Artificial photosynthesis, for the purpose of converting solar energy into fuel, is one of the most viable and promising alternative approaches to solve the current global energy and environmental issues. Among the challenges faced in artificial photosynthesis is in building photosystems that can effectively and efficiently perform light absorption and charge separation in broad-band capturing donor-acceptor systems. While having a broad-band capturing antenna system that can harness incoming photons is crucial, another equally important task is to successfully couple the antenna system, while maintaining its optical properties, to an energy or electron acceptor which serves as the reaction center for the generation of charged species of useful potential energy. The stored potential energy will be utilized in different applications such as driving electrons in solar cells or in splitting water for the generation of fuel. Hence, the particular endeavor of this thesis is to study and synthesize molecular/supramolecular systems with wide-band capturing capabilities to generate long-lived charge separated states. The sensitizer used in building these systems in the present study is 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene, for short, BF2 chelated Azaboron dipyrromenthene or AzaBODIPY. A handful of novel donor-acceptor systems based on AzaBODIPY have been successfully designed, synthesized and their photochemistry have been investigated using various techniques. In these systems, Azabodipy has been covalently attached to several donors like porphyrin, bodipy, subphthalocyanine, phenothiazine, ferrocene, bithiophene and effectively coupled to an electron acceptor, C60. These systems have been fully characterized by NMR, Mass, optical absorption and emission, X-ray crystallographic, computational, electrochemical, and photochemical studies. It has been possible to demonstrate occurrence of efficient electron and energy transfer events and long-lived charge separated states upon photoexcitation in these model compounds. By changing the arrangements of the donor and acceptor entities, it has also been possible to show directional, through-space and through-bond electron transfer processes. The present study brings out the importance of utilizing near-IR sensitizers in building solar energy harvesting model systems.

A conversão de vibração em energia elétrica tem sido investigada por diversos grupos de pesquisa na última década. A principal motivação é a prospecção de fontes alternativas de energia elétrica para sistemas eletroeletrônicos remotamente operados e com fontes limitadas de energia. Diferentes mecanismos de transdução são investigados na literatura para a coleta de energia, entretanto, o piezelétrico tem se destacado devido à densidade de energia que proporciona e também facilidade de uso. Uma alternativa promissora que começa a ser estudada por alguns grupos de pesquisas é a conversão de energia de oscilações aeroelásticas em energia elétrica. Apesar da natureza destrutiva da maioria dos fenômenos aeroelásticos, eles apresentam um grande potencial para o estudo de novos mecanismos e sistemas para coleta de energia. A conversão piezelétrica de energia a partir de oscilações aeroelásticas lineares tem sido investigada. Entretanto, a geração piezoaeroelástica de energia pode se tornar mais atrativa e prática se realizada a partir sistemas aeroelásticos não lineares. A conversão se daria a partir de oscilações persistentes e com amplitude limitada (oscilações em ciclo limite – LCO) ocorrendo em um amplo intervalo de velocidades de escoamento. Define-se o objetivo deste projeto como a investigação numérica da conversão piezelétrica de energia a partir de oscilações aeroelásticas não lineares. Um modelo por elementos finitos para placa plana com piezocerâmicas é desenvolvido, respeitando-se as hipóteses de uma placa de von Kàrmàn. O carregamento aerodinâmico não estacionário é determinado a partir do método de malha de dipolos e uma aproximação do domínio do tempo obtida a partir da formulação apresentada por Roger. Os resultados eletroaeroelásticos são apresentados para asas com diferentes razões de aspecto investigadas em uma ampla faixa de velocidades e considerando-se diversos valores de resistores no domínio elétrico. / The converting of vibration into usable electrical energy has been investigated by several researches groups in the last decade. The main motivation is the possibility of obtaining alternatives electrical energy sources to power electronic system remotely operated and with limited energy sources. Different transduction mechanism has been presented in the energy harvesting literature. However the piezoelectric has been gained more attention because not only of its power density but also its ease of use. A promissory alternative that is becoming studied is the converting of aeroelastic oscillation into electrical energy. Despite of the destructive nature of unstable aeroelastic phenomena (such as, flutter), they present a great potential to the study of innovative mechanism to harvest energy. Although the piezoelectric energy conversion using linear aeroelastic has been investigated in the literature, the use of non linear aeroelastic system can be more practical and attractive. The non linear aeorelastic harvesting occurs by persistent oscillation and with limited amplitudes (Limited Cycle Oscillation – LCO) and can be performed by considerable velocity interval greater than the linear flutter speed. The objective of this work is to investigate the energy harvesting by non linear aeroelastic oscillation. A finite element model of a thin plate (with piezoceramics) is developed), using the non linear hypothesis of von Karman. The unstable aerodynamic loading is obtained by a doublet-lattice method (DLM) and with its time domain conversion using the Roger approximation. The eletroaeroelastic results are presented for several wings with different aspect ratios, and with different resistance values in the electrical domain. The eletroaeroelastic results of the generator wing are investigated for several airspeed greater than its linear flutter speed.

