M.Phil. / The main objectives of this study, which was done in Sasol 2, were to analyse energy utilization in the Sasol process and to develop an energy model that simulates all major energy flows in the Sasol process. Secondary objectives were to study the mechanics of the Sasol process and to do a literature study ...

The sugar beet (Beta vulgaris) plant has in recent years been added to the Biofuel Industrial Strategy (Department of Minerals and Energy, 2007) by the South African government as a crop grown for the production of bio-ethanol. Sugar beet is commonly grown in Europe for the production of sucrose and has recently been cultivated in Cradock and the surrounding areas (Engineering News, 2008). The biofuel industry usually ferments the sucrose with Saccharomyces cerevisiae to yield bio-ethanol. However, researchers are presented with a critical role to increase current yields as there are concerns over the process costs from industrial biotechnologists. The beet factories produce a pulp by-product removed of all sucrose. The hemicellulose-rich pulp can be degraded by microbial enzymes to simple sugars that can be subsequently fermented to bio-ethanol. Thus, the pulp represents a potential source for second generation biofuel. The process of utilising microbial hemicellulases requires an initial chemical pre-treatment step to delignify the sugar beet pulp (SBP). An alkaline pre-treatment with ‘slake lime’ (calcium hydroxide) was investigated using a 23 factorial design and the factors examined were: lime load; temperature and time. The analysed results showed the highest release of reducing sugars at the pre-treatment conditions of: 0.4 g lime / g SBP; 40°C and 36 hours. A partial characterisation of the Clostridium cellulovorans hemicellulases was carried out to verify the optimal activity conditions stated in literature. The highest release of reducing sugars was measured at pH 6.5 – 7.0 and at 45°C for arabinofuranosidase A (ArfA); at pH 5.5 and 40°C for mannanase A (ManA) and pH 5.0 – 6.0 and 45°C for xylanase A (XynA). Temperature studies showed that a complete loss of enzymatic activity occurred after 11 hours for ManA; and 84-96 hours for ArfA. XynA was still active after 120 hours. The optimised lime pre-treated SBP was subsequently degraded using various combinations and percentages of C. cellulovorans ArfA, ManA and XynA to determine the maximal release of reducing sugars. Synergistically, the highest synergy was observed at 75% ArfA and 25% ManA, with a specific activity of 2.9 μmol/min/g protein. However, the highest release of sugars was observed at 4.2 μmol/min/g protein at 100% ArfA. This study has initiated the research within South Africa on SBP and its degradation by C. cellulovorans. Preliminary studies show that SBP has the potential to be utilised as a second generation biofuel source.

There is consensus that Eskom, South Africa’s main energy supplier, needs to expand its energy generating capacity in order to satisfy the growing demand for electricity, but there is less agreement on how it should do this. The existing supply is heavily reliant on thermal generation using coal, but the combustion of fossil fuels for electricity generation may contribute to climate change because it causes harmful greenhouse gases to be emitted into the atmosphere. This emission is something South Africa has committed itself to reducing. One way of achieving this is by the adoption of cleaner technologies for energy generation. One of these technologies is harnessing wind energy. The problem with harnessing wind energy is where to locate the turbines to harness the wind because these turbines ‘industrialise’ the environment in which they are located. They are a source of increased noise, a visual disturbance, cause increased instances of bird and bat mortality and the destruction of flora or the naturalness of the landscape in the areas in which they are located. The residents located near wind farm developments are most negatively affected and bear the greatest cost in this regard. A proper social appraisal of wind turbine projects would have to take this cost into account. Before such developments are approved there should be an assessment made of the impact on the residents, these impacts should be incorporated into the cost-benefit analysis. The negatively affected residents should also be compensated. The objective of this study was not to undertake a cost-benefit analysis of such a wind farm proposal, but to estimate the negative external cost imposed on nearby residents of such an industry, and thereby calculate appropriate compensation to be paid to these residents. Quantifying preferences for proposed, but not-yet developed, wind farms