Peat from the temperate regions has been used for paleoenvironmental reconstruction using diverse proxies for over a century now. Peat is rare and severely understudied in the tropics. The montane peat bogs of the Nilgiris, southern India have been found to preserve global climatic signals including the Holocene Optimum and the Last Glacial Maximum (LGM). At Sandynallah, one of the oldest peat accumulations in the world at >40 kyr BP, we had undertaken a high resolution paleoenvironmental reconstruction using multiple proxies which are yet to be evaluated in the tropical context. The study consists of 3 main objectives, i. Establishing an accurate high resolution chronology for the peat profile using radiocarbon dating, ii. Extracting vegetation and climate information from C/N ratio and Rock-Eval indices and iii. Using elemental profiles to establish the utility of inorganic geochemical proxies for processes such as weathering and dust transport. High resolution chronology for the site was built using Accelerator Mass Spectrometry (AMS) radiocarbon dates. To improve accuracy of the age-depth model, we also tested 4 samples for the effects of the AAA (Acid-Alkali-Acid) extraction method, the most common pre-treatment method for peat in the world. We compared ages on bulk samples (acid washed) and AAA treated samples from 4 different depths. We find that for all depths, the ages of the untreated samples do not lie within the internal uncertainty window and differ from the AAA treated sample age by at least an order of magnitude of the internal error, if not more. Based on these results we argue that the internal error should be used in conjunction with a reliable estimate of external error in an age-depth model for more realistic dating of paleoclimatic events. C/N ratios were explored for their paleoclimatic potential in conjunction with Rock-Eval indices and it was found that decomposition in tropical peat, as opposed to temperate peat, may not be sensitive to climatic perturbations. Inorganic geochemical proxies were also evaluated through this study. We see that the major and trace elements, except the lanthanide series do not show many significant trends for paleoenvironmental interpretation. But the lanthanides show some promise for identifying potential sources of dust and weathered material. Our study has addressed the gap in knowledge about the utility of recent geochemical proxies in tropical peat and has attempted to provide a solution to improve reliability in constructing age-depth models.

3D environment reconstruction has received great interest in recent years in areas such as city planning, virtual tourism and flood hazard warning. With the rapid development of computer technologies, it has become possible and necessary to develop new methodologies and techniques for real time simulation for virtual environments applications. This thesis proposes a novel dynamic simulation scheme for flood hazard warning. The work consists of three main parts: digital terrain modelling; 3D environmental reconstruction and system development; flood simulation models. The digital terrain model is constructed using real world measurement data of GIS, in terms of digital elevation data and satellite image data. An NTSP algorithm is proposed for very large data assessing, terrain modelling and visualisation. A pyramidal data arrangement structure is used for dealing with the requirements of terrain details with different resolutions. The 3D environmental reconstruction system is made up of environmental image segmentation for object identification, a new shape match method and an intelligent reconstruction system. The active contours-based multi-resolution vector-valued framework and the multi-seed region growing method are both used for extracting necessary objects from images. The shape match method is used with a template in the spatial domain for a 3D detailed small scale urban environment reconstruction. The intelligent reconstruction system is designed to recreate the whole model based on specific features of objects for large scale environment reconstruction. This study then proposes a new flood simulation scheme which is an important application of the 3D environmental reconstruction system. Two new flooding models have been developed. The first one is flood spreading model which is useful for large scale flood simulation. It consists of flooding image spatial segmentation, a water level calculation process, a standard gradient descent method for energy minimization, a flood region search and a merge process. The finite volume hydrodynamic model is built from shallow water equations which is useful for urban area flood simulation. The proposed 3D urban environment reconstruction system was tested on our simulation platform. The experiment results indicate that this method is capable of dealing with complicated and high resolution region reconstruction which is useful for many applications. When testing the 3D flood simulation system, the simulation results are very close to the real flood situation, and this method has faster speed and greater accuracy of simulating the inundation area in comparison to the conventional flood simulation models

This thesis results from a pilot study which, driven by repeatedly surprising results, opens up a reliable method of geochronology for Quaternary research. There have been repeated attempts to expand the limits of normal use of U-Pb dating. Geologists typically use U-Pb dating on detrital zircons (DZ) for dating and provenance studies on rocks older than the Cenozoic era. We tested several tephra layers in Utah and New Mexico, USA, with published 40 Ar/ 39 Ar ages between 1.3 and 1.6 Ma and found that the ages derived from clustered U-Pb dating are reliable, even though they were discordant. We used one of these tephra layers in the La Sal Mountains, Utah, to assign a minimum age to slope deposit layers (cover beds) underlying the tephra bed. In doing so, we discovered that we could not only identify unconformities between layers by means of palaeopedology. But that - although they were similar to one another regarding physical and chemical properties - they were not the same at all in terms of the provenance of their aeolian matter as derived from U-Pb analysis of detrital zircons, as one could actually assume. The source of aeolian matter mixed to these layers has changed decisively from layer to layer. The findings also allowed tentatively assigning palpable source areas for each layer. Since this had demonstrated the feasibility of a provenance approach, we then extended our study regionally to cover beds of the central Great Basin (GB) and the northern Colorado Plateau (CP). Using a published sequence-stratigraphic approach based upon stratigraphically consistent phases of soil development, we attempted to study cover