Master of Science / Department of Geology / Matthew E. Brueseke / Previous studies of the northern Great Basin have indicated that mid-Miocene epithermal gold and silver ore deposits distributed regionally are temporally related to the magmatic activity associated with the onset of widespread extension and the Yellowstone hotspot (Saunders and Crowe, 1996; Kamenov et al., 2007). This study is focused on the volcanic rocks and ore deposits from the Silver City district (SCD), ID to address the petrogenesis and magmatic evolution that was influential in forming local precious metal deposits. The goal is to understand the tectonomagmatic conditions that contributed to the petrogenesis of the volcanic suite in the Silver City district, which can be used to provide details on the relationship between coeval mid- Miocene magmatism and mineralization across the northern Great Basin and Oregon Plateau. In order to better constrain the magmatic evolution of the SCD and potential sources of the precious metals, we have undertaken detailed sampling of local crust and mid-Miocene volcanic units to constrain their physical, geochemical, isotopic, and geochronological characteristics, as well as provide constraints on the petrogenesis of the mid-Miocene volcanic package. Prior studies of the local volcanism have yielded K-Ar and [superscript]40Ar/[superscript]39Ar ages of ~16.6 to 14 Ma (Bonnichsen, 1983), while others have dated adularia from one SCD mineral vein and obtained [superscript]40Ar/[superscript]39Ar ages of between 15.6 and 16.3 Ma (Hames et al., 2009; and Aseto et al., 2011). Field observations are consistent with earlier work (Lindgren, 1900; Asher, 1968; Pansze, 1975; Halsor et al., 1988; Bonnichsen and Godchaux, 2006; Camp and Ross, 2009) and reveal a sequence of basalt consisting of regionally prevalent Steens Basalt that pre-dated precious metal mineralization. Some of the basalt appears to have been erupted locally, based on the presence of mafic dikes and thick pyroclastic deposits similar to other regional mid-Miocene magmatic systems. Stratigraphically overlying this lower basalt suite is a complex package of rhyolite flows and domes, thin silicic pyroclastic units, additional basaltic lava flows, intermediate lava flows, and mafic/silicic shallow intrusives. Geochemical analysis indicates that the basaltic and basaltic andesite lava flows are locally erupted flows of Steens Basalt while the intermediate and silicic volcanism in SCD can be classified into nine distinct units including two andesites, one dacite, four rhyolites and two rhyolite tuffaceous units. Geochemical modeling suggest that the intermediate and silicic magmas were formed by a combination of open system processes, including low pressure partial melting and assimilation of mid to upper crustal granitoid basement rock, and magma mixing between silicic and basaltic endmembers. The formation of silicic volcanism in the SCD is similar to other regional mid-Miocene silicic volcanic systems (e.g. Santa Rosa-Calico volcanic field and Jarbidge Rhyolite). Based on new [superscript]40Ar/[superscript]39Ar geochronology of both volcanic units and epithermally emplaced mineralization, SCD volcanism appears to have erupted over a relatively short amount of time that overlaps with local epithermal Au-Ag mineralization.

