31 |
Isothermal and non-isothermal comparative study of Zn-sn system using real-time RBSMnguni, Mmangaliso Mpilonde January 2021 (has links)
>Magister Scientiae - MSc / Solid-state reactions of bi-metallic systems can be driven or activated by various external
stimuli like pressure, energetic photons, energetic charged particles or heat. For an example,
high pressure torsion can be applied to aluminium-copper (Al-Cu) to drive solid-state reaction
[1.1]. Oh-ishi et al. [1.1] applied a pressure of 6 GPa to Al and Cu half discs. Following this,
x-ray diffraction (XRD) and high-resolution transmission electron microscope (HRTEM) were
used to confirm the formation of different intermetallic phases such as Al2Cu and Al4Cu9.
One of the first reported case where photons were used to drive solid phase diffusion was
reported in 1998 by Ditchfield et al. [1.2]. The study was carried out to study the non-thermal
effects of photons illumination on surface diffusion, an important process in microelectronics
fabrication. Surface diffusion governs several important steps in microelectronics fabrication
including the formation of hemispherical grained silicon used in memory devices [1.2], filling
of channels with metals for devices interconnection purposes among others [1.2]. In this study,
germanium-indium (Ge-In) on silicon was used because the thermal diffusion of this system
was well understood [1.3]. Surface diffusion was measured in ultrahigh vacuum via second
harmonic microscopy when the sample was illuminated with pulsed Nd: YAG laser at a
wavelength of 1064 nm [1.3]. This study showed conclusively that photons could be used to
drive solid-state reactions.
|
32 |
Femtosecond Laser Ablation of Selected Dielectrics and MetalsLiu, Qiang 09 1900 (has links)
Ti: sapphire femtosecond laser ablation of dielectrics (fused silica and BK7 glass) and metals (Cu, Fe, Al) is presented. Results of laser -induced breakdown experiments in fused silica and BK7 glass employing 130 fs -1.7 ps, 790 nm laser pulses are reported. The fluence ablation threshold does not follow the scaling of ~ when pulses are shorter than 1 ps. Single-shot and multi-shot (130 fs pulse) ablation of selected materials are investigated with laser wavelengths of 395 nm, 790 nm, and 1300 nm. The ablation threshold is almost independent of the laser wavelength. The surface morphologies in metals after ultrashort pulse ablation are very different from dielectrics and semiconductors. The roughness of the ablated surface depends on the thermal properties of the metal target. The preliminary TEM result from Cu single crystal that was irradiated by single laser pulses shows few defects in the center region of the ablated crater. Single-shot ablation of single-crystal Fe induces much different surface features than on selected samples of poly-crystal Fe metal. / Thesis / Master of Engineering (ME)
|
33 |
Mid-infrared Strong-field Laser Interactions with Nanoclusters and SemiconductorsWang, Zhou 25 May 2018 (has links)
No description available.
|
34 |
Laser-Induced Damage with Femtosecond PulsesKafka, Kyle R P 18 May 2017 (has links)
No description available.
|
35 |
Femtosecond laser material processing for micro-/nano-scale fabrication and biomedical applicationsChoi, Hae Woon 30 July 2007 (has links)
No description available.
|
36 |
Ultrafast Protein Hydration Dynamics Investigated by Femtosecond Fluorescence SpectroscopyQiu, Weihong 07 October 2008 (has links)
No description available.