may be done by applying non-market valuation techniques, e.g. through one of the stated preference methodologies, such as a discrete choice experiment. The selected study site for providing guidance was one where Red Cap Investments Pty (Ltd) has proposed the development of a wind farm - in the Kouga local municipality. The basis for drawing conclusions was the analysis of the response samples of two groups of Kouga residents, distinguished by socio economic status; 270 from each group, 540 in total. The methodology applied to analyse the responses was a discrete choice experiment. The questionnaire administered included attitude, knowledge and demographic questions as well as a choice experiment section. The choice experiment section of the questionnaire required that the respondents choose between two different hypothetical onshore wind energy development scenarios and a status quo option. The hypothetical scenarios comprised different levels of wind farm attributes. The attributes included in the experiment were determined by international studies and focus group meetings. These attributes were: distance between the wind turbines and residential area, clustering of the turbines (job opportunities created by the wind farm development for underprivileged respondent group), number of turbines and subsidy allocated to each household. Three different choice experiment models were estimated for each socio-economic group: a conditional logit (CL), nested logit (NL) and a random parameters logit (RPL) model. It was found that, in the affluent respondent group, the simpler CL model provided the best fit. In the underprivileged respondent group, the RPL model, with the number of jobs created by the wind farm project as a random parameter1, explained by the gender of the respondent, provided the best fit. The estimated models identified distance as an important factor in both sampled respondent groups. Both respondent groups preferred that the wind farm be located further away from their residential areas. In addition to distance, the underprivileged respondent group also valued new job opportunities as an important determinant of choice. The affluent respondent group were very sensitive to densely clustered turbines but were almost indifferent between two of the effects coded levels of the clustering attribute “moderately close together” and “widely spaced apart”. Welfare estimates for the significant attributes in each socio-economic group were computed from the best fit models. Table 1 shows the resulting willingness to accept (WTA) compensation measures for distance in both socio-economic respondent groups.

Thesis (MBA)--Stellenbosch University, 2006. / ENGLISH ABSTRACT: The adoption of the White Paper on the promotion of Renewable Energy and clean fuels in 2003, opened the playing field for participants from other industries than the conventional petroleum, to participate in the fuel industry in South Africa. South Africa is a net importer of crude oil, which accounts for 92% of liquid fuels supply in South Africa. Although the country has significant coal reserves which can supply the country's demand for approximately 200 years, this energy source contributes significantly to CO, emissions. South Africa's participation in the Kyoto Protocol compels it to abide by its commitments to reduce these emissions between 2008 and 2012. The country's dependence on energy to fuel its growing economy, and the infiationary impact that oil imports has had on the country's economy, has prompted government to explore alternative sources of energy to reduce its dependence on fossil fuels and especially importing crude oil. As a result of this, and in an attempt to increase the potential for the successful implementation of ASGISA, government is exploring the feasibility of introducing an E10 fuel blend to the South African petrol blend. In view of th is, government has in it Accelerated and Sustainable Growth Initiative (ASGISA) targeted the development of the bio-fuels industry as an industrial sector that presents opportunities to create opportunities for sustainable growth and development. In view of this, the fiedgling fuel-ethanol industry (which is in its construction phase at the t ime of writing this report), faces lucrative prospects for the agricultural industry, especially maize- and ethanol producers. It is anticipated that the fuel-ethanol industry will create between 8000 and 10000 direct and indirect employment opportunities per plant. This will result in significant investment in rural areas as well. The creation of employment in the rural areas will prevent the large-scale urbanisation that has become a phenomenon in the past decade, as a result of dwindling