京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第19474号 / 理博第4134号 / 新制||理||1595(附属図書館) / 32510 / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)准教授 荒木 武昭, 教授 佐々 真一, 教授 山本 潤 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

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Thesis (Ph. D.)--University of Oregon, 2008. / Typescript. Includes vita and abstract. Includes bibliographical references (leaves 122-127). Also available online in Scholars' Bank; and in ProQuest, free to University of Oregon users.

Thesis (M.S.)--Rochester Institute of Technology, 2009. / Typescript. Includes bibliographical references (leaves 90-92).

Title from PDF of title page (University of Missouri--Columbia, viewed on Feb 11, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dissertation advisor: Dr. Sheryl A. Tucker Vita. Includes bibliographical references.

Thesis (M.S.)--Brigham Young University. Dept. of Chemistry and Biochemistry, 2007. / Includes bibliographical references.

Thesis (MScIng)--University of Stellenbosch, 2004. / ENGLISH ABSTRACT: The moisture content of road foundations plays an important role in the durability of the pavement and the driving comfort of the road. After a pavement has been completed, gradual moisture changes occur in the foundations until equilibrium conditions can be reached, and this can have negative results if expansive clays, for example, are present in the foundation. Pre-wetting of the foundation material is seen as a method to minimilize moisture changes after construction, but if the pavement was already completed, it would be very difficult to change or alter the moisture content in the foundation, because water could then only be applied to the shoulder areas of the road and horizontal infiltration in the soil is exceptionally slow. The research which is reported in this account was undertaken to determine whether the process of electro-osmosis could be applied to accelerate water infiltration underneath covered areas, as in, for example, road foundation layers. Electro-osmosis, if found to be successful, has various advantages, of which the most important is that it can be applied without stopping the normal operations of the road. This research was carried out on a mixture of G5 material (TRH14 classification) and fine material in the form of clay with a low plasticity. Firstly, tests were performed to determine the percentage of fines required. It was found that, if too little fines were present infiltration did not occur, because moisture could flow freely through the openings between the rough aggregate. Electro-osmosis also had no effect on the rate of flow. The allocated amount of fines required to fill sufficient openings was about 30% (TRH14 classification of mixture is G10). Free flow was stopped and true infiltration occurred. Simultaneously, the rate of infiltration could be accelerated with electro-osmosis. Furthermore, a two-dimensional model of a road was constructed with electrodes placed on both sides, with the aim to determine the infiltration pattern controlled by electro-osmosis and what the effect of the initial moisture content would be on the process. Water was introduced to the one side of the model road and the wetting of the foundation was investigated. If the electric current for electro-osmosis was switched off, the infiltration was mainly vertical, as expected, but with the current switched on, there was an obvious acceleration of infiltration in the horizontal direction. As in the case of the initial tests, it was found that electro-osmosis was not very successful to accelerate horizontal infiltration at low percentages of fines. Furthermore, it was obvious that electroosmosis was also more effective if the initial moisture content of the soil was low. Low amounts of fines and high initial moisture contents had rather the electroosmotic flow of water passing underneath the road as a result instead of infiltration acceleration, with the result that the moisture content did not change much. The research thus showed that electro-osmosis is a possible manner in which moisture could be conducted into the foundation layers of roads to increase the moisture content if the appropriate amount of fines and moisture content were present in the foundation material. Further research could still be carried out and the materials in each case should be practically evaluated before this method could be continued with. / AFRIKAANSE OPSOMMING: Die voginhoud van padfondamente speel ’n belangrike rol in die duursaamheid van die plaveisel en die rygerief van die pad. Nadat ’n plaveisel voltooi is, vind daar geleidelike vogverandering in die fondamente plaas totdat ewewigstoestande bereik is, en dit kan nadelige gevolge inhou indien uitsettende kleie byvoorbeeld in die fundament teenwoordig is. Voorafbenatting van die fondamentmateriaal word gereken as ’n metode om vogveranderinge na konstruksie te minimeer, maar indien die plaveisel reeds voltooi is, is dit baie moeilik om die voginhoud in die fondament te verander of beheer omdat water dan slegs buite die skouerareas van die pad toegedien kan word en horisontale infiltrasie in grond uiters stadig is. Die navorsing waaroor hierin verslag gedoen word, is onderneem om te bepaal of die proses van elektro-osmose aangewend kan word om waterinfiltrasie onder bedekte areas, soos byvoorbeeld padfondamentlae, te versnel. Elektro-osmose, indien dit suksesvol blyk te wees, hou verskeie voordele in, waarvan die belangrikste dat dit aangewend kan word sonder om die normale bedryf van die pad te staak. Die ondersoek is uitgevoer op ’n mengsel van G5 materiaal (TRH14 klassifikasie) en fynstof in die vorm van klei met ’n lae plastisiteit. Eerstens is toetse uitgevoer om die persentasie fynstof wat nodig is, te bepaal. Daar is bevind dat, indien te min fynstof teenwoordig is, infiltrasie nie plaasvind nie aangesien water vryelik deur die openinge tussen die growwe aggregaat kan vloei. Elektro-osmose het ook geen effek op die vloeitempo gehad nie. Die aangewese hoeveelheid fynstof om genoegsame openinge te vul was ongeveer 30% (TRH14 klassifikasie van mengsel is G10). Vrye vloei is dan gestuit en ware infiltrasie het plaasgevind. Terselfdertyd kon die tempo van infiltrasie versnel word met elektro-osmose. Voorts is ’n twee-dimensionele model van ’n pad gebou, met elektrodes aan weerskante geplaas, met die doel om te bepaal of die infiltrasiepatroon deur elektro-osmose beheer kon word en wat die effek van beginvoginhoud op die proses sal wees. Water is aan een kant van die modelpad ingevoer en die benatting van die fondament bestudeer. Indien die elektriese stroom vir elektroosmose afgeskakel was, was die infiltrasie hoofsaaklik vertikaal, soos verwag, maar met die stroom aangeskakel was daar duidelike versnelling van infiltrasie in die horisontale rigting. Net soos in die geval van die aanvanklike toetse is bevind dat elektro-osmose nie baie suksesvol was om horisontale infiltrasie te versnel by lae persentasies fynstof nie. Dit het verder geblyk dat elektro-osmose ook meer effektief was indien die aanvanklike voginhoud van die grond laag was. Lae hoeveelhede fynstof en hoë aanvanklike voginhoude het eerder elektroosmotiese deurvloei van water onderdeur die pad tot gevolg gehad as infiltrasieversnelling, met die gevolg dat die voginhoud nie veel verander het nie. Die navorsing het dus getoon dat elektro-osmose ’n moontlike wyse is waarop water in die fondamentlae van paaie ingevoer kan word om die voginhoud te verhoog indien die geskikte hoeveelheid fynstof en voginhoud in die fondamentmateriaal teenwoordig is. Verdere navorsing kan nog uitgevoer word en die materiale van elke geval sal prakties evalueer moet word voordat met die metode voortgegaan kan word.