Made available in DSpace on 2017-07-10T17:11:52Z (GMT). No. of bitstreams: 1 dissert Final Marcel Araujo.pdf: 10392408 bytes, checksum: 3344b21a2f98d64347dd0aea895a4444 (MD5) Previous issue date: 2013-03-01 / The use of piezoelectric devices to harvest vibration energy has found applications in several areas, especially in structural health monitoring, either to recharge batteries or to directly feed sensors and also electronic devices. In general, the practical use of the energy converted by these devices requires, first, converting the alternating current (AC) produced to direct current (DC). This is normally done by using rectifier circuits. However, modeling the harvesting system, usually a PZT sensor bonded on a cantilever micro-beam and coupled to a rectifier circuit, using the same software package is pointed out by some authors as a drawback to overcome, due to its multidisciplinary requirements, involving topics of both mechanical and electrical engineering. In this sense, the main goal of this dissertation is to describe a comprehensive and simple modeling strategy, which considers a single computational platform and, simultaneously, account for both the electromechanical model of a clamped piezoelectric beam and the practical energy harvesting circuit, seeking ways to facilitate the analysis and design of energy harvesting systems. Numerical simulations and experimental tests are performed to illustrate the proposed approach, considering a full-wave diode bridge as the non-controlled rectifier circuit and a resistive load, which are directly connected to the cantilevered piezoelectric beam. Additionally, experimental tests carried out with a commercial harvesting system are presented, aiming to characterize and compare its performance with a full-wave diode bridge and a resistive circuit, both developed by the author. A single degree of freedom model of this system is also presented. The results showed that the model is suitable to perform simulations of systemshaving the characteristics described in this dissertation and confirmed the need of using active circuits to better use the produced energy. / A utilização de dispositivos piezelétricos para reaproveitamento de energia vibratória tem en- contrado aplicações em várias áreas, sobretudo em monitoramento de integridade estrutural, seja para recarregar baterias ou alimentar diretamente sensores e outros dispositivos eletrôni- cos. Em geral, o uso prático da energia convertida por estes transdutores requer, primeiramente, a transformação da corrente alternada (CA) produzida em corrente contínua (CC). Isto é fre- quentemente obtido por meio da utilização de circuitos retificadores. Entretanto, utilizar o mesmo pacote de software para modelar sistemas de energy harvesting, geralmente compostos por um sensor piezelétrico acoplado em uma microviga e conectados a um circuito retificador, é apontado por alguns autores como um grande desafio a ser superado, pois necessita de requisi- tos multidisciplinares que incluem tópicos de engenharia elétrica e mecânica. Neste sentido, o principal objetivo deste trabalho é apresentar uma estratégia de modelagem simples, que utilize apenas uma plataforma computacional e considere, simultaneamente, os modelos de uma viga piezelétrica e um circuito prático de extração/armazenamento de energia, buscando meios de facilitar a análise e o projeto de sistemas de energy harvesting. Simulações numéricas e testes experimentais são realizados para ilustrar a abordagem proposta, considerando um circuito retificador de onda completa e uma carga resistiva conectados diretamente a uma viga piezelétrica sob condição engastada-livre. Além disso, são apresentados testes experimentais realizados com um sistema comercial de energy harvesting visando caracterizar e comparar seu desempenho frente aos circuitos retificadores de onda completa e resistivo, ambos confeccionados pelo autor. Um modelo de um grau de liberdade deste sistema também é apresentado. Os resultados mostraram que o modelo é adequado para realizar simulações de sistemas que possuam as características descritas neste trabalho e comprovaram a necessidade de se utilizar um circuito ativo para se ter um melhor reaproveitamento da energia gerada.