beds from the same two Upper Quaternary time slices. We expanded our range of methods by end-member modelling analyzes (EMMA) and the analysis of surface and shape of detrital zircons. We used statistical methods such as multidimensional scaling (MDS) and density functions (probability density functions and kernel density estimations) to visualize similarities and distances of age distributions. The MDS and the density functions showed very clearly that the patterns of ages between the GB and the CP can be divided into two groups that differ from one another. This is probably due to different transport cascades of the zircons to and within both areas. Due to the lack of databases on the morphology of in-situ zirconia, it is not yet possible to draw precise conclusions about transport routes from them, although we have probably been able to identify traces of several stages of aeolian transport on many zircons. Conclusions can also be drawn about detrital zircons that were transported to the sampling point purely by the kinetic energy of volcanic eruptions during the Cretaceous (Cordilleran magmatic arc) and the Paleogene (strong volcanism within the study area). Moreover, we can show main similarities of the layers across the CP. Although they are separated spatially and temporally, they have a similar age distribution. The only exception here is the upper La Sal Mountains profile, for which I have several assumptions as to why this is so. We did not have enough conclusions for the reconstruction of the palaeoenvironmental conditions during the layer and soil formation phases; further investigations will have to follow. However, we show that a provenance study on Quaternary layers and further conclusions from the results are possible and would like to condense this approach for the study area in the future, but also try to transfer it to other study areas.:Abstract .......................................................................................................................3 Kurzfassung ................................................................................................................5 Contents ......................................................................................................................7 List of figures ............................................................................................................ 11 List of tables ............................................................................................................. 13 List of abbreviations and units .................................................................................. 14 1 Introduction ........................................................................................................... 16 1.1 Research questions ........................................................................................... 16 1.2 Cover beds ......................................................................................................... 17 1.3 Palaeosols .......................................................................................................... 17 1.4 Study area .......................................................................................................... 18 1.5 Zircons ............................................................................................................... 21 1.6 Thesis format ...................................................................................................... 23 2 Capability of U-Pb dating of zircons from Quaternary tephra: Jemez Mountains, NM, and La Sal Mountains, UT, USA ....................................................................... 24 2.1 Abstract .............................................................................................................. 25 2.2 Kurzfassung ....................................................................................................... 25 2.3 Introduction ........................................................................................................ 26 2.4 Geological setting ............................................................................................... 27 2.4.1 Jemez Mountains, New Mexico ...................................................................... 27 2.4.2 La Sal Mountains, Utah ................................................................................... 30 2.5 Methods ............................................................................................................. 30 2.6 Results and discussion ..................................................................................... 33 2.6 Conclusions ........................................................................................................ 38 Data availability ........................................................................................................ 38 Competing interests.................................................................................................. 38 Acknowledgements .................................................................................................. 38 2.7 References ......................................................................................................... 39 3 Cover beds older than the mid-Pleistocene revolution and the provenance of their aeolian components, La Sal Mountains, Utah, USA ........................................ 42 3.1 Abstract .............................................................................................................. 43 3.2 Introduction ........................................................................................................ 43 3.3 Material and methods ........................................................................................ 44 3.3.1 The La Sal Mountains tephra layer ................................................................. 44 3.3.2 Cover beds and palaeosols............................................................................. 45 3.3.3 Samples and analyses .................................................................................... 46 3.4 Results and discussion ...................................................................................... 49 3.5 Conclusions ....................................................................................................... 56 Acknowledgments ................................................................................................... 58 Summary information A. Supplementary data ......................................................... 58 3.6 References ........................................................................................................ 58 4 Zircon provenance of Quaternary cover beds using U-Pb dating: regional differences in the south-western USA ...................................................................... 