agricultural industries. The production of ethanol presents the opportunity to earn foreign exchange, especially if the industry embarks on large scale export strategies. In addition to the export market, the local market for ethanol consist of the possible E10 petrol-blend and to supply Eskom with ethanol to fuel its gas turbine electricity generators at Acacia, Port Rex, as well as the anticipated generators at Atlantis and Mossel Bay. This document is a report on the investigation of the economic evaluation of a bio-fuel industry in South Africa. It will explore the current outlook for fossil fuel reserves, supplies and demand, both internationally and locally. It will report on the phenomenon of peak oil production and some opinions thereon . An investigation into the most probable biomass that can be used as feedstock for bio-fuel production will conducted. In this regard, specific investigation into maize, sugar cane (for fuelethanol) and Jatropha eureas (for bio-diesel) will be conducted. The report will explore the most efficient ethanol production processes, for both maize- and sugar-to-ethanol production, with the weight of the document to be attributed to the economic impact that the adoption of the fuel-ethanol programme / AFRIKAANSE OPSOMMING: Die publisering van die Witskrif oor die promosie van hernieubare energiebronne en skoon brandstowwe in 2003, het die speelveld vir deelname aan die brandstof industrie oopgemaak vir rolspelers buiten die konvensionele petroleum maatskappye. Suid-Afrika is 'n netto invoerder van ru-olie en het in 2004 ongeveer 92% van die totale vloeibare brandstowwe ingevoer. Alhoewel die land aansienlike steenkool reserwes het om te voorsien in die aanvraag vir die volgende ongeveer 200 jaar, dra hierdie energiebron aansienlik by tot die koolstofdioksied vrystellings. Suid-Afrika se deelname aan die Kyoto Protokol van 1998, dwing die land om te voldoen aan die ondernemings wat gemaak is om hierdie koolstofdioksied vrystellings te verminder tussen 2008 en 2012. Die land se afhanklikheid van energiebronne om groei te stimuleer, asook die inflasionistiese effek van olie invoere op die ekonomie, het die regering genoop om alternatiewe bronne van energie te ondersoek sodat die afhanklikheid van olie verminder kan word. Uiteenlopend hiervan en om die implementering van ASGISA te stimuleer, ondersoek die regering tans die moontlikheid om 'n E10 petrol vermenging in die petrol formule te spesifiseer. Uit die oogpunt van ASGISA (Accelerated and Sustainable Growth Initiative) van Suid-Afrika, het die regering die ontwikkeling van die bio-brandstowwe industrie geoormerk om geleenthede te skep vir volhoubare ontwikkeling en groei. Met die oog hierop, voorspel die etanol bedryf, wat ten tyde van die skryf van hierdie verslag nog in kontruksie was, winsgewende potensiaal vir die landboubedryf, veral mielie produsente. Dit word verwag dat die etanol bedryf tussen ongeveer 8000 en 10000 direkte en indirekte werksgeleenthede sal skep, veral in die landelike gebiede. Dit sal grotendeels bydra tot die voorkoming van die voortslepende ontvolking van die platteland wat oor die afgelope jare 'n verlammende effek op plattelandse gebiede gehad het. Dit word ook voorsien dat daar aansienlike belegging in die platteland sal plaasvind en al hierdie faktore sal bydra tot die voorkoming van verstedeliking . Die etanol bedryf skep die geleentheid om buitelandse valuta te genereer, veral as die industrie op uitvoere gaan konsentreer. Indien 'n plaaslike mark beoog word , sal die implementering van die E10 vermenging 'n besliste mark skep. 'n Alternatiewe mark wat ondersoek kan word, en wat groot geleentheid skep, is Eskom, wat tans ingevoerde diesel verbruik om hul gas turbine krag opwekkers by Acacia en Port Rex van brandstof te voorsien . Indien die beoogde turbines by Atlantis en Mosselbaai gebou word, sal die mark vir plaaslike etanol verdubbel. Hierdie dokument is 'n verslag oor die ondersoek wat gedoen is na die lewensvatbaarheid van 'n brandstof etanol bedryf in Suid-Afrika. Dit berig oor die huidige uitkyk oor die fossiel brandstof reserwes in die wereld en plaaslik. Dit opper die vraagstuk oor piek olie produksie fenomeen wat uiteenlopende debate ontketen het. Die verslag dek die waarskynlike bronne van biomassa wat aangewend kan word in die produksie van etanol, met spesifieke verwysing na mielies, suikerriet en Jatropha curcas. Die mees effektiewe produksie metodes word verder ondersoek wat van toepassing is op beide mielies en suikerriet. Die mees relevante deeI van die verslag is die ondersoek na die ekonomiese impak wat die industrie op die Suid-Afrikaanse ekonomie mag hê, waarna die nodige gevolgtrekkings en aanbevelings gemaak sal word.