A conversão de vibração em energia elétrica tem sido investigada por diversos grupos de pesquisa na última década. A principal motivação é a prospecção de fontes alternativas de energia elétrica para sistemas eletroeletrônicos remotamente operados e com fontes limitadas de energia. Diferentes mecanismos de transdução são investigados na literatura para a coleta de energia, entretanto, o piezelétrico tem se destacado devido à densidade de energia que proporciona e também facilidade de uso. Uma alternativa promissora que começa a ser estudada por alguns grupos de pesquisas é a conversão de energia de oscilações aeroelásticas em energia elétrica. Apesar da natureza destrutiva da maioria dos fenômenos aeroelásticos, eles apresentam um grande potencial para o estudo de novos mecanismos e sistemas para coleta de energia. A conversão piezelétrica de energia a partir de oscilações aeroelásticas lineares tem sido investigada. Entretanto, a geração piezoaeroelástica de energia pode se tornar mais atrativa e prática se realizada a partir sistemas aeroelásticos não lineares. A conversão se daria a partir de oscilações persistentes e com amplitude limitada (oscilações em ciclo limite – LCO) ocorrendo em um amplo intervalo de velocidades de escoamento. Define-se o objetivo deste projeto como a investigação numérica da conversão piezelétrica de energia a partir de oscilações aeroelásticas não lineares. Um modelo por elementos finitos para placa plana com piezocerâmicas é desenvolvido, respeitando-se as hipóteses de uma placa de von Kàrmàn. O carregamento aerodinâmico não estacionário é determinado a partir do método de malha de dipolos e uma aproximação do domínio do tempo obtida a partir da formulação apresentada por Roger. Os resultados eletroaeroelásticos são apresentados para asas com diferentes razões de aspecto investigadas em uma ampla faixa de velocidades e considerando-se diversos valores de resistores no domínio elétrico. / The converting of vibration into usable electrical energy has been investigated by several researches groups in the last decade. The main motivation is the possibility of obtaining alternatives electrical energy sources to power electronic system remotely operated and with limited energy sources. Different transduction mechanism has been presented in the energy harvesting literature. However the piezoelectric has been gained more attention because not only of its power density but also its ease of use. A promissory alternative that is becoming studied is the converting of aeroelastic oscillation into electrical energy. Despite of the destructive nature of unstable aeroelastic phenomena (such as, flutter), they present a great potential to the study of innovative mechanism to harvest energy. Although the piezoelectric energy conversion using linear aeroelastic has been investigated in the literature, the use of non linear aeroelastic system can be more practical and attractive. The non linear aeorelastic harvesting occurs by persistent oscillation and with limited amplitudes (Limited Cycle Oscillation – LCO) and can be performed by considerable velocity interval greater than the linear flutter speed. The objective of this work is to investigate the energy harvesting by non linear aeroelastic oscillation. A finite element model of a thin plate (with piezoceramics) is developed), using the non linear hypothesis of von Karman. The unstable aerodynamic loading is obtained by a doublet-lattice method (DLM) and with its time domain conversion using the Roger approximation. The eletroaeroelastic results are presented for several wings with different aspect ratios, and with different resistance values in the electrical domain. The eletroaeroelastic results of the generator wing are investigated for several airspeed greater than its linear flutter speed.

