfs tydens die vroeë stadium van degradasie, is bevestig. Dit was ook moontlik om die dikte van die silika-agtige laag wat gedurende die korona blootstelling gevorm het, en wat verantwoordelik is vir die verlies aan hidrofobisiteit, te bepaal. Die oppervlakhardheid en hidrofilisiteit verandering van PDMS monsters as gevolg van korona behandeling, was gelyktydig met krag-afstand metings deur middel van atoomkragmikroskopie (AKM) bestudeer. Die kleefkrag, soos bereken van aftrek kragafstandkurwes, dui daarop dat kleefkragte tussen die taster en die monster afneem met toenemende korona behandelingstyd, wat beduidend is op die herstel van hidrofobisiteit. Daarbenewens is die toename van oppervlakhardheid na korona blootstelling "n indirekte bewys van die formasie van 'n silika-agtige laag. In alle gevalle het die hidrofilisiteit en die oppervlakhardheid van die PDMS monsters toegeneem direk na afloop van korona behandeling en gevolglik herstel met tyd. Twee tipes IR spektroskopie metodes is gebruik vir die chemiese-oppervlak analises