Evapotransipration by vegetation cover is an important component of the water budget and energy balance in any ecosystem. A key to more improved water management therefore lies in improving our understanding of evapotranspiration, the process that drives water use by plants. Estimations of the turbulent fluxes are required for various applications in micrometeorology, hydrology, environmental studies and agriculture. Numerous methods for estimation of turbulent fluxes have been developed and tested. Direct measurements of fluxes are usually achieved by the eddy covariance (EC) method, which is considered as the most reliable. However, the application of the EC method is often problematic. The necessary sensors for wind, temperature and humidity must respond very fast (resolution of 10 Hz or better) and at the same time must not show noticeable drift. This makes them delicate, expensive and difficult to calibrate among other problems associated with the method. Due to their ability to integrate atmospheric processes along a path length that may range between a few hundred metres to a few kilometres, optical methods based on the analysis of scintillation appear to be an alternative and possible supplement to classical micrometeorological methods such as the EC method, which may provide local fluxes typically at the scale of 100 m. The use of the scintillometry technique in surface flux measurements is therefore gaining in popularity. The accuracy of the measurements obtained by one method is judged by comparison of the measurements obtained by those of another method considered as the standard. For turbulent flux measurements, the EC method is taken as the standard method for the determination of sensible heat fluxes. This research presents the measurement of sensible heat fluxes using the surface layer scintillometer (SLS). The SLS system used has a dual-beam and a recommended path length of between 50 and 250 m. The method was tested against the EC method for different Bowen ratio (f3) values, as required by the theory, under different atmospheric stability conditions, as well as for different wind directions relative to the SLS beam path and slanting beam path orientation. Also presented is an analysis of the different forms of the Monin-Obukhov Similarity (MOST) functions used in micrometeorology and suggested by various authors, done by comparing the resulting sensible heat flux measured by the SLS method with the ones calculated through an iterative determination of the Monin-Obukhov parameters. A comparison of the structure function parameter of temperature (Ci ) corrected for fJ and those measured (using SLS) was carried out, with the results showing very good correspondence between the corrected and uncorrected ci values, indicating that not correcting for fJ for SLS measured ci does not result in significant error in the resulting ci values, and hence sensible heat flux estimates. A comparison of the sensible heat flux Fh obtained using EC and SLS methods for fJ < 0.6 and fJ > 0.6 followed and the results also show good correspondence between the values obtained using the EC and SLS methods, although the agreement is slightly improved for cases when fJ > 0.6. A sensitivity analysis indicates that both the ECand SLS-measurements of Fh are influenced by fJ values. A sensitivity analysis on the influence of fJ on Fh measurements by both the EC and SLS methods further indicates that the influence of fJ on Fh measurements is not large enough to warrant correcting Fh measurements for fJ . The F" measurements by the EC method appears to be influenced more by fJ especially for fJ values less than 0.74. A comparison of the various methods for computing the empirical similarity functions used by MOST was also carried out and the results show a significant difference in the Fh computed following the various methods suggested by different researchers. As for the agreement between the EC and SLS methods determination of Fh for the different atmospheric stability conditions, there seems to be a better agreement in the Fh measurements as noted by correlation coefficients closer to 1 and greater tvalues obtained during unstable atmospheric conditions in the colder months of June and August while reduced agreement in the values is recorded in the warmer summer period from November to December. Also noted is a slight difference in the EC measurements compared to the SLS measurement of F". The difference in the measurements is noticed for unstable atmospheric conditions. Also noted is that EC and SLS measurements of Fh differ slightly when the atmospheric condition is nearneutral. However the agreement between the Fh values measured by the two measurement methods is still good. was set up in an inclined position, with the receiver set at 0.68 m above the ground level and transmitter at 1.68 m, resulting in an effective height difference of 1.00 m. There was generally good agreement in the 2-min measurements of F" by the two methods for the SLS set up in inclined position, with the 30-min data resulting in even better agreements. The findings confirm that