Thesis (Ph. D.)--University of Washington, 2004. / Vita. Includes bibliographical references (leaves 214-228).

Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references (leaves 418-425). Available also in a digital version from Dissertation Abstracts.

Major paper (M.U.R.P.)--Virginia Polytechnic Institute and State University, 1992. / Vita. Abstract. Includes bibliographical references (leaves 64-69). Also available via the Internet.

Thesis (Ph. D.)--Drexel University, 2005. / Includes abstract and vita. Includes bibliographical references (leaves 148-164).

In this study, the formation mechanisms, distribution characteristics, and potential environmental risks of hazardous air pollutants from industrial-scale waste incineration processes were investigated. First, to clarify the dominant formation mechanism of polychlorinated dibenzo- p-dioxins and dibenzofurans (PCDD/Fs) in a hazardous waste (HW) incinerator, three tests were designed by adding different precursors in phenol-containing raw materials. With the addition of p-dichlorobenzene, PCDD/F levels at the quenching tower outlet were ten times higher than levels observed at the inlet. This indicates that the quenching tower failed to suppress the formation of PCDD/Fs and surface-mediated precursor reaction is the dominant formation mechanism in low-temperature stages. Besides, adsoprtive memory effect in air pollution control devices (APCDs) also led to high PCDD/F emissions. These findings suggest that to control PCDD/F emissions, strict regulation of chlorine contents in feed materials and frequent cleaning of APCDs are necessary. Meanwhile, single particles and solid residues were collected from the same HW incinerator. Morphologies and elemental compositions of particles in flue gas and indoor air were characterized by transmission electron microscopy-energy dispersive X-ray spectrometry (TEM-EDS). Eight types of single particles were classified, as organic, soot, K-rich, S-rich, Na-rich, Fe-rich, mineral and fly ash particles. The heavy metal partitioning behavior study suggested that Hg, Cd and Pb were mainly enriched in fly ash through evaporation, condensation, and adsorption; while Cr, Cu, Mn, and Ni were mostly remained in the bottom ash due to their low volatilities. In addition, the study also investigated environmental behaviors of certain characteristic pollutants. Thrity-two soil samples surrounding a cement plant co- processing HW were collected and analyzed for the presence of 16 polycyclic aromatic hydrocarbons (PAHs) and 12 heavy metals. Ten samples were selected for PCDD/Fs analysis. The highest concentration of PCDD/Fs occurred 1200 meters downwind from the cement plant. Levels of ∑16 PAHs ranged from 130.6 to 1134.3 μg/kg in soil. Source identification analysis suggested that the cement plant was the most likely source of PAH contamination. The concentrations of Cd and Hg were on average two times and six times higher than background values, respectively. Both incremental lifetime cancer risk model (ILCR) for PAHs and potential ecological risk index (RI) for heavy metals indicate potential risks to the population and the environment surrounding the cement plant. Last, to identify whether waste incineration is a major source for airborne environmentally persistent free radicals (EPFRs), tree leaf samples were collected from 120 sites surrounding four waste incinerators and one urban area. EPFR concentrations on leaves ranged from 7.5 × 10 16 to 4.5 × 10 19 spins/g. For the 10 N.D. samples, they were all collected from areas inaccessible by vehicles. Although previous work has linked atmospheric EPFRs to waste incineration, the evidence in this study suggests that vehicle emissions, especially from heavy-duty vehicles, are the main sources. According to our estimation, over 90% of the EPFRs deposited on tree leaves might be attributed to automotive exhaust emissions, as a synergistic effect of primary exhausts and degradation of aromatic compounds in road dust

