There is a requirement in the European Union to divert organic wastes from landfill because of the risk of methane emissions. One alternative is anaerobic digestion of organic wastes, such as food waste, to stabilise them whilst at the same time recovering the energy from them. One problem with this approach is that the high nitrogen content of food waste may lead to ammonia inhibition. A solution to this has been found for mesophilic digestion but had not been attempted in thermophilic digestion where ammonia toxicity is known to be more acute. The work was carried out in laboratory-scale semi-continuous digesters operated over long time periods to provide maximum opportunity for acclimatisation, and in duplicate to give an indication of reproducibility. A series of experimental runs were undertaken at thermophilic temperatures to assess the influence of trace element (TE) addition on the digestion process. These were carried out at organic loading rates (OLR) of 2, 3 and 4 g volatile solids (VS) l-1 day-1 against unsupplemented controls at OLR 2 g VS l-1 day-1. Although TE addition could offset the accumulation of VFA which occurred in response to an increasing concentration of total ammonical nitrogen (TAN), it could not prevent this. The high alkalinity resulting from ammonia, however, allowed the digesters to continue to produce methane until VFA had accumulated to high concentrations before eventual failure due to a rapid drop in pH. To determine the threshold inhibitory ammonia concentration in thermophilic digestion, one pair of digesters was run on synthetic low nitrogen food waste (low-N food waste) at an OLR 2 g VS l-1 day-1 and compared to a control pair running on domestic food waste at the same loading. All four digesters received TE supplementation. The digesters fed with low-N food waste showed consistently stable performance with pH ~7.4, IA/PA ratio ~0.4-0.5, SMP 0.39 l CH4 g-1 VS, 52-55% CH4, total VFA <500 mg l-1 and 88% VS destruction whereas the controls showed signs of failure after 112 days and irreversible VFA accumulation at a TAN concentration >3.5 g N l-1. One of the low N digesters was supplemented with urea slowly and one by a shock dose: both showed signs of VFA accumulation at TAN >2.5 gl-1 and, again, an irreversible trend in propionic acid build-up when TAN >4 g N l-1. Long term operation showed meta-stable conditions when the digesters were operated at TAN between 2.5 - 3.5g l-1 with oscillations in VFA (especially propionic acid) concentration. Mesophilic digestion at 37oC with TE addition showed very stable performance with pH ~8, IA/PA ≤ 0.3, SMP ~0.48 l CH4 g-1 VS, 55-60% CH4, total VFA < 300 mg l-1 and VS destruction ~75-78% with a final total ammonia nitrogen (TAN) concentration of 4.5 g N l-1. As the temperature in digesters was raised from 35 to 43 oC in 1oC steps a change in performance was noted when the temperature reached 40 oC. Above this temperature VFA concentrations rose above 4000 mg l-1 and biogas and methane production fluctuated. It is probable that the higher temperature increased the concentration of free ammonia nitrogen (FAN) to ~800 g N l-1 at the measured TAN concentration ~5.5-6.0 g N l-1 and this was sufficient be inhibitory even with TE dosing. Fluorescent in situ hybridisation (FISH) was used to identify the methanogenic populations in some of the trials over selected time periods. This showed changes in population structure both in relation to temperature (mesophilic or thermophilic) and also in response to increasing concentrations of TAN. At high TAN concentrations Methanomicrobiales was the dominant methanogenic group and under mesophilic conditions this proved to be extremely ammonia tolerant. A 14C radio-labelling assay confirmed the dominant pathway to methane formation was by the hydrogenotrophic route which reflected the known metabolic pathway of this methanogen. It was concluded that thermophilic digestion of source segregated domestic food waste would lead to instability and failure of the process unless measures were introduced to reduce the TAN concentration to < 3.5 g N l-1, and preferably to < 2.5 g N l-1. Keywords: Anaerobic digestion, food waste, biogas, VFA accumulation, ammonia inhibition, Fluorescent in situ Hybridisation (FISH).