Die wechselhafte Energiebereitstellung für drahtlose Sensorknoten durch Solarzellen stellt das Energiemanagement dieser Systeme vor große Herausforderungen. Bedingt durch saisonale und kurzfristige Effekte treten kontinuierlich Schwankungen in der Eingangsleistung auf, gleichzeitig soll jedoch eine zuverlässige und konstante Systemfunktion realisiert werden. Um dies miteinander zu vereinbaren, wird ein Modell zur Beschreibung der erwarteten Eingangsleistung aufgestellt, mit welchem der planmäßige Energieverlauf bestimmt werden kann. Dieser kann wiederum mit der realen Eingangsleistung verglichen werden, um den tatsächlichen energetischen Zustand des Sensorknotens zu bestimmen. Daraus lassen sich beispielsweise Entscheidungskriterien für die Steuerung der Energieverteilung oder Betriebszustände ableiten. Im Rahmen der Arbeit werden die physikalischen Hintergründe zur Modellierung der eingehenden Sonnenenergie beschrieben, der Stand der Technik zur Modellierung aufgezeigt und ein Modell als Basis für die weiteren Untersuchungen ausgewählt. Dieses wird auf die stark limitierte Hardware von drahtlosen Sensorknoten angepasst. Die Herausforderungen liegen dabei hauptsächlich in der geringen verfügbaren Rechenleistung, wenig Datenspeicher im System und dem Ziel, möglichst wenig Energie für die Berechnung zu verbrauchen. Im Ergebnis zeigt sich, dass ein angepasstes Modell auf drahtlosen Sensorsystemen umgesetzt werden kann und trotz der starken Limitierungen lauffähig ist. Es wird eine deutliche Verbesserung in der Verteilung der Energie über den Tag ermöglicht, wodurch sich trotz wechselhafter Quelle eine konstante Systemfunktion ergibt. Nebenher wird die Zuverlässigkeit und Ausfallsicherheit erhöht und Überdimensionierungen in Energiespeicher und Solarzelle können verringert werden. Das modellbasierte Energiemanagement stellt somit einen wichtigen Baustein für eine gesicherte Energieversorgung drahtloser Sensorsysteme dar. / The volatile energy supply by solar cells for wireless sensor nodes causes vast challenges for the energy management of such systems. Conditioned by seasonal and short time effects, the incoming power continuously varies. Simultaneously a reliable and constant function of the system has to be realized. To reconcile this, a model for the expected incoming solar power has been derived, which enables the estimation of the planned energy curve. This curve can be compared with the real progression of incoming power measured in parallel, to determine the current state of energy of a sensor node. This comparison is used to derive decision criteria for the control of the energy distribution or operating conditions. Within this work, the physical backgrounds for the modelling of the incoming solar energy and the state of the art of modelling solar power are described. A model is chosen as basis for further investigations and adapted to the limited hardware of wireless sensor nodes. The main challenges are the reduced processing power, few data memory in the system and the objective to consume as few energy as possible for the calculation. The results show that an adapted model can be implemented on wireless sensor systems and that it is executable despite the heavy limitations. This enables a distinct improvement of the distribution of energy across the day, which results in a constant systems function, despite the varying incoming power. At the same time the reliability and failure safety are being improved and the oversizing of the solar cell and the storage elements can be reduced. Therefore the model based energy management is an important component for a stable power supply of wireless sensor systems.

Improvements in embedded electronics which have effectively reduced power consumption requirements as well as advancements in IC technology allowing utilization of low power inputs have made Energy Harvesting a popular power solution for low power applications such as WSNs. In many implementation areas, we can see solar, thermal, and vibration energy harvesting techniques have taken the role of batteries as power source. Now that Energy Harvesting is a popular and considerably mature technology, with proper design and installation, any object exposing energy has the ability to be promoted as a power source. We are currently living in Internet age where we connect to the world through network packets. Ethernet, by far, is the most popular LAN technology which allows us to plug and play. Therefore, on an Ethernet link, billions of packets where our data are encapsulated in are traversing every hour. We assume each of these packets exposes some level of energy on an Ethernet link. The challenge here is harvesting the energy available from Ethernet packets and transforming it into useful energy so that it can be used to power devices such as WSNs. In this thesis work, we have revealed how much energy is available from Ethernet packets, and how much of it can be made usable. We have also designed a system where a WSN is generating all of its operating power solely from Ethernet packets and consuming this energy in communication with a base station.