M.Ing. / In a country that ranks forty seventh on a list of fifty countries in a world competitive survey economic growth should be a high priority in South Africa. The main player in South Africa's energy industry took up the gauntlet and is moving to economic growth with the vision 'to provide the world's cheapest electricity for growth and prosperity." Competition was introduced among the electricity producers by a process called trading and brokering. Majuba power station, the most expensive electricity producer on the South African grid, was left out in the cold. Management of Majuba is challenged to derive resourceful strategies to ensure sustained profitability. These strategies will require a study into world trends to enable them to be more competitive. Crystal ball gazing is not needed to know that major restrictions on pollution of the atmosphere by industry will be curbed by stringent legislation. The current electrification programme in South Africa is bound to impact the shape of the daily load curve. Labour cost and the rate of inflation have been increasing and can be expected to keep on rising in the foreseeable future. It is important to know what macro effect these factors will have on the South African power industry. Majuba must be able to identify the changes lurking on the horizon and have contingency plans in place to meet these challenges. In this work different types of plant needed to meet the daily load demand are researched from literature. It is then compared to the types of plant installed in South Africa. This leads to the conclusion that the installed plant in South Africa is not sufficient to meet the daily demand effectively. A case study is done on Majuba Power Station that has been operating in a two shifting mode since December 1996. This means that the units is started every day to be on full load in time for morning peak and then shut down after evening peak. It is also shown that this mode of operation is proffitable for a relatively expensive power generator.

MESMEG / Department of Mining and Environmental Geology / The future of energy in South Africa depends on coal as it is one of the cheapest and most affordable sources of energy; however, some of the coal is uneconomical to mine due to the thickness and depth of the coal seams. For many years the coal resources of the Soutpansberg Coalfield remained untapped and limitedly researched and with the coal resources running out in the other coalfields, the Soutpansberg Coalfield remained the bright coalfield of tomorrow in South Africa. Coal seams in the Soutpansberg Coalfield occur within the Madzaringwe Formation. Three coal basins have been identified in this coalfield, are the Venda-Pafuri, Tshipise and Mopane. Sedimentological basin analysis of the coal stratigraphy and characterisation of the Soutpansberg Coalfield in the Makhado area, Limpopo Province was investigated within the farms of Rissik, Fannie, Duel, and Lurkin. The main purpose of the study was to establish the variation of the coal stratigraphy and how coal influenced the stratigraphy within the area. Fieldwork involved core logging and core sampling from the different farms within the Makhado coal area, while laboratory work included petrographic studies, investigation of the physical and chemical properties of coal. Core logging revealed the occurrence of coal zones where coal seams were intercalating with mudstones, but rarely with siltstone that formed the footwall of coal. Rarely was coal intruded by dolerite dyke as was the case along borehole W6610001. Core logging further revealed the sedimentary structures in the lithologies and the depth at which different lithologies were intersected. From these sedimentary structures, the environment of coal deposition was deduced supported by the geochemical analysis of major oxides and trace elements. Correlation of boreholes along the strike showed that the shale and mudrock were the predominant rocks within the coal horizon leading to the conclusion that these were the coal host rocks. Whole rock geochemical analysis was undertaken, using X-Ray Fluorescence Spectroscopy in order to establish the rock types and their trace element contents. The collected samples were analysed at the University of Venda, Department of Mining and Environmental Geology Laboratory, Siza Coal Services in Secunda and Council for Geoscience. The study indicated that the coal seams of the Soutpansberg Coalfield were deposited within the floodplain of a mixed-load fluvio-deltaic (fluvial and braided) systems. This sedimentary channel has been the major influence on the development of the coal seams. Locational changes in sedimentary facies above and below the coal seams within the study area has caused variations in the rates of compaction and subsidence which influenced the coal basin morphology and the coalification pattern. These two parameters (variations in the rates of compaction and