Due to legislative pressures and the recent ban of trybutyl tin, alternative environmentally acceptable ship hull antifouling systems are required. This thesis uses a multidisciplinary approach to combine two disparate areas of research namely marine biology and surface engineering, to develop a novel natural product (NP) based antifouling system. The overall objective of this thesis is to transfer a natural marine biological defence mechanism into an engineered antifouling coating system. By combining natural product extraction and incorporation into a trial coating an extensive test programme was able to investigate the antifouling performance and address the issues of bringing this active area of research to the next technological readiness level. By using a stepwise approach to the development of the engineered solution, a suite of techniques were used to fully characterise a NP based system. The biological and surface engineering techniques adapted and developed are described here and their future use to evaluate a novel NP based antifoulant system is critically assessed. After an extensive literature review, an ethanol extract from the red seaweed Chondrus crispus was selected as the natural product source. NP specimens were harvested locally and also purchased as industrially processed dried algae. The industrially processed algae showed good antifoulant activity ( ≤ 25 μg mL-1) in laboratory bioassays and had a greater efficacy than the locally harvested samples highlighting its potential as an economically viable solution. The direct incorporation of the NP into a commercial control depletion polymer binder, allowed for the rapid development of characterisation techniques to evaluate the effects this had on the performance of the NP-binder matrix. The feasibility of a range of electrochemical techniques to measure corrosion potential, impedance, resistance and water uptake in the NP coating was critically assessed. A combination of open-circuit potential and electrochemical impedance spectroscopy provided a unique and rapid means to non-destructively measure the contribution of incorporated NPs to the degradation and water uptake of the binder film. Studies of biofilm growth were used to successfully measure community viability and structure using fluorescent staining and differential interference contrast microscopy. These techniques were found to be very informative on Southampton water marine biofilm community structure and were cross correlated by fourier transform infrared measurements. Resistance to biofouling was determined through field trials, an important testing platform for an antifouling system, and specifically trials which test the entire coated system including any primers and substrate preparation requirements. An initial NP antifouling performance greater than the booster biocide (Chlorothalonil) control was documented for one field trial over a period of the first 6 weeks. A key aspect was to determine the potential efficacy of NPs and their viability in a coating system. To achieve this, a range of standard and non-standard techniques were used to assess this novel combination of crude NP extract and commercial binder system. This work has shown that a limited antifoulant activity is achievable. By evaluating the effect of a NP on both the fouling community and a binder system this unique approach helps define key techniques to assess future NP antifoulants and identifies the optimisation required to increase their functionality.

A collection of hardware weightless Boolean elements has been developed. These form fundamental building blocks which have particular pertinence to the field of weightless neural networks. They have also been shown to have merit in their own right for the design of robust architectures. A major element of this is a collection of weightless Boolean sum and threshold techniques. These are fundamental building blocks which can be used in weightless architectures particularly within the field of weightless neural networks. Included in these is the implementation of L-max also known as N point thresholding. These elements have been applied to design a Boolean weightless hardware version of Austin’s ADAM neural network. ADAM is further enhanced by the addition of a new learning paradigm, that of non-Hebbian Learning. This new method concentrates on the association of ‘dis-similarity’, believing this is as important as areas of similarity. Image processing using hardware weightless neural networks is investigated through simulation of digital filters using a Type 1 Neuroram neuro-filter. Simulations have been performed using MATLAB to compare the results to a conventional median filter. Type 1 Neuroram has been tested on an extended collection of noise types. The importance of the threshold has been examined and the effect of cascading both types of filters was examined. This research has led to the development of several novel weightless hardware elements that can be applied to image processing. These patented elements include a weightless thermocoder and two weightless median filters. These novel robust high speed weightless filters have been compared with conventional median filters. The robustness of these architectures has been investigated when subjected to accelerated ground based generated neutron radiation simulating the atmospheric radiation spectrum experienced at commercial avionic altitudes. A trial investigating the resilience of weightless hardware Boolean elements in comparison to standard weighted arithmetic logic is detailed, examining the effects on the operation of the function when implemented on hardware experiencing high energy neutron bombardment induced single event effects. Further weightless Boolean elements are detailed which contribute to the development of a weightless implementation of the traditionally weighted self ordered map.

A combination of climate change, due to anthropogenic CO2 emissions and concerns over energy security, due to fluctuating fuel prices, has led to the UK pushing to increase its renewable energy production. Harnessing tidal stream energy is an infant sector in the UK’s renewable energy portfolio, despite the UK’s large tidal stream resource, and is harnessed through deploying tidal stream energy converters. This thesis focuses on the design of a novel vertical axis tidal turbine (VATT) called CarBine which is driven by drag force and therefore has several unique advantages, including slow rotational speed, omni-directionality and a simple design. This research focused on the optimisation of the CarBine design and was split into two areas: physical testing and numerical modelling. A conventional Savonius was also analysed in both of these respects and this enabled a direct comparison of CarBine to a competing drag force driven VATT. Physical testing measured the power of the turbines and was conducted in hydraulic flumes at both Cardiff University (CU) and IFREMER in Northern France for a range of flow conditions. Testing at IFREMER enabled the quantification of the blockage effect in the CU experiments. Physical testing resulted in the optimised design of CarBine being one with a four arm configuration. From physical testing at CU, CarBine showed inferior efficiency performance to that of the conventional Savonius, a Cp of 0.117 compared to 0.225 at U∞=0.72 m/s. As a result a hybrid of both the Savonius and CarBine was tested, namely a Savonius with flaps. However, results from physical testing showed the Savonius with flaps to have inferior performance to both CarBine and the conventional Savonius, with a Cp of 0.103 at U∞=0.72 m/s at CU. Numerical modelling was conducted using the commercial CFD software package, Ansys CFX. Both transient and steady state simulations along with 2D and 3D models were used to model both CarBine and the Savonius. Both the k-ε and SST turbulence models were used for comparison. The two degrees of rotational freedom present in the CarBine design resulted in CarBine being difficult to model precisely. The numerical modelling results were validated against the physical testing results and where available, 3D results showed closer validation than the 2D results.