63 4.1 Abstract .............................................................................................................. 64 4.2 Introduction ........................................................................................................ 65 4.3 Materials ............................................................................................................. 66 4.3.1 Study areas ..................................................................................................... 66 4.3.2 Stratigraphy and sampling sites ...................................................................... 68 4.3.3 Palaeolake deposits ........................................................................................ 71 4.3.4 Potential sources of detrital zircons ................................................................ 71 4.4 Methods ............................................................................................................. 75 4.4.1 End-member modelling of grainsize composition ........................................... 75 4.4.2 U-Pb dating ..................................................................................................... 75 4.4.3 Zircon dimensions and surfaces ..................................................................... 77 4.4.4 Statistical and graphical representations ........................................................ 78 4.5 Results and discussion ...................................................................................... 79 4.5.1 Aeolian contribution to cover beds .................................................................. 79 4.5.2 Zircon morphology .......................................................................................... 82 4.5.3 Age distributions of detrital zircons ................................................................. 88 4.5.4 Multidimensional scaling (MDS) ..................................................................... 94 4.6 Conclusions ....................................................................................................... 98 Appendix ................................................................................................................ 102 Acknowledgements ................................................................................................ 102 4.7 References ....................................................................................................... 103 5 Extended summary .............................................................................................. 118 5.1 Synthesis .......................................................................................................... 118 5.2 Regional differences and similarities ................................................................ 123 5.3 Outlook ............................................................................................................. 128 6 Supplementary Information ................................................................................. 130 6.1 Supplementary material chapter ‘Capability of U-Pb dating of zircons from Quaternary tephra: Jemez Mountains, NM, and La Sal Mountains, UT, USA’........ 130 6.1.1 Raw data electron microprobe analyses of glass shards from tephra layers .131 6.1.2 Raw data U-Pb ratios and calculated ages for all samples ............................137 6.2 Supplementary material chapter 3 ‘Cover beds older than the mid-Pleistocene revolution and the provenance of their eolian components, La Sal Mountains, Utah, USA’ .............................................................................................................. 160 6.3 Supplementary material chapter 4 ................................................................... 175 6.3.1 SI1 Raw U-Pb ratios and calculated ages ......................................................175 6.3.2 SI 3 Grainsize diagrams of samples of the present study (except for PL)......266 6.3.3 SI 4 Zircon morphology data .........................................................................269 6.3.3.1 Great Basin .................................................................................................269 6.3.3.2 Colorado Plateau ........................................................................................289 7 References (excluding chapters 2, 3 and 4) ....................................................... 308 8 Acknowledgements ............................................................................................. 312 / Diese Arbeit ist das Ergebnis einer Pilotstudie, die aufgrund immer wieder neuer, unerwarteter Ergebnisse eine zuverlässige geochronologische Methode für die Quartärforschung eröffnet. Es wurde mehrfach versucht, die üblichen Grenzen der Verwendung der U-Pb-Datierung zu erweitern. In der Geologie wird die U-Pb-Datierung an detritischen Zirkonen (DZ) normalerweise für Datierungs- und Provenienzstudien an Gesteinen, die älter als das Känozoikum sind, eingesetzt. Wir haben mehrere Tephra-Schichten in Utah und New Mexico, USA, mit veröffentlichten 40 Ar/ 39 Ar-Altern zwischen 1.3 und 1.6 Ma getestet und festgestellt, dass die Alter, die aus den Clustern der U-Pb-Datierungen abgeleitet wurden, zuverlässig sind, obwohl sie diskordant waren. Wir haben eine dieser Tephra-Schichten in den La Sal Mountains, Utah, verwendet, umlagernden Deckschichten ein Mindestalter zuzuweisen. Dabei stellten wir fest, dass wir nicht nur mittels Paläopädologie Schichtgrenzen zwischen Schichten ausweisen konnten. Sondern dass sie sich, obwohl sie sich in Bezug auf physikalische und chemische Eigenschaften ähneln, in Bezug auch auf die Herkunft ihres äolischen Materials (abgeleitet aus der U-Pb-Analyse der DZ) überhaupt nicht glichen, wie man eigentlich annehmen könnte. Die Herkunft des eingemischten äolischen Materials hat sich von Schicht zu Schicht entscheidend verändert. Die Ergebnisse ermöglichten es auch, jeder Schicht konkrete wahrscheinliche Liefergebiete zuzuweisen. Da dies die Möglichkeit einer Provenienz-Analyse belegt hatte, erweiterten wir unsere Studie regional auf Deckschichten des zentralen Great Basin (GB) und des nördlichen Colorado Plateaus (CP). Unter Verwendung eines publizierten sequenz-stratigraphischen Ansatzes, der auf stratigraphisch konsistenten Phasen der Bodenentwicklung basiert, haben wir versucht, Deckschichten aus denselben beiden oberen quartären Zeitscheiben zu untersuchen. Wir erweiterten unser Methodenspektrum um End Member-Modellierung (EMMA) und die Analyse der Oberfläche und Form von DZ. Wir verwendeten statistische Methoden wie mehrdimensionale Skalierung (MDS) und Dichtefunktionen (Wahrscheinlichkeitsdichtefunktionen und Kerndichteschätzungen), um Ähnlichkeiten und Abstände von Altersverteilungen zu visualisieren. MDS und Dichtefunktionen zeigten