the SLS set up does not impair its performance in measuring sensible heat fluxes. This also shows that the SLS would also work well in non-ideal (heterogeneous) conditions which the inclined optical beam path mimics. For those days when wind direction was mainly approximately perpendicular to the beam, the F" values obtained by SLS and EC methods are more in agreement than when the wind direction was either irregular or parallel to the SLS beam path. Wind speed also seems to influence the F" estimates by the two methods since the agreement in the Fh values obtained by the two methods is greater when wind speed is higher compared to times of the day when the wind speed is reduced. The atmospheric stability influences the peak position of footprint with the peak footprint position being further from the measurement point when the atmospheric stability condition is closer to stable as denoted by the Obukhov length of -5 and closer to the measurement point for convectively unstable atmospheric conditions as shown by the Obukhov length of -30. Also shown is that a larger fetch is required when the atmosphere is convectively unstable as indicated by the contours plotted on top of the footprint plots. In general, there seems to be very good agreement in the sensible heat flux values obtained by the two methods, especially since SLS offers areal-averaged sensible heat flux measurements compared to the EC method which basically provides a point measurement. The SLS method therefore offers a better alternative for obtaining sensible heat flux from larger and heterogeneous area - although to a limit of250 m since beyond 250 m, the method suffers from a saturation problem. / Thesis (Ph.D.)-University of KwaZulu-Natal, Pietermaritzburg, 2007.

The demand for the world’s increasingly scarce water supply is rising rapidly, challenging its availability for agriculture and other environmental uses, especially in water scarce countries, such as South Africa, with mean annual rainfall is well below the world’s average. The implementation of effective and sustainable water resources management strategies is then imperative, to meet these increasingly growing demands for water. Accurate assessment of evaporation is therefore crucial in agriculture and water resources management. Evaporation may be estimated using different micrometeorological methods, such as eddy covariance (EC), Bowen ratio energy balance (BR), surface renewal (SR), flux variance (FV), and surface layer scintillometry (SLS) methods. Despite the availability of different methods for estimating evaporation, each method has advantages and disadvantages, in terms of accuracy, simplicity, spatial representation, robustness, fetch, and cost. Invoking the shortened surface energy balance equation for which advection and stored canopy heat fluxes are neglected, the measurement of net irradiance, soil heat flux, and sensible heat flux allows the latent energy flux and hence the total evaporation amount to be estimated. The SR method for estimating sensible heat, latent energy, and other scalars has the advantage over other micrometeorological methods since it requires only measurement of the scalar of interest at one point. The SR analysis for estimating sensible heat flux from canopies involves high frequency air temperature measurements (typically 2 to 10 Hz) using 25 to 75 ìm diameter fine-wire thermocouples. The SR method is based on the idea that parcel of air near a surface is renewed by an air parcel from above. The SR method uses the square, cube, and fifth order of two consecutive air temperature differences from different time lags to determine sensible heat flux. Currently, there are three SR analysis approaches: an ideal SR analysis model based on structure function analysis; an SR analysis model with finite micro-front period; and an empirical SR analysis model based on similarity theory. The SR method based on structure function analysis must be calibrated against another standard method, such as the eddy covariance method to determine a weighting factor á which accounts for unequal heating of air parcels below the air temperature sensor height. The SR analysis model based on the finite micro-front time and the empirical SR analysis model based on similarity theory need the additional measurement of wind speed to estimate friction velocity. The weighting factor á depends on measurement height, canopy structure, thermocouple size, and the structure function air temperature lag. For this study, á for various canopy surfaces is determined by plotting the SR sensible heat flux SR H against eddy covariance EC H estimates with a linear fit forced through the origin. This study presents the use of the SR method, previously untested in South Africa, to estimate sensible heat flux density over a variety of surfaces: grassland; Triffid weed (Chromolaena odorata); Outeniqua Yellow wood (Podocarpus Falcatus) forest; heterogeneous surface (Jatropha curcas); and open water surface. The sensible heat flux estimates from the SR method are compared with measurements of sensible heat flux obtained using eddy