<p> The use of gamma radiation to initiate the iodination of methane in liquid phase was studied using a semi-batch technique whereby the methane was bubbling through a column of iodine solution in a reactor. Yields of CH3I and CH2I2 lower than 10% and G < 500 were obtained as contrasted with the 60% yield and G=7xl0^7 reported in the gas-phase reaction. In view of the propensity of the iodine as a radical scavenger and the endothermic nature of the reaction, various attempts to improve the low yields were carried out. Results are eiven that indicate the chances of achieving a laree G value for liquid-phase reaction are very low even if the operating conditions are optimized. </p> / Thesis / Master of Engineering (MEngr)

Energy storage within hypersonic aircraft is becoming increasingly important with the development of more sophisticated electronic components and is an integral piece of expanding their overall capabilities. Hypersonics not only produce large external thermal loads, but also an abundance of internal thermal loads from components such as power electronics, avionics, and batteries. Additionally, limited volume within such vehicles introduces additional constraints. Thus, having efficient heat sinks that are capable of storing much of these heat loads is imperative. Passive thermal management systems, i.e., heat sinks, are preferable in most applications because they do not require power input to operate, and they are typically smaller than active systems such as coolant loops. In identifying and developing heat sinks with increased energy storage capability, an exhaustive search of available phase change materials (PCMs) is conducted. PCMs have been used in hypersonic vehicles in the past as a means of energy storage. Additionally, the use of energy-consuming endothermic reactions is considered. An innovative PCM-endothermic reaction hybrid approach is also developed. Both thermodynamic and transient/quasi-stationary models are developed for each of these proposed heat sink technologies. Prototypes are then developed for the best candidates to validate the models and draw conclusions on each heat sink's performance. Both the thermodynamic modeling and experimental results presented in this paper suggest that PCMs, endothermic reactions, and, especially, the hybrid system show greater energy storage capabilities than what is being used in hypersonic vehicles currently. / Master of Science / Hypersonic vehicles are an important topic of interest in the aerospace and defense industries. To be classified as hypersonic, a vehicle must travel at or above Mach 5, which is at least five times the speed of sound. Hypersonic vehicles often travel at high altitudes and a common application of the technology is in missiles. One major hurdle in developing hypersonic technologies at lower altitudes is that because of the high speeds, the outside skin temperature of the vehicle can reach thousands of degrees. Clearly, these temperatures can affect the heat load on the inside of the vehicle as can the thermal energy release of internal components such as the power electronics, the avionics, etc. To deal with these internal heat loads, innovative energy storage solutions are needed to efficiently and effectively store the thermal energy released internally. One approach considered here is the use of phase change materials (PCMs) as a storage medium. Melting such a material requires large amounts of energy and occurs at constant temperature. This is much more advantageous than heating a material in which only the temperature rises. Another approach considered in this thesis is that of using a chemical reaction, which requires energy input to proceed. Such a reaction is called an endothermic reaction and often results in a temperature decrease. Thus, simply mixing a set of reactants and adding energy helps cool the system. A final approach considered is a hybrid one, which combines a PCM material and an endothermic reaction. Such an approach combines the advantages of both. Each of these approaches are modeled thermodynamically to better understand how devices based on them work. Physical prototypes are then designed, built, and tested to confirm their performance. Both the modeling and experimental results presented in this thesis suggest that these devices show significantly improved energy storage capabilities over the devices currently used in hypersonic vehicles.