<p> The Mauch Chunk Group has been interpreted as a product of multiple transgressions and regressions (Miller and Eriksson, 2000; Beuthin and Blake, 2004). An outcrop containing the upper Hinton Formation and Princeton Formation, the middle two formations of the Mauch Chunk Group, occurs along US-460 in Princeton, West Virginia, 2.6 kilometers east of the Interstate 77 Princeton exit. In order to understand the sedimentology and depositional history at those outcrops, sedimentologic logs were compiled, facies were identified and bundled into facies associations, photographic panoramas with line drawing overlays were constructed, and rock samples were taken. From the logged sections and facies architecture, a depositional history was interpreted. That history was supplemented with a provenance study where the samples were analyzed with a scanning electron microprobe to document oxide weight percentages. The upper Hinton Formation and the Princeton Formation were deposited through a combination of autocyclic and allocyclic processes. The mineralogy does not conclusively tie the sandstone deposits to the same source; however, mineral identifications did indicate the provenance to be an area with both igneous and metamorphic rocks. The presence of growth faulting indicates that the location of the cross-bedded sandstone that comprises the Princeton Formation at the US-460 outcrop may have been influenced by syn-depositional tectonism.</p><p>

<p> The search for clean, fresh water is of the utmost importance, especially considering the highly industrialized age in which we live and the rising demand caused by increasing population. Many once-clean groundwater reservoirs have been tainted due to the inadequate storage and handling procedures for hazardous materials. One such site operated as a wood-preservation facility between 1937 and 1999 located in western Louisiana in the town of DeRidder. The contaminants that leached into the soils and groundwater supply at this site included creosote, a coal-tar distillate that is an amalgamate of several toxic constituents. The contamination was first detected in 1981, and within the year monitoring wells were installed to evaluate the extent of the pollution. For this study, 61 monitoring wells, 16 of which consistently record hazardous compounds within the subsurface, were analyzed in order to evaluate the temporal and spatial changes of contamination. The data were further correlated with rising and falling groundwater levels, precipitation data, and lithology in order to better understand the trends of the constituents and how they are affected by their environment. Additionally, an indication as to the efficiency of the current remediation practices put in place is examined by evaluating the diminishing contamination values over time compared to previous studies in the area. Hazardous levels within the soil are at their peak near the contamination sources, and spread outward while following the direction of local groundwater flow. This study shows that the total contamination quantities are slowly declining due to the current remediation practices, however, the total area covered by contamination fluctuates over time, and is currently in a state of expansion towards the southwest. A correlation between rainfall events and contamination spikes was noted in a previous study of the area, however, no such correlation was observed in the more recent data.</p>

<p> This project explored the potential fate and transport of seawater-based drilling fluid used in the Antarctic Drilling Program (ANDRILL) South McMurdo Sound project (SMS). The SMS drilling reported a loss of 5.6 &times; 10⁵ liters of drilling fluid to the surrounding formation throughout a borehole depth of 1139m. The introduction of these drilling fluids raise concerns of potential contamination to a pristine, isolated environment. The volume of fluid lost to the subsurface is unrecoverable and will only break down through natural attenuation processes, such as biodegradation. The objectives of this study are to estimate the extent of fluid migration laterally from the borehole and to determine when biodegradation of the water-based drilling fluid is effectively occurring. Variable density groundwater flow modeling (SEAWAT) was used to simulate the environment around the borehole. Applying stresses similar to the drilling events produced an estimate of how far fluid will be transported as drilling fluid is being circulated. Results show the fluid to migrate up to 7.5m into the subsurface. Additionally, laboratory microcosms were set up to incubate drilling fluid samples at various temperatures (5, 25, and 50&deg;C) under aerobic and anaerobic conditions. Experimental data collected over 188 days was analyzed to evaluate the time frame when biodegradation of drilling fluids occurred. Carbon isotope fractionation (¹³C/¹²C) was used to determine the ability of the drilling fluids to be used as a food source. Biological data observed changes in microbial growth using DNA quantification, and changes in microbial communities using Biolog EcoPlates&trade;. Results show a positive correlation between the increase of &delta;¹³C (&permil;) values and an increase in DNA (ng/&micro;l) quantity. Data from geochemical and community changes indicate biodegradation of the drilling fluid occurred between time 40 and time 100. The methods employed to investigate fate and transport is a unique approach, and applied to these water-based drilling fluids for the first time in this study.</p>