covariance, Bowen ratio, flux variance, and surface layer scintillometer methods, to investigate the accuracy of the estimates. For all methods used except the Bowen ratio method, evaporation is estimated as a residual using the shortened energy balance from the measured sensible heat and from the additional measurements of net irradiance and soil heat flux density. Sensible heat flux SR H estimated using the SR analysis method based on air temperature structure functions at a height of 0.5 m above a grass canopy with a time lag r = 0.5 s, and á =1 showed very good agreement with the eddy covariance EC H , surface layer scintillometer SLS H , and Bowen ratio BR H estimates. The half-hourly latent energy flux estimates obtained using the SR method SR ë E at 0.5 m above the grass canopy for a time lag r = 0.5 s also showed very good agreement with EC ë E and SLS ë E . The 20-minute averages of SR ë E compared well with Bowen ratio BR ë E estimates. Sensible heat and latent energy fluxes over an alien invasive plant, Triffid weed (C. odorata) were estimated using SR , EC , FV and SLS methods. The performance of the three SR analysis approaches were evaluated for unstable conditions using four time lags r = 0.1, 0.4, 0.5, and 1.0 s. The best results were obtained using the empirical SR method with regression slopes of 0.89 and root mean square error (RMSE) values less than 30 W m-2 at measurement height z = 2.85 and 3.60 m above the soil surface for time lag r = 1.0 s. Half-hourly SR H estimates using r = 1.0 s showed very good agreement with the FV and SLS estimates. The SR latent energy flux, estimated as a residual of the energy balance ë ESR , using time lag r = 1.0 s provided good estimates of EC ë E , FV ë E , and SLS ë E for z = 2.85 and 3.60 m. The performance of the three SR analysis approaches for estimating sensible heat flux above an Outeniqua Yellow wood stand, were evaluated for stable and unstable conditions. Under stable conditions, the SR analysis approach using the micro-front time produced more accurate estimates of SR H than the other two SR analysis approaches. For unstable conditions, the SR analysis approach based on structure functions, corrected for á using EC comparisons produced superior estimates of SR H . An average value of 0.60 is found for á for this study for measurements made in the roughness sublayer. The SR latent energy flux density estimates SR ë E using SR H based on structure function analysis gave very good estimates compared with eddy covariance ( EC ë E ) estimates, with slopes near 1.0 and RMSE values in the range of 30 W m-2. The SR ë E estimates computed using the SR analysis approach using the micro-front time also gave good estimates comparable to EC ë E . The SR and EC methods were used to estimate long-term sensible heat and latent energy flux over a fetch-limited heterogeneous surface (J. curcas). The results show that it is possible to estimate long-term sensible heat and latent energy fluxes using the SR and EC methods over J. curcas. Continuous measurements of canopy height and leaf area index measurements are needed to determine á . The weighting factor á was approximately 1 for placement heights between 0.2 and 0.6 m above the Jatropha tree canopy. The daily sensible heat and latent energy flux estimates using the SR analysis gave excellent estimates of daily EC sensible heat and latent energy fluxes. Measurements of sensible heat and estimates of the latent energy fluxes were made for a small reservoir, using the SR and EC methods. The SR sensible heat flux SR H estimates were evaluated using two air temperature time lags r = 0.4 and 0.8 s at 1.0, 1.3, 1.9, 2.5 m above the water surface. An average á value of 0.175 for time lag r = 0.4 s and 0.188 for r = 0.8 s was obtained. The SR H and EC H estimates were small (-40 to 40 W m-2). The heat stored in water was larger in magnitude (-200 to 200 W m-2) compared to the sensible heat flux. The SR and EC latent energy fluxes were almost the same in magnitude as the available energy, due to the small values of the sensible heat fluxes. The daily evaporation rate ranged between 2.0 and 3.5 mm during the measurement period. The SR method can be used for routine estimation of sensible heat and latent energy fluxes with a reliable accuracy, over a variety of surfaces: short canopies, tall canopies, heterogeneous surface, and open water surface, if the weighting factor á is determined. Alternatively, the SR method can be used to estimate sensible heat flux which is exempt from calibration using the other two SR analysis approaches, with additional measurement of wind speed for estimating friction velocity iteratively. The advantages of the SR method over other micrometeorological methods are the relatively low cost, easy installation and maintenance, relatively low cost for replicate measurements. These investigations may pave the way for the creation of evaporation stations from which real-time and sub-hourly estimates of total evaporation may be obtained relatively inexpensively. / Thesis (Ph.D.)-University of KwaZulu-Natal, Pietermaritzburg, 2008.