Considering the prominence of green supply chain management (GrSCM) research has developed expressively in this field. However, there is a dearth of studies from emerging economies comprised of modelling and empirical testing of hypotheses. Moreover, the literature is lacking the empirical evidence on the determinants of GrSCM practices by small and medium enterprises (SMEs) especially in the case of Pakistan. The literature has yet to determine what green practices are being adopted by SMEs in Pakistan, an elucidation why GrSCM practices are adhered, what construct is appropriate to evaluate adoption of GrSCM practices by SMEs in Pakistan, and whether mediation of internal factors exits between the relationship of GrSCM practices and external pressure. This dissertation uses Structural Equation Modelling (SEM) to investigate GrSCM practices adoption, the appropriate construct for evaluating green practices, and examining three potentially important determinants in Pakistani SMEs. With the data collected in two stages from the SMEs sector of Pakistan, exploratory factor analysis (EFA) revealed a three-dimension structure for measuring the GrSCM practices. Subsequently, the confirmatory factor analysis (CFA) was carried out on two measurement models (i.e. first and second order) of GrSCM adoption based on EFA. The empirically outcomes advocates that both models for GrSCM adoption are valid and reliable, however the second order model has better fit indices. The SEM testing shows significant results for mediation of internal factors in the hypothesized relationship among the GrSCM practices and external pressures. For academicians and supply chain mangers these results yield several exciting theoretical and practical implications.

In this study, the formation mechanisms, distribution characteristics, and potential environmental risks of hazardous air pollutants from industrial-scale waste incineration processes were investigated. First, to clarify the dominant formation mechanism of polychlorinated dibenzo- p-dioxins and dibenzofurans (PCDD/Fs) in a hazardous waste (HW) incinerator, three tests were designed by adding different precursors in phenol-containing raw materials. With the addition of p-dichlorobenzene, PCDD/F levels at the quenching tower outlet were ten times higher than levels observed at the inlet. This indicates that the quenching tower failed to suppress the formation of PCDD/Fs and surface-mediated precursor reaction is the dominant formation mechanism in low-temperature stages. Besides, adsoprtive memory effect in air pollution control devices (APCDs) also led to high PCDD/F emissions. These findings suggest that to control PCDD/F emissions, strict regulation of chlorine contents in feed materials and frequent cleaning of APCDs are necessary. Meanwhile, single particles and solid residues were collected from the same HW incinerator. Morphologies and elemental compositions of particles in flue gas and indoor air were characterized by transmission electron microscopy-energy dispersive X-ray spectrometry (TEM-EDS). Eight types of single particles were classified, as organic, soot, K-rich, S-rich, Na-rich, Fe-rich, mineral and fly ash particles. The heavy metal partitioning behavior study suggested that Hg, Cd and Pb were mainly enriched in fly ash through evaporation, condensation, and adsorption; while Cr, Cu, Mn, and Ni were mostly remained in the bottom ash due to their low volatilities. In addition, the study also investigated environmental behaviors of certain characteristic pollutants. Thrity-two soil samples surrounding a cement plant co- processing HW were collected and analyzed for the presence of 16 polycyclic aromatic hydrocarbons (PAHs) and 12 heavy metals. Ten samples were selected for PCDD/Fs analysis. The highest concentration of PCDD/Fs occurred 1200 meters downwind from the cement plant. Levels of ∑16 PAHs ranged from 130.6 to 1134.3 μg/kg in soil. Source identification analysis suggested that the cement plant was the most likely source of PAH contamination. The concentrations of Cd and Hg were on average two times and six times higher than background values, respectively. Both incremental lifetime cancer risk model (ILCR) for PAHs and potential ecological risk index (RI) for heavy metals indicate potential risks to the population and the environment surrounding the cement plant. Last, to identify whether waste incineration is a major source for airborne environmentally persistent free radicals (EPFRs), tree leaf samples were collected from 120 sites surrounding four waste incinerators and one urban area. EPFR concentrations on leaves ranged from 7.5 × 10 16 to 4.5 × 10 19 spins/g. For the 10 N.D. samples, they were all collected from areas inaccessible by vehicles. Although previous work has linked atmospheric EPFRs to waste incineration, the evidence in this study suggests that vehicle emissions, especially from heavy-duty vehicles, are the main sources. According to our estimation, over 90% of the EPFRs deposited on tree leaves might be attributed to automotive exhaust emissions, as a synergistic effect of primary exhausts and degradation of aromatic compounds in road dust