deutlich, dass GB und CP unterschiedliche Altersspektren aufweisen. Dies ist wahrscheinlich auf unterschiedliche Transportkaskaden der Zirkone in beide und innerhalb beider Gebiete zurückzuführen. Aufgrund des Fehlens von Datenbanken zur Morphologie von gesteinsbürtigen Zirkonen kann man daraus noch keine genauen Rückschlüsse über Transportwege ziehen, obwohl wir wahrscheinlich an vielen Zirkonen Spuren mehrerer Schritte des äolischen Transports identifizieren konnten. Es liegen auch DZ vor, die vermutlich ausschließlich durch die kinetische Energie von Vulkanausbrüchen während der Kreidezeit (Cordilleran Magmatic Arc) und des Paläogens (starker Vulkanismus innerhalb des Untersuchungsgebiets) zum Probenahmepunkt transportiert wurden. Darüber hinaus können wir Ähnlichkeiten zwischen den verschiedenen Schichten im CP zeigen. Obwohl sie räumlich und zeitlich getrennt sind, haben sie eine ähnliche Altersverteilung. Die einzige Ausnahme hiervon ist das Profil der höheren La Sal Mountains, wofür es mehrere mögliche Gründe gibt. Wir konnten nicht genügend Erkenntnisse für die Rekonstruktion der paläoökologischen Bedingungen während der Schicht- und Bodenbildungsphasen gewinnen; weitere Untersuchungen müssen folgen. Wir zeigen jedoch, dass eine Provenienzstudie an quartären Schichten und weiterreichende Schlussfolgerungen möglich sind, und möchten diesen Ansatz für das Untersuchungsgebiet in Zukunft verdichten, aber auch versuchen, ihn auf andere Untersuchungsgebiete zu übertragen.:Abstract .......................................................................................................................3 Kurzfassung ................................................................................................................5 Contents ......................................................................................................................7 List of figures ............................................................................................................ 11 List of tables ............................................................................................................. 13 List of abbreviations and units .................................................................................. 14 1 Introduction ........................................................................................................... 16 1.1 Research questions ........................................................................................... 16 1.2 Cover beds ......................................................................................................... 17 1.3 Palaeosols .......................................................................................................... 17 1.4 Study area .......................................................................................................... 18 1.5 Zircons ............................................................................................................... 21 1.6 Thesis format ...................................................................................................... 23 2 Capability of U-Pb dating of zircons from Quaternary tephra: Jemez Mountains, NM, and La Sal Mountains, UT, USA ....................................................................... 24 2.1 Abstract .............................................................................................................. 25 2.2 Kurzfassung ....................................................................................................... 25 2.3 Introduction ........................................................................................................ 26 2.4 Geological setting ............................................................................................... 27 2.4.1 Jemez Mountains, New Mexico ...................................................................... 27 2.4.2 La Sal Mountains, Utah ................................................................................... 30 2.5 Methods ............................................................................................................. 30 2.6 Results and discussion ..................................................................................... 33 2.6 Conclusions ........................................................................................................ 38 Data availability ........................................................................................................ 38 Competing interests.................................................................................................. 38 Acknowledgements .................................................................................................. 38 2.7 References ......................................................................................................... 39 3 Cover beds older than the mid-Pleistocene revolution and the provenance of their aeolian components, La Sal Mountains, Utah, USA ........................................ 42 3.1 Abstract .............................................................................................................. 43 3.2 Introduction ........................................................................................................ 43 3.3 Material and methods ........................................................................................ 44 3.3.1 The La Sal Mountains tephra layer ................................................................. 44 3.3.2 Cover beds and palaeosols............................................................................. 45 3.3.3 Samples and analyses .................................................................................... 46 3.4 Results and discussion ...................................................................................... 49 3.5 Conclusions ....................................................................................................... 56 Acknowledgments ................................................................................................... 58 Summary information A. Supplementary data ......................................................... 58 3.6 References ........................................................................................................ 58 4 Zircon provenance of Quaternary cover beds using U-Pb dating: regional differences in the south-western USA ...................................................................... 63 4.1 Abstract .............................................................................................................. 64 4.2 Introduction ........................................................................................................ 65 4.3 Materials ............................................................................................................. 