The focus of the research is on investigations of various methods for obtaining sensible heat flux (H) for estimating evaporation. The key for this approach is the application of the shortened energy balance equation, and in the case of methods based on the Monin-Obukhov similarity theory (MOST), such as surface-layer scintillometrv and temperature variance with adjusted for stability using air temperature skewness, and surface renewal (SR), die iterative procedures. The application of the shortened energy balance requires that errors associated with measurement of net irradiance (Rnet) and soil heat flux (S) are kept to a minimum To this end. methodology for the calibration of net radiometers for both the infrared and short wave irradiances receive attention. A field study attempts to quantify the error in soil heat flux measurement for a mesic grassland. A standard, convenient and accurate method for calibrating net radiometers would assist in unravelling reasons for the perplexing lack of surface energy balance closure when employing the eddy covariance (EC) flux estimation method as well as improve on the accuracy of the energy balance residual method for estimating evaporation. A relatively inexpensive, accurate and quick laboratory method, based on physical theory, for non-steady radiative conditions above a large water-heated or water-cooled radiator containing circulated water, with surface-embedded thermocouples is used to obtain reproducible net radiometer calibration factor's for the infrared waveband for a wide range in net irradiance. When applied, the method would reduce error m the most important term of the shortened energy balance and assist in energy balance closure aspects of EC measurements. The SLS method, reliant on MOST, is used for estimating a really-averaged H for a mesic grassland for a 30-month period. Comparisons with EC measurements feature prominently in this unique study. These comparisons include using different MOST procedures and the influence of the Bowen ratio on SLS measurement: of if is investigated. Furthermore, since there are reports in the literature that the EC method may underestimate H and or latent energy flux (LE), resulting in the shortened energy balance not being closed, effort is devoted to this aspect. Other methods used for comparison purposes are the traditional Bowen ratio energy balance (BREB), SR, TV and ETo (grass reference) methods. The TV and SLS and/or EC measurements of H are compared above three contrasting canopy surfaces. It is shown that other high frequency air temperature-based methods, for example, for the first time the TV method with adjustment for skewness, may pave the way for evaporation stations from which real-time and sub-hourly estimates may be obtained relatively inexpensively. Another area of research that receives attention is the placement height of EC instruments above short-canopy surfaces and a spectral analysis of the vertical wind speed and some temperature measurement: for close-canopv placement heights. The SR method is used to estimate, for the first time, open-water evaporation. The ideal SR method applied above canopies is the most inexpensive micrometeorological method for estimating H, but the SR weighting factor a needs to be determined using EC and for this reason, the TV method with adjustment for skewness was investigated. Finally, a unique implementation of SR uses an iterative method for calculating H. A similar iterative procedure is applied for MOST and ETo calculations. / Thesis (DScAgric)-University of KwaZulu-Natal, Pietermaritzburg, 2010.

