This research examines first the consequences of a learned, individualistic construction of masculinity as it exists within an aging population of farm men, and second the influence of this form of masculinity on possibilities for change in human relationships and industry practices. It is suggested that in a context of diminishing economic power and political influence, the prevailing model of masculinity has disabled the capacity of many farm men to manage change proactively. It is argued that evidence of a necessary change from instrumental, to-values and feelings-based engagement with human and natural systems has been slow to appear. A range of beliefs and attitudes are identified from the research data.Alternatives to traditional models of masculinity are examined. The research has been conducted using a Social Ecology approach, in which the personal autonomy arising from a coherent integration of values and beliefs informs our approach to all human and natural systems. Some possible consequences of such a change in personal orientation are explored, in relation to agricultural practices, community viability, and the fostering of social capital, and reference is made to alternative forms of community organisation. / Master of Science (Hons)

Extraction, production, utilization and disposal of material resources have been undertaken continuously for much of human histories. Unavoidably, all of these activities have disturbed our environment, and subsequently have been harmful to humans and ecosystems in this and future generations. Due to time lag associated with both environment impact and the effects of measures taken to reduce this impact, existing approaches (i.e. monitoring and reacting) do not give sufficiently rapid feedback for effective environmental management. With regard to the complexity and concern related to environment-health chain effects, there is currently no environmental tool or approach that can provide comprehensive information and indicators covering all major environment and health themes, to enable decision makers to make informed judgements about regional policies and plans, relating to the sustainable use and disposal of material resources. Consequently, there is a need for developing a new approach by taking account of a multidisciplinary concept used in this thesis. Substance Flow Analysis (SFA) has been mainly applied in order to provide input information for Health Risk Assessment (HRA). The SFA approach provides the quantity of the substance that is transported (flows) and stored in the system (stock), and of which sub-system, flow, and process is the greatest concern. The HRA approach provides estimates of human health risk associated with site, activity and facility. An environmental fate and transport model is another key knowledge area incorporated into the HRA process. An integrating method of SFA, environmental fate and transport, and HRA is developed and illustrated by a case study of cadmium in Australia. This thesis shows that this new integration of existing stand-alone methods can provide holistic information and useful indicators covering all significant economic activities, environment, flows, and health risk assessment for selected substances. This enables better decision making on the use and disposal of substances at a range of levels in the economy, from corporations to regions and nations.

The adsorption of tributyltin onto materials commonly used for the construction of sampling and analytical equipment from aqueous solutions of varying ionic composition has been examined. The adsorption appears to be controlled by non-polar interactions between tributyltin and the surface involved. Since the speciation and hence polarity of tributyltin is affected by the ionic composition of the medium, the extent of adsorption is affected by the salinity and pH of a sample. The adsorption is rapid and, unless strategies are adopted to eliminate its effects, may render analytical results invalid. The electrochemistry of tributyltin, dibutyltin and monobutyltin, individually and in mixtures, has been investigated in aqueous media at mercury electrodes. The basic electrochemistry of each compound is summarised by the reaction BunSn (4-n)+ + (4-n)e- right left harpoons BunSn where n is the number of butyl groups attached to the tin atom. However, the electrochemistry of each compound is largely confined to the surface of the mercury electrode, and the simplicity of the above reaction is disrupted by polymerisation reactions and by butyl exchange processes occurring with the mercury electrode. When mixtures of butyltin compounds are present, the various processes that occur for each individual compound interfere with each other. A direct voltaminetric method for the determination of butyltin compounds in natural waters is therefore probably not possible.

Volatile loss rates of pesticides from turfgrass were measured using the Backward-Time Lagrangian Stochastic Dispersion model (Flesch et al., 1995). Solar radiation, ambient temperature, surface temperature, relative humidity, wind direction, and wind speed were monitored continuously. Growth regulator was applied to the turf plot several days before pesticide application to maintain a constant grass height and aerodynamic roughness length during the experiment. No irrigation occurred following application. Pesticides were applied as mixtures to allow direct comparison of evaporative loss. Mixtures studied were chlorpyrifos + triadimefon + ethofumesate and triclopyr (acetic acid) + propiconazole + cyfluthurin. Airborne flux estimates correlated with temperature, solar radiation, wind speed, time, and vapor pressure of the active ingredient. A log vapor pressure vs. 1/Temperature (K) relationship was observed between flux and surface temperature over a single day for most pesticides. An exponential attenuation of flux was observed over a period of several days and correlated with attenuation of dislodgeable surface residues for two of the pesticides. A fugacity-based model for predicting initial evaporative loss rates from turf grass is presented. Input parameters include pesticide vapor pressure, molecular diffusion coefficient, surface temperature, wind speed profile, atmospheric stability, surface roughness, and average upwind fetch. The GC retention method (Jensen, 1966) was used to estimate pesticide vapor pressures over an environmentally relevant temperature range. The model predicts fluxes that are an order of magnitude greater than measured values. This bias may be due, in part, to deviation from the assumption of pesticide saturated vapor density at the foliar surface. In addition, sensitivity analysis suggests improved estimates of leaf surface temperature and pesticide vapor pressures have the greatest potential to improve model performance. / Graduation date: 2003