<p> The need for an expedient and economical field method for identifying the upper boundary of the capillary fringe (CF) led to an investigation of the clay-rich surficial units of two sites in New Iberia, Louisiana. Tension-sensing instruments capable of indirectly measuring water content were installed to monitor changing subsurface conditions throughout the vadose zone in response to water table fluctuation and rainfall. Tension measurements of 10 kPa and 33 kPa, correlated with the agricultural concept of field capacity by previous studies, functioned as indicators of two possible upper capillary fringe surfaces. Interpreted tension boundaries were plotted at depth to outline temporal changes in capillary fringe thicknesses, which ranged from approximately 1&ndash;5 ft depending on rainfall rates. </p><p> A comparison of gravimetric water content profiles with interpreted tension boundaries suggested that CF thickness was heavily influenced by the presence and composition of surficial fill, root systems, and the depth of the shallow water table. Collected tension and water content measurements were plotted as water retention points onto a series of estimated soil water retention curves (SWRCs). The hysteretic nature of soil-water retention relationships of the clay-rich media, evidenced by several examples of near equivalent water contents corresponding to vastly different tension measurements, and vice versa, illustrated the potential errors in basing capillary fringe thickness solely on tension measurements. While tension measurements did prove useful in recording variable conditions in the vadose zone, further research into accounting for hysteresis is required before tension boundaries can be employed in capillary fringe surface identification.</p><p>

<p>Changes in the concentration of atmospheric carbon dioxide (pCO2) affect global climate. Accurate determination of paleo-pCO2 can therefore provide information on the response of climate to changing pCO2. Such pCO2 proxies have been developed from a variety of terrestrial (e.g., plant stomata, paleosol carbonate, and liverworts) and marine (e.g., alkenones and boron) substrates. However, these proxies show a wide range of values and uncertainty throughout the Cenozoic and especially for the early Paleogene (53-63 mya). Here, I demonstrate the use of the carbon isotope composition of n-alkanes extracted from C3 plant waxes as an accurate recorder of changes in atmospheric chemistry. My results show that the uncertainty and range of pCO2 estimates determined using this new proxy are similar to other proxies. Because n-alkanes are abundant, chemically resistant, and not subject to degradation, this proxy represents an excellent opportunity to reconstruct pCO2 across the last 400 Myr of Earth history. By examining across 4 different chain lengths (n-27, n-29, n- 31, and n-33), I find that only n-29 and n-31 show clear changes in carbon isotope discrimination in response to changes pCO2, whereas chain-lengths n-27 and n-31 did not show any significant response. Using chain lengths n-29 and n-31, I calculate early Paleogene pCO2 = 566 ? 190 and 469 ? 165 ppmv (median ? 1?), respectively. These results demonstrate that n-alkanes can serve as a potential pCO2 proxy across geologic timescales.

No description available.

No description available.

No description available.