<b>Structure of the thesis</b><p><p>The present work has been organized in two main parts: in the first one, the focus will be on the scientific and theoretical aspects of the evaporation process in presence of an inert gas flow while in the second all the technical aspects and more practical tests related to the real implementation of the micro-gravity experiment CIMEX-1 will be detailed. In any cases, the discussion will always start from the phenomenology observed considering that ” Nature is far more reach of any speculations.”<p><p><b>Part I: Evaporation in presence of inert gas</b> <p><p>In chapter 1, a detailed presentation of the experimental setups for the on-ground tests is given together with the presentation of the qualitative and quantitative results obtained. Actually, the main parameters that regulate such kind of experiments are the mass flow rate of inert gas, the total pressure of the cell and the geometrical shape and dimensions of the evaporating regions.<p>Consequently, the experiments aimed at covering the maximal possible combination of these three parameters with special attention to the variation of the inert gas flow and of the thickness of the evaporating liquid layer. More precisely, the liquid layer thickness was in the range 1.2 to 3.8 mm while the inert gas flow was set in the range 50 to 2500 ml/min. The pressure has been partially neglected as control parameter because its control was discovered not to be very reliable.<p>The visualization system used in all the experiments consisted in a opportunely calibrated infrared camera. It allowed for having a quantitative analysis of the temperature distribution at the interface of the evaporating liquid.<p>The infrared images also helped to follow the thermal history of the interface. In many cases, it has been possible to clearly observe the evolution of instability patterns at the interface that represent an original contribution to the understanding of such a kind of phenomena.<p>The physical and mathematical modeling of the observed phenomenology will be the subject of the chapter 2. One of the peculiar issue of the problem under consideration is that the thermal gradient normal to the interface is not directly imposed like in the usual Marangoni-Bénard experience, but is a result of the cooling of the interface due to the evaporation.<p>Moreover,the interface is subject to the shear stress of the inert gas flow and to the one due to the thermo-capillarity. Finally, the gas phase is to be considered as a mixture; this oblige to solve a diffusion problem in the gas phase. A physical model that takes into account the different aspects mentioned above is presented together with the governing equations and the appropriate boundary conditions.<p>Numerical issues involved in solving the model are also analyzed. Numerical results obtained are finally discussed and compared when possible with experimental results.<p><p><b>Part II: Preparation of the CIMEX-1 experiment on-board the International Space Station.</b><p><p>In chapter 3, we will describe the main platforms used to perform low-gravity experiments. They will be classified according to the low-gravity level and to the low-gravity interval duration that could be ensured for experiments. According to these criteria, the list of the low-gravity platforms will be as follows: Drop Towers with ≈ 4 sec. of micro-gravity, Parabolic Flights that can assure not more than ≈ 25 sec. Sounding Rockets with a low-gravity time of the order of several minutes depending on the rockets, Foton Capsules that assure for many days of high quality - i.e. without perturbations - low-gravity level and ,last but not least, the International Space Station where the low-gravity duration could be even of several weeks which is a sufficient time duration for the most part of the experiments.<p>The chapter 4 will be entirely devoted to the ITEL experiment that is the precursor and the core of the CIMEX-1. After a brief overview of the experiment that has been performed twice on-board sounding rockets of the MASER class, the experimental setups used both on-ground and in micro-gravity will be detailed.<p>The focus will be on the experimental results obtained on-ground during the preparatory tests and during the two sounding rocket flights with special attention to the first one. The analysis will be supported by the presentation of many results obtained in numerical simulations.<p>The two parabolic flight campaigns performed to test one of the key sub-systems of the CIMEX-1 setup are the subject of the chapter 5. The separating-condensing unit is mandatory for performing the experiment on-board the International Space Station because the limitations on the crew intervention oblige to have a closed loop experiment.<p>The goal of the two parabolic flights will be detailed together with the setup and the experimental scenario. The main results will be also shown and some considerations on the efficiency of the system will be presented.<p>It is worthy to stress that the results obtained during these parabolic flights have been determinant at the European Space Agency level to fly the CIMEX-1 experiment on-board the International Space Station.<p>Finally, in the section conclusions and perspectives the main results obtained will be summarized together with the new scenarios opened by the present work and some guidelines for further development in the experimental, theoretical and technical analysis. / Doctorat en sciences appliquées / info:eu-repo/semantics/nonPublished