This thesis addresses the architectural integration of transpired solar collectors (TSC), as a building envelope technology patented in 1980s to pre-heat ambient air that would be used for space heating. It explores the reasons for low take up of the technology. It further explores the preferences, perceptions and recommendations of architectural integration quality of TSC in buildings. The research analyses the associated technological innovation development at entrepreneurial level in the UK and North America in a variety of terms including knowledge diffusion and research and development. Building-integrated renewable energy is an important response to concerns about climate change and energy poverty. As space heating accounts for 61% of total domestic energy consumption in countries with long cold seasons, the transpired solar collector (TSC) is a promising technology. However, TSC suffers from low take up despite its apparent technical competitiveness. A large-scale questionnaire, an experimental prototype and technological innovation system analysis were used to provide insight into architecturally integrating and developing TSC technology in buildings, and clarifying its potential contribution to pre-heating ambient air. The research outcomes inferred multi-dimensional reasons behind limited adoption of the technology. Respondents were generally aware of TSC technology; however, few were satisfied with available technology. Various preferences determining selection of TSCs were investigated, including: ‘invisible’ integration, planning guidelines for traditional buildings, stage of integration and sustainable factors. Respondents indicated that the ultimate feature considered when sourcing TSC technology was its reliability followed by capital cost. The solar irradiation only needed to exceed 60W/m2 for TSC to generate an output temperature greater than the ambient temperature. A significant temperature increase was observed when solar irradiation exceeded 400W/m2. Output temperature increased to 16ºC above ambient temperature in autumn and 12ºC in winter in the TSC prototype. A comparison of relevant actors, institutions and networks of TSC in the United Kingdom (UK) with North America, found both to be cautious about communication to protect intellectual property: this hampers knowledge exchange and development. Despite TSC take up in North America being restricted by cheap gas prices, end-user feedback reflects a level of satisfaction versus fewer such examples in the UK. Identified barriers included immaturity of technology, reluctance to implement new technology, lack of supply chain and low institutional support. A framework of potential enablers and architectural design guidelines were proposed to breakthrough take up of TSC.

Abrasive flow machining (AFM) is a non-traditional manufacturing technology used to expose a substrate to pressurised multiphase slurry, comprised of superabrasive grit suspended in a viscous, typically polymeric carrier. Extended exposure to the slurry causes material removal, where the quantity of removal is subject to complex interactions within over 40 variables. Flow is contained within boundary walls, complex in form, causing physical phenomena to alter the behaviour of the media. In setting factors and levels prior to this research, engineers had two options; embark upon a wasteful, inefficient and poor-capability trial and error process or they could attempt to relate the findings they achieve in simple geometry to complex geometry through a series of transformations, providing information that could be applied over and over. By condensing process variables into appropriate study groups, it becomes possible to quantify output while manipulating only a handful of variables. Those that remain un-manipulated are integral to the factors identified. Through factorial and response surface methodology experiment designs, data is obtained and interrogated, before feeding into a simulated replica of a simple system. Correlation with physical phenomena is sought, to identify flow conditions that drive material removal location and magnitude. This correlation is then applied to complex geometry with relative success. It is found that prediction of viscosity through computational fluid dynamics can be used to estimate as much as 94% of the edge-rounding effect on final complex geometry. Surface finish prediction is lower (~75%), but provides significant relationship to warrant further investigation. Original contributions made in this doctoral thesis include; 1) A method of utilising computational fluid dynamics (CFD) to derive a suitable process model for the productive and reproducible control of the AFM process, including identification of core physical phenomena responsible for driving erosion, 2) Comprehensive understanding of effects of B4C-loaded polydimethylsiloxane variants used to process Ti6Al4V in the AFM process, including prediction equations containing numerically-verified second order interactions (factors for grit size, grain fraction and modifier concentration), 3) Equivalent understanding of machine factors providing energy input, studying velocity, temperature and quantity. Verified predictions are made from data collected in Ti6Al4V substrate material using response surface methodology, 4) Holistic method to translating process data in control-geometry to an arbitrary geometry for industrial gain, extending to a framework for collecting new data and integrating into current knowledge, and 5) Application of methodology using research-derived CFD, applied to complex geometry proven by measured process output. As a result of this project, four publications have been made to-date – two peer-reviewed journal papers and two peer-reviewed international conference papers. Further publications will be made from June 2014 onwards.