Master of Science / Department of Geology / Matthew E. Brueseke / Mid-Miocene epithermal Au-Ag ores of the northern Great Basin USA are related to magmatism associated with the inception of the Yellowstone hotspot. The geochemical chemical connection between these ores and spatially and temporally related volcanism is not well understood, but has been suggested (Kamenov, 2007; Saunders et al., 2015). These Cu- and Pb- isotope studies show that the ore and associated gangue minerals have different sources of Pb, which supports evidence that the metal(loids) originate from a deep magmatic source (Saunders et al., 2008). Cu isotopes as a tool for exploring linkages between ore deposits and related volcanic rocks is a new and evolving field. A suite of mid-Miocene Northern Great Basin (NGB) and Snake River Plain (SRP) volcanic rocks was analyzed by aquaregia leach for their δ⁶⁵Cu compositions. These samples have all been previously characterized and include basalts, trachybasalt, basaltic andesites, and basaltic trachyandesites that are representative of regional flood basalt magmatism and younger basalt eruptions in central Idaho. Included are rocks from the Santa Rosa-Calico volcanic field, NV (e.g., Buckskin-National district); Owyhee Mountains, ID (Silver City District); Midas, NV region, near Jarbidge, NV; and a locality proximal to Steens Mountain, OR. Also included are two Pleistocene basalts from the central Snake River plain unequivocally related to the Yellowstone hotspot volcanism (McKinney Basalt and Basalt of Flat Top Butte), and one Eocene basalt from the Owyhee Mountains that is related to pre-hotspot arc volcanism. International rock standards ranging from ultramafic to intermediate were also analyzed in this study for comparison. Our new δ⁶⁵Cu data greatly expands the range of known Cu isotopic compositions for basalts, with values ranging from -0.84‰ to +2.61‰. These values overlap with the δ⁶⁵Cu of regional ores, further suggesting a link between the source(s) of the ores and the NGB rocks. The range of δ⁶⁵Cu values also overlaps with mantle rock values, suggesting that the Cu isotopic composition may be a signature derived from the mantle source. Fractionation mechanisms that cause such a broad range in Cu isotopes are still unclear but liquid-vapor transitions and mantle metasomatism are being explored. Furthermore, δ⁶⁵Cu values of international rock standards reported in this study did not agree with previously reported data (Archer and Vance, 2004; Bigalke et al., 2010; Moeller et al., 2012; Liu et al., 2014, 2015) suggesting that aquaregia leach may not be a preferable technique when analyzing volcanic rocks.

Ammonium has been detected in and around several epithermal Au-Ag deposits, including those in Nevada, Japan, Argentina, Mexico, and New Zealand, using short-wave infrared (SWIR) reflectance spectroscopy. This study examined the distribution and occurrence of ammonium in three epithermal low-sulfidation vein-type deposits in the Hauraki goldfield of New Zealand: Martha (>6.7Moz Au, >42.1Moz Ag), Favona (>0.6Moz Au, >2.36Moz Ag), and the recently discovered Wharekirauponga (WKP; 0.42Moz Au, 0.8Moz Ag) deposit. The Martha and Favona auriferous quartz-adularia veins are hosted by late Miocene to Pliocene andesite, whereas auriferous veins at WKP are hosted by late Miocene to Pliocene rhyolite. The wallrock of all three deposits is altered to form quartz, illite, smectite, adularia, chlorite, and pyrite +/- kaolinite. Ammonium contents are enriched (>137 ppm) in wallrock samples from all three deposits and low (<94 ppm) in vein samples. Ammonium contents are higher at Favona (<10,675 ppm) than at Martha (<192 ppm) and WKP (<2,783 ppm). Leaching experiments using a 2N KCl solution show that most ammonium is in mineral structures (>90% at Favona, >80% at Martha, >70% at WKP). There is a positive correlation of ammonium contents with LOI (0.6 – 16.3 wt%) and with K2O (1.3 – 8.0 wt%) in all samples which suggest a hydrous potassium mineral as the major host of the ammonium. This is supported by the SWIR data obtained by previous workers of these samples where they show an absorption at ~1410 nm due to OH. At Favona, samples with high ammonium (>990 ppm) are reported to have significant absorption at ~2000 nm and ~2100 nm in the SWIR spectra likely due to ammonium. High ammonium contents (990 – 10,675 ppm) are found in rocks less than ~100m from the Favona vein which occur within an ammonium-bearing zone identified by previous workers based on SWIR. Samples outside of this zone contain low ammonium (107 – 301 ppm) with the smectite altered samples being the lowest. Ammonium contents within the hangingwall (1,827 – 10,675 ppm) of the Favona vein tend to be higher than in the footwall (990 – 4,301 ppm) and are highest within the most intensely illite altered rocks. At WKP, the intensely adularia +/- minor illite altered samples within 100m of the main East-Graben (EG) vein contain low ammonium (<200 ppm). The intensely illite altered samples away from the EG vein (>100m) have higher ammonium contents (200 – 800 ppm). This relationship of high ammonium contents to high illite abundance confirms illite as the major host of ammonium in these deposits. δ15N values for all samples (n=54) including near and far from auriferous veins range from +0.5 to +7.9 ‰, suggesting the derivation of most of the ammonium from the Jurassic greywacke basement or sediments intercalated within the volcanic rocks.