|
37 |
Controlling Light-Matter Interactions and Spatio-Temporal Properties of Ultrashort Laser PulsesCoughlan, Matthew Anthony January 2012 (has links)
The SPECIFIC method a fast and accurate method for generating shaped femtosecond laser pulses. The femtosecond pulses are user specified from pulse parameters in the temporal domain. The measured spectral and recovered temporal phase and amplitudes from SEA TADPOLE are compared with the theoretical pulse profile from the user specified input. The SPECIFIC method has been shown to be a technique that can generate a diverse array of spectral/temporal phase and amplitude as well as polarization pulse shapes for numerous scientific applications. The spatio -temporal -spectral properties of focusing femtosecond laser pulses are studied for several pulse shapes that are important for non-linear spectroscopic studies. We have shown with scanning SEA TADPOLE that the spatio-spectral phase of focusing double pulse profile changes across the laterally across the beam profile. The spectral features of the sinusoidal spectral phase shaped pulse has been shown to tilt at with a changing angle away from the focus of the lens. Using spatio-spectral coupling, we have shown that multiple spatio-temporal foci can be generated along and perpendicular to the focusing direction of a femtosecond laser pulse. The spatial position of the spatio-temporal foci is controlled optically. Using sinusoidal spectral phase modulated pulse trains fragment ion production from Benzonitrile parent molecule can be controlled. A spectral transmission window perturbed the temporal pulse amplitudes resulting in fragment ion production dependant on spectral window position. The spectral window ion production was shown to also be dependant on temporal phase sequence. / Chemistry
|
38 |
SPATIAL CHARACTERIZATION OF LASER FILAMENTS BY DETECTION OF SIGNATURES OF IONIZATIONFisher, Reginald January 2018 (has links)
Laser filamentation is a phenomenon currently being widely studied in which an ultrashort laser pulse self focuses as a result of the nonliner Kerr effect. Lim- ited data is available in terms of spatial characterization of the filament. We study the spatial distribution of molecular and atomic species generated by the filament in order to infer the relevant dynamics. We find evidence for a new impulsive vibrational excitation scheme which we introduce in this dissertation. Insight into the mechanisms of ionization is gained by consideration of the details of this process. In addition, the suitability of filaments to stimulate impulsive Raman scattering for spectroscopic purposes is evaluated. The data presented show the first measurements of ions by impulsive Raman spectroscopy. This method has advantages over previous techniques. Signal is directional and so it can be more completely collected and can be measured stand off. The energy required for detection is also provided by a probe beam rather than from the analyte molecules themselves and so there is no limit to its intensity as in the case of fluorescence spectroscopy. / Physics
|
39 |
Characterization of Femtosecond Laser Machining on Dielectric MaterialsBudiman, Mariana 08 1900 (has links)
This thesis presents the investigations of femtosecond laser machining on
three different dielectric materials, namely quartz, sapphire and diamond. The
laser micromachining experiments were performed with a Titanium:Sapphire
solid state laser with a repetition rate of 1 kHz, centered at a wavelength of
800 nm and pulse duration of 150-200 femtoseconds (fs). A 5x microscope
objective for surface micromachining and a 50x microscope objective for subsurface micromachining. The 50x microscope objective was used to obtain a smaller spot size and a shorter confocal parameter. The purpose of this research was to study the interaction between the femtosecond laser pulses and quartz, sapphire and diamond which have bandgap energies of 8.4 eV (λ=148 nm), 9.9 eV (125 nm), and c)· diamond 5.5 eV (225 nm) respectively. Since the photon energy of the laser was below the wide bandgap energies of the aforementioned dielectrics, the materials were essentially transparent to the incident laser. In order to study the behavior of the dielectric materials under femtosecond laser irradiation, several experiments with varying type and number of pulses (N) were performed, such as single pulse ablation, plural pulse ablation (N ≤ 100 pulses), multiple pulse ablation (N ≤ 100 pulses), and continuous lines micromachining on the surface and in the sub-surface of materials were performed. The features, damage, and structural changes introduced by femtosecond laser irradiation on the materials studied were characterized through examination of both the plan and cross-section views. The characterization process was carried out using optical microscopy (operated in the Nomarski mode), scanning electron microscopy, focused ion beam, atomic force microscopy, and transmission electron microscopy. The laser micromachining demonstrated distinct behaviors of the three wide bandgap materials. Quartz was very prone to cracking and showed nearwavelength alternating crystalline and amorphous sub-structure with the orientation parallel with respect to the electric field direction. Sapphire showed sub-wavelength ripples formation in lower fluences. Finally, diamond showed a strong tendency for ripples formation from near- to sub-wavelength spacing with the orientation of the ripples perpendicular and parallel with respect to electric field polarization. / Thesis / Master of Applied Science (MASc)
|
40 |
Computer-Assisted Material Processing Using a Femtosecond LaserMarthinsson, Gustav, Thorén, Karl January 2024 (has links)
In recent decades, advancements in laser technology has made the creation of femtosecond lasers possible. This is a special type of laser where the laser beam consists of repeated high energy light bursts just a few hundred femtoseconds long as opposed to of the continuous laser beams found in every common laser pointer. The short pulse duration paired with the high energy in each burst results in a significant peak power, making the laser capable of processing materials in a way that a regular laser cannot. However, the large size and weight of the machines capable of producing femtosecond laser beams often require them to remain stationary. To utilize the laser beam for processing, precise redirection is necessary. In this report, we describe our process of converting a regular CNC machine into a laser processing station and present our findings from writing on glass, metal foil and KTP crystals. The machine is capable of following CAD instructions with micrometer precision to alter, inscribe and cut a range of materials. Processing was conducted with green ($\lambda$=514 nm) as well as infrared laser ($\lambda$=1028 nm), yielding better results for the latter. The finished laser setup could be used to repeatedly and reliably process all materials, with promising results on KTP when combined with chemical etching.
|
Page generated in 0.0147 seconds