Many households in developing countries rely on biomass (wood, charcoal, agricultural wastes, sawdust, and animal dung) and coal to meet their energy needs. The burning of these fuels in open fires creates environmental problems one of which is indoor air pollution (IAP). For effective reduction of indoor air pollution in sub-Saharan Africa, it is therefore, important to understand factors that determine the choice and uptake of cleaner fuels for household energy use. This research investigates the salient factors influencing households in developing countries in choosing fuel types, using the households in peri-urban areas of Ado Ekiti, Ekiti State, Nigeria as a case study. This research used holistic approaches to understand energy issues in the study area and used methods such as questionnaires, interviews, and field observation during data collection. Key findings suggest that underlying socio-cultural contexts of households’ ethnic groups guided wood-fuel harvesting in the peri-urban areas of Ado Ekiti, Ekiti State, Nigeria. Wood fuel continues to be households’ main domestic energy source irrespective of their socio-economic status. The open burning of wood fuel causes indoor air pollution as the recorded 24-hour particulate matter levels was between 42µg/m3 – 275µg/m3 for indoor kitchens and 48µg/m3 – 648µg/m3 for outdoor kitchens. The cultural perception of the households that natural aeration blows particulates into buildings hinders them from believing that the open of burning of biomass fuels for domestic activities is the cause of indoor air pollution. Based on the findings of this study, it is argued that the traditional norms and values of the householders, being embedded in their socio-cultural contexts, are vital for understanding energy issues in the global South.

This research investigated novel decontamination methods of airborne microorganisms in enclosed public spaces. There are many ways the pathogenic micro-organisms can be transmitted from one body to another, which includes for example, physical contact between the contaminated surface to another, transfer of infected blood from a donor to another medium, or respiratory infections where the large droplets containing micro-organisms caused by talking, sneezing or coughing can infect another whether by direct or close contact, and airborne transmission where the tiny aerosol droplets containing the micro-organisms remain in the air for a long period of time thus spreading to wider areas, making this mode of transmission the most effective and thus dangerous. There are many technique and systems in the market today in the field of air cleaning, and many more under development, these include: ozone, plasma, UV, IR, microwave irradiation, passive solar exposure, pulsed light, electrostatic precipitation, photo-catalytic oxidation etc. However air decontamination using a laser is an unexplored approach. In general two different mechanisms are studied in detail in this research. The possibility of using radiation from the laser and also using plasma and its bi-products were investigated. Many variations and techniques were evaluated for both mechanisms to optimise each decontamination effect. Two types of lasers were used to investigate the concept of using lasers to decontaminate air: a CO2 laser producing a beam at 10.6 μm in the IR region and a KrF excimer laser producing a beam at 248 nm in the UV region. This research was to investigate and make use of the power that is available in the laser in a certain way to decontaminate the air. The effect of laser beam absorption in the presence of microorganisms was modelled in Matlab and this could be used to analyse any wavelength. Two variations of creating a plasma were investigated, one method used a Chang profiled, uniform field electrode and the other used an increased size flat electrode. The plasma produced from these systems emitted radiation around 200 nm to 900 nm. The Chang profiled electrode, which was manufactured in house, was originally designed to be used as a Nitrogen air laser. However, experiments with a purchased Nitrogen laser (detailed in Chapter 3) did not show any significant bacterial killing so the system was modified to be used as a plasma air decontamination device. The electrode was sized 60 mm x 10 mm, and the discharge volume was varied by altering the discharge gap. The effects of various parameters were investigated including: the discharge voltage, type of pre-ionisers to optimise the discharge and air flow shaping through the discharge region. Microbiological experiments conducted using air seeded with microorganisms was used to test the system’s decontamination efficiency. The second plasma system used larger 200 mm x 30 mm aluminium electrodes. Again various parameters were investigated to maximise the discharge stability which included, type of dielectric medium, type of power source, electrical circuit setup, use of laser marked electrodes, air flow shaping and using multiple electrode pairs running off the same power supply. Again, microbiological experiments conducted using air seeded with microorganisms was used to test the system’s decontamination efficiency. Two further systems were built using the results obtained from testing the 200 mm x 30 mm aluminium electrodes, an Industrial Based Air Decontamination Unit and a Ozone Shock Plasma System. Both systems were comprised with multiple pairs of laser marked electrodes with dielectric media and possible addition of flow shaping. The two systems were tested as before with good effect. The developed prototypes can be applied to most applications where air cleanliness is required.