66 4.3.1 Study areas ..................................................................................................... 66 4.3.2 Stratigraphy and sampling sites ...................................................................... 68 4.3.3 Palaeolake deposits ........................................................................................ 71 4.3.4 Potential sources of detrital zircons ................................................................ 71 4.4 Methods ............................................................................................................. 75 4.4.1 End-member modelling of grainsize composition ........................................... 75 4.4.2 U-Pb dating ..................................................................................................... 75 4.4.3 Zircon dimensions and surfaces ..................................................................... 77 4.4.4 Statistical and graphical representations ........................................................ 78 4.5 Results and discussion ...................................................................................... 79 4.5.1 Aeolian contribution to cover beds .................................................................. 79 4.5.2 Zircon morphology .......................................................................................... 82 4.5.3 Age distributions of detrital zircons ................................................................. 88 4.5.4 Multidimensional scaling (MDS) ..................................................................... 94 4.6 Conclusions ....................................................................................................... 98 Appendix ................................................................................................................ 102 Acknowledgements ................................................................................................ 102 4.7 References ....................................................................................................... 103 5 Extended summary .............................................................................................. 118 5.1 Synthesis .......................................................................................................... 118 5.2 Regional differences and similarities ................................................................ 123 5.3 Outlook ............................................................................................................. 128 6 Supplementary Information ................................................................................. 130 6.1 Supplementary material chapter ‘Capability of U-Pb dating of zircons from Quaternary tephra: Jemez Mountains, NM, and La Sal Mountains, UT, USA’........ 130 6.1.1 Raw data electron microprobe analyses of glass shards from tephra layers .131 6.1.2 Raw data U-Pb ratios and calculated ages for all samples ............................137 6.2 Supplementary material chapter 3 ‘Cover beds older than the mid-Pleistocene revolution and the provenance of their eolian components, La Sal Mountains, Utah, USA’ .............................................................................................................. 160 6.3 Supplementary material chapter 4 ................................................................... 175 6.3.1 SI1 Raw U-Pb ratios and calculated ages ......................................................175 6.3.2 SI 3 Grainsize diagrams of samples of the present study (except for PL)......266 6.3.3 SI 4 Zircon morphology data .........................................................................269 6.3.3.1 Great Basin .................................................................................................269 6.3.3.2 Colorado Plateau ........................................................................................289 7 References (excluding chapters 2, 3 and 4) ....................................................... 308 8 Acknowledgements ............................................................................................. 312

3D environment reconstruction has received great interest in recent years in areas such as city planning, virtual tourism and flood hazard warning. With the rapid development of computer technologies, it has become possible and necessary to develop new methodologies and techniques for real time simulation for virtual environments applications. This thesis proposes a novel dynamic simulation scheme for flood hazard warning. The work consists of three main parts: digital terrain modelling; 3D environmental reconstruction and system development; flood simulation models. The digital terrain model is constructed using real world measurement data of GIS, in terms of digital elevation data and satellite image data. An NTSP algorithm is proposed for very large data assessing, terrain modelling and visualisation. A pyramidal data arrangement structure is used for dealing with the requirements of terrain details with different resolutions. The 3D environmental reconstruction system is made up of environmental image segmentation for object identification, a new shape match method and an intelligent reconstruction system. The active contours-based multi-resolution vector-valued framework and the multi-seed region growing method are both used for extracting necessary objects from images. The shape match method is used with a template in the spatial domain for a 3D detailed small scale urban environment reconstruction. The intelligent reconstruction system is designed to recreate the whole model based on specific features of objects for large scale environment reconstruction. This study then proposes a new flood simulation scheme which is an important application of the 3D environmental reconstruction system. Two new flooding models have been developed. The first one is flood spreading model which is useful for large scale flood simulation. It consists of flooding image spatial segmentation, a water level calculation process, a standard gradient descent method for energy minimization, a flood region search and a merge process. The finite volume hydrodynamic model is built from shallow water equations which is useful for urban area flood simulation. The proposed 3D urban environment reconstruction system was tested on our simulation platform. The experiment results indicate that this method is capable of dealing with complicated and high resolution region reconstruction which is useful for many applications. When testing the 3D flood simulation system, the simulation results are very close to the real flood situation, and this method has faster speed and greater accuracy of simulating the inundation area in comparison to the conventional flood simulation models