A dissertation submitted to the Faculty of Science, University of the Witwatersrand in fulfilment of the requirements for the degree of Master of Science. Johannesburg 2015 / Exposure to inorganic and organic pollutants residues causes negative effects to human health. They can cause damage to the living organism as well as to the environment. Humans take up these pollutants through skin absorption, respiration and ingestion of contaminated food and also the drinking water as a potential contaminants exposure route for inorganic and organic pollutants to humans. Studies have shown that inorganic and organic pollutants can be retained in food crops at higher than the permissible levels, thus posing some health risks to consumers. This study sought to assess the potential risk posed by inorganic and organic pollutants to human health as a result of consuming raw food and processed food cooked in traditional utensils. The food samples and the traditional utensils were collected in Kinshasa and Johannesburg markets. In total ninety- two food samples were assessed. The food crops included: cabbage, cassava, beans, beef meat and fish (tilapia). Ten trace elements, namely: Al, As, Cd, Cr, Cu, Hg, Mn, Pb, Se and Zn were analysed in raw food samples using ICP-OES, ICP-MS and mercury analyser. These metals were also analysed in food cooked with the traditional utensils. The health risk indices calculated were: Daily Intake of Metal (DIM) and Hazard Index (HI). The results obtained reveal that the raw food collected in Johannesburg markets contained a significant (p ˂ 0.05) higher concentration in all elements than the food samples collected in Kinshasa markets. Hg was detected only in fish samples. It was observed that cooking utensils can leach some significant quantities of trace elements into food during processing, hence resulting increase the concentration of these metals in processed foods. The DIM exceeded the oral reference dose (Rfd) and the HI were ˃ 1 in all the food cooked. The results of metal found in this current investigation were above the standard permissible limit set by FAO/WHO. On the other hand, the levels of 17 organochlorine pesticides were assessed in uncooked and cooked beans, cabbage, cassava, fish and beef meat collected in Kinshasa and Johannesburg markets. It was noticed from the results recorder that the mean concentration of organochlorine pesticides in uncooked food collected in Johannesburg market were significantly high (p ˂ 0.05) than the uncooked food from Kinshasa markets. DDE recorded its highest mean level (253.58±4.78 μg kg-1) in beef meat samples collected in Johannesburg markets. The results from the current study revealed that after cooking the amounts of organochlorines were significantly reduce than the uncooked food. Residue amounts of organochlorine pesticides found in this study are considerably lower than the recommended amount of organochlorines set by WHO/FAO (300 μg kg-1). / MT2016

A research report submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in partial fulfillment of the requirements for the degree of Master of Science in Resource Conservation Biology (Coursework and Research Report) Johannesburg, February 2016 / Environmental perceptions have been researched in a wide range of communities globally. However, the environmental perceptions of rural people in the developing world, as well as their determinants, remain understudied. Investigating rural inhabitants’ environmental perceptions and what shapes them can produce useful information that could be incorporated into decision-making process that help resolve environmental issues. This study aimed to investigate dominant environmental perceptions and their determinants at individual, household and village levels, with a focus on environmental resource use, resource availability, and resource governance and management, among rural inhabitants of Bushbuckridge region in Mpumalanga Province, South Africa. This study used unanalysed pre-existing data for 300 rural households across five villages, collected via a questionnaire in 2006. Of the twelve local resources considered, fuelwood, edible wild herbs, grass and twigs for brooms, reed mats and wooden carvings were the most widely used resources. Building poles, thatch for roofs, and bushmeat were the least widely used resources. On the frequency of use of consumable resources, most households consumed fuelwood every day while edible wild herbs, wild fruits and edible insects were mostly consumed 1-3 times/week. The majority of user households used traditional medicine and bushmeat less than once a month. The majority of respondents perceived local availability of edible wild herbs, traditional medicine, edible insects, and wild fruits to be adequate. By contrast, less than a third of respondents indicated sufficient local supply of building poles, bushmeat and fuelwood. However, it was dominantly perceived that it is not necessary to get harvesting permits for most resources, except in the case of traditional medicines. The chief was repeatedly perceived to be the ultimate authority in issuing harvesting permits and regulating access to natural resources. Individual and household level characteristics, as well as village resided in, were found to shape a range of individuals’ environmental perceptions with regards to resource availability and resource governance and management, but their influence was not consistent across resource or governance issues. For instance, at the individual level, age significantly shaped individuals perceptions of resource governance and management regarding who controls access to natural resources. The youth and middle aged compared to elderly were less likely to perceive that the chief controls access to resources and were also more likely to perceive that the government controls access to resources than elderly. Household-level characteristics were found to have no influence on perceptions of who controls access to resources. Village resided in shaped perceptions of resource availability, for every resource, and most aspects of resource governance issues. Village resided in had a stronger influence on range of individuals’ environmental perceptions than individual and household level factors. Households which depended highly on natural resources were more likely to perceive shortages of resources and an increase in household resource use, the likelihoods of individuals perceiving community development forum and the community itself regulating access to the natural resources increased. It is clear that environmental perceptions vary within and between communities, and are shaped by the characteristics and circumstances of the individual, their households and the community they live in. Furthermore, the strength of influence of these determinants varies according to the particular resource and environmental governance issue concerned. The understanding and identification of factors that shapes individuals’ environmental perceptions will be helpful for policy makers, as it could establish solutions that are grounded in rural communities’ realities and their environmental perceptions.