The growing need and desire for the harvesting of energy from everyday mechanical interactions impose a challenge on the current design of such systems. Often their nature indicates slow response times and unsteady AC voltages. The objective of this work is to present a new method of designing and controlling an oscillating energy harvesting system using a cutting-edge algorithm for fast determination of the optimal operating condition. In this thesis, an energy harvesting backpack, which captures energy from the interaction between the user and the spring decoupled load, is being introduced. The new control strategy, Maximum Energy Harvesting Control (MEHC), is developed and applied to the aforementioned system to evaluate its improvement over the basic Maximum Power Point Tracking (MPPT) algorithm. MEHC algorithm can also be used in many different applications, ranging from ocean wave to sports shoes energy harvesting.

Dans les dernières années, l'utilisation intensive des combustibles fossiles a déclenché une crise mondiale due à la forte production de polluants et à la réduction des stocks, en raison de sa nature de source d'énergie non renouvelable. Parce que l'utilisation généralisée des combustibles fossiles a entraîné la production de grandes quantités de CO2, ce qui est un facteur aggravant du réchauffement de la planète. Les piles à combustible microbiennes (MFC) représentent une technique de récupération d'énergie qui convertit l'énergie chimique des composés organiques en énergie électrique par le biais de réactions catalytiques de micro-organismes. La MFC peut être considérée comme un archétypique de système microbien bioélectrochimique (BES), qui exploite l’activité bio-électrocatalytique de micro-organismes vivants pour la génération de courant électrique. Durant la dernière décennie, l’évolution de l’électronique de faible consommation a rendu la technologie des MFC plus attrayante, car elle commence à pouvoir fournir une énergie comparable à celle consommée par des périphériques dit à faible consommation, comme un nœud de réseau de capteurs sans fil (WSN). En plus, les MFC ont gagné en intérêt car elles peuvent générer de l'énergie électrique tout en traitant des déchets. Contrairement aux autres piles à combustible, les MFC peuvent générer en permanence une énergie propre à une température ambiante, à la pression atmosphérique et à un pH neutre, sans entretien supplémentaire. Les seuls sous-produits sont le CO2 et H2O, qui ne nécessitent aucune manipulation supplémentaire, car le CO2 produit est biogénique, ce qui est inclus dans le cycle du carbone biogéochimique, évitant l'émission nette de carbone dans l'atmosphère. Ce manuscrit examine certains aspects liés à la technologie des piles à combustible microbiennes, depuis les réactions chimiques jusqu’aux systèmes de gestion de l'énergie requis pour exploiter la puissance fournie par les MFC. Une campagne expérimentale a été menée sur les MFCs concernant la caractérisation électrique, la connexion multiple des MFCs et l’influence des principaux paramètres qui affectent les performances de conversion de l’énergie. Le contexte de la pile à biocarburant est introduit et les principes de base de fonctionnement et les applications principales sont expliqués. L'enquête comprend une évaluation de l'impact des différents matériaux d'électrode, du substrat utilisé et des bactéries impliquées dans le processus chimique. Une perspective consiste à ajuster les paramètres afin de maximiser la production d'électricité. La conception spécifique de nos MFC de laboratoire est également présentée. Les essais expérimentaux ont été effectués sur deux types de réacteurs : la pile à combustible microbienne terrestre et la pile à combustible microbienne à eau usée. Un système de mesure approprié est présenté, il est spécialement conçu pour les tests sur les MFC. Il est capable d'assurer une mesure précise de toutes les valeurs et paramètres électriques nécessaires à la caractérisation électrique des réacteurs dans une configuration unique ou dans une connexion multiple. Les solutions utilisées pour alimenter les WWMFC étaient différentes et dans certains cas, on utilisait de vraies eaux usées, alors que dans d'autres, des solutions synthétisées appropriées étaient conçues à cet effet. Les méthodes de synthèse des solutions sont décrites. L'influence des principaux paramètres tels que le pH et la température a été analysée pour les deux types de cellules. La campagne expérimentale comprend des mesures de réacteurs en configuration unique ou disposées dans des connexions en série ou en parallèle. Les résultats confirment l'augmentation de la tension dans le cas de connexions en série et l'augmentation de