<p>The Swedish Road Administration (SRA) is responsible for maintenance of the state-run roads in Sweden. The SRA also has an overarching responsibility for the state of the environment in the road transport sector. The overall aim of this thesis is to examine the implementation of environmental requirements in SRA road maintenance contracts and to develop an improved model for the implementation of environmental requirements, making it easier for the SRA to establish an optimal contracting strategy for routine road maintenance. Using several qualitative methodologies, the thesis is mainly based on a content analysis of 18 tender documents, two case studies consisting of five cases and a questionnaire. The study shows that the SRA have stipulated environmental requirements in procurements of routine road maintenance since 1997. The formulation of the environmental requirements was initially carried out at the Regional Road Management Directorates. However, in the case of trucks and construction vehicles relevant organisations were given the opportunity to actively participate in the development of environmental requirements. The contractors in the study fulfil about three-quarters of the environmental requirements in the contracts. The main reasons for not complying with the environmental requirements are: i) absence of consultation with municipalities and competent authorities, and ii) inadequate communication of environmental requirements to subcontractors. The benefit to the environment of laying down environmental requirements for road maintenance is difficult to assess, due to unclear environmental requirements and the fact that the SRA does not systematically follow up the environmental requirements. The findings of the research indicate that the SRA have made a serious effort to integrate environmental aspects in their maintenance contracts through the use of environmental requirements. However, the SRA need to adopt a more systematic approach towards road maintenance contracts in order to make green procurement an effective tool for environmental adaptation of road maintenance. The thesis proposes an improved process for development, implementation and follow-up of environmental requirements. The proposed process can be summarised in five criteria that need to be fulfilled in order to achieve an environmentally efficient application of environmental requirements: i) the environmental requirements have to be based on legislation, environmental quality objectives, identified environmental problems and/or research, ii) environmental indicators and baselines have to be established in order to facilitate follow-up of compliance with the requirements, iii) the environmental requirements have to be stated clearly in order to limit misinterpretations and to facilitate follow-up, iv) the contractors have to develop working processes, routines and training based on the environmental requirements, v) routines for following-up compliance with the requirements and the environmental effectiveness need to be developed, and there has to be a feedback of the results. Furthermore, the purchasing function needs to be integrated with the implementation of the contracts. Although, having faced several problems during the introduction of environmental requirements, the SRA have managed to meet the main arguments that are used for justification of green procurement. However, if slightly changed, the process of green procurement has the potential of becoming an important tool in the work for enhancing the environmental performance of the SRA.</p>

<p>Given a special focus on Design for Environment (DfE) methods and tools, the objectives of this thesis are to, <i>“Identify basic design-related requirements that a method or tool should fulfill in order to become actively used by engineering designers”</i>, and to <i>“Investigate how those basic requirements could be used to make DfE methods and tools more actively used in industry among engineering designers”</i>.</p><p>The research has shown that designers in general have three main purposes for utilizing methods and tools, of which the last two could be seen as subsets of the first one. The purposes are to: (1) <i>facilitate various kinds of communication within the product development process;</i> (2)<i> integrate knowledge and experience into the methods and tools as a know-how backup;</i> and (3) contribute with structure in the product development process. The low degree of follow-up implies a risk that methods and tools are used that affect the work within the company in a negative way. In order to be able to better follow-up methods and tools regarding both their utilization and usefulness, there is a need for a better definition of requirements for methods and tools.</p><p>Most of all designers’ related requirements are related to their’ aims to fulfill the product performance and keep down the development time. This can be concluded as four major requirements, that a DfE method or tool, as well as a common method or tool, must exhibit: (1)<i> be easy to adopt and implement, </i>(2)<i> facilitate designers to fulfill specified requirements on the presumptive produc</i>t, and at the same time (3) <i>reduce the risk that important elements in the product development phase are forgotten</i>. Both these two latter requirements relate to a method or tool’s degree of appropriateness. The second and the third requirements are related to the fourth requirement, which is found to be the most important: that the use of the method or tool (4)<i> must reduce the total calendar time (from start to end) to solve the task.</i> The conclusion is that DfE methods and tools must be designed to comply to a higher degree with the main users - in this case the designers’ requirements for methods and tools</p>