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The flow profiles of pressure-driven and electro-kinetic driven flows were compared for a microfluidic chip. It was found that the pressure-driven flow had a parabolic profile while the electro-kinetic flow had a plug shaped flow profile. The measured velocities were similar to those determined by the Poiseuille flow model and the Helmholtz-Smoltchowski equation. Flow uniformity is very important for control in microfluidic mixers. Parabolic flow profiles lead to inconsistent reactions while the more uniform plug shape flow allow for a more steady reaction across the channel. Previous work had been performed to measure the flow of a solution of fluorescent polystyrene beads in PDMS channels using a laser confocal microscope. This showed that particles easily stuck to the channel making it difficult to measure over time. In addition, bubble formation in the channel made measuring velocities difficult. Current work used a LabSmith Video Synchronized microscope with software to measure the flow rates at different areas of the channel. Solutions of fluorescent polystyrene beads were used to visually observe the flow within a channel under a microscope. Four different channels were used for the pressure-driven flows of varying dimensions and materials. The channel with the best measured profile was also measured under electro-kinetic flow. A LabSmith High Voltage Sequencer was used to apply a voltage across the channel for electro-kinetic measurements. This research confirmed the different flow profiles under pressure-driven and electro-kinetic driven flow. Future work can be done to determine how this effects mixing in the channels.

Cette thèse de doctorat présente une étude expérimentale des propriétés rhéologiques d’électrolytes confinés et de la mécanique des doubles couches électrostatiques.Afin d’étudier simultanément les propriétés d’équilibre et de transport d’électrolytes confinés proches de parois électriquement chargées, nous avons développé un appareil à forces de surfaces dynamique. Cette technique combine à la fois des mesures à l’équilibre, à l’instar des appareils à forces de surfaces classiques, et des mesures dynamiques permettant de caractériser les phénomènes de transport.Nous avons tout d’abord étudié le cas d’électrolytes très dilués. Nous avons montré l’existence d’une sur-dissipation induite par les ions issus des électrolytes par rapport à un comportement newtonien classique. De plus, nous avons mis en évidence un comportement élastique des doubles couches électrostatiques dépendant de la fréquence. Une approche théorique vient compléter et expliquer en partie les résultats expérimentaux.Enfin nous nous sommes intéressés à la dynamique d’électrolytes concentrés : les liquides ioniques. Nous avons étudié l’influence, sur la viscosité et les propriétés du liquide à l’interface solide-liquide, d’un champ électrique intense appliqué perpendiculairement à l’écoulement, comme rencontré dans les super-condensateurs. / This thesis presents an experimental study of rheological properties of confined electrolytes and mechanics of electric double layer.In order to study simultaneously equilibrium and transport of confined electrolytes nearby charged surfaces, we developed a dynamic surface force apparatus. This technique enables both steady state measurements, as provided by common surface forces apparatus, and dynamic measurements that allow characterizing the transport phenomenona.First, we showed the existence of an over-dissipative behavior of weak electrolytes compared to a classical newtonian fluid. Furthermore we highlighted a frequency dependence of the EDL elastic behavior. Alongside, a theoretical approach completes and explains partially the experimental observations.Finally we studied the dynamics of ionic liquid, a type of concentrated electrolytes. We looked at the influence of a huge electric field, applied perpendicularly to the surfaces, on the viscosity and the properties of the liquid nearby the surfaces, as found in super-capacitors.