la puissance dans le cas de connexions en parallèle. [...] / In recent years, the extensive use of fossil fuels has triggered into a global crisis due to high pollution and stock reduction, because of its nature of non-renewable source of energy. Because the wide use of fossil fuels has led to the production of high amounts of CO2, as a result is a trigger of the global warming issue. Microbial fuel cells (MFCs) is an energy harvesting technique that converts chemical energy from organic compounds to electrical energy through catalytic actions of microorganisms. MFC can be considered as archetypical microbial Bioelectrochemical Systems (BESs), that exploit the bio-electrocatalytic activity of living microorganisms for the generation of electric current. In the past decade, the evolution of low power electronics has made MFCs technology more attractive, because it has begun to be able to power low-power devices forming complete systems, such as the nodes of a wireless sensor network (WSN). Moreover, MFCs gained more interest because they can generate electric power while treating wastes. Unlike other fuel cells, MFCs can continuously generate clean energy at normal temperature, atmospheric pressure, and neutral pH value without any supplementary maintenance. The only by-products are CO2 and H2O, which do not require additional handling. The production of CO2 is part of a short duration carbon cycle. The CO2 produced is biogenic, which is included in the biogeochemical carbon cycle, avoiding net carbon emission into atmosphere. This manuscript examines many aspects related to microbial fuel cell technology from chemical reactions inside the cells to the energy management systems required to exploit energy delivered from MFCs for practical usage in autonomous sensors. Experimental campaign was performed on MFCs regarding electrical characterization, multiple connections of MFCs and influence of main parameters that affect energy conversion performances. The experimental tests were performed on two different lab-scale reactor typologies: terrestrial microbial fuel cell and waste water microbial fuel cell. A survey is presented about different proposed energy management systems and other devices able to build a node of a WSN powered by MFCs.

Die Weiterentwicklung klassischer, elektronischer Identifikationstechnologien leistet einen wichtigen Beitrag zum technischen Fortschritt in Industrie, Logistik und Gesundheitswesen. Die vorliegende Dissertationsschrift beschreibt die Entwicklung eines Dual-Feed-Antennendesigns für passive UHF-RFID-Transponder auf kritischen Oberflächen. Die zu Grunde liegende Antennenstruktur besteht aus einem Microstrip-Patch unter Verwendung eines verlustarmen Substratmaterials. Dieser erfährt eine Optimierung hinsichtlich seiner Lesereichweite, insbesondere auf kritischen Oberflächen. Ein Zwei-Port-Konzept mit gekoppeltem Feed-Line-Anpassnetzwerk reduziert die Anzahl benötigter, diskreter Komponenten und ermöglicht eine kostengünstige Herstellung mittels klassischer Ätzverfahren. Verschiedene Ansätze zur Modellierung und zur analytischen Berechnung der Antennenparameter werden dargestellt. Des Weiteren erfolgt eine Verifikation der Antennenstruktur anhand eines Konzepts für einen passiven Energy-Harvesting-RFID-Transponder, der zur Temperaturüberwachung in den genannten Branchen eingesetzt werden kann. Dieses Konzept schließt ein effizientes Energiemanagement mittels eines Ultra-Low-Power-Mikrocontrollers sowie Ansätze zur Energiegewinnung und -speicherung mit ein und stellt die Wahl wichtiger Systemparameter und Bauelemente anhand anwendungsspezifischer Abschätzungen dar.

With higher frequencies now being used in RFID systems, antennas are becoming much smaller resulting in more space on tags that can be used for innovative array designs to harvest more wireless energy. This master's thesis outlines and details a new methodology for designing and simulating the staggered pattern charge collector, a technique to improve harvesting wireless energy. Staggered pattern charge collectors enable RFID tag's to produce a higher DC voltage from a charge pump circuit by creatively using multiple arrays to increase the antenna power conversion gain without limiting the half power beamwidth. This thesis discusses the basics of patch antennas and charge pumps as well as an optimization technique for the staggered pattern array by maximizing integrated power conversion gain (IPCG). An example of a staggered pattern charge collector is fully specified from design through simulation, in preparation for fabrication. This methodology allows for the staggered pattern charge collectors to be designed, simulated, and fabricated quickly and effectively.