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This thesis focuses on investigating the stability, dynamics and physical mechanisms of thermocapillary flows undergoing phase change by means of direct numerical simulations and experiments. The novelty of the general approach developed in this work lies in the fact that the problems under consideration are addressed with novel fully-coupled transient two-phase flow models in 3D. Traditional simplifications are avoided by accounting for deformable interfaces and by addressing advection-diffusion mechanisms not only in the liquid but also in the gas. This strategy enables a realistic investigation of the interface energy and mass transfer at a local scale for the first time. Thorough validations of the models against theory and experiments are presented. The thesis encompasses three situations in detail: liquid layers in saturated environments, liquid layers in unsaturated environments and evaporation of liquid droplets. Firstly, a model grounded in the volume-of-fluid method is developed to study the stability of laterally-heated liquid layers under saturated environments. In this configuration, the planar layer is naturally vulnerable to the formation of an oscillatory regime characterized by a myriad of thermal wave-like patterns propagating along the gas-liquid interface, i.e. hydrothermal waves. The nonlinear growth of the instabilities is discussed extensively along with the final bulk flow for both the liquid and gas phases. Previously unknown interface deformations, i.e. physical waves, induced by, and enslaved to, the hydrothermal waves are reported. The mechanism of heat transfer across the interface is found to contradict previous single-phase studies since the travelling nature of the hydrothermal waves leads to maximum heat fluxes not at the points of extreme temperatures but somewhere in between. The model for saturated environments is extended in a second stage to assess the effect of phase change in the hydrothermal waves for the first time. New numerical results reveal that evaporation affects the thermocapillary instabilities in two ways: the latent energy required during the process tends to inhibit the hydrothermal waves while the accompanying level reduction enhances the physical waves by minimizing the role of gravity. Interestingly, the hydrothermal-wave-induced convective patterns in the gas decouple the interface vapour concentration with that in the bulk of the gas leading to the formation of high (low) concentrations of vapour at a certain distance above interface cold (hot) spots. At the interface the behavior is the opposite. The phase-change mechanism for stable layers is also discussed. The Marangoni effect plays a major role in the vapour distribution and local evaporation flux and can lead to the inversion of phase-change process, i.e. the thermocapillary flow can result into local condensation in an otherwise evaporating liquid layer. The third problem discussed in this thesis concerns with the analysis of evaporating sessile droplets by means of both experiments and 3D numerical modeling. An experimental apparatus is designed to study the evaporation process of water droplets on superheated substrates in controlled nitrogen environments. The droplets are simultaneously recorded with a CCD camera from the side and with an infrared camera from top. It is found that the contact line initially remains pinned for at least 70% of the time, period after which its behaviour changes to that of the stick-slip mode and the drop dries undergoing contact line jumps. For lower temperatures an intermediate stage has been observed wherein the drop evaporates according to a combined mode. The experimental work is complemented with numerical simulations. A new model implementing the diffuse-interface method has been developed to solve the more complex problems of this configuration, especially those associated with the intricate contact-line dynamics. Further insights into the two-phase flow dynamics have been provided as well as into the initial transient stage, in which the Marangoni effect has been found to play a major role in the droplet heating. For the first time, a fully-coupled two-phase direct numerical simulations of sessile drops with a moving contact line has been performed. The last part of this work has been devoted to the investigation of three-dimensional phenomena on drops with irregular contact area. Non-sphericity leads to complex three-dimensional drop shapes with intricate contract angle distributions along the triple line. The evaporation rate is found to be affected by 3D features as well as the bulk flow, which become completely non-axisymmetric. To the best of our knowledge, this work is the first time that three-dimensional two-phase direct numerical simulations of evaporating sessile drops have been undertaken.