<p> This study examines the natural background concentrations of arsenic in the soils of southwest Oregon, using new samples in addition to data collected from previous theses (Khandoker, 1997 and Douglas, 1999). The original 213 samples were run by ICP-AES with a reporting limit of 20 ppm, and only three samples had detected values. The original samples were tested again (2013) at a lower reporting limit of 0.2 ppm by ICP-MS, as were 42 new samples (2013), to better ascertain the natural levels of arsenic in undisturbed soils. The aim is to add to the existing DEQ data set, which has been used to establish new regulatory levels based on natural levels in the environment that are both safer and more economically viable than the former risk-based remediation levels (DEQ, 2013). </p><p> The maximum and mean concentrations, respectively, for each province (with high formation map unit) are 85.4 and 21.99 ppm for South Willamette Valley (Tfee), 45.4 and 5.42 ppm for the Klamath Mountains (Jub), 11.9 and 2.76 ppm for the Cascade Range (Tbaa), 10.6 and 5.15 ppm for the Coast Range (Ty), 2.32 and 1.29 ppm for the Basin and Range (Qba) and 1.5 and 1.20 ppm for the High Lava Plains (Tmv). </p><p> In addition, the distribution and variance of arsenic in the A and B soil horizons is assessed in this study by comparing deviation at a single site, and also by comparing A and B horizons of 119 PSU sites. One of 18 new sites sampled for this study (distinguished with the HH prefix), site HH11, was randomly chosen to evaluate differences at a single location. Site HH11 is an Inceptisol soil above volcanic rock (KJdv map unit) located at 275 meters elevation in Douglas County within the Klamath province. Five samples were taken from the A and from the B horizons at site HH11. The means and standard deviations were 3.74 &plusmn; 0.44 for the A horizon and 4.53 &plusmn; 0.39 for the B horizon. The consistency and low deviation within each horizon indicate that a single sample within a horizon is a good representative of that horizon and supports the field methodology used in this study of taking only one sample in the A horizon and one sample in the B horizon. </p><p> Wilcoxon Rank-Sum test determined that A and B horizons for the 119 sites that had data for both the A and B horizons were not statistically different (p-value 0.76). Arsenic concentration is not associated with a particular horizon for these sites. However, differentiation between soil horizons increases with age (Birkeland, 1999), as does accumulation of the iron oxides and sulfide minerals on clay surfaces (McLaren et al., 2006) which concentrate in the B horizon. These associations warrant further study to see how they relate to arsenic level, soil development and age in Oregon soils. </p><p> Lastly, this study statistically examines six potentially important environmental predictors of naturally occurring arsenic in southwestern Oregon: site elevation, geomorphic province, mapped rock type and age, and sample soil order and color (redness). A Classification and Regression Tree Model (CART) determined soil order, elevation and rock type to be of significant importance in determining arsenic concentrations in the natural environment. According to the regression tree, arsenic concentrations are greater within Alfisol and Ultisol/Alfisol and Vertisol soil orders, at lower elevations below 1,207 meters, and within soils from sedimentary, mixed volcanic/sedimentary and unconsolidated rock types.</p>

Master of Science / Department of Geology / Saugata Datta / To understand ambient nitrate dynamics in an unmanaged grassland environment, the stable isotope chemistry of various substrates at the Konza Prairie Biological Station were studied. Sediments consisted of alluvium, loess and bedrock materials are mostly limestone and shale. To gain a better understanding of the biogeochemistry of N cycling in this unmanaged grassland, 34 water samples have been collected along a full stretch of the major onsite creeks (Kings and Shane Creeks). These samples have been analyzed for δD, δ18O, and δ15N to determine the manner by which water allows nitrates to be leached into sediment, and to determine if additional nitrate is contributed from weathering of the bedrock. The anion chemistry of the waters show the presence of bicarbonates, sulfates, chlorides, nitrates, and fluorides. Although an obvious correlation among the anions is not present, data shows high alkalinity content due to the presence of shallow bedrock that is continuously being weathered. Using a hydraulic geoprobe, sediment cores were collected up to 8 ft deep using 2 ft core liners adjacent to the creeks to study δ15N and δ13C spatial variation of the sediments. This research also indicated the presence of C3 and C4 derived soil organic carbon with the latter being dominant. There is also an approximate 1:9 correlation between the total nitrogen and carbon content of these core sediments including NO3 and NH4 that are mostly concentrated in the upper 2 – 4 ft of the sediment profile. The results of this study provide a broader context for ambient nitrate cycling in unmanaged grassland and a baseline comparison for nitrate levels in surrounding agricultural lands.