Graduation date: 1994

No description available.

This dissertation is concerned with developing new methods for exploring the pressing problems of uncertainty, Environmental Justice, and tolling as they relate to long-range transportation planning. While these topics are seemingly disparate, much of the work in this dissertation is motivated by the increasing number of roadway projects concessioned to the private sector, and the lack of tools available for evaluating the impact of such agreements on the public given high levels of uncertainty over the length of the contracts and concern for the welfare of traditionally underserved population groups. These issues will be considered separately and together, offering insights into how transportation investment decisions can be improved. To this end, the impacts of considering long-range uncertainty in the traffic assignment model as well as in an integrated transportation and land use model (ITLUM) are assessed in terms of the effects on network performance measures and roadway improvement decisions. A new method for accounting for correlations between the future travel demands of origin-destination zone pairs is developed for the traffic assignment problem that can more effectively model the effects of potential economic changes. Results showed that neglecting correlations can lead to measures of variance of future total system travel time that range from underestimating the actual measure by seventy-five percent to overestimating it by one hundred percent, and to different selections for a network improvement project in up to fifty percent of all scenarios. Uncertainty in a basic ITLUM is considered more broadly, incorporating probability distributions for population and employment inputs as well as several travel demand model parameters, and examining how the choice of performance measure impacts the effect of uncertainty on the decision of where to increase system capacity. Comparing the network improvement projects selected when uncertainty is considered to a deterministic analysis, showed differences in up to 25% of scenarios. Challenges of considering Environmental Justice, a type of group-based equity that is required for metropolitan transportation plan compliance in the United States, are explored, particularly with regard to appropriately defining the term equity for the analysis. Several of these potential definitions are then transformed into objective functions for use in a new formulation of the user equilibrium-based discrete network design problem. A multi-objective genetic-algorithm solution method is developed to solve the problem efficiently, and insights are revealed into how different definitions of equity can lead to different decisions. The following objectives, both commonly used in practice, were found to be conflicting: 1) minimizing the difference in post-improvement performance across populations and 2) minimizing the difference across populations in the change in performance due to improvements. The problem of roadway tolling is first examined from the perspective of a private sector toll road operator seeking to maximize the asset's value by exercising flexibility. A stochastic recourse model is developed to account for the first stage investment decision and the second stage decisions to alter network capacity and toll rates. The flexibility to engage in non-compete clauses whereby the public sector cannot improve competing roadways, and also to improve feeder links in the surrounding network were found to play important roles in asset valuation. The value of having these options was found to increase with an increase in uncertainty of future demand, complexity of network structure, and the consequence of failure to meet debt obligations. The three original issues of uncertainty, Environmental Justice, and tolling are woven together into the development of a new method for determining the maximum toll rate that can be applied in a private sector operation scenario (first option) such that each group within the population, as defined for analysis of Environmental Justice, is no worse off than if the road had been constructed by the public sector without tolling (second option). Three stochastic dominance criteria are implemented to find the toll rate at which the first option dominates the second given uncertainty about the future travel demand. Findings suggest that there may be many toll rates that equate the benefits resulting from the two options, so the minimum rate is considered the optimal one. The difference in benefits to the groups was found to increase with increasing value of time, and the differences in optimal toll rates using each of the three dominance criteria increased similarly. The analytical tools developed in this dissertation, and the resulting insights obtained should offer significant contributions to several areas of long-range transportation planning, particularly informing the process of concessioning roadways to private entities, developing a transportation system that is robust to future uncertainty, and ensuring that Environmental Justice criteria is met by considering the transportation needs of each group within the population. / text

published_or_final_version / Civil Engineering / Master / Master of Philosophy

published_or_final_version / Housing Management / Master / Master of Housing Management

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management