In the Canterbury region, New Zealand, water is a contentious issue when irrigation and dairy farming are involved. The Canterbury region accounts for 70% of the total irrigated land area in New Zealand and is one of the most productive agricultural regions. Traditionally, water has been seen as an abundant resource, but growing water demands are now outstripping the supply of water, hence threatening the sustainability of agricultural productivity. In the long term, this problem may worsen as a result of climate change, which is predicted to increase water demands and reduce supply in many parts of Canterbury. In the recent and on-going expansion of irrigation systems, modern sprinkler irrigation methods, namely centre pivot and lateral spray irrigation technology, have replaced the old border-dyke systems. This has been due to the need to increase irrigation flexibility and efficiency to guarantee pasture growth for dairy production in dry periods. This conversion has resulted in a reduction of windbreaks to 2 m heights or sometimes led to 100% removal of windbreaks so as to accommodate centre pivot or linear move irrigation systems. Removal of windbreaks or reduction of windbreak height may increase wind speed across a field. Both spray evaporation loss and evapotranspiration are a function of wind speed. Hence, any increase in wind speed may lead to an increase in irrigation requirements. There is little information currently available on outlining how reduction of windbreak height or the complete removal of windbreaks affects efficiency in water application. Thus, this research was done to quantify the effects of windbreaks on water savings under sprinkler irrigation systems in the Canterbury region under various climatic conditions. The research was done in three major steps: (1) spray evaporation loss (SEL)was measured under various climatic conditions for two typical spray nozzles(Nelson Irrigation Corporation Rotator R3000 and Spinner S3000 nozzles) to develop SEL prediction models; (2) wind speed reduction behind windbreaks was quantified for fields under various wind conditions; and (3) the effects of wind speed reduction by windbreaks was modelled for evapotranspiration, spray evaporation loss and irrigation. The results showed that an increase of wind speed, due to the removal of windbreaks or a reduction of height of windbreaks, leads to an increase in evapotranspiration and spray evaporation losses in irrigated agriculture. For the size of the fields considered in this study which are 80 m by 80 m (Site 1 with medium porosity windbreaks) and 120 m by 120 m (Site 2 with low porosity windbreaks), extra irrigation water of up to 14% is needed in one growing season when windbreaks are reduced to 2 m in height. When windbreaks are completely removed from the field, extra irrigation water of up to 38% and 64% is needed when irrigating using the Rotator R3000 nozzle and the Spinner S3000 nozzle, respectively. Thus, reduction of water resource use can be achieved in irrigated agriculture if irrigation systems can be designed to operate under existing windbreaks. Other savings can follow, from reduced requirements for pumping, fuel and labour costs. Lastly, with future climate change projections showing that the Canterbury region will get windier and hotter, windbreaks can help mitigate water losses associated with sprinkler irrigation

<p>Abstract to“Interfacial colloidal particle films andtheir structure formation”; a licentiate thesis, whichwill be presented by Sandra Rödner in Q2, 29 November 2002at 13.00.</p><p>Colloidal particles can be made to organise themselves intoordered arrays. These colloidal structures acquire interestingand useful properties, not only from their constituentmaterials but also from the spontaneous emergence of mesoscopicorder that characterises their internal structure. Orderedarrays of colloidal particles, with lattice constants rangingfrom a few nanometers to a few microns, have potentialapplications as optical computing elements and chemicalsensors, and also has an important influence on the mechanicalproperties and optical appearance of paint films and papercoatings.</p><p>The control of colloidal structure formation starts with theparticle interactions (attractive or repulsive) and colloidaldynamics, which is the topic of this thesis. To enable adetailed understanding of the different factors that controlthe formation of dense 2D colloidal films, a method forstructural characterisation was developed. The degree of orderin the hexagonal close-packed structure, displayed by thecolloidal films, was characterised by the size of ordereddomains and by the distribution of pore sizes. The size ofordered domains was obtained from the pair distributionfunction, and the distribution of pores from a Delaunaytriangulation procedure. These methods are based on theparticle positions in the film, which were determined by lightmicroscopy and processed digital images.