subsidence) controlled the coal quality parameters, and coal seam thickness as well as the coal composition. The study confirmed that coal quality and thickness vary markedly from place to place in this coalfield due to varying local depositional environments. Most of the drill holes intersected mainly 3 coal seams, although in some cases either 2 or 5 seams were intersected. The thickest coal seam (borehole F578002) was 8 m. It was concluded that the coal was sub-bituminous to bituminous coal rank class (medium-volatile bituminous coal rank class). The coal had low moisture content ranging from 0.7-0.8%, and ash content ranging from 21.4-32%. The fixed carbon and volatile matter values of the coal samples ranged from 42.5 to 50.4% and from 25.2 to 27.4% respectively. The carbon and hydrogen were the main principal combustible elements in coal, however; carbon is the predominant one based on weight, constituting about 5.3% (the lowest) to 70.3% (highest) of the total. Due to the nature and thickness of the coal seams we conclude that this coal was economical to be mined and can be used for electricity generation and in cement grinding plants. A graph of coal gas concentrations over combustion time showed that methane (CH4) and carbon dioxide (CO2) had high gas concentrations, amounting to 1.75% and 1.70% respectively. / NRF

Countries and governments around the world have accepted the scientific argument on the prevalence and the possible effect of global warming and climate change on the environment, world economy and ultimately human life (Nhamo, 2011). Amongst all industrial corporations, the mining industry is the biggest environmental polluter due to its extractive nature and energy intensive operations. However because of its economic importance, it cannot be abandoned, instead it needs to find a win-win situation, where it continues to succeed but minimizes environmental damage. This thesis aims to examine the possible impact of clean technology on the sustainability of South African gold mining sector. Specifically, the study aims to determine the drivers behind the move towards clean technologies and methods, identify challenges and opportunities associated with this transition at Harmony Gold’s Kusasalethu mine. This was achieved through using Kusasalethu as a case study to which investigations of the effectiveness of clean technology and methods were carried out. The case study was multidimensional; exploring the effect of clean technology on energy consumption, greenhouse gas emission (GHG), water consumption, cyanide management and Kusasalethu’s financial performance. While the case study was largely qualitative it involved quantitative data analysis that had to be triangulated with other data sources and data gathering instruments to achieve legitimacy. This meant that the study had to adopt the mixed research methods. The instruments used included; key informant interviews, and document analysis, structured questionnaire and a set of open ended questions that served as interview guide. The qualitative data were analyzed by means of coding, descriptions, typologies, taxonomies and visual representations, whilst quantitative data were processed through Microsoft Excel to generate various forms of descriptive statistics. The findings indicate that resource consumption (energy, water, cyanide) depends on the mine design and gold output rate. Clean technology implementation at Kusasalethu helped the mine reduce energy consumption and GHG emissions. However scope 2 (indirect GHG emissions associated with energy consumption) is also determined by coal production technologies and methods used by coal mines. Although data on Kusasalethu water and cyanide management and related technologies was not available, the aggregate data for all Harmony Gold mines indicated higher annual water and cyanide consumption during 2010 and 2012. In terms of Kusasalethu’s financial performance and clean technology adaptation, acquisition of clean technologies increased capital expenditure temporarily. However, the positive effects of the clean technology transition and implementation minimized operational cost and increased operational profit greatly. Although adopting clean technologies calls for increased capital expenditure, this study reveals that this expenditure pays off in lower operation costs for the mine and the environment benefits through lower GHG emission. However, clean technologies are yet to impact significantly in lowering water and cyanide consumption levels as they do with energy consumption. The study concluded that clean technology and methods played a positive role on Kusasalethu’s environmental impact and financial performance by reducing energy consumption and GHG emissions. Though, more need to be done in terms of water and cyanide management. / Environmental Sciences / M. Sc. (Environmental Management)

