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The physics of oil and petroleum evaporation are investigated. Literature on oil spill evaporation shows that most workers use boundary-layer equations adapted from water evaporation work. These equations predict a constant evaporation mass-transfer rate, dependent on scale size and wind speed. Evaporation was studied further by measuring evaporation of commercial oil products. An experimental apparatus for the study of evaporation was developed. Evaporation was determined by weight loss measured on a balance and recorded constantly on a computer. Examination of the data shows that most oil and petroleum products evaporate at a logarithmic rate with respect to time. This is attributed to the overall logarithmic appearance of many components evaporating at different linear rates. Petroleum products with fewer chemical components such as diesel fuel, evaporate at a rate which is square root with respect to time. The particular behaviour is shown to be a result of the number of components evaporating. Oils with greater than seven to ten components can be predicted with logarithmic equations, those with three to seven components, with square root equations. Evaporation of oils and petroleum products is not strictly boundary-layer regulated. This is largely a result of the high saturation concentrations of oil components in air, which is associated with a high boundary-layer regulated rate. Typical oil evaporation rates do not exceed that of molecular-diffusion, and thus turbulent diffusion does not increase the evaporation rates. Some volatile oils and petroleum products show some effect of boundary-layer regulation at the start of the evaporation process, but after several minutes, evaporation slows because of the loss of the more volatile components, at which point evaporation ceases to be boundary-layer regulated. Overall, boundary-layer regulation can be ignored in the prediction of oil and petroleum evaporation. A simple equation relating only the logarithm of t

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Evapotransipration by vegetation cover is an important component of the water budget and energy balance in any ecosystem. A key to more improved water management therefore lies in improving our understanding of evapotranspiration, the process that drives water use by plants. Estimations of the turbulent fluxes are required for various applications in micrometeorology, hydrology, environmental studies and agriculture. Numerous methods for estimation of turbulent fluxes have been developed and tested. Direct measurements of fluxes are usually achieved by the eddy covariance (EC) method, which is considered as the most reliable. However, the application of the EC method is often problematic. The necessary sensors for wind, temperature and humidity must respond very fast (resolution of 10 Hz or better) and at the same time must not show noticeable drift. This makes them delicate, expensive and difficult to calibrate among other problems associated with the method. Due to their ability to integrate atmospheric processes along a path length that may range between a few hundred metres to a few kilometres, optical methods based on the analysis of scintillation appear to be an alternative and possible supplement to classical micrometeorological methods such as the EC method, which may provide local fluxes typically at the scale of 100 m. The use of the scintillometry technique in surface flux measurements is therefore gaining in popularity. The accuracy of the measurements obtained by one method is judged by comparison of the measurements obtained by those of another method considered as the standard. For turbulent flux measurements, the EC method is taken as the standard method for the determination of sensible heat fluxes. This research presents the measurement of sensible heat fluxes using the surface layer scintillometer (SLS). The SLS system used has a dual-beam and a recommended path length of between 50 and 250 m. The method was tested against the EC method for different Bowen ratio (f3) values, as required by the theory, under different atmospheric stability conditions, as well as for different wind directions relative to the SLS beam path and slanting beam path orientation. Also presented is an analysis of the different forms of the Monin-Obukhov Similarity (MOST) functions used in micrometeorology and suggested by various authors, done by comparing the resulting sensible heat flux measured by the SLS method with the ones calculated through an iterative determination of the Monin-Obukhov parameters. A comparison of the structure function parameter of temperature (Ci ) corrected for fJ and those measured (using SLS) was carried out, with the results showing very good correspondence between the corrected and uncorrected ci values, indicating that not correcting for fJ for SLS measured ci does not result in significant error in the resulting ci values, and hence sensible heat flux estimates. A comparison of the sensible heat flux Fh obtained using EC and SLS methods for fJ < 0.6 and fJ > 0.6 followed and the results also show good correspondence between the values obtained using the EC and SLS methods, although the agreement is slightly improved for cases when fJ > 0.6. A sensitivity analysis indicates that both the ECand SLS-measurements of Fh are influenced by fJ values. A sensitivity analysis on the influence of fJ on Fh measurements by both the EC and SLS methods further indicates that the influence of fJ on Fh measurements is not large enough to warrant correcting Fh measurements for fJ . The F" measurements by the EC method appears to be influenced more by fJ especially for fJ values less than 0.74. A comparison of the various methods for computing the empirical similarity functions used by MOST was also carried out and the results show a significant difference in the Fh computed following the various methods suggested by different researchers. As for the agreement between the EC and SLS methods determination of Fh for the different atmospheric stability conditions, there seems to be a better agreement in the Fh measurements as noted by correlation coefficients closer to 1 and greater tvalues obtained during unstable atmospheric conditions in the colder months of June and August while reduced agreement in the values is recorded in the warmer summer period from November to December. Also noted is a slight difference in the EC measurements compared to the SLS measurement of F". The difference in the measurements is noticed for unstable atmospheric conditions. Also noted is that EC and SLS measurements of Fh differ slightly when the atmospheric condition is nearneutral. However the agreement between the Fh values measured by the two measurement methods is still good. was set up in an inclined position, with the receiver set at 0.68 m above the ground level and transmitter at 1.68 m, resulting in an effective height difference of 1.00 m. There was generally good agreement in the 2-min measurements of F" by the two methods for the SLS set up in inclined position, with the 30-min data resulting in even better agreements. The findings confirm that the SLS set up does not impair its performance in measuring sensible heat fluxes. This also shows that the SLS would also work well in non-ideal (heterogeneous) conditions which the inclined optical beam path mimics. For those days when wind direction was mainly approximately perpendicular to the beam, the F" values obtained by SLS and EC methods are more in agreement than when the wind direction was either irregular or parallel to the SLS beam path. Wind speed also seems to influence the F" estimates by the two methods since the agreement in the Fh values obtained by the two methods is greater when wind speed is higher compared to times of the day when the wind speed is reduced. The atmospheric stability influences the peak position of footprint with the peak footprint position being further from the measurement point when the atmospheric stability condition is closer to stable as denoted by the Obukhov length of -5 and closer to the measurement point for convectively unstable atmospheric conditions as shown by the Obukhov length of -30. Also shown is that a larger fetch is required when the atmosphere is convectively unstable as indicated by the contours plotted on top of the footprint plots. In general, there seems to be very good agreement in the sensible heat flux values obtained by the two methods, especially since SLS offers areal-averaged sensible heat flux measurements compared to the EC method which basically provides a point measurement. The SLS method therefore offers a better alternative for obtaining sensible heat flux from larger and heterogeneous area - although to a limit of250 m since beyond 250 m, the method suffers from a saturation problem. / Thesis (Ph.D.)-University of KwaZulu-Natal, Pietermaritzburg, 2007.