</p><p>The two methods were used to study the effect of particleinteractions on the structure of colloidal monoparticulatefilms, formed at the air-liquid interface. The size of theordered domains decreased exponentially with increasing bondstrength, while the pore density increased. The transfer andsubsequent drying of the formed film on a solid substrateinduced structural changes; the capillary forces transformedsmall pores into triangular order while some of the largervoids and cracks increased in size.</p><p>The structural features of colloidal monolayers, formed bydrying a dilute silica suspension on a substrate, wereinvestigated. Addition of small amounts of salt resulted indrastic changes of the particle film structure. The size of theordered domains decreased exponentially with increasing amountsof added salt (0-2.9% NaCl/Silica ratio), with a simultaneousincrease of the concentration of large defects. This suggeststhat loss of colloidal stability and onset of particle adhesionto the substrate inhibit rearrangement and ordering. Theevaporation rate was controlled by varying the relativehumidity during drying. Colloidal monolayers with the largestordered domains and the lowest concentration of stacking faultswere formed at an intermediate humidity (55% RH).</p><p>The rearrangement process during drying of dilute silicasuspensions was followed in detail by studying the changes inthe structural features during growth of colloidal monolayers.Low crystal growth rate promoted the transition of squarelattice domains to a hexagonal close-packed structure. Additionof salt to the electrostatically stabilised dispersionincreased the formation of square structured regions at thecrystal-suspension interface, due to increasing adhesion to thesubstrate. The loss of colloidal stability inhibited therearrangement process, resulting in higher concentrations ofsquare lattice domains at large distances from the crystal edgecompared to systems without added salt.</p>

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Evaporation and wetting of droplets are a phenomena present in everyday life and in many industrial, biological or medical applications; thus controlling and understanding the underlying mechanisms governing this phenomena becomes of paramount importance. More recently, breakthroughs in the fabrication of new materials and nanomaterials have led to the synthesis of novel nanoscale particulates that dispersed into a base fluid modify the properties of this latter. Enhancement in heat transfer or the self-assembly of the particles in suspension during evaporation, are some of the areas in which nanofluids excel. Since it is a relatively new area of study, the interplay particle-particle, particle-fluid or particle-substrate at the macro-, micro-, and nanoscale is yet poorly understood. This work is an essay to elucidate the fundamental physics and mechanisms of these fluids during free evaporation, of great importance for the manipulation and precise control of the deposits. The evaporative behaviour of pure fluids on substrates varying in hydrophobicity has been studied and an unbalance Young’s force is proposed to explain the effect of substrate hydrophilicity on the pinning and the depinning forces involved during droplet evaporation. On other hand, the addition of nanoparticles to a base fluid modifies the evaporative behaviour of the latter and: a more marked “stick-slip” behaviour is observed when increasing concentration on hydrophobic substrates, besides the longer pinning of the contact line reported on hydrophilic ones when adding nanoparticles. A deposition theory to explain the final deposits observed, for the outermost ring, after the complete vanishing of a 0.1% TiO2-ethanol nanofluid droplet has also been developed. In addition, the evaporation of pinned nanofluid droplets on rough substrates at reduced pressures has been systematically studied. A revisited Young-Lippmann equation is proposed as one of the main findings to explain the enhancement on electrowetting performance of nanoparticle laden fluid droplets when compared to the pure fluid case. On the other hand, of relevant importance is the absence of “stick-slip” behaviour and the more homogeneous deposits found after the complete evaporation of a nanofluid droplet under an external electric field applied when compared to free evaporation of these fluids.