Countries and governments around the world have accepted the scientific argument on the prevalence and the possible effect of global warming and climate change on the environment, world economy and ultimately human life (Nhamo, 2011). Amongst all industrial corporations, the mining industry is the biggest environmental polluter due to its extractive nature and energy intensive operations. However because of its economic importance, it cannot be abandoned, instead it needs to find a win-win situation, where it continues to succeed but minimizes environmental damage. This thesis aims to examine the possible impact of clean technology on the sustainability of South African gold mining sector. Specifically, the study aims to determine the drivers behind the move towards clean technologies and methods, identify challenges and opportunities associated with this transition at Harmony Gold’s Kusasalethu mine. This was achieved through using Kusasalethu as a case study to which investigations of the effectiveness of clean technology and methods were carried out. The case study was multidimensional; exploring the effect of clean technology on energy consumption, greenhouse gas emission (GHG), water consumption, cyanide management and Kusasalethu’s financial performance. While the case study was largely qualitative it involved quantitative data analysis that had to be triangulated with other data sources and data gathering instruments to achieve legitimacy. This meant that the study had to adopt the mixed research methods. The instruments used included; key informant interviews, and document analysis, structured questionnaire and a set of open ended questions that served as interview guide. The qualitative data were analyzed by means of coding, descriptions, typologies, taxonomies and visual representations, whilst quantitative data were processed through Microsoft Excel to generate various forms of descriptive statistics. The findings indicate that resource consumption (energy, water, cyanide) depends on the mine design and gold output rate. Clean technology implementation at Kusasalethu helped the mine reduce energy consumption and GHG emissions. However scope 2 (indirect GHG emissions associated with energy consumption) is also determined by coal production technologies and methods used by coal mines. Although data on Kusasalethu water and cyanide management and related technologies was not available, the aggregate data for all Harmony Gold mines indicated higher annual water and cyanide consumption during 2010 and 2012. In terms of Kusasalethu’s financial performance and clean technology adaptation, acquisition of clean technologies increased capital expenditure temporarily. However, the positive effects of the clean technology transition and implementation minimized operational cost and increased operational profit greatly. Although adopting clean technologies calls for increased capital expenditure, this study reveals that this expenditure pays off in lower operation costs for the mine and the environment benefits through lower GHG emission. However, clean technologies are yet to impact significantly in lowering water and cyanide consumption levels as they do with energy consumption. The study concluded that clean technology and methods played a positive role on Kusasalethu’s environmental impact and financial performance by reducing energy consumption and GHG emissions. Though, more need to be done in terms of water and cyanide management. / Environmental Sciences / M. Sc. (Environmental Management)

MENVM / Department of Geography and Geo-Information Sciences / Fuel wood is regarded as a major source of energy around the world, particularly in developing nations. Most rural communities around the world, consider forests as the repository of stored energy. The high dependence on forests as a source of fuel wood has a major impact on vegetation because trees take a long time to regenerate to maturity, hence high dependence leads to deforestation. Fuel wood is used for household needs, such as cooking and heating and its uses contribute to the emissions of Green House Gases (GHG) such as CO2, CH4, and Black Carbon amongst others. The study assesses household energy use, the amount of carbon dioxide emitted from the combustion of fuel wood, the extent of de-vegetation and strategies to ensure sustainable energy provisions in the case study areas. Primary and secondary methods were used to collect data. The data were analysed using Statistical Package for the Social Sciences (SPSS 21.0), showing the frequency distribution, measures of central tendency and chi-square to determine the extent of fuel wood used in relation to electricity. The primary data were collected through personal observations, field surveys, interviews and questionnaires, while secondary data included the 2011 South Africa Census data and remote sensing images, which with the aid of GIS, were used in mapping the vegetation change.

MENVSC / Department of Ecology and Resource Management