Population growth, increasing affluence, and greater access to medicines have led to an increase in active pharmaceutical ingredients (APIs) entering sewerage networks. Wastewater in lower and lower middle-income countries use that use wastewater for irrigation may use untreated or poorly treated wastewater resulting in the potential for greater concentrations of APIs to enter soils in this way. Wastewater re-used for irrigation is currently not included in environmental risk assessments for APIs in soils. The addition of wastewater to soils changes the organic content and can increase the pH of soils, which will have an impact on the fate of any ionisable APIs introduced during the irrigation process. As the input of APIs to soil from wastewater irrigation is not currently included in the risk assessments, this is an area that requires increased attention. A study was undertaken using a modified sorption-desorption batch equilibrium method (OECD 106) to simulate the addition of synthetic wastewater (SWW) to soils compared to a normal OECD 106 study. The APIs studied were ofloxacin, propranolol, naproxen and nevirapine, and represent a range of API physico-chemical properties. These experiments showed that the changes to soil properties (pH and dissolved organic carbon (DOC)) caused by irrigation with SWW can change the fate of APIs in soils. The ionisation state of the API at the altered pH was more important for the positively charged propranolol than it was for the negatively charged naproxen and neutral nevirapine. The Kd and Log Koc increased during the sorption experiment in some cases with SWW. This has implications on the current terrestrial risk assessment where the trigger value for a more detailed soil risk assessment in at Log Koc >4. If the experiment is only performed in 10 mM CaCl2 as is currently required this may lead to unknown risks of APIs in wastewater irrigated soils not being taken into account. Three soil sterilisation or microbial enzyme suppression methods were investigated to identify how successful they were and if there was any impact on the soil physical chemical structure. Gamma irradiation, autoclaving and the addition of 0.2 g L-1 sodium azide were studied. None of the methods successfully sterilised the soils and some changes in soils were identified post-treatment. Autoclaving destroyed the soil structure, turning it into a fine powder and significantly increasing DOC. Sodium azide changed the pH of the loam soil but not the sandy loam soil. Literature suggested that gamma irradiation was the most likely to sterilise the soils with the least amount of disturbance to its physico-chemical properties but increases in DOC were identified in the current study. The changes to soils after sterilisation varied depending on the individual soil properties, indicating that soils should be studied on a case-by-case basis. Irrigation with wastewater provides continuous inputs of chemicals into soils throughout the growing season so it is vital that more work is done to understand the ultimate fate of pollutants in soil as a result. Wastewater has the potential to change the fate of chemicals in soils meaning that current risk assessments may not thoroughly assess all risks involved.