Many environmental crises are threatening to collapse human societies, but also life on the Earth as we may know. Climate change due to anthropogenic global emissions is one of the main issues, but also soil degradation, and the management of the enormous amount of organic wastes that are harmfully released into the environment by human activities. On the one hand, direct spreading of biowastes onto the land is often limited due to eutrophication or pollution by toxic compounds. On the other hands, these biomasses may contain nutrients, such as phosphorus (listed as a critical raw material) and nitrogen, which could be recovered to sustain the high demand in expensive soil amendments and fertilizers. Thus, finding new solution to close the loop towards circular economy and sustainable processes is crucial, nowadays, to convert the global trends and restore the delicate equilibrium in the water-food-energy nexus, with soil ‘under special surveillance’. In this framework, many researchers are focusing their attention on hydrothermal carbonization (HTC) as a possible candidate, in particular to treat moist biowastes and obtain useful solid (hydrochar) and liquid (HTC liquor) products. Nutrients contained in biowastes are sensitive to HTC process parameters and initial feedstock properties, thus it is crucial to analyze their distribution and (im)mobilization among the HTC products for their reuse in soil. On the other hand, since some organic compounds are generated during the thermochemical process, which may be responsible for toxicity to plants and other organisms, analysis of their possible toxicity towards the biosphere becomes crucial before implementation at a large scale. This thesis collects our efforts to explore new processes and deepen the knowledge about the possibility to produce amendments suitable for soil application from hydrochar. The core is from a process engineering perspective, focusing on the production phase and the characterization of the products, never forgetting any possible limits or the implications on ecotoxicological issues. In the first part of the thesis, ‘How to make hydrochar a soil amendment?’ is the main question. Based on few pioneer studies about composting of hydrochar, we assessed a complete analysis of hydrochar co-compost, produced from the 25-day aerobic stabilization of digestate of organic fraction of municipal solid waste, together with a fraction of its hydrochar, and green waste. Under the umbrella of C2Land project (funded by The European Institute of Innovation & Technology -EIT), we produced this new amendment in specifically designed bioreactors, then we characterized the products from the point of view of physico-chemical properties, nutrients distribution, toxicity to plants and mammalian cells. We are confident that the crucial result of toxicity removal from hydrochar through composting will attract the interest of many stakeholders, since implementing HTC in anaerobic/aerobic plants is almost ready to be applied at a large scale. Moreover, an experimental campaign performed at the University of Leeds further explored the effect of some other post-treatments on hydrochar composition and phytotoxicity, depending on the initial feedstocks (manure, sewage digestate, water hyacinth, and grass). The second part of the thesis was dedicated to nutrients recovery, necessary when some harmful matrixes - such as the municipal sewage sludge digestate - are not allowed to be reused for agricultural purposes, due to law limitations or pollution issues. In this case, nutrients recovery (N, P) could be achieved chemically, via HTC and struvite precipitation, being struvite recognized as a good fertilizer. Firstly, we performed a techno-economic assessment of the implementation at a district level of HTC-centered sewage sludge management. The mass reduction of waste streams may have some important effects on transportation costs, while the recirculation of HTC liquor back to the anaerobic digestors can imply more biomethane production with increased revenues. A mass balance for the potential of N and P recovery through struvite precipitation in the centralized facility was also assessed. Secondly, a near-zero waste treatment process for municipal sewage sludge via HTC was designed according to the available literature and preliminarily analyzed at lab level. The fractionation of the different types of phosphorus was analyzed through the STM-P protocol before and after HTC, confirming the mineralization of organic phosphorus during the process. Citric acid was validated as a good green solvent for phosphorus extraction and high-quality struvite precipitation, even if the process was not still optimized in terms of yields. Future works may identify the best process parameters for final metal recovery from liquid byproducts in order to internally recirculate them back to water line, and to characterize the leached hydrochar as purified renewable fuel or soil amendment. Thus, the proof-of-concept chain would be confirmed and could be applied to the sustainable HTC-centered biorefineries of the future.

Vorliegende Arbeit zeigt die jüngsten Möglichkeiten hochauflösender Fernerkundung am Beispiel von Stadtbäumen in Berlin, Deutschland. Es wurden neuste methodische Ansätze eingesetzt, wie beispielsweise maschinelles Lernens und individuelle Baumdetektion. Sie erwiesen sich von großem Vorteil für die detaillierte Analyse urbaner Ökosystemdienstleistungen in einer heterogenen Umwelt. Neueste Fernerkundung von hoher zeitlicher Auflösung hat Möglichkeiten gezeigt, Veränderungen des Stadtwaldes präziser zu untersuchen. Diesbezüglich konnten Baumspezies klassifiziert werden auf Grundlage saisonaler Veränderungen, die mittels Fernerkundungsdaten aufgenommen wurden. Dies ist für den urbanen Bereich einmalig und über große Flächen noch nicht durchgeführt worden. Darüber hinaus haben diese Baumarten einzelnen Bäumen zugeordnet werden können, deren Abmessung fernerkundlich erfasst worden ist. Diese neu erzeugten Umweltinformationen einzelner Bäume können damit verbundene urbane Ökosystemdienstleistungen präzise aktualisieren. Zum Beispiel haben so Unsicherheiten in der Schätzung zur Kohlenstoffspeicherung städtischer Wälder reduziert werden können. Es ist zudem von Vorteil gewesen, den gegenwärtigen Mangel an räumlich expliziten dreidimensionalen Informationen über Stadtwälder anzusprechen. Allerdings ist die Rolle städtischen Wälder, das Treibhausgas CO2 langfristig auszugleichen, immer noch wenig untersucht. Gerade der Mangel an präzisen, konsistenten und aktuellen Details führt zu großen Unsicherheiten im Rahmen von Lebenszyklus-Analysen. Auf Grund des aktuellen Fortschritts in hochauflösender Fernerkundung könnten diese Unsicherheiten reduziert werden. Dazu werden Möglichkeiten ausgiebig kritisch bewertet und anhand einer Lebenszyklus-Analyse am Beispiel Berlin andiskutiert, inwieweit sie präzisere langfristige Prognosen zum Stadtwald als Kohlenstoffspeicher liefern. / This work shows recent options for implementing high resolution remote sensing in assessing urban trees in Berlin, Germany. State-of-the-art methodological approaches like machine learning and individual tree detection proved to be highly advantageous for analyzing details of urban ecosystem services within a heterogeneous urban environment. Recent remote sensing of high temporal resolution offers new options for more precisely addressing urban forest dynamics. This successfully shows that tree species could be identified from seasonal changes of remotely sensed imagery, though this has not yet been applied across cities. Furthermore, these tree species results could be combined with remotely sensed individual tree dimensions. This newly generated data can be suggested to update spatially explicit information on related urban ecosystem services. For example, this could reduce the uncertainties of such estimates as urban forest carbon storage, and also address the present lack of spatially explicit three-dimensional information on urban forests. However, few studies have considered the local scale of urban forests to effectively evaluate their potential long-term carbon offset. The lack of precise, consistent and up-to-date forest details is challenging within the scope of life cycle assessments. This can cause high uncertainties in urban forest carbon offset. Although, recent progress in high resolution remote sensing is promising to reduce these uncertainties. For this purpose, remote sensing options are extensively reviewed and briefly discussed using an example of life cycle assessment for Berlin, which allow more precise long-term prognoses of urban forest carbon offset.